CN1272561A - Alkali-resistant basalt continuous fibre and its production method - Google Patents
Alkali-resistant basalt continuous fibre and its production method Download PDFInfo
- Publication number
- CN1272561A CN1272561A CN 00110460 CN00110460A CN1272561A CN 1272561 A CN1272561 A CN 1272561A CN 00110460 CN00110460 CN 00110460 CN 00110460 A CN00110460 A CN 00110460A CN 1272561 A CN1272561 A CN 1272561A
- Authority
- CN
- China
- Prior art keywords
- alkali
- raw material
- basalt
- temperature
- wire drawing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003513 alkali Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000000835 fiber Substances 0.000 title claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 238000009987 spinning Methods 0.000 claims abstract description 5
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000010436 fluorite Substances 0.000 claims abstract description 4
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract 3
- 238000005491 wire drawing Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000004513 sizing Methods 0.000 claims description 7
- 238000013467 fragmentation Methods 0.000 claims description 6
- 238000006062 fragmentation reaction Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 238000007885 magnetic separation Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 5
- 239000007769 metal material Substances 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000011810 insulating material Substances 0.000 abstract 1
- 238000010309 melting process Methods 0.000 abstract 1
- 239000004568 cement Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229940085805 fiberall Drugs 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The present invention relates to an alkali-resistant basalt continuous fibre and its production method, belonging to the field of inorganic non-metallic material alkali-resistant fibre development technology. Its production method includes four steps of raw material preparation, melting, drawing and spinning. Its raw material is formed from basalt powder, fluorite powder and zircon powder which are mixed according to a certain weight ratio, and its melting process includes the steps of melting, clarifying, operating and bushing-forming. Said invention is simple in production process, low in cost, its product has excellent physical and chemical properties, can be substituted for alkali-resisting glass fibre and other fibre, and can be used as fire-resisting, heat-insulating and electric insulating material, etc..
Description
What the present invention announced is a kind of Inorganic Non-metallic Materials, alkali-resistant basalt continuous fibre and manufacture method thereof.
At present, the research and the application of alkali resistant glass fiber all paid much attention in countries in the world, and the country that particularly forbids asbestos especially payes attention to, in order that substitute asbestos with it.Again because alkali resistant glass fiber refinforced cement composite in building industry, widely apply, a large amount of alkali resistant glass fibers just must be arranged as raw material, but alkali resistant glass fiber must with the compound use of low basicity high-early (strength) cement, this manufacture of cement cost is very high.And alkali resistant glass fiber can not with the compound use of Portland cement.Yet the production technology of alkali resistant glass fiber is very complicated again, and cost is very high.Therefore can find out a kind of emphasis problem that can substitute alkali resistant glass fiber, reduce the production cost of complex cement member, can become various countries to research and develop again with the Inorganic Non-metallic Materials of the compound use of ordinary cement.Up to the present, also in related publication, do not deliver, or use aborning with like products of the present invention and manufacture method thereof.
The purpose of this invention is to provide that a kind of manufacture method is simple, the alternative alkali resistant glass fiber of product, have the alkali-resistant basalt continuous fibre of good physics, chemistry, mechanical mechanics property and its manufacture method again.
The present invention is that as described below technical scheme is achieved.Its manufacture method by feedstock production, found, wire drawing, move back and spin four operations and form.
One, feedstock production
The basalt ore is a base volcano effusive rock widely distributed on the earth, because widely distributed, its formation condition, geological structure difference are so its physical and chemical composition is also inequality.Therefore must select for use the physical and chemical composition index to meet the ore of drawing process needs, through test, its main component should be:
| Composition | ????SiO 2 | ??AL 2O 3 | ??Fe 2O 3 | ??TiO 2 | CaO | ??MgO | ?K 2O | ?Na 2O |
| ?We％ | ??45～50 | ??12～18 | ??6～10 | ??1～3 | 6～12 | ??5～6 | ?1～4 | ?1～5 |
Then, the basalt ore is carried out fragmentation, magnetic separation, be mixed with the raw material of making alkali proof fiber.Fragmentation can be selected palate crusher, the violent pulverizer of thunder for use.Breeze after the fragmentation requires to reach 40～60 orders.
