CN103382599B - Milk protein fibre, Viloft fiber and blend polyester fabric - Google Patents

Milk protein fibre, Viloft fiber and blend polyester fabric Download PDF

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Publication number
CN103382599B
CN103382599B CN201310340765.5A CN201310340765A CN103382599B CN 103382599 B CN103382599 B CN 103382599B CN 201310340765 A CN201310340765 A CN 201310340765A CN 103382599 B CN103382599 B CN 103382599B
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China
Prior art keywords
fiber
fibre
ceramic powder
milk protein
viloft
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Expired - Fee Related
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CN201310340765.5A
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CN103382599A (en
Inventor
黄璜
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Duo Girl Holding Co., Ltd.
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Yiwu City Jushuang Trading Co Ltd
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Abstract

The present invention discloses a kind of milk protein fibre, Viloft fiber and blend polyester fabric, and the raw material blending adopting following weight part to form has been weaved: 15-25 part milk protein fibre, 30-50 part Viloft fiber, 30-50 part polyster fibre. The milk protein fibre of the present invention, Viloft fiber and blend polyester fabric, quality is merrily and lightheartedly fine and closely woven, and ventilative smooth, fabric gloss gracefulness is luxurious, beautiful in colour, and human body has effect of Glycerin.

Description

Milk protein fibre, Viloft fiber and blend polyester fabric
Technical field
The present invention relates to a kind of fabric, particularly relate to a kind of milk protein fibre, Viloft fiber and blend polyester fabric.
Background technology
Blending chemical & blended fabric is that man-made fiber waits until that with other cotton wool, silk, fiber crops natural fiber mixes the textile product spinning and being made into. Such as: polyester-mixed cotton cloth, wash mao gabardine etc. Such as polyester cotton blending thing take terylene as major ingredient, adopts the textiles that the cotton mixed yarn of 65%-67% terylene and 33%-35% is made into, and it is really cool that polyester-mixed cotton cloth is commonly called as cotton. Feature: not only highlight the style of terylene but also have the strong point of cotton fabric, in dry, wet situation, elasticity and wear resistance are all better, dimensional stabilizing, and washing shrinkage is little, have tall and straight, not easily fold, easily wash, the feature of quick-drying, can not soak with high temperature flatiron and boiling water.
Blended yarn weaved fabric, is the effective combination making various different fiber, has complementary functions between fiber, improve the performance of fiber, expanded the usage space of fiber.
Visible, it is provided that novel blended yarn weaved fabric, meet the different demand of human consumer and become extremely important.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of milk protein fibre, Viloft fiber and blend polyester fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of milk protein fibre, Viloft fiber and blend polyester fabric, the raw material blending adopting following weight part to form has been weaved: 15-25 part milk protein fibre, 30-50 part Viloft fiber, 30-50 part polyster fibre.
The milk protein fibre of the present invention, Viloft fiber and blend polyester fabric can adopt industry universal method first milk protein fibre, Viloft fiber and polyster fibre to be carried out blending, obtained union yarn, then adopt industry universal method to be woven into milk protein fibre, Viloft fiber and blend polyester fabric this union yarn.The preparation method of obvious described blended yarn weaved fabric itself does not have originality, is only adopt prior art, and the innovation part of the present invention is the difference of fabric mixed fibre raw material and proportioning.
Preferably,
Described polyster fibre is anion terylene fiber.
Described anion terylene fiber, containing 0.5-1.5wt% ceramic powder, described ceramic powder is made up of by weight following component: 20-40 part zirconium dioxide, 20-40 part silicon-dioxide, 30-50 part titanium dioxide.
Described anion terylene fiber is also containing coupling agent, and described coupling agent is the 0.5-1.5% of described ceramic powder weight.
Described coupling agent is the one in sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, 1,2-stearin and glyceryl monostearate or its mixture.
Described coupling agent is made up of by weight following component: 30-50 part sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, 20-40 part 1,2-stearin, 30-50 part glyceryl monostearate.
Wherein, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, English name: Isopropyltri (dioctylphosphate) titanate, No. CAS: 65345-34-8. 1,2-stearin, English name: Octadecanoicacid, diesterwith1,2,3-propanetriol, No. CAS: 1323-83-7. Glyceryl monostearate, English name: Monostearin, CAS:123-94-4.
The median size of described ceramic powder is 0.2-0.8 micron.
Concrete, described anion terylene fiber, is prepared from by following step:
(1) by zirconium dioxide, silicon-dioxide and titanium dioxide mixing, the ceramic powder that median size is 0.2-0.8 micron after sintering, it is crushed to;
