CN108301239A - A kind of method that Multifunctional aramid fiber is yarn beam printed - Google Patents

A kind of method that Multifunctional aramid fiber is yarn beam printed Download PDF

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Publication number
CN108301239A
CN108301239A CN201810118544.6A CN201810118544A CN108301239A CN 108301239 A CN108301239 A CN 108301239A CN 201810118544 A CN201810118544 A CN 201810118544A CN 108301239 A CN108301239 A CN 108301239A
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China
Prior art keywords
aramid fiber
yarn
function
multifunctional
type self
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Pending
Application number
CN201810118544.6A
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Chinese (zh)
Inventor
张小丽
瞿建刚
张陈成
王文元
张永辉
王鸿博
孙丰鑫
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Nantong University
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Nantong University
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Priority to CN201810118544.6A priority Critical patent/CN108301239A/en
Publication of CN108301239A publication Critical patent/CN108301239A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/53Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with hydrogen sulfide or its salts; with polysulfides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • D06M2101/36Aromatic polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention discloses a kind of methods that Multifunctional aramid fiber is yarn beam printed, include the following steps:The micronizing of photic light storage type self luminous material, anionic additive;Function micro mist is the same as bath warp prints color paste deployment;Function warp prints technical process.The present invention utilizes the fire-retardant aramid fiber piece yarn after warping that difference is added during coating rotary scream printing with functional materials such as fluorescence and anions, it is multi-functional to assign aramid fiber warp thread, warp thread and untreated weft yarn are weaved, have the function of persistently effective warning, antibacterial and anti-electromagnetic-radiation etc. while assigning fire-retardant aramid fiber PRINTED FABRIC dim effect.The weaving of various aramid fibers is applied to by addition several functions material using the alternative conventional yarn dyeing of the present invention and the technique for arranging two-step method, finishing technique is simple, realizes printing paste joint, anhydrous printing, energy conservation and environmental protection.

