CN103388153B - Environment-friendlyantirust antirust clean-out system - Google Patents
Environment-friendlyantirust antirust clean-out system Download PDFInfo
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- CN103388153B CN103388153B CN201310320587.XA CN201310320587A CN103388153B CN 103388153 B CN103388153 B CN 103388153B CN 201310320587 A CN201310320587 A CN 201310320587A CN 103388153 B CN103388153 B CN 103388153B
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Abstract
The invention provides Environment-friendlyantirust antirust clean-out system, the raw material of following weight percent is adopted to be prepared from: the mixture of one or more in 2%-5% phosphoric acid or phosphoric acid salt, the mixture of one or more in 2%-5% boric acid or borate, 0%-5% highly basic, 0.5%-1% aniorfic surfactant, 0.5%-1% nonionic surface active agent, the mixture of one or more in 0.5%-1% ethylenediamine tetraacetic acid (EDTA) or edetate and the water of surplus.Above-mentioned raw materials is dropped in order the anti-rust cleaning agent can prepared in water and the present invention relates to.Safety of the present invention, environmental protection, and there is good antirust cleaning capacity.
Description
Technical field
The invention provides a kind of clean-out system, be specially adapted to the Environment-friendlyantirust antirust clean-out system of clean metal.
Background technology
Metal processing piece often carries out the lubrication and cooling in the course of processing with various lubricant in the course of processing; just can enter next procedure after the rear workpiece of processing will clean to carry out being assembled into finished product; and most of clean-out system is when washing away the greasy dirt of metallic surface; destroy protective layer; its surface just gets rusty easily, and later process also will carry out derusting rust-proofing process, so not only extends operation; increase production cost, easily produce secondary pollution simultaneously and improve the problems such as energy consumption.
In addition, the Environment-friendlyantirust antirust clean-out system that dual-use function that is antirust and cleaning can be combined at present, often with the addition of nitrite or nitrate or the dichromate of carcinogenic teratogenesis, as the patent publication No. invention that is CN102586788 provides the technical scheme of a kind of cleaning anti-rust agent and preparation method thereof method antirust with using this cleaning anti-rust agent scale removal, this cleaning anti-rust agent is primarily of citric acid, edetate, ammonium nitrate, dirt dispersion agent, permeate agent, inhibiter, solubilizing agent and deionized water composition, this invention in preparation process owing to have employed this component of ammonium nitrate, obviously can give and produce and use the client of link to bring certain potential safety hazard.
Summary of the invention
In view of above defect, the object of the invention is to overcome the deficiencies in the prior art, provide a kind of and adopt the new safety of formula preparation, the Environment-friendlyantirust antirust clean-out system of environmental protection.
For achieving the above object, the feature of Environment-friendlyantirust antirust clean-out system provided by the invention is, adopts the raw material of following weight percent to be prepared from:
On the other hand, for achieving the above object, the feature of Environment-friendlyantirust antirust clean-out system provided by the invention is, adopts the raw material of following weight percent to be prepared from:
On the other hand, for achieving the above object, the feature of Environment-friendlyantirust antirust clean-out system provided by the invention is, adopts the raw material of following weight percent to be prepared from:
On the other hand, for achieving the above object, the feature of Environment-friendlyantirust antirust clean-out system provided by the invention is, adopts the raw material of following weight percent to be prepared from:
On the other hand, for achieving the above object, the feature of Environment-friendlyantirust antirust clean-out system provided by the invention is, adopts the raw material of following weight percent to be prepared from:
Environment-friendlyantirust antirust clean-out system provided by the invention, also has such technical characteristic: phosphoric acid salt is the mixture of one or more in tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, Potassium tripolyphosphate, hexa metaphosphoric acid potassium, dipotassium hydrogen phosphate, potassium primary phosphate.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention, also has such technical characteristic: borate is one or several mixtures in potassium tetraborate, sodium tetraborate, potassium per(oxy)borate, Sodium peroxoborate.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention, also there is such technical characteristic: aniorfic surfactant is the potassium of higher fatty acid, sodium, ammonium salt and Lamepon A, alkylbenzene sulfonate, sulfonated α-olefin, alkylsulfonate, alpha-sulfo monocarboxylate salt, lipid acid sulfoalkyl ester salt, sulfosuccinate, sulfonated alkyl naphathalene, sulfonated petro-leum, sulfonated lignin, alkyl glyceryl ether sulfonate, aliphatic alcohol sulfate, alkyl-sulphate, secondary alkyl sulfate, the sulfuric acid of derivative of fatty acid, alkylphosphonic acid carboxylic acid list/dibasic acid esters salt, the mixture of one or more in the mono phosphoric acid ester/dibasic acid esters salt of fatty alcohol-polyoxyethylene ether and the mono phosphoric acid ester/dibasic acid esters salt of alkylphenol polyoxyethylene.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention, also has such technical characteristic: aniorfic surfactant is preferred: the mixture of one or more in sodium alkyl benzene sulfonate, Seconary Alkane Sulphonate Sodium, sodium alkyl sulfate.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention, also has such technical characteristic: nonionogenic tenside is the mixture of one or more in the derivative of alkylphenol polyoxyethylene, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate, the ethylene oxide adduct of polypropylene glycol, polyoxyethylated derivative, sorbitan fatty acid ester Soxylat A 25-7, sucrose ester, alkylol amide.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention, also has such technical characteristic: edetate is disodium EDTA or tetrasodium salt of EDTA.