(2) being mixed with described ceramic powder by coupling agent, obtain modified ceramic powder, the add-on of described coupling agent is the 0.5-1.5wt% of described ceramic powder;
(3) by blended to described modified ceramic powder and terylene, extrude, cut into slices, obtained anion terylene section;
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping, can obtain described anion terylene fiber.
Anion terylene staple fibre the ceramic powder of effective anion releasing to be added in terylene; Further, in order to strengthen the consistency of ceramic powder and terylene, also it is added with coupling agent. The anion terylene staple fibre of the present invention can continue efficient anion releasing, have and regulate the nourishing function such as air, absorption peculiar smell, active cells, raising immunizing power, and the heat energy of thermal source can be absorbed in a large number, and the far infrared rays converting 2-20 micron to is launched to human body, body local is made to produce thermogenetic effect, stimulate circulation, also effectively suppress distributing of human heat simultaneously, there is higher spectral emittance when envrionment temperature is 20-50 DEG C, it is possible to be applied on the products such as underwear dress ornament, bedclothes, adornment.
Below main raw material fiber of the present invention is introduced:
Milk protein fibre is using cow's milk as basic raw material, through dehydration, de-oiling, degreasing, separation, purification, makes it to become a kind of milk casein with linear macromolecule structure; Adopt high-tech means to carry out blended, crosslinked, grafting with polyacrylonitrile again, it is prepared into spinning solution; Finally by wet-spinning fibroblast, solidification, drawing-off, drying, curling, setting, staple fibre cut off (winding filament) become. It is a kind of novel animal protein fibre being different from natural fiber, regenerated fibre and synthon, and people are again its milk filaments, milk fibre.
Milk protein fibre had both been different from the natural fibers such as cotton, fiber crops, silk, hair, and different with chemical fibres such as polyamide fibre, acrylic fibers, terylene and polypropylene fibre again, therefore its performance is between natural fiber and synthon.Its physical and chemical indexes detected value is as follows: dry breaking tenacity >=2.5cn/dtex; The dry ultimate strength variation coefficient≤14%; Dry elongation at break 16.0%-25.0%; The dry elongation at break variation coefficient≤12%; Linear density deviation ratio ± 4.0%; The linear density variation coefficient≤3.5%; Dye uniformity (ash card) >=3-4 level; Moisture regain 4%-6%; Fiber bacteriostasis rate >=80%.
The important source material producing milk fibre is dairy protein, therefore it contains 17 kinds of being rich in nutrition amino acid, also there is natural lasting bacteria resistance function simultaneously, the broad-spectrum antibacterial rate of streptococcus aureus, Candida albicans, fungi, mould is reached the home textile product of more than 80%, due to the effect of activated protein in fiber, human body is had effect of Glycerin. Fabric texture is merrily and lightheartedly fine and closely woven, and ventilative smooth, fabric gloss gracefulness is luxurious, beautiful in colour.
Viloft fiber is produced by the ACORDIS of one of cellulosic fibre manufacturer maximum in the world, its main raw material be the artificial growth forest zone trees coming from nature wood pulp in extract, raw material quantity is big and has recyclability, and resource can not cause predatory exploitation. Environment also can not be polluted by Viloft fiber production process, the auxiliary material, the auxiliary agent that are used are all nontoxic, and major part auxiliary agent and work in-process fiber is all recyclable reuses, its production process meets environmental requirement completely, so Viloft fiber is green novel environment-friendlyfiber fiber, the representative of the novel environment-friendlyfiber fiber in tec fiber epoch.
The feature of Viloft fiber is: (1) soft (2) warming (3) moisture regulates (4) natural matter: raw material 100% comes from nature, and Viloft fiber extract from the wood pulp of artificial growth district trees. (5) ventilation property is good: allow the breathing that skin is comfortable, wears more comfortable. (6) dress is slim and graceful: the functional lining cloth being applicable to doing cotte, sensation smooth comfortable. (7) washing is arranged conveniently: ready-made clothes can be washed at 40 DEG C, both can not be out of shape, and also can not fade. The present invention selects the Viloft fiber of Kelheim company of Germany, ultimate fibre linear density 2.2D.
Terylene is the important kind of in synthon, is the trade name of China's trevira. It is by raw material of pure terephthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) through esterification or transesterify and polycondensation and obtained fiber-forming polymer polyethylene terephthalate (PET), through the fiber that spinning and aftertreatment are made.
Polyster fibre processes the maximum chemical fibre kind of total amount in all textile fibress, develops differential kind, it is to increase added value of product, to improve business economic benefit, the impact of whole chemical fibre industry is most important. Seeing on the whole, China's polyster fibre industry also has very big potentiality to be exploited, and product differentiation is the developing direction of following polyster fibre.