Breeze after fragmentation, deironing.Sneak into fluorite powder, zircon powder again and can be made into the raw material of alkaline-resisting continuous fibers.Its prescription is:
Raw material title percentage by weight
Basalt powder 85.0～90.0%
Fluorite powder 1.0～5.0%
Zircon powder 5.0～10.0%
Before mixing, also to carry out deironing for three kinds of raw material and handle, still adopt magnetic separator to carry out magnetic separation and handle.Mixing for standby use again after pending.
Two, found
The process of founding is to finish in the high temperature melting furnaces.The raw material of the some of under kiln normal temperature, packing into earlier, the heating-up furnace that heats up then, along with the continuous rising of temperature, additional fillers constantly is till the design capacity that reaches stove.Raw material is fused into glassy fused mass in stove.At this moment stove temperature is controlled in 1450～1550 ℃ of scopes.Along with the continuous fusion of raw material, continuous filler, the raw material after the fusion passes through fining end, passage, homework department respectively to rear flow.It is that 1425～1485 ℃, passage are that 1295～1305 ℃, homework department are 1280～1250 ℃ that temperature during this is controlled at fining end respectively, and the last bushing temperature of homework department is controlled at 1200～1220 ℃.More than each temperature requirement in 24 hours, must not fluctuate and surpass ± 10 ℃, the bushing temperature fluctuation must not be above ± 3 ℃.
Three, wire drawing
After raw material passes through the bushing moulding at last through each one of stove, handle through sizing agent.Soak into to handle and be provided with the sizing agent groove in the wire drawing machine front portion exactly, interior dress sizing agent.Soaking into processing is will pull out silk through a sizing agent groove, makes fiber surface coated one deck sizing agent.Directly deliver to wire drawing machine then and carry out the high temperature wire drawing.Wire drawing machine is selected automatic creeling wire drawing machine for use.The head rotating speed is controlled at 3500～7000 rev/mins.Pull out filametntary diameter requirement at 6～20 μ.The prescription of its sizing agent is: (percentage by weight)
Water soluble phenol resin 2.0～2.5
Color-fixing agent 2.0～3.0
Polyvinyl acetate emulsion 3.0～3.5
EL--40 (castor oil) 0.3～0.5
KH--550 (silane coupler) 0.3～0.5
Water 90.0～92.4
Four, move back also spinning process
The alkali-resistant basalt continuous fibre that wire drawing machine is pulled out at first is to be wrapped on the bobbins, by operations such as unwinding, plying and spinning, can weave various needed products.Adopt MB-III type roving machine, can move back and separate into the multistrand yarn roving, adopt 150B-I type or II type spinning machine, can move back and separate into sub-thread, plying has twist yarn, its twist can be controlled in 80～200 sth. made by twisting scopes.
The composition of alkali-resistant basalt continuous fibre of the present invention is as follows:
Ingredient w e (%)
SiO
2???????????????????45.0～55.0
Al
2O
3?????????????????12.0～15.0
Fe
2O
3?????????????????9.0～12.0
TiO
2???????????????????2.0～3.0
CaO?????????????????????5.0～8.0
MgO?????????????????????5.0～8.0
K
2O????????????????????1.5～3.0
Na
2O???????????????????2.0～3.5
ZrO
2???????????????????3.0～10.0
Production technology of the present invention is simple, and raw material sources are abundant, low cost of manufacture, and the product of producing is a kind of broad-spectrum Inorganic Non-metallic Materials.Have good physical and chemical performance, compare with alkali-resistant glass fibre with the simple glass fiber, its tensile strength height, elastic modelling quantity is big, and chemical stability is good, and production cost is low.Alternative alkali-free, middle alkali, high-alkali and alkali resistant glass fiber.Can be as the refinforced cement composite.Also can be as fire prevention, insulation, insulation, material such as ageing-resistant, corrosion-resistant.Purposes is very extensive.
