CN103407215A - Electrostatic flocking fabric made of alginate fiber and preparation method of electrostatic flocking fabric - Google Patents
Electrostatic flocking fabric made of alginate fiber and preparation method of electrostatic flocking fabric Download PDFInfo
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Abstract
The invention discloses electrostatic flocking fabric made of alginate fiber. The electrostatic flocking fabric comprises a flock layer, an adhesive layer and a base cloth layer, and is characterized in that the flock layer is the alginate fiber; the base cloth layer is aramid plain woven cloth; the middle adhesive layer is an organic silicon modified epoxy resin adhesive. The invention also discloses a preparation method of the electrostatic flocking fabric made of the alginate fiber. The preparation method is characterized by comprising the following steps of cutting alginate fiber strands into alginate fiber flock, and performing electric conduction and coloring treatment; pre-coating and mainly coating adhesives on flocking base cloth, wherein the total thickness of the adhesives is 0.2 to 0.25mm; performing flocking in an electrostatic flocking room to obtain flocked cloth; and performing baking to firmly composite the flock with the base cloth so as to obtain the electrostatic flocking fabric. The electrostatic flocking fabric has good flame resistance and is applicable to army combat uniforms, warship and submarine combat uniforms, bedding equipment, airman training combat uniforms, second artillery training combat uniforms and the like.
Description
Technical field
The present invention relates to a kind of electrostatic flocking fabric and manufacture method thereof, particularly relate to the military alginate fibre electrostatic flocking fabric of a kind of special type and manufacture method thereof.。
Background technology
Flocked fiber used is mostly fibers material at present, and the use natural fiber is less as flocked material, and environmental-protecting performance is poor, easily in manufacturing process and later stage use procedure, produces environmental pollution.Alginate fibre has far infrared, anion, antibiotic, deodorization, fire-retardant excellent specific property, and has an excellent high-hydroscopicity, easily removal property, plastic is obstructive, biocompatibility, degradable absorbability and environmental-protecting performance, it is the most excellent in recent years tencel, for extraordinary military natural fire-retardant, radiation proof, far infrared, to do extraordinary military excellent selection, therefore need the military alginate fibre electrostatic flocking fabric of a kind of special type of exploitation, can be applicable to the fight of army clothes, warship Submarine Combat clothes and bed necessaries equipment, the air arm instructs fighting uniform, Second Artillery Force makes instruction fighting uniform etc.
Summary of the invention
The extraordinary military alginate fibre electrostatic flocking fabric of flame retardant type that the purpose of this invention is to provide a kind of natural environmental-protective with and preparation method thereof.
In order to address the above problem, the technical solution used in the present invention is:
A kind of alginate fibre electrostatic flocking fabric, comprise tapetum, adhesive phase and bottom cloth layer, and described tapetum is alginate fibre, and base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, and intermediary adhesive layer is modifying epoxy resin by organosilicon glue.
Described tapetum is one or more the blend fibre in alginate fibre and viscose glue, cotton, chemical fibre.
Described base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, base fabric fabric density 108 * 58, and fineness of yarn is 16tex.
The technical indicator of alginate fibre electrostatic flocking fabric: fire resistance reaches A level requirement in GB 8965 flame-resistant garment-fire-retardant protection; Environmental-protecting performance reaches I class and II class index request in HJ/T 307-2006; Critical radiant flux: NEPA 253; The electrostatic propensity test: AATCC 134; Antistatic property: ISO6356.
The manufacture method of above-mentioned a kind of alginate fibre electrostatic flocking fabric, is characterized in that comprising the steps:
A, by the alginate fibre tow through cutting, making length is the 1.0-1.2 millimeter, fineness is the alginate fibre fine hair at 1.5 dawn, rear fine hair is carried out to conductive processing, and carries out as required painted processing, then fine hair is dry, screening;
B, by the base fabric aramid fiber plain weaving machine coating adhesive of weaving cotton cloth, adhesive divides two-layer, main painting is carried out in first precoating again after preliminary drying, the adhesive gross thickness is the 0.2-0.25 millimeter;
C, indoor at electrostatic spinning, adopt the flocking of high-voltage alternating generation of static electricity electric field, in the high-voltage alternating electrostatic field, makes fine hair under the effect of electric field force and the neat base fabric surface that scribbles adhesive of implanting;
D, the base fabric that step c is made, at following fan parameter, utilize pressure-air at matte, to carry out the air cotton ginning by the cylinder decorative pattern that covers on the air knife periphery, fan pressure 42-44Pa, cylinder rotating speed 12-14rpm, rotation speed of fan 35-38rpm, in the situation that speed of a motor vehicle 10m/min carries out, become the electrostatic flocking fabric with special air cotton ginning decorative pattern;
E, by the fabric that step c or steps d make, utilize the anti-processing method of foaming type three to carry out three anti-processing.