The milk protein fibre of the present invention, Viloft fiber and blend polyester fabric, quality is merrily and lightheartedly fine and closely woven, ventilative smooth, fabric gloss gracefulness is luxurious, beautiful in colour, human body is had effect of Glycerin, after special interpolation anion terylene fiber, more can continue efficient anion releasing, there is nourishing functions such as absorbing peculiar smell, active cells, raising immunizing power.
Embodiment
Embodiment 1
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
By milk protein fibre, Viloft fiber and polyster fibre, adopting artificial mixed in a small amount, volume made by opening picking machinery, and blended sliver made by cotton card;
By above-mentioned blended sliver, obtain described milk protein fibre, Viloft fiber and blend polyester fabric by pre-drawing frame, drawing frame, fly frame, spinning frame and cheese winder successively. Obtained blending yarn, number is 21S, the twist is 330.
Again by above-mentioned obtained milk protein fibre, Viloft fiber and blend polyester fabric, adopting conventional woven method can obtain described milk protein fibre, Viloft fiber and blend polyester fabric, plain goods, fabric gram is heavily 180 grams/m.
Above-mentioned polyster fibre selects 1.32dtex × 38mm carefully special terylene that Yizheng, Jiangsu factory produces, mean length 37.8mm, ultimate fibre breaking tenacity 5.68cN/dtex, elongation 22.8%, overlength fiber 0.07%, oil-containing 0.17%. The Viloft fiber of Kelheim company of Germany selected by above-mentioned Viloft fiber, ultimate fibre linear density 2.2D.
The milk protein fibre of the present invention, Viloft fiber and blend polyester fabric, quality is merrily and lightheartedly fine and closely woven, ventilative smooth, fabric gloss gracefulness is luxurious, beautiful in colour, human body is had effect of Glycerin, after special interpolation anion terylene fiber, more can continue efficient anion releasing, there is nourishing functions such as absorbing peculiar smell, active cells, raising immunizing power.
Embodiment 2
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
Preparation method and raw material composition are substantially the same manner as Example 1, and unique difference is that polyester fiber raw materials is different.
The polyster fibre of the present embodiment is anion terylene fiber.
Described anion terylene fiber adopts following method to be prepared from:
(1) by 30 weight part zirconium dioxides, 30 parts by weight of silica and the mixing of 40 parts by weight of titanium dioxide, the ceramic powder that median size is 0.2-0.8 micron after sintering, it is crushed to;
(2) being mixed in high-speed stirring situation with described ceramic powder by coupling agent, rotating speed can control to obtain modified ceramic powder 500r/min, churning time 3 minutes, and the add-on of described coupling agent is the 1wt% of described ceramic powder;
Described coupling agent is uniformly mixed with 40 weight part glyceryl monostearates by 40 weight part sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, 30 weight part 1,2-stearins;
(3) by blended to described modified ceramic powder and terylene, extruding, cut into slices, obtained anion terylene section, in control anion terylene section, the content of ceramic powder is 1wt%;
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping, can obtain described anion terylene fiber.
Embodiment 3
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
Preparation method and raw material composition are substantially the same manner as Example 2, it is sec.-propyl three (dioctyl phosphoric acid acyloxy) titanate ester monomers that unique difference is in described anion terylene fiber preparation process coupling agent used, instead of the composite coupling agent of embodiment 2.
Embodiment 4
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
Preparation method and raw material composition are substantially the same manner as Example 2, and it is 1,2-stearin monomer that unique difference is in described anion terylene fiber preparation process coupling agent used, instead of the composite coupling agent of embodiment 2.
Embodiment 5
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
Preparation method and raw material composition are substantially the same manner as Example 2, and unique difference is in described anion terylene fiber preparation process coupling agent used is glyceryl monostearate monomer, instead of the composite coupling agent of embodiment 2.
Embodiment 6
The blending mass ratio of milk protein fibre, Viloft fiber, polyster fibre is 20:40:40.
Preparation method and raw material composition are substantially the same manner as Example 2, and unique difference is used in described anion terylene fiber preparation process not add any coupling agent.
Test case 1
According to " SFJJ-QWX25-2006 negative ion concentration inspection detailed rules and regulations " to the milk protein fibre obtained by embodiment 2-6, Viloft fiber and the test of blend polyester fabric.
Negative ion concentration, individual/cubic centimetre
Embodiment 2 1480
Embodiment 3 1260
Embodiment 4 1220
Embodiment 5 1290
Embodiment 6 1170

