CN103382584B - Anion terylene fiber and preparation method thereof - Google Patents
Anion terylene fiber and preparation method thereof Download PDFInfo
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- CN103382584B CN103382584B CN201310340781.4A CN201310340781A CN103382584B CN 103382584 B CN103382584 B CN 103382584B CN 201310340781 A CN201310340781 A CN 201310340781A CN 103382584 B CN103382584 B CN 103382584B
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- anion terylene
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Abstract
The invention discloses a kind of anion terylene fiber and preparation method thereof, described anion terylene fiber contains 0.2-3wt% ceramic powders, and described ceramic powder is made up of zirconium dioxide, silica and titanium dioxide.Anion terylene staple fibre of the present invention can continue efficient anion releasing, have and regulate the health care such as air, absorption peculiar smell, activating cell, raising immunity, and the heat energy of thermal source can be absorbed in a large number, and the far infrared converting 2-20 micron to is to human-body emitting, body local is made to produce thermogenetic effect, stimulate circulation, also effectively suppress distributing of human heat simultaneously, when environment temperature is 20-50 DEG C, there is higher spectral emissivity, can be applied on the products such as underwear dress ornament, bedding, adornment.
Description
Technical field
The present invention relates to a kind of polyster fibre and preparation method thereof, particularly relate to a kind of anion terylene fiber and preparation method thereof.
Background technology
Terylene is an important kind in synthetic fiber, is the trade name of China's polyester fiber.It is with p-phthalic acid (PTA) or dimethyl terephthalate (DMT) (DMT) and ethylene glycol (EG) for raw material is through esterification or ester exchange and polycondensation reaction and obtained fiber-forming polymer---polyethylene terephthalate (PET), through the fiber that spinning and post processing are made.
Polyster fibre processes the maximum chemical fibre kind of total amount in all textile fabrics, develops differential kind, improves added value of product, to improve Business Economic Benefit, most important on the impact of whole chemical fibre industry.See on the whole, Chinese polyster fibre industry also has very large potentiality to be exploited, and the differentiation of product is the developing direction of following polyster fibre.
People can obviously feel in living environment indoor and outdoors, house and park, city and rural air freshness widely different.If roam leisurely in forest or park, stream is connected in beach and waterfall presensation to fresh air, relaxed and joyful, and this is exactly mainly the effect of anion in air.Anion in air directly acts among the nervous centralis core blood circulation of human body, effectively improves cerebral function, strengthens immunity of organisms, enhances metabolism, regulates nervous function.Eliminate human-body fatigue.Anion can also effect of anti-bacteria viral growth.
Develop a anion terylene fiber and just seem particularly important.
Summary of the invention
For the deficiencies in the prior art, one of technical problem to be solved by this invention is to provide a kind of anion terylene fiber.
For the deficiencies in the prior art, the youngster of technical problem to be solved by this invention is to provide a kind of preparation method of ion polyster fibre.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of anion terylene fiber, containing 0.2-3wt% ceramic powders, described ceramic powder is made up of zirconium dioxide, silica and titanium dioxide.
Preferably,
A kind of anion terylene fiber, containing 0.5-1.5wt% ceramic powders, described ceramic powder is made up of by weight following component: 20-40 part zirconium dioxide, 20-40 part silica, 30-50 part titanium dioxide.
Described anion terylene fiber is also containing coupling agent, and described coupling agent is the 0.5-1.5% of described ceramic powder weight.
Described coupling agent is one in isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, 1,2-tristerin and glycerin monostearate or its mixture.
Optimally, described coupling agent is made up of by weight following component: 30-50 part isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, 20-40 part 1,2-tristerin, 30-50 part glycerin monostearate.
Wherein, isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, English name: Isopropyltri (dioctylphosphate) titanate, No. CAS: 65345-34-8.1,2-tristerin, English name: Octadecanoic acid, diester with1,2,3-propanetriol, No. CAS: 1323-83-7.Glycerin monostearate, English name: Monostearin, CAS:123-94-4.
The average grain diameter of described ceramic powder is 0.2-0.8 micron.
Present invention also offers a kind of preparation method of anion terylene fiber, be made up of following step:
(1) zirconium dioxide, silica and titanium dioxide are mixed, after sintering, are crushed to the ceramic powder that average grain diameter is 0.2-0.8 micron,
(2) mixed with described ceramic powder by coupling agent, obtain modified ceramic powder, the addition of described coupling agent is the 0.5-1.5wt% of described ceramic powder;
(3) by described modified ceramic powder and terylene blended, extrude, cut into slices, obtained anion terylene section;
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping, can obtain described anion terylene fiber.
Anion terylene staple fibre of the present invention the ceramic powder of effective anion releasing to be added in terylene; Further, in order to strengthen the compatibility of ceramic powder and terylene, also coupling agent is added with.Anion terylene staple fibre of the present invention can continue efficient anion releasing, have and regulate the health care such as air, absorption peculiar smell, activating cell, raising immunity, and the heat energy of thermal source can be absorbed in a large number, and the far infrared converting 2-20 micron to is to human-body emitting, body local is made to produce thermogenetic effect, stimulate circulation, also effectively suppress distributing of human heat simultaneously, when environment temperature is 20-50 DEG C, there is higher spectral emissivity, can be applied on the products such as underwear dress ornament, bedding, adornment.
Detailed description of the invention
Embodiment 1:
(1) 30 weight portion zirconium dioxides, 30 parts by weight of silica and 40 parts by weight of titanium dioxide are mixed, after sintering, be crushed to the ceramic powder that average grain diameter is 0.2-0.8 micron.
