CN108373951A - Neutral degreaser agent - Google Patents
Neutral degreaser agent Download PDFInfo
- Publication number
- CN108373951A CN108373951A CN201810116247.8A CN201810116247A CN108373951A CN 108373951 A CN108373951 A CN 108373951A CN 201810116247 A CN201810116247 A CN 201810116247A CN 108373951 A CN108373951 A CN 108373951A
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- parts
- neutral degreaser
- sulfate
- surfactant
- neutral
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention relates to a kind of neutral degreaser agent and preparation method thereof, neutral degreaser agent includes each component of following mass parts:20 parts~45 parts of surfactant;5 parts~10 parts of phosphate;2 parts~5.6 parts of borate;2 parts~7.5 parts of sulfate;3 parts~7.8 parts of octylphenol polyethylene vinethene.Relative to it is existing have to human body larger harm in acid or alkalinity degreaser, above-mentioned degreaser is by using 20 parts~45 parts of surfactant;5 parts~10 parts of phosphate;2 parts~5.6 parts of borate;2 parts~7.5 parts of sulfate;3 parts~7.8 parts of octylphenol polyethylene vinethene, harm to the human body is smaller, can effectively remove the greasy dirt on alloy surface, and can also preferably protect the surface of alloy.
Description
Technical field
The present invention relates to degreasing technique fields, more particularly to a kind of neutral degreaser agent.
Background technology
Degreaser is the complex mixture formed with the organic and inorganic chemical of water-based, is to utilize " emulsification " " saponification "
Principle and the infant industry degreaser developed.In intermetallic composite coating, food, weaving, traffic, ship, building, electric appliance, medicine, chemical industry
Equal industrial circles all have been widely used, although the surface matrix of cleaning is not quite similar, cleaning purpose is consistent, and is all extensive
The cleanliness factor of multiple stromal surface and the integrality for keeping stromal surface.
Degreaser is mainly formulated by a variety of surfactants and builder etc..In liquid cleaning agent, therefore use
It is easy.Ultrasonic cleaning or cleaning showers are generally used in modern industry cleaning.It is completely molten instead of inflammable and explosive oil
Agent can remove lubricant grease, carbon agent, mildew of various material surfaces etc., safe to use, easy, economy, significant effect easily.
Feature:Strong osmotic emulsifies, and decontamination speed is fast;Containing unique rust inhibitor, short-term rust prevention is had both;It is non-ignitable not quick-fried;In alkalescent,
Do not corrode machine and equipment.Degreaser has point metal degreasing and plastic cement oil removing.Composition is different.
However, existing degreaser in acid or alkalinity, all has human body larger harm, and existing degreaser removes
Oil is ineffective.
Invention content
Based on this, it is necessary to provide that a kind of harm to the human body is smaller and the preferable neutral degreaser agent of deoiling effect.
A kind of neutral degreaser agent, includes each component of following mass parts:
The surfactant is the emulsifiers of OP~10, neopelex and sun in one of the embodiments,
At least one of ionic surface active agent.
The cationic surfactant includes cetyltrimethylammonium bromide in one of the embodiments,.
The phosphate is at least one of sodium dihydrogen phosphate and sodium tripolyphosphate in one of the embodiments,.
The borate is sodium tetraborate in one of the embodiments,.
The sulfate is fatty acid glyceride sulfate, sulphation natrium ricinoleicum, cycloalkanes in one of the embodiments,
At least one of sodium sulphate and fatty acyl aminoalkyl sodium sulphate.
The temperature in use of the neutral degreaser agent is 70 DEG C~110 DEG C in one of the embodiments,.
A kind of preparation method of neutral degreaser agent, includes the following steps:
Surfactant, phosphate, borate, sulfate and octylphenol polyethylene vinethene are provided;
By the surfactant, the phosphate, the borate, the sulfate and the octylphenol polyethylene vinethene
It is mixed, obtains neutral degreaser agent, wherein the surfactant, the phosphate, the borate, the sulfate
Mass ratio with the octylphenol polyethylene vinethene is (20~45):(5~10):(2~5.6):(2~7.5):(3~7.8).