Claims (2)

1. a milk protein fibre, Viloft fiber and blend polyester fabric, it is characterised in that, the raw material blending adopting following weight part to form has been weaved: 15-25 part milk protein fibre, 30-50 part Viloft fiber, 30-50 part polyster fibre;
Described polyster fibre is anion terylene fiber, and containing 0.5-1.5wt% ceramic powder, described ceramic powder is made up of by weight following component: 20-40 part zirconium dioxide, 20-40 part silicon-dioxide, 30-50 part titanium dioxide;
Described anion terylene fiber is also containing coupling agent, and described coupling agent is the 0.5-1.5% of described ceramic powder weight;
Described coupling agent is made up of by weight following component: 30-50 part sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester, 20-40 part 1,2-stearin, 30-50 part glyceryl monostearate.
2. milk protein fibre as claimed in claim 1, Viloft fiber and blend polyester fabric, it is characterised in that, described anion terylene fiber, is prepared from by following step:
(1) by zirconium dioxide, silicon-dioxide and titanium dioxide mixing, the ceramic powder that median size is 0.2-0.8 micron after sintering, it is crushed to;
(2) coupling agent is mixed with described ceramic powder, obtain modified ceramic powder;
(3) by blended to described modified ceramic powder and terylene, extrude, cut into slices, obtained anion terylene section;
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping.
CN201310340765.5A 2013-08-06 2013-08-06 Milk protein fibre, Viloft fiber and blend polyester fabric Expired - Fee Related CN103382599B (en)

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CN103556338A (en) * 2013-11-11 2014-02-05 海安县中山合成纤维有限公司 Blended yarn of polyester cotton, tencel fiber and milk protein fiber
CN104213305B (en) * 2014-08-20 2016-09-14 浙江富亿达科技股份有限公司 Textile fabric and preparation method thereof on a kind of Novel imitation cotton bed
CN105088488A (en) * 2015-09-25 2015-11-25 太仓市虹鹰印花有限公司 Wear-resistant thermal fabric for sleeping bag
CN109629045B (en) * 2018-12-24 2021-12-31 上海正家牛奶丝科技有限公司 Milk protein fiber recovery and separation method
CN116180285A (en) * 2023-02-01 2023-05-30 张家港市荣昌涤纶毛条有限公司 Composite polyester ultra-soft long cilia strip and preparation method thereof

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