The present invention does not have accompanying drawing
Enforcement of the present invention relates to professional equipment, can adopt state-of-the-art in the world all-electric melting tank furnace fused basalt ore, whole kiln is divided into melting end, fining end, four parts of passage and homework department, and such furnace construction helps temperature and controls degree and precision automatically.
Kiln is to adopt 33
#With 41
#Electro-corundum brick and natural white afrodite are built by laying bricks or stones as refractory material and are formed.Electrode is to adopt the thick molybdenum plate of 8mm to process.Kiln temperature adopts the silicon-controlled conversion Regulation Control.Adopt thermocouple to carry out the kiln temperature monitoring.Kiln forming wire drawing bushing is made with platinum rhodium (Pt-Rh) alloy.Hole count in 200 holes～400 holes.The aperture requires to decide according to drawing fiber at 1.6～2.2mm.Requirement operation according to this specification the 5th part can realize.
The main performance of alkali-resistant basalt continuous fibre is an alkali resistance, the assay method of its alkaline resistance properties has two: the one, this fiber was soaked 4 hours in 100 ℃ saturated Ca (OH) 2 solution, the tensile strength of fiber is answered＞800Mpa, filament strength retention rate＞75%, the percentage reduction of diameter＜10%.
The 2nd, this fiber soaked one hour in 100 ℃, 10% NaOH solution after, its rate of mass reduction＜5.0%.Meet one of above-mentioned two conditions person, promptly be considered to qualified alkali-resistant basalt continuous fibre.
Claims (3)
1. alkali-resistant basalt continuous fibre is characterized in that its contained composition is: (percentage by weight)
Ingredient w e (%)
SiO
2???????????????????45.0～55.0
Al
2O
3?????????????????12.0～15.0
Fe
2O
3?????????????????9.0～12.0
TiO
2???????????????????2.0～3.0
CaO?????????????????????5.0～8.0
MgO?????????????????????5.0～8.0
K
2O????????????????????1.5～3.0
Na
2O???????????????????2.0～3.5
ZrO
2???????????????????3.0～10.0
2. the manufacture method of alkali-resistant basalt continuous fibre, by feedstock production, found, wire drawing and move back and spinning process is formed, it is characterized in that:
One, feedstock production
Feedstock production comprises ore dressing and preparation, and the main component of the basalt ore of selection should be:
Composition ??SiO
2 ?Al
2O
3 ??Fe
2O
3 ?TiO
2 ?CaO ?MgO ?K
2O
?Na
2O
?We％ ??45～50 ?12～18 ??6～10 ?1～3 ?6～12 ?5～6 ?1～4 ?1～5
Then the basalt ore is carried out fragmentation, the breeze after the fragmentation requires to reach 40～60 orders.Carrying out magnetic separation again handles.
Preparation of raw material:
Raw material title percentage by weight
Basalt powder 85.0～90.0%
Fluorite powder 1.0～5.0%
Zircon powder 5.0～10.0%
Before mixing, also to carry out magnetic separation for three kinds of raw material and handle,
Two, found
The process of founding is to finish in the high temperature melting furnaces, the stove temperature is controlled in 1450～1550 ℃ of scopes, it is that 1295～1305 ℃, homework department are 1280～1250 ℃ that the fining end temperature is controlled at 1425～1485 ℃, passage, the last bushing temperature of homework department is controlled at 1200～1220 ℃, more than each temperature requirement in 24 hours, must not fluctuate and surpass ± 10 ℃, the bushing temperature fluctuation is not
Must surpass ± 3 ℃,
Three, wire drawing
Wire drawing machine is selected automatic creeling wire drawing machine for use, and the head revolution is controlled at 3500～7000 rev/mins, pulls out the requirement of filament diameter at 6～20 μ, behind the wire-drawing shape, also will soak into processing.