It is above-mentioned neutrality degreaser using surfactant as oil removing main body, harm to the human body is smaller, and deoiling effect compared with
It is good, and the alkalinity of phosphate, borate and sulfate is weaker, and three has preferably coordinated effect, can remove conjunction
Greasy dirt in gold surface, for example, the releasing agent on alloy surface can be removed, for example, the protection oil etc. on alloy surface is removed,
And the surface that can also preferably protect alloy, avoids excessive erosion problem, deoiling effect preferable.
Description of the drawings
Fig. 1 is the step flow chart of the preparation method of the neutral degreaser agent of an embodiment of the present invention.
Specific implementation mode
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, below in conjunction with the accompanying drawings to the present invention
Specific implementation mode be described in detail.Many details are elaborated in the following description in order to fully understand this hair
It is bright.But the invention can be embodied in many other ways as described herein, those skilled in the art can be not
Similar improvement is done in the case of violating intension of the present invention, therefore the present invention is not limited by following public specific embodiment.
Neutral degreaser agent in one embodiment, includes each component of following mass parts:
It is above-mentioned neutrality degreaser using surfactant as oil removing main body, harm to the human body is smaller, and deoiling effect compared with
It is good, and the alkalinity of phosphate, borate and sulfate is weaker, not will produce harmful acid mist and alkali mist, and three
Person has preferably coordinated effect, can remove the greasy dirt on alloy surface, for example, can remove de- on alloy surface
Mould agent for example, removing the protection oil etc. on alloy surface, and can also preferably protect the surface of alloy, avoid excessive erosion
Problem, deoiling effect are preferable.Octylphenol polyethylene vinethene can also form layer protecting film in alloy surface, further function as protection
The effect of alloy surface, in this way, deoiling effect and alloy protecting effect have both.
In order to further increase deoiling effect, for example, the surfactant is the emulsifiers of OP~10, detergent alkylate sulphur
At least one of sour sodium and cationic surfactant, for another example, the surfactant are the emulsifiers of OP~10, dodecyl
Benzene sulfonic acid sodium salt and cationic surfactant, for another example, the emulsifiers of the OP~10, neopelex and cationic surface
The mass ratio (1~2.5) of activating agent:(1~1.5):(1~2.5) so, it is possible to further increase deoiling effect.
In order to further increase deoiling effect, the cationic surfactant includes cetyltrimethylammonium bromide;Again
Such as, the phosphate is sodium dihydrogen phosphate;For another example, the borate is sodium tetraborate;For another example, the sulfate is glycerin fatty
At least one of acid esters sulfate, sulphation natrium ricinoleicum, cycloalkanes sodium sulphate and fatty acyl aminoalkyl sodium sulphate, in this way, energy
Enough further increase deoiling effect.
In order to further increase deoiling effect, the temperature in use of the neutral degreaser agent is 70 DEG C~110 DEG C, in this way, energy
Enough further increase deoiling effect.
Referring to Fig. 1, the preparation method of the neutral degreaser agent of an embodiment, includes the following steps:
S110, surfactant, phosphate, borate, sulfate and octylphenol polyethylene vinethene are provided.
S120, by the surfactant, the phosphate, the borate, the sulfate and the octylphenol polyethylene
Vinethene is mixed, and neutral degreaser agent is obtained, wherein the surfactant, the phosphate, the borate, described
The mass ratio of sulfate and the octylphenol polyethylene vinethene is (20~45):(5~10):(2~5.6):(2~7.5):(3~
7.8)。
Neutral degreaser agent can be prepared by step S110 and step S120.Above-mentioned neutrality degreaser is lived using surface
Property agent is as oil removing main body, and harm to the human body is smaller, and deoiling effect is preferable, and the alkali of phosphate, borate and sulfate
Property it is weaker, not will produce harmful acid mist and alkali mist, and three has preferably coordinated effect, can remove
Greasy dirt on alloy surface, for example, the releasing agent on alloy surface can be removed, for example, removing the protection oil on alloy surface
Deng, and the surface of alloy can also be preferably protected, avoid excessive erosion problem, deoiling effect preferable.Octylphenol polyethylene vinethene
Layer protecting film can also be formed in alloy surface, the effect of protection alloy surface be further functioned as, in this way, deoiling effect and conjunction
Golden protecting effect has both.