In addition, the preparation method of Environment-friendlyantirust antirust clean-out system provided by the invention is: after being taken by the regulation of above-mentioned mass percent by the mixture of one or more in the mixture of one or more in the mixture of one or more in phosphoric acid or phosphoric acid salt, boric acid or borate, sodium hydroxide or potassium hydroxide, aniorfic surfactant, nonionic surface active agent, ethylenediamine tetraacetic acid (EDTA) or edetate, be added to the water successively and be stirred to all components and dissolve completely, till container bottom sediment-free.
In addition, Environment-friendlyantirust antirust clean-out system provided by the invention can with after the dilution of 0-20 water doubly for the cleaning rust-proof under different complete processing and different condition.
the effect of invention and effect
In the technical solution adopted in the present invention, the phosphoric acid salt that phosphoric acid and highly basic (as: sodium hydroxide etc.) reaction generate is auxiliary agent good in clean-out system, phosphate radical, hydrogen phosphate, dihydrogen phosphate can generate phosphoric acid molysite with iron ion reaction simultaneously, be attached to metallic surface, can effectively prevent metal from continuing corrosion.
Boric acid is a kind of good rush-resisting material, and the borate that highly basic reaction generates, and can form layer protective layer in metallic surface, in addition, and borate or a kind of good clean-out system auxiliary agent.
Aniorfic surfactant and nonionogenic tenside composite in the ratio designed by the present invention after, reach the effect (i.e. synergistic effect) of synergism, better washing effect can be realized, the greasy dirt of more effective removal metallic surface.
Ethylenediamine tetraacetic acid (EDTA) and its esters can with the inorganic salt dirt chelating of metallic surface, make it be easier to be dissolved to after in water and remove.
Embodiment
Embodiment one
The preparation method of 1# Environment-friendlyantirust antirust clean-out system:
Take 3kg phosphoric acid, 3kg boric acid, 3kg sodium hydroxide, 0.8kg sodium lauryl sulphate, the sorbitan monooleate Soxylat A 25-7 (tween-80) of 0.8kg, 0.8kg disodium ethylene diamine tetraacetate, add successively and be stirred to all the components in 88.6kg water and dissolve completely, till container bottom sediment-free.
By 1# Environment-friendlyantirust antirust clean-out system, clean and carry out antirust humid heat test result by GB/T2361: 72 hours, 1 grade.
1# Environment-friendlyantirust antirust clean-out system is done liquid phase corrosion experiment by GB/T11143-2008 test method: result is qualified.
After 1# Environment-friendlyantirust antirust clean-out system thin up 20 times, the 45# steel that cleaning is processed with emulsion, after 48 hours, cutting surface is without the visible rusty stain of naked eyes.
Embodiment two
The preparation method of 2# Environment-friendlyantirust antirust clean-out system:
Take 2kg sodium phosphate, 5kg boric acid, 2.5kg sodium hydroxide, 0.5kg Sodium dodecylbenzene sulfonate, lauryl alcohol polyethylene glycol oxide (9) ether of 1kg, 0.5kg ethylenediamine tetraacetic acid (EDTA), add successively and be stirred to all the components in 88.5kg water and dissolve completely, till container bottom sediment-free.
Embodiment three
The preparation method of 3# Environment-friendlyantirust antirust clean-out system:
Take 5kg phosphoric acid, 2kg potassium tetraborate, 2kg potassium hydroxide, 1kg Seconary Alkane Sulphonate Sodium SAS60, Nonyl pheno (10) ether of 0.5kg, 1kg tetrasodium ethylenediamine tetraacetate, add successively and be stirred to all the components in the 88.5kg water taken and dissolve completely, till container bottom sediment-free.
Embodiment four
The preparation method of 4# Environment-friendlyantirust antirust clean-out system:
Take the mixture of the mixture of 4.2kg Potassium tripolyphosphate and sodium phosphate, 2kg boric acid, 2kg sodium hydroxide, 0.6kg sulfosuccinate, the polyoxyethylene carboxylate (A-103A-105) of 0.6kg, 0.6kg ethylenediamine tetraacetic acid (EDTA) and tetrasodium ethylenediamine tetraacetate, add successively and be stirred to all the components in the 90kg water taken and dissolve completely, till container bottom sediment-free.
Embodiment five
The preparation method of 5# Environment-friendlyantirust antirust clean-out system:
Take the mixture of 2.5kg phosphoric acid, 4kg potassium per(oxy)borate, 5kg potassium hydroxide, 1kg Sodium dodecylbenzene sulfonate, the tween-80 of 1kg, 1kg ethylenediamine tetraacetic acid (EDTA) and tetrasodium salt of EDTA, add successively and be stirred to all the components in the 85.5kg water taken and dissolve completely, till container bottom sediment-free.