3. method according to claim 2 is characterized in that the prescription of said sizing agent is: (percentage by weight)
Water soluble phenol resin 2.0～2.5
Color-fixing agent 2.0～3.0
Polyvinyl acetate emulsion 3.0～3.5
EL--40 (castor oil) 0.3～0.5
KH--550 (silane coupler) 0.3～0.5
Water 90.0～92.4
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00110460A CN1100166C (en) | 2000-05-26 | 2000-05-26 | Alkali-resistant basalt continuous fibre and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00110460A CN1100166C (en) | 2000-05-26 | 2000-05-26 | Alkali-resistant basalt continuous fibre and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1272561A true CN1272561A (en) | 2000-11-08 |
| CN1100166C CN1100166C (en) | 2003-01-29 |
Family
ID=4580449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00110460A Expired - Fee Related CN1100166C (en) | 2000-05-26 | 2000-05-26 | Alkali-resistant basalt continuous fibre and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1100166C (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838885A (en) * | 2010-05-10 | 2010-09-22 | 泰安鲁普耐特塑料有限公司 | Method for producing basalt fiber rope net |
| CN101982442A (en) * | 2010-10-27 | 2011-03-02 | 朱奎 | Heat reserving brick for curing room |
| US8037719B2 (en) | 2005-06-20 | 2011-10-18 | Toyota Jidosha Kabushiki Kaisha | Method for manufacturing basalt fiber |
| CN102583995A (en) * | 2012-02-20 | 2012-07-18 | 河北通辉科技有限责任公司 | High-strength high-purity basalt continuous fiber production technique |
| CN103382584A (en) * | 2013-08-06 | 2013-11-06 | 上海婉静纺织科技有限公司 | Negative ion polyester fiber and preparing method thereof |
| CN103964697A (en) * | 2014-04-23 | 2014-08-06 | 东南大学 | Basalt fiber composition with high alkali resistance and application method of basalt fiber composition |
| CN104059374A (en) * | 2014-06-25 | 2014-09-24 | 四川航天五源复合材料有限公司 | Basalt fiber complex stirrup |
| RU2540676C2 (en) * | 2013-02-13 | 2015-02-10 | Закрытое акционерное общество "Институт новых углеродных материалов и технологий" (ЗАО "ИНУМиТ") | Method of obtaining continuous basalt-based fibre |
| CN106242305A (en) * | 2016-09-05 | 2016-12-21 | 东南大学 | Continuous basalt fiber production technology |
| CN109023166A (en) * | 2017-06-12 | 2018-12-18 | 南京天淦新材料科技有限公司 | A kind of aluminium the enhancing high sial magnesium material of amorphous and Preparation method and use |
| CN109052974A (en) * | 2018-06-27 | 2018-12-21 | 四川省玻纤集团有限公司 | A kind of distribution of basalt fibre, mineral mixture and production technology |
| CN109052975A (en) * | 2018-06-27 | 2018-12-21 | 四川省玻纤集团有限公司 | A kind of basalt fibre and its production technology |
| CN109879598A (en) * | 2019-04-24 | 2019-06-14 | 衡水瑞纤新材料科技有限公司 | A kind of high alkaline-resisting basalt fibre composition |
| CN109896748A (en) * | 2019-04-24 | 2019-06-18 | 衡水瑞纤新材料科技有限公司 | A kind of high-modulus basalt fibre composition |
| CN112209622A (en) * | 2019-07-10 | 2021-01-12 | 贵州玄武岩新材料工程技术开发有限公司 | Basalt fiber monomer furnace wire drawing process |
| CN116354608A (en) * | 2023-02-14 | 2023-06-30 | 华润水泥技术研发有限公司 | Multi-mineral combined alkali-resistant basalt fiber raw material formula and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE547386T1 (en) * | 2006-05-19 | 2012-03-15 | Kibol Viktor F | METHOD FOR PRODUCING CONTINUOUS BASALT FIBER |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2118300C1 (en) * | 1996-11-19 | 1998-08-27 | Людмила Григорьевна Асланова | Method and device for production of basalt fiber |