Specific embodiment is as follows:
Embodiment 1
The 20g emulsifiers of OP~10 are added in beaker, 5g sodium dihydrogen phosphates are added, 2g sodium tetraborates, 2g cycloalkanes sulphur is added
Sour sodium and 3g octylphenol polyethylene vinethenes add water 500g, stir 5 minutes, and substance to be added dissolving is complete, and embodiment is prepared
1 neutral degreaser agent.
Embodiment 2
The 25g emulsifiers of OP~10 are added in beaker, 5g sodium dihydrogen phosphates are added, 2g sodium tetraborates, 2g glyceride is added
Fat acid esters sulfate and 3g octylphenol polyethylene vinethenes add water 500g, stir 5 minutes, and substance to be added dissolving is complete, is prepared into
To the neutral degreaser agent of embodiment 1.
Embodiment 3
The 30g emulsifiers of OP~10 are added in beaker, 9g sodium tripolyphosphates are added, 3g sodium tetraborates, 4g glyceride is added
Fat acid esters sulfate and 2g octylphenol polyethylene vinethenes add water 500g, stir 5 minutes, and substance to be added dissolving is complete, is prepared into
To the neutral degreaser agent of embodiment 1.
Embodiment 4
30g neopelexes are added in beaker, 5g sodium dihydrogen phosphates are added, 2g sodium tetraborates, 2g rings is added
Vinic acid sodium and 3g octylphenol polyethylene vinethenes add water 500g, stir 5 minutes, and substance to be added dissolving is complete, and reality is prepared
Apply the neutral degreaser agent of example 1.
Embodiment 5
The 15g emulsifiers of OP~10 are added in beaker, 15g neopelexes are added 5g sodium tripolyphosphates, add
Enter 3g sodium tetraborates, 2g fatty acid glycerides sulfate, 1g sulphations natrium ricinoleicum and 4g octylphenol polyethylene vinethenes, adds water
500g is stirred 5 minutes, and substance to be added dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
Embodiment 6
25g neopelexes are added in beaker, 6g sodium dihydrogen phosphates are added, 2g sodium tetraborates, 2g rings is added
Vinic acid sodium and fatty acyl aminoalkyl sodium sulphate and 4g octylphenol polyethylene vinethenes add water 500g, stir 5 minutes, object to be added
Matter dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
Embodiment 7
The 10g emulsifiers of OP~10 are added in beaker, 15g neopelexes are added 7g sodium dihydrogen phosphates, add
Enter 3g sodium tetraborates, 2g sulphations natrium ricinoleicum and 2g octylphenol polyethylene vinethenes, add water 500g, stirs 5 minutes, object to be added
Matter dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
Embodiment 8
30g cetyltrimethylammonium bromides are added in beaker, 8g sodium dihydrogen phosphates are added, 4g sodium tetraborates, 2g is added
Fatty acid glyceride sulfate, 1g cycloalkanes sodium sulphate and fatty acyl aminoalkyl sodium sulphate and 5g octylphenol polyethylene vinethenes, add water
500g is stirred 5 minutes, and substance to be added dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
Embodiment 9
The 9g emulsifiers of OP~10 are added in beaker, 14g cetyltrimethylammonium bromides are added 6g sodium tripolyphosphates, add
Enter 3g sodium tetraborates, 3g fatty acid glyceride sulfate, 2 sulphation natrium ricinoleicums and 7g octylphenol polyethylene vinethenes, add water 500g,
Stirring 5 minutes, substance to be added dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
Embodiment 10
The 20g emulsifiers of OP~10,10g neopelexes, 15g cetyltrimethylammonium brominations are added in beaker
Ammonium, is added 3g sodium dihydrogen phosphates, and 5g sodium tetraborates, 1g fatty acid glyceride sulfate, 3g sulphations is added in 7g sodium tripolyphosphates
Natrium ricinoleicum, 2g cycloalkanes sodium sulphate, 1g fatty acyl aminoalkyl sodium sulphate and 7g octylphenol polyethylene vinethenes add water 500g, stir 5 points
Clock, substance to be added dissolving is complete, and the neutral degreaser agent of embodiment 1 is prepared.