Embodiment six
The preparation method of 6# Environment-friendlyantirust antirust clean-out system:
Take 4kg potassiumphosphate, 5kg Sodium peroxoborate, the monoalkyl phosphate (AEOPNa) of 0.7kg fatty alcohol-polyoxyethylene ether, the fatty acid methyl ester ethoxylate (FMEE) of 1kg, 0.6kg ethylenediamine tetraacetic acid (EDTA), add successively and be stirred to all the components in the 88.7kg water taken and dissolve completely, till container bottom sediment-free.
Embodiment seven
The preparation method of 7# Environment-friendlyantirust antirust clean-out system:
Take the mixture of 3kg phosphoric acid, 3kg boric acid, 3kg potassium hydroxide and sodium hydroxide, 0.8kg sodium lauryl sulphate, the isomery 13 carbon Soxylat A 25-7 1309 of 1kg, 0.8kg tetrasodium ethylenediamine tetraacetate, add successively and be stirred to all the components in the 88.4kg water taken and dissolve completely, till container bottom sediment-free.
After 7# Environment-friendlyantirust antirust clean-out system thin up 20 times, the 45# steel that cleaning is processed with emulsion, after 48 hours, cutting surface is without the visible rusty stain of naked eyes.
Embodiment eight
The preparation method of 8# Environment-friendlyantirust antirust clean-out system:
Take 3kg phosphoric acid, 3kg boric acid, 3kg potassium hydroxide, 1kg Lamepon A, the isomery 13 carbon Soxylat A 25-7 1309 of 1kg, 1kg tetrasodium ethylenediamine tetraacetate, add successively and be stirred to all the components in the 88kg water taken and dissolve completely, till container bottom sediment-free.
Claims (6)
1. Environment-friendlyantirust antirust clean-out system, is characterized in that, adopts the raw material of following weight percent to be prepared from:
Described phosphoric acid salt is the mixture of one or more in Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, Potassium tripolyphosphate, hexa metaphosphoric acid potassium, dipotassium hydrogen phosphate, potassium primary phosphate;
Described borate is one or more mixtures in potassium tetraborate, potassium per(oxy)borate, Sodium peroxoborate;
Described aniorfic surfactant is the potassium of higher fatty acid, sodium, ammonium salt, Lamepon A, alkylbenzene sulfonate, sulfonated α-olefin, alkylsulfonate, alpha-sulfo monocarboxylate, lipid acid sulfoalkyl ester, sulfosuccinate, sulfonated alkyl naphathalene, sulfonated petro-leum, sulfonated lignin, alkyl glyceryl ether sulfonate, aliphatic alcohol sulfate, secondary alkyl sulfate, the sulfuric acid of derivative of fatty acid, alkylphosphonic acid carboxylic acid list/dibasic acid esters salt, the mixture of one or more in the mono phosphoric acid ester/dibasic acid esters salt of fatty alcohol-polyoxyethylene ether and the mono phosphoric acid ester/dibasic acid esters salt of alkylphenol polyoxyethylene,
Described nonionogenic tenside is the mixture of one or more in the derivative of alkylphenol polyoxyethylene, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate, the ethylene oxide adduct of polypropylene glycol, polyoxyethylated derivative, sorbitan fatty acid ester Soxylat A 25-7, sucrose ester, alkylol amide.
2. Environment-friendlyantirust antirust clean-out system as claimed in claim 1, is characterized in that: adopt the raw material of following weight percent to be prepared from:
3. Environment-friendlyantirust antirust clean-out system as claimed in claim 1, is characterized in that: adopt the raw material of following weight percent to be prepared from:
4. Environment-friendlyantirust antirust clean-out system as claimed in claim 1, is characterized in that: adopt the raw material of following weight percent to be prepared from:
5. Environment-friendlyantirust antirust clean-out system as claimed in claim 1, is characterized in that: adopt the raw material of following weight percent to be prepared from:
6. the Environment-friendlyantirust antirust clean-out system as described in as arbitrary in claim 1-5, is characterized in that:
Described aniorfic surfactant is selected from the mixture of one or more in sodium alkyl benzene sulfonate, Seconary Alkane Sulphonate Sodium, sodium alkyl sulfate.
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Effective date of registration: 20190124 Address after: 518109 No. 9 Qikeng South Road, Fucheng Office, Longhua New District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Sea Aerosol Co., Ltd. Address before: 200062 414, room second, 1006 Jinsha River Road, Putuo District, Shanghai. Patentee before: Shanghai Jinzhao Conservation of Energy Science & Technology Co., Ltd. |
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Effective date of registration: 20210310 Address after: No.6, Sha Dong Road, Shatian Town, Dongguan City, Guangdong Province, 523000 Patentee after: Dongguan Saiya aerosol Co.,Ltd. Address before: 518109 No. 9 Qikeng South Road, Fucheng Office, Longhua New District, Shenzhen City, Guangdong Province Patentee before: SHENZHEN SEA AEROSOL Co.,Ltd. |