Description

A kind of method that Multifunctional aramid fiber is yarn beam printed
Technical field
The invention belongs to function textile function dyeing and finishing manufacture fields, and in particular to a kind of Multifunctional aramid fiber warp beam print Colored method.
Background technology
In general functional mainly arranged by cheese of yarn assigns its functionality, and cheese arrangement is by yarn Line or the process of the dyed final finishing of long filament, the method complex process, high energy consumption high pollution.The present invention, which utilizes, has superelevation Intensity, high-modulus and high temperature resistant, acid-fast alkali-proof and fire-retardant aramid fiber carry out network by yarn beam printed technique, using aramid yarn Warping after silk twisting carries out coating rotary scream printing to organizine;Sizing after stamp, then carry out wearing brown reed, weaving, finally to fabric into Row desizing, preshrunk (backtwisting), washing, stabilised finish and at product examine packet.Aramid fiber piece yarn after warping is in coating rotary scream printing Different functionalities material is added in technical process, assigns aramid fiber warp thread functionality, aramid fiber warp thread and untreated weft yarn is knitted It makes, has the function of that antibacterial anti-electromagnetic-radiation warns etc. other while assigning aramid fiber high-tenacity, high flame retardant.
Invention content
Goal of the invention:In order to solve the deficiencies in the prior art, the present invention provides a kind of Multifunctional aramid fiber warp beam prints Colored method, the present invention utilize the aramid fiber piece yarn after warping to be added in rotary scream printing technique with warning, anionic additive Equal functional materials realize anhydrous printing with the aramid fiber piece yarn after warping in the circle rotary scream printing one-bath finishing of printing paste combination plant, Have the function of that antibacterial anti-electromagnetic-radiation warns etc. other while assigning aramid fiber high-tenacity, high flame retardant.
Technical solution:A kind of method that Multifunctional aramid fiber is yarn beam printed, includes the following steps:
(1) micronizing of photic light storage type self luminous material, anionic additive:
Grain size is ground to grain by photic light storage type self luminous material, anionic additive by ball mill or colloid mill Diameter is less than 5 μm of functional material micro mist, spare;
(2) method of the function micro mist with bath warp prints color paste deployment:
Photic light storage type self luminous material and anionic additive powder content are respectively 1-5%, low-temperature adhesive dosage 20- 70%, coating 10-50%, acrylic crosslinking agent 0-3%, water and appropriate emulsion thickening, total amount 100% are configured to function stamp Mill base;
(3) function warp prints technical process:
By the aramid fiber piece yarn after warping, by printing paste combination plant in rotary scream printing technical process concentrator stamp, Starching after thermosetting color, the aramid fiber warp thread after stamp are weaved to obtain the multi-functional fabric in one, specific steps with weft yarn It is as follows:Raw yarn → beam warping → printing paste joint → weaving → fabric is examined;
The printing paste process integration includes the following steps:And axis → function micro mist bathes stamp → fixation → starching together, In, technological parameter is:Speed 20-60m/min, 100-160 DEG C of temperature bake time 1-4min.
As an optimization:The photic light storage type self luminous material is:Zinc sulphide/copper, cobalt compound or rare earth metal salt, Fluorescent paint.
As an optimization:The anionic additive is:Tourmaline or opal ore.
Advantageous effect:The yarn beam printed method of Multifunctional aramid fiber of the present invention, utilizes the fire-retardant virtue after warping Difference, which is added, in synthetic fibre piece yarn during coating rotary scream printing has the functional materials such as fluorescence and anion, and it is more to assign aramid fiber warp thread Functionality weaves warp thread and untreated weft yarn, has while assigning fire-retardant aramid fiber PRINTED FABRIC dim effect and holds The functions such as effective warning, antibacterial and anti-electromagnetic-radiation long.Using the alternative conventional yarn dyeing of the present invention and arrange two-step method Technique, by add several functions material, be applied to various aramid fibers weaving, finishing technique is simple, realize printing paste Joint, anhydrous printing, energy conservation and environmental protection.
The present invention knits the kevlar fabric flame retardant property of technology formation by print:Limit oxygen index value 28-30;Anion is dense Degree:800-1000/cm3;Persistence:15-20min, colorfastness to rubbing:Dry fastness is 4-5 grades, fastness to wet rubbing 3 ~4 grades;4 grades of color fastness to washing, 4 grades of colour fastness to perspiration meet the requirement of features textile items fastness.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, so that the technology of this field Personnel can be better understood from advantages and features of the invention, to make apparent boundary to protection scope of the present invention It is fixed.Embodiment described in the invention is only a part of the embodiment of the present invention, instead of all the embodiments, based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained without making creative work Example, shall fall within the protection scope of the present invention.
Specific embodiment 1
A kind of method that Multifunctional aramid fiber is yarn beam printed, includes the following steps:
(1) micronizing of photic light storage type self luminous material, anionic additive:
The photic light storage type self luminous material is:Zinc sulphide/copper, cobalt compound or rare earth metal salt, fluorescent paint; The anionic additive is:Tourmaline or opal ore.
Grain size is ground to grain by photic light storage type self luminous material, anionic additive by ball mill or colloid mill Diameter is less than 5 μm of functional material micro mist, spare.
(2) method of the function micro mist with bath warp prints color paste deployment:
Photic light storage type self luminous material and anionic additive powder content are respectively 1%, low-temperature adhesive dosage 20%, Coating 10%, water and appropriate emulsion thickening, total amount 100% are configured to function print paste.
(3) function warp prints technical process:
By the aramid fiber piece yarn after warping, by printing paste combination plant in rotary scream printing technical process concentrator stamp, Starching after thermosetting color, the aramid fiber warp thread after stamp are weaved to obtain the multi-functional fabric in one, specific steps with weft yarn It is as follows:Raw yarn → beam warping → printing paste joint → weaving → fabric is examined;
The printing paste process integration includes the following steps:And axis → function micro mist bathes stamp → fixation → starching together, In, technological parameter is:Speed 20m/min, 100 DEG C of temperature, bakes time 1min.
Specific embodiment 2
A kind of method that Multifunctional aramid fiber is yarn beam printed, includes the following steps:
(1) micronizing of photic light storage type self luminous material, anionic additive:
The photic light storage type self luminous material is:Zinc sulphide/copper, cobalt compound or rare earth metal salt, fluorescent paint; The anionic additive is:Tourmaline or opal ore.
Grain size is ground to grain by photic light storage type self luminous material, anionic additive by ball mill or colloid mill Diameter is less than 5 μm of functional material micro mist, spare.
(2) method of the function micro mist with bath warp prints color paste deployment:
Photic light storage type self luminous material and anionic additive powder content are respectively 5%, low-temperature adhesive dosage 70%, Coating 50%, acrylic crosslinking agent 3%, water and appropriate emulsion thickening, total amount 100% are configured to function print paste.
(3) function warp prints technical process:
By the aramid fiber piece yarn after warping, by printing paste combination plant in rotary scream printing technical process concentrator stamp, Starching after thermosetting color, the aramid fiber warp thread after stamp are weaved to obtain the multi-functional fabric in one, specific steps with weft yarn It is as follows:Raw yarn → beam warping → printing paste joint → weaving → fabric is examined;
The printing paste process integration includes the following steps:And axis → function micro mist bathes stamp → fixation → starching together, In, technological parameter is:Speed 60m/min, 160 DEG C of temperature, bakes time 4min.
Specific embodiment 3
A kind of method that Multifunctional aramid fiber is yarn beam printed, includes the following steps:
(1) micronizing of photic light storage type self luminous material, anionic additive:
The photic light storage type self luminous material is:Zinc sulphide/copper, cobalt compound or rare earth metal salt, fluorescent paint; The anionic additive is:Tourmaline or opal ore.
Grain size is ground to grain by photic light storage type self luminous material, anionic additive by ball mill or colloid mill Diameter is less than 5 μm of functional material micro mist, spare.
(2) method of the function micro mist with bath warp prints color paste deployment:
Photic light storage type self luminous material and anionic additive powder content are respectively 3%, low-temperature adhesive dosage 40%, Coating 30%, acrylic crosslinking agent 2%, water and appropriate emulsion thickening, total amount 100% are configured to function print paste.
(3) function warp prints technical process:
By the aramid fiber piece yarn after warping, by printing paste combination plant in rotary scream printing technical process concentrator stamp, Starching after thermosetting color, the aramid fiber warp thread after stamp are weaved to obtain the multi-functional fabric in one, specific steps with weft yarn It is as follows:Raw yarn → beam warping → printing paste joint → weaving → fabric is examined;
The printing paste process integration includes the following steps:And axis → function micro mist bathes stamp → fixation → starching together, In, technological parameter is:Speed 50m/min, 140 DEG C of temperature, bakes time 3min.
The present invention knits the kevlar fabric flame retardant property of technology formation by print:Limit oxygen index value 28-30;Anion is dense Degree:800-1000/cm3;Persistence:15-20min, colorfastness to rubbing:Dry fastness is 4-5 grades, fastness to wet rubbing 3 ~4 grades;4 grades of color fastness to washing, 4 grades of colour fastness to perspiration meet the requirement of features textile items fastness.
The yarn beam printed method of Multifunctional aramid fiber of the present invention is being applied using the fire-retardant aramid fiber piece yarn after warping Expect that rotary scream printing is added difference and has the functional materials such as fluorescence and anion in the process, assigns aramid fiber warp thread multifunctionality, it will Warp thread is weaved with untreated weft yarn, is had while assigning fire-retardant aramid fiber PRINTED FABRIC dim effect persistently effective alert Show, the functions such as antibacterial and anti-electromagnetic-radiation.Using the technique of the present invention alternative conventional yarn dyeing and arrangement two-step method, pass through Several functions material is added, the weaving of various aramid fibers is applied to, finishing technique is simple, realizes printing paste joint, no-watermark Flower, energy conservation and environmental protection.