| CN1057070C (en) * | 1998-04-01 | 2000-10-04 | 鸡西市梨树区人民政府 | Continuous basalt fiber and its production technology |
| CN1210094A (en) * | 1998-09-17 | 1999-03-10 | 李洪安 | Method, apparatus and products of alkaliproof basalt fibers |
-
2000
- 2000-05-26 CN CN00110460A patent/CN1100166C/en not_active Expired - Fee Related
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8037719B2 (en) | 2005-06-20 | 2011-10-18 | Toyota Jidosha Kabushiki Kaisha | Method for manufacturing basalt fiber |
| US8501643B2 (en) | 2005-06-20 | 2013-08-06 | Toyota Jidosha Kabushiki Kaisha | Method for manufacturing basalt fiber |
| CN101838885A (en) * | 2010-05-10 | 2010-09-22 | 泰安鲁普耐特塑料有限公司 | Method for producing basalt fiber rope net |
| CN101982442A (en) * | 2010-10-27 | 2011-03-02 | 朱奎 | Heat reserving brick for curing room |
| CN101982442B (en) * | 2010-10-27 | 2012-09-12 | 朱奎 | Heat reserving brick for curing room |
| CN102583995A (en) * | 2012-02-20 | 2012-07-18 | 河北通辉科技有限责任公司 | High-strength high-purity basalt continuous fiber production technique |
| RU2540676C2 (en) * | 2013-02-13 | 2015-02-10 | Закрытое акционерное общество "Институт новых углеродных материалов и технологий" (ЗАО "ИНУМиТ") | Method of obtaining continuous basalt-based fibre |
| CN103382584B (en) * | 2013-08-06 | 2015-10-28 | 上海婉静纺织科技有限公司 | Anion terylene fiber and preparation method thereof |
| CN103382584A (en) * | 2013-08-06 | 2013-11-06 | 上海婉静纺织科技有限公司 | Negative ion polyester fiber and preparing method thereof |
| CN103964697A (en) * | 2014-04-23 | 2014-08-06 | 东南大学 | Basalt fiber composition with high alkali resistance and application method of basalt fiber composition |
| CN103964697B (en) * | 2014-04-23 | 2016-01-06 | 东南大学 | A kind of high alkali-resistant basalt fiber composition and application method thereof |
| CN104059374A (en) * | 2014-06-25 | 2014-09-24 | 四川航天五源复合材料有限公司 | Basalt fiber complex stirrup |
| CN106242305B (en) * | 2016-09-05 | 2019-05-21 | 东南大学 | Continuous basalt fiber production technology |
| CN106242305A (en) * | 2016-09-05 | 2016-12-21 | 东南大学 | Continuous basalt fiber production technology |
| CN109023166A (en) * | 2017-06-12 | 2018-12-18 | 南京天淦新材料科技有限公司 | A kind of aluminium the enhancing high sial magnesium material of amorphous and Preparation method and use |
| CN109052974A (en) * | 2018-06-27 | 2018-12-21 | 四川省玻纤集团有限公司 | A kind of distribution of basalt fibre, mineral mixture and production technology |
| CN109052975A (en) * | 2018-06-27 | 2018-12-21 | 四川省玻纤集团有限公司 | A kind of basalt fibre and its production technology |
| CN109879598A (en) * | 2019-04-24 | 2019-06-14 | 衡水瑞纤新材料科技有限公司 | A kind of high alkaline-resisting basalt fibre composition |
| CN109896748A (en) * | 2019-04-24 | 2019-06-18 | 衡水瑞纤新材料科技有限公司 | A kind of high-modulus basalt fibre composition |
| CN112209622A (en) * | 2019-07-10 | 2021-01-12 | 贵州玄武岩新材料工程技术开发有限公司 | Basalt fiber monomer furnace wire drawing process |
| CN116354608A (en) * | 2023-02-14 | 2023-06-30 | 华润水泥技术研发有限公司 | Multi-mineral combined alkali-resistant basalt fiber raw material formula and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1100166C (en) | 2003-01-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1100166C (en) | Alkali-resistant basalt continuous fibre and its production method | |
| CN102482142B (en) | What improve modulus does not contain lithium glass | |