(2) coupling agent and described ceramic powder are uniformly mixed, rotating speed 400r/min, mixing time 3 minutes, obtains modified ceramic powder, and the addition of described coupling agent is the 1wt% of described ceramic powder;
Described coupling agent is uniformly mixed by 40 weight portion isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, 30 weight portion 1,2-tristerins and 40 weight portion glycerin monostearates and forms.
(3) by described modified ceramic powder and terylene blended, extrude, cut into slices, obtained anion terylene section, the content controlling ceramic powders in anion terylene section is 1wt%.
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping, can obtain described anion terylene fiber.
According to " SFJJ-QWX25-2006 negative ion concentration inspection detailed rules and regulations " test, this anion terylene fiber, negative ion concentration is 4200/cubic centimetre.
Embodiment 2:
Embodiment 2 is substantially the same manner as Example 1, and its difference is: coupling agent used is isopropyl three (dioctyl phosphoric acid acyloxy) titanate ester monomers.This anion terylene fiber, negative ion concentration is 3960/cubic centimetre.
Embodiment 3:
Embodiment 3 is substantially the same manner as Example 1, and its difference is: coupling agent used is 1,2-tristerin monomer.This anion terylene fiber, negative ion concentration is 3890/cubic centimetre.
Embodiment 4:
Embodiment 4 is substantially the same manner as Example 1, and its difference is: coupling agent used is glycerin monostearate monomer.This anion terylene fiber, negative ion concentration is 3870/cubic centimetre.
Embodiment 5:
Embodiment 5 is substantially the same manner as Example 1, and its difference is: do not add and anyly add coupling agent.This anion terylene fiber, negative ion concentration is 3550/cubic centimetre.
Visible employing coupling agent can modified ceramic powder more effectively, strengthens the compatibility of itself and terylene, improves the bonding interface situation of material system, have good lifting to the anion effect of product.Particularly, adopt specific composite coupling agent, improve effect more obvious.
Claims (3)
1. an anion terylene fiber, is characterized in that, containing 0.5-1.5wt% ceramic powders, described ceramic powder is made up of by weight following component: 20-40 part zirconium dioxide, 20-40 part silica, 30-50 part titanium dioxide;
Described anion terylene fiber is also containing coupling agent, and described coupling agent is the 0.5-1.5% of described ceramic powder weight;
Described coupling agent is made up of by weight following component: 30-50 part isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters, 20-40 part 1,2-tristerin, 30-50 part glycerin monostearate.
2. anion terylene fiber as claimed in claim 1, it is characterized in that, the average grain diameter of described ceramic powder is 0.2-0.8 micron.
3. the preparation method of anion terylene fiber as claimed in claim 1 or 2, is characterized in that, be made up of following step:
(1) zirconium dioxide, silica and titanium dioxide are mixed, after sintering, are crushed to the ceramic powder that average grain diameter is 0.2-0.8 micron,
(2) mixed with described ceramic powder by coupling agent, obtain modified ceramic powder, the addition of described coupling agent is the 0.5-1.5wt% of described ceramic powder;
(3) by described modified ceramic powder and terylene blended, extrude, cut into slices, obtained anion terylene section;
(4) by described anion terylene section heating and melting, extruding, spray silk is shaping, can obtain described anion terylene fiber.
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| CN201310340781.4A CN103382584B (en) | 2013-08-06 | 2013-08-06 | Anion terylene fiber and preparation method thereof |
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| CN201310340781.4A CN103382584B (en) | 2013-08-06 | 2013-08-06 | Anion terylene fiber and preparation method thereof |
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| CN103382584A CN103382584A (en) | 2013-11-06 |
| CN103382584B true CN103382584B (en) | 2015-10-28 |
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| CN103710784B (en) * | 2013-12-18 | 2016-01-20 | 广州市中诚新型材料科技有限公司 | A kind of anion polyester fiber and preparation method thereof |
| CN104480565B (en) * | 2015-01-15 | 2016-06-15 | 宁波保税区韬鸿化工科技有限公司 | Anion healthy polyster fibre |
| CN106702572A (en) * | 2016-12-29 | 2017-05-24 | 郑州德惠纺织科技有限公司 | Anion containing bamboo carbon fiber quilt with antibacterial and deodorizing functions and preparation method of bamboo carbon fiber quilt |
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| CN110253991A (en) * | 2019-06-11 | 2019-09-20 | 南通北岸纺织科技有限公司 | A kind of fabric of waterproof antiwear and preparation method thereof |
| CN110359158A (en) * | 2019-06-20 | 2019-10-22 | 南通明富纺织品有限公司 | A kind of moisture absorbing and sweat releasing and the polyester fabric of antibacterial and preparation method thereof |
| CN114457454A (en) * | 2022-03-04 | 2022-05-10 | 苏州世祥生物纤维有限公司 | Functional stock solution coloring fiber and preparation method and application thereof |
| CN114622294A (en) * | 2022-03-29 | 2022-06-14 | 苏州世祥生物纤维有限公司 | Functional stock solution coloring master batch and preparation method and application thereof |
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| JPS6112908A (en) * | 1984-06-28 | 1986-01-21 | Hoton Ceramic Kk | Textile product containing ceramic powder |
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Inventor after: Li Wei Inventor before: Yuan Juan |
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Effective date of registration: 20160413 Address after: 362256 Fujian city of Quanzhou province Jinjiang City Ying Lin Industrial Zone of Jinjiang town Patentee after: FUJIAN JINXING ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Patentee before: SHANGHAI WANJING TEXTILE SCIENCE & TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20151028 |