CN103384693B - 间同立构聚苯乙烯的无序纳米多孔结晶形式,其制备方法和包含它的制品 - Google Patents

间同立构聚苯乙烯的无序纳米多孔结晶形式,其制备方法和包含它的制品 Download PDF

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Publication number
CN103384693B
CN103384693B CN201180067400.9A CN201180067400A CN103384693B CN 103384693 B CN103384693 B CN 103384693B CN 201180067400 A CN201180067400 A CN 201180067400A CN 103384693 B CN103384693 B CN 103384693B
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amorphous
syndiotactic polystyrene
particles
crystalline form
disordered
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Chinese (zh)
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CN103384693A (zh
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A·R·阿尔布尼亚
R·比安基
L·迪马约
M·加林贝蒂
G·圭拉
R·潘塔尼
S·塞纳托雷
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Nano Active Film SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/02—Chemical treatment or coating of shaped articles made of macromolecular substances with solvents, e.g. swelling agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/06—Polystyrene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/20—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain
    • D01F6/22—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of cyclic compounds with one carbon-to-carbon double bond in the side chain from polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • C08J2425/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wrappers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201180067400.9A 2010-12-30 2011-12-29 间同立构聚苯乙烯的无序纳米多孔结晶形式,其制备方法和包含它的制品 Active CN103384693B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2010A002460A IT1404157B1 (it) 2010-12-30 2010-12-30 Forma cristallina nanoporosa disordinata di polistirene sindiotattico, suo processo di preparazione e articoli comprendenti la stessa.
ITMI2010A002460 2010-12-30
PCT/EP2011/074227 WO2012089805A1 (en) 2010-12-30 2011-12-29 Disordered nanoporous crystalline form of syndiotactic polystyrene, process for its preparation and articles comprising the same

Publications (2)

Publication Number Publication Date
CN103384693A CN103384693A (zh) 2013-11-06
CN103384693B true CN103384693B (zh) 2015-06-10

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CN201180067400.9A Active CN103384693B (zh) 2010-12-30 2011-12-29 间同立构聚苯乙烯的无序纳米多孔结晶形式,其制备方法和包含它的制品

Country Status (8)

Country Link
US (1) US9328181B2 (enExample)
EP (1) EP2658904B1 (enExample)
JP (1) JP5918265B2 (enExample)
CN (1) CN103384693B (enExample)
BR (1) BR112013016801A2 (enExample)
ES (1) ES2565994T3 (enExample)
IT (1) IT1404157B1 (enExample)
WO (1) WO2012089805A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016089063A (ja) * 2014-11-06 2016-05-23 国立大学法人静岡大学 シンジオタクチックポリスチレン共結晶材料及びその製造方法
GB2538255B (en) * 2015-05-12 2020-02-26 Innovia Films Ltd Film for packaging
JP2017110311A (ja) * 2015-12-16 2017-06-22 東洋紡株式会社 シンジオタクチックポリスチレン繊維の製造方法
AU2018246257B2 (en) * 2017-03-30 2022-05-12 Merck Patent Gmbh Solid form of (S)-[2-chloro-4-fluoro-5-(7-morpholin-4-ylquinazolin-4-yl)phenyl]-(6-methoxy-pyridazin-3-yl)methanol
GB2570705A (en) * 2018-02-05 2019-08-07 Innovia Films Ltd Packaging substrate
IT201800007712A1 (it) * 2018-07-31 2020-01-31 Materias Srl Filati e tessuti attivi per stabilizzazione e rilascio controllato di composti attivi
JP2021091791A (ja) * 2019-12-10 2021-06-17 出光興産株式会社 スチレン系樹脂粒子の製造方法、スチレン系樹脂粒子、低誘電材用樹脂組成物及び成形体
IT202000027660A1 (it) 2020-11-18 2022-05-18 Materias S R L Film a base di ppo con alta area superficiale e procedure per il loro ottenimento
IT202000027645A1 (it) 2020-11-18 2022-05-18 Materias S R L Film sottili a base di ppo con fasi cristallino-nanoporose o fasi co-cristalline attive con orientazione delle catene perpendicolari al piano del film e procedure per il loro ottenimento

Citations (2)

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WO2005012402A1 (en) * 2003-07-21 2005-02-10 Universita' Degli Studi Di Salerno Nanoporous and microporous manufacts based on syndiotactic polystyrene and processes for their preparation
WO2008023331A2 (en) * 2006-08-22 2008-02-28 Gaetano Guerra New nanoporous crystalline form of syndiotactic polystyrene, processes for its preparation and related molecular-complex crystalline forms

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IL84797A (en) 1986-12-15 1993-01-14 Montedison Spa Production of crystalline vinyl aromatic polymers having mainly a syndiotactic structure
JP2672589B2 (ja) * 1988-08-31 1997-11-05 出光興産株式会社 スチレン系重合体成形品およびその製造方法
IT1228915B (it) 1989-02-28 1991-07-09 Himont Inc Manufatti in una nuova forma cristallina del polistirene sindiotattico.
US5889069A (en) * 1997-07-15 1999-03-30 The Dow Chemical Company High temperature syndiotactic styrene polymer foam
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KR20020010142A (ko) 1999-05-06 2002-02-02 가즈토 도미나가 스티렌계 중합체로 구성된 흡착체
JP4984360B2 (ja) * 2001-08-24 2012-07-25 東レ株式会社 低誘電率樹脂およびその製造方法
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EP1562551A1 (en) * 2002-11-18 2005-08-17 E.I. du Pont de Nemours and Company Media milling using nonspherical grinding media

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
WO2005012402A1 (en) * 2003-07-21 2005-02-10 Universita' Degli Studi Di Salerno Nanoporous and microporous manufacts based on syndiotactic polystyrene and processes for their preparation
WO2008023331A2 (en) * 2006-08-22 2008-02-28 Gaetano Guerra New nanoporous crystalline form of syndiotactic polystyrene, processes for its preparation and related molecular-complex crystalline forms

Non-Patent Citations (3)

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Title
Direct Formation of γ Form Crystal of Syndiotactic Polystyrene from Amorphous State in Supercritical CO2;Weiming Ma et al.;《Macromolecules》;20040831;第37卷(第18期);第6912-6913页实验部分 *
The mass transport of ethyl acetate in syndiotactic polystyrene;I. J. CHIANG et al.;《Polymer Engineering & Science》;20020404;第42卷(第4期);第725页左栏第15-35行，右栏第37-51行 *
Thermal Transitions of ε Crystalline Phases of Syndiotactic Polystyrene;Paola Rizzo et al.;《Macromolecules》;20071122;第40卷(第26期);图1A中的B曲线，第9471页左栏 *

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Publication number Publication date
US20130280534A1 (en) 2013-10-24
US9328181B2 (en) 2016-05-03
BR112013016801A2 (pt) 2016-10-18
ES2565994T3 (es) 2016-04-08
JP2014504659A (ja) 2014-02-24
EP2658904B1 (en) 2015-12-23
WO2012089805A1 (en) 2012-07-05
IT1404157B1 (it) 2013-11-15
JP5918265B2 (ja) 2016-05-18
CN103384693A (zh) 2013-11-06
EP2658904A1 (en) 2013-11-06
ITMI20102460A1 (it) 2012-07-01

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