Below to further improvement in the technical proposal:
In step a, the fine hair moisture control, at 8%-10%, is controlled at 3.6 * 10 than resistance
8-3.6 * 10
9Ω ㎝.
Step c mesohigh electrode network is for exchanging static, and electrostatic high-pressure is controlled to be 20-22kv, and the distance scribbled on high voltage electrode net and base fabric between the one side of adhesive is 15-20 centimetre.
In step b, adhesive is modifying epoxy resin by organosilicon glue, and the preliminary drying temperature is 80-90 ℃ of rising successively, and the preliminary drying time is 1-1.5min; Main baking temperature is 110-140 ℃ of rising successively, and the main baking time is 3-4min.
In step e, utilize foaming machine by the three-proof finishing agent processing of foaming, blowing agent is the fluorocarbon polymer finishing agent, by the mode of blade coating, be coated onto the fabric surface, then carry out drying and processing, the equipment speed of service is 10m/min, bake out temperature is 130-150 ℃ of rising successively, and drying time is 4-5 minute.
The invention has the beneficial effects as follows: because the alginate fibre price is higher, utilizing electrostatic flocking technology to make the alginate fibre electrostatic flocking fabric is distributed in alginate fibre on the fabric significant surface, not only give full play to the unique but also good quality heterosis of alginate fibre, and compare and can effectively reduce the alginate fibre cost with the alginate fiber fabric of same grammes per square metre.
The combination of alginate fibre, modifying epoxy resin by organosilicon glue and aramid fiber base fabric, making fabric have the characteristics such as outstanding fire-retardant, environmental protection, natural antibacterial, far infrared, radiation proof, high strength, acid and alkali-resistance, life cycle be long, is the excellent textile of extraordinary function.That alginate fibre has is fire-retardant, the excellent specific property of far infrared, anion, antibiotic, deodorization, and have excellent high-hydroscopicity, easily obstructive, the biocompatibility of the property removed, plastic, degradable absorbability and environmental-protecting performance, be the most excellent in recent years tencel; The premium properties such as aramid fiber has superhigh intensity, high-modulus and high temperature resistant, acid-fast alkali-proof, lightweight, insulation, anti-aging, life cycle is long; Modifying epoxy resin by organosilicon glue has good resistance to elevated temperatures, and the flocked fabric that uses this adhesive to make is formaldehydeless, good flame resistance, environmental protection, and fastness is high, and the fabric wearability is good.Therefore this alginate fibre electrostatic flocking fabric is applicable to fight of army clothes, warship Submarine Combat clothes and bed necessaries equipment, the air arm instructs fighting uniform, Second Artillery Force's work instruction fighting uniform etc., and DEVELOPMENT PROSPECT is wide, and economic benefit and social benefit are good.
The specific embodiment:
Embodiment 1
A kind of alginate fibre electrostatic flocking fabric, comprise tapetum, adhesive phase and bottom cloth layer, and described tapetum is alginate fibre, and base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, and intermediary adhesive layer is modifying epoxy resin by organosilicon glue.Wherein:
Described tapetum is one or more the blend fibre in alginate fibre and viscose glue, cotton, chemical fibre.
Described base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, base fabric fabric density 108 * 58, and fineness of yarn is 16tex.
The fire resistance of described alginate fibre electrostatic flocking fabric reaches A level requirement in GB 8965 flame-resistant garment-fire-retardant protection.
The manufacture method of above-mentioned alginate fibre electrostatic flocking fabric, comprise the steps:
A, by the alginate fibre tow through the cutting, making length is 1.0 millimeters, fineness is the alginate fibre fine hair at 1.5 dawn, after fine hair is carried out to conductive processing and painted processing, then fine hair is dry, screening, control the fine hair moisture content 8%, is controlled at 3.6 * 10 than resistance
8Ω ㎝.
B, by base fabric with the first precoating layer adhesive of blade coating mode, blade surface is close to the base fabric surface, then preliminary drying, temperature 80-90 ℃ raises successively, and drying time is 1min, through the not only surfacing of the pre-baked base fabric of precoating, seamless, be beneficial to the attractive in appearance of final flocked fabric cloth cover, and more be conducive to the combination between adhesive and base fabric after the precoating preliminary drying, make the adhesives fastness higher; After main painting layer of adhesive again, main baking temperature is 110-140 ℃ and raises successively, the main baking time is 3min, the adhesive gross thickness is 0.2 millimeter.
C, indoor at electrostatic spinning, adopt the flocking of high-voltage alternating generation of static electricity electric field, in the high-voltage alternating electrostatic field, makes fine hair under the effect of electric field force and the neat base fabric surface that scribbles adhesive of implanting.High voltage electrode net is for exchanging static, and electrostatic high-pressure is controlled to be 20kv, on high voltage electrode net and base fabric, scribble between the one side of adhesive apart from being 15 centimetres.
D, the flocked fabric that step c is made, through baking, make fine hair and base fabric firmly compound.
The processing of foaming of e, the flocked fabric that utilizes foaming machine that three-proof finishing agent is made steps d, blowing agent is the fluorocarbon polymer finishing agent that the Shandong damp new material of neck Co., Ltd produces, by the mode of blade coating, be coated onto the fabric surface, then carry out drying and processing, the equipment speed of service is 10m/min, bake out temperature is 130-150 ℃ of rising successively, and drying time is 4 minutes, becomes the static flocking cloth without decorative pattern.
Embodiment 2:
A kind of alginate fibre electrostatic flocking fabric, comprise tapetum, adhesive phase and bottom cloth layer, and described tapetum is alginate fibre, and base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, and intermediary adhesive layer is modifying epoxy resin by organosilicon glue.Wherein:
Described tapetum is one or more the blend fibre in alginate fibre and viscose glue, cotton, chemical fibre.
Described base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, base fabric fabric density 108 * 58, and fineness of yarn is 16tex.
The fire resistance of described alginate fibre electrostatic flocking fabric reaches A level requirement in GB 8965 flame-resistant garment-fire-retardant protection.
The manufacture method of above-mentioned alginate fibre electrostatic flocking fabric, comprise the steps:
A, by the alginate fibre tow through the cutting, making length is 1.2 millimeters, fineness is the alginate fibre fine hair at 1.5 dawn, after fine hair is carried out to conductive processing and painted processing, then fine hair is dry, screening, control the fine hair moisture content 10%, is controlled at 3.6 * 10 than resistance
9Ω ㎝.
B, flocking base fabric adopt the aramid fiber plain weaving machine to weave cotton cloth, the modifying epoxy resin by organosilicon glue that adhesive adopts the Shandong damp new material of neck Co., Ltd to produce, modifying epoxy resin by organosilicon glue has good resistance to elevated temperatures, the flocked fabric that uses this adhesive to make is formaldehydeless, good flame resistance, environmental protection, and fastness is high, the fabric wearability is good.
By the base fabric first precoating layer adhesive of blade coating mode, blade surface is close to the base fabric surface, then preliminary drying, temperature 80-90 ℃ raises successively, and drying time is 1.5min, through the not only surfacing of the pre-baked base fabric of precoating, seamless, be beneficial to the attractive in appearance of final flocked fabric cloth cover, and more be conducive to the combination between adhesive and base fabric after the precoating preliminary drying, make the adhesives fastness higher; After main painting layer of adhesive again, main baking temperature is 110-140 ℃ and raises successively, the main baking time is 4min, the adhesive gross thickness is 0.25 millimeter;
C, indoor at electrostatic spinning, adopt the flocking of high-voltage alternating generation of static electricity electric field, in the high-voltage alternating electrostatic field, makes fine hair under the effect of electric field force and the neat base fabric surface that scribbles adhesive of implanting.High voltage electrode net is for exchanging static, and electrostatic high-pressure is controlled to be 22kv, on high voltage electrode net and base fabric, scribble between the one side of adhesive apart from being 20 centimetres.
D, the flocked fabric that step c is made, through baking, make fine hair and base fabric firmly compound.
The processing of foaming of e, the flocked fabric that utilizes foaming machine that three-proof finishing agent is made steps d, blowing agent is the fluorocarbon polymer finishing agent that the Shandong damp new material of neck Co., Ltd produces, by the mode of blade coating, be coated onto the fabric surface, then carry out drying and processing, the equipment speed of service is 10m/min, bake out temperature is 130-150 ℃ of rising successively, and drying time is 5 minutes, becomes the static flocking cloth without decorative pattern.
Embodiment 3:
A kind of alginate fibre electrostatic flocking fabric, comprise tapetum, adhesive phase and bottom cloth layer, and described tapetum is alginate fibre, and base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, and intermediary adhesive layer is modifying epoxy resin by organosilicon glue.Wherein:
Described tapetum is one or more the blend fibre in alginate fibre and viscose glue, cotton, chemical fibre.
Described base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, base fabric fabric density 108 * 58, and fineness of yarn is 16tex.
The fire resistance of described alginate fibre electrostatic flocking fabric reaches A level requirement in GB 8965 flame-resistant garment-fire-retardant protection.
The manufacture method of above-mentioned alginate fibre electrostatic flocking fabric, comprise the steps:
A, by the alginate fibre tow through cutting, making length is 1.0 millimeters, fineness is the alginate fibre fine hair at 1.5 dawn, rear fine hair is carried out to conductive processing and painted processing, then fine hair is dry, screening.Control the fine hair moisture content 8%, be controlled at 3.6 * 10 than resistance
8Ω ㎝.
B, by base fabric with the first precoating layer adhesive of blade coating mode, blade surface is close to the base fabric surface, then preliminary drying, temperature 80-90 ℃ raises successively, and drying time is 1min, through the not only surfacing of the pre-baked base fabric of precoating, seamless, be beneficial to the attractive in appearance of final flocked fabric cloth cover, and more be conducive to the combination between adhesive and base fabric after the precoating preliminary drying, make the adhesives fastness higher; After main painting layer of adhesive again, main baking temperature is 110-140 ℃ and raises successively, the main baking time is 3min, the adhesive gross thickness is 0.2 millimeter.
C, indoor at electrostatic spinning, adopt the flocking of high-voltage alternating generation of static electricity electric field, in the high-voltage alternating electrostatic field, makes fine hair under the effect of electric field force and the neat base fabric surface that scribbles adhesive of implanting.High voltage electrode net is for exchanging static, and electrostatic high-pressure is controlled to be 20kv, on high voltage electrode net and base fabric, scribble between the one side of adhesive apart from being 15 centimetres.
D, the flocked fabric that step c is made, at following fan parameter, utilize pressure-air at matte, to carry out the air cotton ginning by the cylinder decorative pattern that covers on the air knife periphery, fan pressure 42-44Pa, cylinder rotating speed 12-14rpm, rotation speed of fan 35-38rpm, in the situation that speed of a motor vehicle 10m/min carries out, become the electrostatic flocking fabric with special air cotton ginning decorative pattern.
The processing of foaming of e, the flocked fabric that utilizes foaming machine that three-proof finishing agent is made steps d, blowing agent is the fluorocarbon polymer finishing agent that the Shandong damp new material of neck Co., Ltd produces, by the mode of blade coating, be coated onto the fabric surface, then carry out drying and processing, the equipment speed of service is 10m/min, bake out temperature is 130-150 ℃ of rising successively, and drying time is 4-5 minute, makes the electrostatic flocking fabric with special air cotton ginning decorative pattern.
Get respectively the alginate fibre electrostatic flocking fabric that embodiment 1,2,3 makes and test, technical indicator is as follows:
Flame-retarding characteristic: reach A level requirement in GB 8965 flame-resistant garment-fire-retardant protection
Environmental protection test: reach I class and II class index request in HJ/T 307-2006
4 grades of color fastness to light: AATCC
Fastness to rubbing: AATCC 165 dry grinding 4-5 levels; Wet-milling 4-5 level
Flocking fastness: GB/21196.1 >=75000
Change in size and appearance after laundering: get three samples with advancing test, press GB/8628, GB/T8629, the execution of GB/T8630 standard, select the 5A program, the 2Kg that always feeds, drying means F, baking temperature are no more than 40 ℃, average.Rank reaches Pyatyi.
Critical radiant flux: NEPA 253
The electrostatic propensity test: AATCC 134
Antistatic property: ISO6356
Antibiotic property: AATCC 100
By above technical indicator, can be found out, its key technical indexes of alginate fibre electrostatic flocking fabric made reaches I class and II class index request in the environmental protection industry standard HJ/T 307-2006 of the People's Republic of China (PRC), and flame-retarding characteristic reaches GB 8965 flame-resistant garment
-A level requirement in fire-retardant protection, can be used as extraordinary military electrostatic spinning product, instructs fighting uniform, Second Artillery Force's work instruction fighting uniform etc. for fight of army clothes, warship Submarine Combat clothes and bed necessaries equipment, air arm.
The present invention is not limited to above-mentioned embodiment; every pure alginate fibre or blending alginate fibre; as alginate fibre and viscose glue, alginate fibre and cotton, alginate fibre and chemical fibre etc., the aspects such as electric treatment, the selection of fine hair pigment, the selection of base fabric material, adhesive allotment, electric-field intensity control are adjusted accordingly as long as at fine hair and within the electrostatic spinning product that makes all falls into protection scope of the present invention.
Claims (9)
1. an alginate fibre electrostatic flocking fabric, comprise tapetum, adhesive phase and bottom cloth layer, it is characterized in that: described tapetum is alginate fibre, and base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, and intermediary adhesive layer is modifying epoxy resin by organosilicon glue.
2. a kind of alginate fibre electrostatic flocking fabric according to claim 1 is characterized in that: described tapetum is one or more the blend fibre in alginate fibre and viscose glue, cotton, chemical fibre.
3. a kind of alginate fibre electrostatic flocking fabric according to claim 1, it is characterized in that: described base fabric is that the aramid fiber plain weaving machine is weaved cotton cloth, base fabric fabric density 108 * 58, fineness of yarn is 16tex.
4. a kind of alginate fibre electrostatic flocking fabric according to claim 1, it is characterized in that: the technical indicator of alginate fibre electrostatic flocking fabric: fire resistance reaches A level requirement in GB 8965 flame-resistant garment-fire-retardant protection; Environmental-protecting performance reaches I class and II class index request in HJ/T 307-2006; Critical radiant flux: NEPA 253; The electrostatic propensity test: AATCC 134; Antistatic property: ISO6356.
5. the manufacture method of an a kind of alginate fibre electrostatic flocking fabric as claimed in claim 1, is characterized in that comprising the steps:
A, by the alginate fibre tow through cutting, making length is the 1.0-1.2 millimeter, fineness is the alginate fibre fine hair at 1.5 dawn, rear fine hair is carried out to conductive processing, and carries out as required painted processing, then fine hair is dry, screening;
B, by the base fabric aramid fiber plain weaving machine coating adhesive of weaving cotton cloth, adhesive divides two-layer, main painting is carried out in first precoating again after preliminary drying, the adhesive gross thickness is the 0.2-0.25 millimeter;
C, indoor at electrostatic spinning, adopt the flocking of high-voltage alternating generation of static electricity electric field, in the high-voltage alternating electrostatic field, makes fine hair under the effect of electric field force and the neat base fabric surface that scribbles adhesive of implanting;
D, the base fabric that step c is made, at following fan parameter, utilize pressure-air at matte, to carry out the air cotton ginning by the cylinder decorative pattern that covers on the air knife periphery, fan pressure 42-44Pa, cylinder rotating speed 12-14rpm, rotation speed of fan 35-38rpm, in the situation that speed of a motor vehicle 10m/min carries out, become the electrostatic flocking fabric with special air cotton ginning decorative pattern;
E, by the fabric that step c or steps d make, utilize the anti-processing method of foaming type three to carry out three anti-processing.
6. the manufacture method of a kind of alginate fibre electrostatic flocking fabric according to claim 5, it is characterized in that: in step a, the fine hair moisture control, at 8%-10%, is controlled at 3.6 * 10 than resistance
8-3.6 * 10
9Ω ㎝.
7. the manufacture method of a kind of alginate fibre electrostatic flocking fabric according to claim 5, it is characterized in that: step c mesohigh electrode network is for exchanging static, electrostatic high-pressure is controlled to be 20-22kv, and the distance scribbled on high voltage electrode net and base fabric between the one side of adhesive is 15-20 centimetre.
8. the manufacture method of a kind of alginate fibre electrostatic flocking fabric according to claim 5, it is characterized in that: in step b, adhesive is modifying epoxy resin by organosilicon glue, and the preliminary drying temperature is 80-90 ℃ and raises successively, and the preliminary drying time is 1-1.5min; Main baking temperature is 110-140 ℃ of rising successively, and the main baking time is 3-4min.
9. the manufacture method of a kind of alginate fibre electrostatic flocking fabric according to claim 5, it is characterized in that: in step e, utilize foaming machine by the three-proof finishing agent processing of foaming, blowing agent is the fluorocarbon polymer finishing agent, by the mode of blade coating, be coated onto the fabric surface, then carry out drying and processing, the equipment speed of service is 10m/min, and bake out temperature is 130-150 ℃ of rising successively, and drying time is 4-5 minute.
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| CN103660406A (en) * | 2014-01-15 | 2014-03-26 | 绍兴县恒兆纺织有限公司 | Colorful flocked fabric and preparation method thereof |
| CN107415359A (en) * | 2017-06-09 | 2017-12-01 | 山东领潮新材料有限公司 | Nanoscale heat-insulating noise-reducing tank interior composite material and preparation method thereof |
| CN108998985A (en) * | 2018-09-06 | 2018-12-14 | 山东领潮新材料有限公司 | A kind of green production method of electrostatic flocking fabric space pattern |
| CN109023989A (en) * | 2018-09-06 | 2018-12-18 | 山东领潮新材料有限公司 | A kind of flaxen fiber electrostatic flocking fabric and preparation method thereof that natural antibacterial is mould proof |
| CN109225769A (en) * | 2018-09-06 | 2019-01-18 | 山东领潮新材料有限公司 | Multi-electric-field electrostatic flocking method and equipment |
| CN109281191A (en) * | 2018-09-06 | 2019-01-29 | 山东领潮新材料有限公司 | A kind of heat-resistant fireproof electrostatic flocking fabric and preparation method thereof |
| CN109674103A (en) * | 2018-12-29 | 2019-04-26 | 湖州大南服饰有限公司 | A kind of summer sports underwear fabric and preparation method thereof |
| CN110331518A (en) * | 2019-07-31 | 2019-10-15 | 太仓市梓怡纺织有限公司 | The production technology of seaweed aryl fiber cloth |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103660406A (en) * | 2014-01-15 | 2014-03-26 | 绍兴县恒兆纺织有限公司 | Colorful flocked fabric and preparation method thereof |
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| CN109281191A (en) * | 2018-09-06 | 2019-01-29 | 山东领潮新材料有限公司 | A kind of heat-resistant fireproof electrostatic flocking fabric and preparation method thereof |
| CN109225769A (en) * | 2018-09-06 | 2019-01-18 | 山东领潮新材料有限公司 | Multi-electric-field electrostatic flocking method and equipment |
| CN109023989A (en) * | 2018-09-06 | 2018-12-18 | 山东领潮新材料有限公司 | A kind of flaxen fiber electrostatic flocking fabric and preparation method thereof that natural antibacterial is mould proof |
| CN108998985A (en) * | 2018-09-06 | 2018-12-14 | 山东领潮新材料有限公司 | A kind of green production method of electrostatic flocking fabric space pattern |
| CN109674103A (en) * | 2018-12-29 | 2019-04-26 | 湖州大南服饰有限公司 | A kind of summer sports underwear fabric and preparation method thereof |
| CN110331518A (en) * | 2019-07-31 | 2019-10-15 | 太仓市梓怡纺织有限公司 | The production technology of seaweed aryl fiber cloth |
| CN111118917A (en) * | 2019-12-30 | 2020-05-08 | 苏州大学 | Real silk flocking material and preparation method and application thereof |
| CN111118917B (en) * | 2019-12-30 | 2022-04-01 | 苏州大学 | Real silk flocking material and preparation method and application thereof |
| CN114507987A (en) * | 2022-02-23 | 2022-05-17 | 湖北金龙新材料股份有限公司 | Vertical fiber array modified coating fabric and preparation method thereof |
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