Claims (3)

1. a kind of method that Multifunctional aramid fiber is yarn beam printed, it is characterised in that:Include the following steps:
(1) micronizing of photic light storage type self luminous material, anionic additive:
By photic light storage type self luminous material, anionic additive that grain size is ground to grain size by ball mill or colloid mill is low It is spare in 5 μm of functional material micro mist;
(2) method of the function micro mist with bath warp prints color paste deployment:
Photic light storage type self luminous material and anionic additive powder content are respectively 1-5%, low-temperature adhesive dosage 20- 70%, coating 10-50%, acrylic crosslinking agent 0-3%, water and appropriate emulsion thickening, total amount 100% are configured to function stamp Mill base;
(3) function warp prints technical process is as follows:
By the aramid fiber piece yarn after warping, concentrator stamp, thermosetting in rotary scream printing technical process by printing paste combination plant Starching after color, the aramid fiber warp thread after stamp are weaved to obtain the multi-functional fabric in one with weft yarn, be as follows: Raw yarn → beam warping → printing paste joint → weaving → fabric is examined;The printing paste process integration includes the following steps:And axis → function micro mist is the same as bathing stamp → fixation → starching, wherein technological parameter is:Speed 20-60m/min, 100-160 DEG C of temperature, Bake time 1-4min.
2. the yarn beam printed method of Multifunctional aramid fiber according to claim 1, it is characterised in that:The photic storage Light type self-luminescent material is:Zinc sulphide/copper, cobalt compound or rare earth metal salt, fluorescent paint.
3. the yarn beam printed method of Multifunctional aramid fiber according to claim 1, it is characterised in that:The anion Additive is:Tourmaline or opal ore.
CN201810118544.6A 2018-02-06 2018-02-06 A kind of method that Multifunctional aramid fiber is yarn beam printed Pending CN108301239A (en)

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CN201810118544.6A CN108301239A (en) 2018-02-06 2018-02-06 A kind of method that Multifunctional aramid fiber is yarn beam printed

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Application Number Priority Date Filing Date Title
CN201810118544.6A CN108301239A (en) 2018-02-06 2018-02-06 A kind of method that Multifunctional aramid fiber is yarn beam printed

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823744A (en) * 2018-07-30 2018-11-16 如皋市金轶纺织有限公司 Sand washing jacquard fabric production technology
CN114921981A (en) * 2022-06-20 2022-08-19 南通大学 Flame-retardant pigment dyed para-aramid fabric and dyeing method thereof

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Publication number Priority date Publication date Assignee Title
CN87103494A (en) * 1986-05-14 1987-11-25 伯林顿工业公司 The printing method of shaped articles derived from aramid fibers
CN101058946A (en) * 2007-04-29 2007-10-24 浙江理工大学 Process of preparing photochromic printing coated fabric
CN102433643A (en) * 2010-09-29 2012-05-02 江苏金纺针织有限公司 Noctilucent printed textile fabric
CN104562734A (en) * 2013-10-15 2015-04-29 青岛三秀新科技复合面料有限公司 Printing technology with noctilucent function
CN106638019A (en) * 2016-11-28 2017-05-10 恩平锦兴纺织印染企业有限公司 Printing process of knitted fabric with multi-element functions

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87103494A (en) * 1986-05-14 1987-11-25 伯林顿工业公司 The printing method of shaped articles derived from aramid fibers
CN101058946A (en) * 2007-04-29 2007-10-24 浙江理工大学 Process of preparing photochromic printing coated fabric
CN102433643A (en) * 2010-09-29 2012-05-02 江苏金纺针织有限公司 Noctilucent printed textile fabric
CN104562734A (en) * 2013-10-15 2015-04-29 青岛三秀新科技复合面料有限公司 Printing technology with noctilucent function
CN106638019A (en) * 2016-11-28 2017-05-10 恩平锦兴纺织印染企业有限公司 Printing process of knitted fabric with multi-element functions

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梁军等: "《三维编织复合材料力学性能分析方法》", 31 March 2014, 哈尔滨工业大学出版社 *
王授伦: "《纺织品印花实用技术》", 30 November 2002, 中国纺织出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823744A (en) * 2018-07-30 2018-11-16 如皋市金轶纺织有限公司 Sand washing jacquard fabric production technology
CN114921981A (en) * 2022-06-20 2022-08-19 南通大学 Flame-retardant pigment dyed para-aramid fabric and dyeing method thereof
CN114921981B (en) * 2022-06-20 2024-04-09 南通大学 Flame-retardant coating dyed para-aramid fabric and dyeing method thereof

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Application publication date: 20180720

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