The neutral degreaser agent that embodiment 1 to 10 is prepared below carries out aluminium alloy material at 70 DEG C~110 DEG C
Oil removing is proved through experiment, and the neutral degreaser agent that embodiment 1-10 is prepared totally is in neutrality, and not will produce acid mist and alkali mist,
It is good to the removal effect of various greasy dirts, and point will not be formed on aluminium alloy material surface, i.e., etching problem is not will produce, especially
The neutral degreaser agent that embodiment 10 is prepared is fabulous to the removal effect of the releasing agent of oiliness.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each piece of technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Only several embodiments of the present invention are expressed for embodiment described above, the description thereof is more specific and detailed, but
It cannot be construed as a limitation to the scope of the present invention.It should be pointed out that for the ordinary skill people of this field
For member, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the present invention's
Protection domain.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (8)
1. a kind of neutral degreaser agent, which is characterized in that include each component of following mass parts:
2. neutral degreaser agent according to claim 1, which is characterized in that the surfactant be the emulsifiers of OP~10,
At least one of neopelex and cationic surfactant.
3. neutral degreaser agent according to claim 2, which is characterized in that the cationic surfactant includes cetyl
Trimethylammonium bromide.
4. neutral degreaser agent according to claim 1, which is characterized in that the phosphate is sodium dihydrogen phosphate and trimerization phosphorus
At least one of sour sodium.
5. neutral degreaser agent according to claim 1, which is characterized in that the borate is sodium tetraborate.
6. neutral degreaser agent according to claim 1, which is characterized in that the sulfate is fatty acid glyceride sulfuric acid
At least one of salt, sulphation natrium ricinoleicum, cycloalkanes sodium sulphate and fatty acyl aminoalkyl sodium sulphate.
7. neutral degreaser agent according to claim 1, which is characterized in that the temperature in use of the neutral degreaser agent is 70 DEG C
~110 DEG C.
8. a kind of preparation method of neutral degreaser agent, which is characterized in that include the following steps:
Surfactant, phosphate, borate, sulfate and octylphenol polyethylene vinethene are provided;
The surfactant, the phosphate, the borate, the sulfate and the octylphenol polyethylene vinethene are carried out
Mixing, obtains neutral degreaser agent, wherein the surfactant, the phosphate, the borate, the sulfate and institute
The mass ratio for stating octylphenol polyethylene vinethene is (20~45):(5~10):(2~5.6):(2~7.5):(3~7.8).
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CN201810116247.8A CN108373951A (en) | 2018-02-06 | 2018-02-06 | Neutral degreaser agent |
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CN201810116247.8A CN108373951A (en) | 2018-02-06 | 2018-02-06 | Neutral degreaser agent |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109865789A (en) * | 2019-05-06 | 2019-06-11 | 山东鲁电线路器材有限公司 | Oily integrated inline process is got rid of in a kind of bolt cold-heading thread rolling |
CN113637531A (en) * | 2020-05-11 | 2021-11-12 | 江苏久茂精密电子科技有限公司 | Oil removing agent for cleaning metal workpiece of electronic product and preparation method thereof |
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CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environmental protection anti-rust cleaning agent |
CN104099621A (en) * | 2014-06-24 | 2014-10-15 | 江门百得利包装材料有限公司 | Weakly alkaline environment-friendly aluminum product surface degreasing agent and preparation method thereof |
CN106893653A (en) * | 2015-12-17 | 2017-06-27 | 天津微都市科技有限公司 | A kind of environmentally friendly degreaser |
-
2018
- 2018-02-06 CN CN201810116247.8A patent/CN108373951A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103388153A (en) * | 2013-07-26 | 2013-11-13 | 上海金兆节能科技有限公司 | Environmental protection anti-rust cleaning agent |
CN104099621A (en) * | 2014-06-24 | 2014-10-15 | 江门百得利包装材料有限公司 | Weakly alkaline environment-friendly aluminum product surface degreasing agent and preparation method thereof |
CN106893653A (en) * | 2015-12-17 | 2017-06-27 | 天津微都市科技有限公司 | A kind of environmentally friendly degreaser |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109865789A (en) * | 2019-05-06 | 2019-06-11 | 山东鲁电线路器材有限公司 | Oily integrated inline process is got rid of in a kind of bolt cold-heading thread rolling |
CN113637531A (en) * | 2020-05-11 | 2021-11-12 | 江苏久茂精密电子科技有限公司 | Oil removing agent for cleaning metal workpiece of electronic product and preparation method thereof |
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Application publication date: 20180807 |