| AU692712B2 (en) | Boron-free glass fibers | |
| JP5458228B2 (en) | Glass composition with resistance to chemical media for the production of glass reinforced yarns | |
| CN111892302B (en) | Low-cost glass fiber composition with good alkali resistance and glass fiber | |
| JPS62288137A (en) | Alkali-resistant glass fiber | |
| CN111533442B (en) | Corrosion-resistant glass composition and preparation method thereof | |
| CN107216042A (en) | A kind of high-modulus glass fiber composition and glass fibre | |
| CN112125528B (en) | High modulus glass fiber with excellent alkali resistance and preparation method thereof | |
| CN103228591A (en) | Glass composition for producing high strength and high modulus fibers | |
| CN107082569A (en) | A kind of glass fiber compound and glass fibre | |
| CN109982982B (en) | Glass composition for glass fiber, and method for producing glass fiber | |
| CN101575172A (en) | Glass fiber compound | |
| CN107056075A (en) | Glass fiber compound and glass fibre | |
| KR101887211B1 (en) | Temperature-resistant aluminosilicate glass fibers and method for the production thereof and use thereof | |
| CN103025673A (en) | Glass composition for producing high strength and high modulus fibers | |
| CN108395109A (en) | A kind of high-modulus glass fiber composition and glass fibre | |
| CN1566005A (en) | Method for manufacturing continuous fibre using basalt ore | |
| CN108609859A (en) | A kind of novel high-modulus glass fiber composition and glass fibre | |
| CN1210094A (en) | Method, apparatus and products of alkaliproof basalt fibers | |
| CN111433166A (en) | Glass fiber and method for producing same | |
| DE2656002A1 (en) | Glass fibres for reinforcing concrete and cement - contg. silica, zirconia, alumina, lime and magnesia | |
| CN108503227A (en) | A kind of high-performance glass fiber composition and glass fibre | |
| CN108455863B (en) | Lanthanum-doped phosphate alkali-resistant glass fiber and preparation method thereof | |
| CN116023035B (en) | Glass composition, glass fiber, composite material and glass fiber preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: QIU YINGDONG Free format text: FORMER OWNER: YINGKOU MATERIALS SCIENCE INSTITUTE Effective date: 20100301 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 115000 NO.22, NANPINGLI, ZHANQIAN DISTRICT, YINGKOU CITY, LIAONING PROVINCE TO: 100121 HOUSE 430, YARD 58, LANGXINZHUANG NORTH ROAD, CHAOYANG DISTRICT, BEIJING CITY |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20100301 Address after: 100121, Beijing, Chaoyang District, 58 Xin Xin North Road, No. 430 hospital building Patentee after: Qiu Yingdong Address before: 115000 No. 22, Nanping lane, Yingkou District, Liaoning Patentee before: Yingkou Inst. of Building Material Sciences Effective date of registration: 20100301 Address after: 100121, Beijing, Chaoyang District, 58 Xin Xin North Road, No. 430 hospital building Patentee after: Qiu Yingdong Address before: 115000 No. 22, Nanping lane, Yingkou District, Liaoning Patentee before: Yingkou Inst. of Building Material Sciences |
|
| DD01 | Delivery of document by public notice |
Addressee: Li Hongan Document name: Notification of Passing Examination on Formalities Addressee: Li Hongan Document name: Notification of Passing Examination on Formalities |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030129 Termination date: 20190526 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |