CN102583995A - High-strength high-purity basalt continuous fiber production technique - Google Patents
High-strength high-purity basalt continuous fiber production technique Download PDFInfo
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- CN102583995A CN102583995A CN201210037392XA CN201210037392A CN102583995A CN 102583995 A CN102583995 A CN 102583995A CN 201210037392X A CN201210037392X A CN 201210037392XA CN 201210037392 A CN201210037392 A CN 201210037392A CN 102583995 A CN102583995 A CN 102583995A
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Abstract
The invention discloses a high-strength high-purity basalt continuous fiber production technique which comprises the main procedures of selection, quarrying, crushing, screening, cleaning, picking, charging, founding by heating up, filament cooling, bushing, drawing, conserving by atomizing, infiltration, clustering, winding, yarn driving, detwisting and finished product inspection. During selection, natural basalt is used as a single component raw material, and natural basalt with uniform crystalline structure and high purity is selected. The basic oxide acidity modulus: MK= (SiO2+Al2O3)/(CaO+MgO), the basic oxide acidity modulus is maintained within the range of 4.3-5.8, and meanwhile, Fe2O3+FeO is controlled between 8-15%. The average fracture strength of the produced continuous fiber base yarn can be stabilized within 0.6-0.7 N/tex and is 50-75% higher than 0.4 N/tex specified by national standards, and the filamentation rate is increased by 10%. The technique has easiness and convenience for operation, stable production and low cost, the technical process is friendly to environment and free of pollution, and the product quality is obvious improved.
Description
Technical field
The present invention relates to a kind of production technique of inorganic non-metallic fiber, relate in particular to the production technique of the pure basalt continuous fiber of a kind of high-performance novel high-strength.
Background technology
The basalt continuous fiber high-strength light, and have excellent properties such as high temperature resistant, anti-oxidant, radioprotective, thermal insulation, insulation, sound insulation.Can be widely used in fields such as fire-fighting, environmental protection, Aeronautics and Astronautics, military project, automobile, shipbuilding, communications and transportation, electric, equipment protection, communal facility, chemical building, simultaneously; It in process of production; No obnoxious flavour, discharge of wastewater; Not producing waste residue, is pollution-free not carcinogenic green material.Basalt continuous fiber is to be the filamentary material that raw material is processed by natural basalt, however the difference at the zone that distributes because of its Irish touchstone ore, ore deposit point, aspect, position, its basic oxide compound attribute content also there are differences, and the Chemical Composition fluctuation is bigger.And wherein some oxide compound fusing point is higher, do not have fixed fusing point, melt diathermancy poor, be prone to crystallization, material property is short, wetting angle is little.Thereby, be difficult to stably produce high performance high-quality basalt continuous fiber according to existing manufacturing technique.Some producer is in order to pursue manufacturability; Production technique with reference to glass; Artificially having added some other raw mineral materialss makes up; Had a strong impact on the due quality of basalt continuous fiber, caused the reduction of the fundamental propertys such as intensity, chemicalstability, thermostability of fiber, so press for research and development and improve a kind of comparatively production technique of suitable high-strength pure basalt continuous fiber.
High-strength pure basalt continuous fiber, be by a kind of natural basalt as single component raw material, be pulled through founding.Irish touchstone is to be formed after cooling off by the lava flow that volcanic explosion is sprayed and spoiled over out; Because of the abundant fusion migration of the lava high pressure-temperature in 1 years of magma chamber under the earth's crust; Spray and spoil over through outburst suddenly again; So lava is the slaking homogeneous already, toxic gas volatilizees totally already, and has characteristics such as significant acid and alkali-resistance, high temperature resistant, physicochemical property be stable.
Irish touchstone is the product of volcanic explosion, and is very wide in distribution on global, and volcanic explosion is the geological phenomenon of Earth Activities, has with living.Because of differences such as its geological age, regional distribution, tectonic structure, power mechanism, magmatic origin, migration process, land occupation conditions; And general Irish touchstone mineral deposit is many at the repeatedly dissimilar compound ore body of the stratiform that outburst built up of different periods warps; So the Irish touchstone ore between different distributed areas, ore deposit point and each aspect, the position, its oxide compound attribute and content and Chemical Composition all have than great fluctuation process.
Summary of the invention
Influence the due quality of basalt continuous fiber in order to overcome the deficiency of existing technology, to solve, cause the problem of the fundamental property reductions such as intensity, chemicalstability, thermostability of fiber, a kind of high-strength pure basalt continuous fiber production technique is provided.
The technical scheme that the present invention solves its technical problem can be:
High-strength pure basalt continuous fiber production technique; Master operation by select, quarry, broken screening is cleaned, pick, feed intake, heat up found, the cooling of silk root, bushing wire drawing, fog curing, infiltration, boundling twine, dry by the fire yarn, move back also and inspection after construction; Its described selecting is as single component raw material with a kind of natural basalt; Natural basalt is selected the crystalloid even structure for use, and purity is high, acid modulus: the MK=(Sio2+Al2o3)/(Cao+Mgo) of basic oxide compound; The acid modulus of basic oxide compound remains in the 4.3-5.8 scope, and Fe2o3+Feo is controlled between the 8-15% simultaneously.
The technical scheme that the present invention solves its technical problem also can be:
Described high-strength pure basalt continuous fiber production technique, its described quarrying are that according to selecting definite ore deposit point and aspect position thereof, employing mining excavating equipment takes through peeling off, and selected Irish touchstone ore extraction is come out; Described broken screening is cleaned and is, the Irish touchstone ore with exploitation is come out carries out the fragmentation screening with palate crushed stone machine, filters out the particulate state of 6-13mm, cleans up with clear water; Described picking be, the Irish touchstone ore of rinsing well spread out dried, and through artificial careful picking, the particle or the assorted stone foreign material of foreign peoples that will have the corrosion spot are rejected; Described feeding intake is that with the Irish touchstone ore input loading hopper of select, the enforcement autocontrol mode is delivered to its leakage in the stove at regular time and quantity successively; Described intensification is founded and is, qualified Irish touchstone ore is heated two above hot spots of furnace kiln body device in stove; The Irish touchstone ore is founded to heat up in the process at stove and is reached 1430 ℃-1700 ℃, and the Irish touchstone ore particles impels solution further to merge homogenizing through the full and uniform fusing of high temperature; Get rid of bubble; Component diffusion, Irish touchstone ore become high plastic state by solid-state gradually, and wriggling cross flow is in platinum rhodium bushing groove; The cooling of described silk root is, respectively installs a water circulation type nozzle shield at the upper and lower of platinum rhodium bushing, makes solution reach the viscoelastic state of suitable wire-drawing shape fast; Described bushing wire drawing is, with viscoelastic state solution through the platinum rhodium bushing through small opening moment moulding, under the drawing wire machine tension, form fiber, the bushing temperature is controlled between 1210 ℃-1275 ℃; Described fog curing is that below bushing, the attenuating zone of baster top is provided with micro-sprayer; With clear water fiber is carried out fog curing, viscoelastic attitude fiber is changed into rapidly solidify attitude, play the curing enhancement; Avoid collision friction between the fiber, the adhesion fracture of wire; Described infiltration is that fiber is provided with baster midway at pulling process, adorns treating compound in the baster, the fiber of pulling out in time is coated with to roll to soak into handles; It is that fiber is wrapped on the cylinder of drawing wire machine through the gathering roll boundling under the traction of drawing wire machine again that described boundling twines; Described baking yarn is that the fiber that draws out is in time sent into the baking of heating in the baking yarn case; The treating compound that fiber surface is adhered to evenly spreads film forming, and moisture content obtains evaporation, and fiber is further gained in strength; Storing time 1-2 hour, temperature was controlled between 110 ℃-135 ℃; Describedly move back and be, baked raw yarn is moved back separate Split Down, form complete high-strength pure basalt continuous fiber; Described inspection after construction is that the high-strength pure basalt continuous fiber of Split Down is done the breaking tenacity check.
The technical scheme that the present invention solves its technical problem can also be:
Described high-strength pure basalt continuous fiber production technique, its described treating compound is: silane, epoxy and polyester Polyurethane, nonionic, positively charged ion.
The invention has the beneficial effects as follows:
1, the continuous fibre raw yarn average fracture strength produced of the present invention can be stabilized in 0.6-0.7N/tex, than the 0.4N/tex of national Specification, improves 50%-75%, becomes the silk rate to improve 10%.
2, the present invention is easy and simple to handle, produces and stablizes, and with low cost, technological process is environment friendly and pollution-free, and product quality obviously improves.
Description of drawings
Fig. 1 is a process flow sheet of the present invention.
Embodiment
Among Fig. 1; High-strength pure basalt continuous fiber production technique; Master operation by select, quarry, broken screening is cleaned, pick, feed intake, heat up found, the cooling of silk root, bushing wire drawing, fog curing, infiltration, boundling twine, dry by the fire yarn, move back also and inspection after construction, it is described select be with a kind of natural basalt as single component raw material, natural basalt is selected the crystalloid even structure for use; Purity is high; Acid modulus: the MK=(Sio2+Al2o3)/(Cao+Mgo) of basic oxide compound, the acid modulus of basic oxide compound remains in the 4.3-5.8 scope, and Fe2o3+Feo is controlled between the 8-15% simultaneously.
Described high-strength pure basalt continuous fiber production technique, its described quarrying are that according to selecting definite ore deposit point and aspect position thereof, employing mining excavating equipment takes through peeling off, and selected Irish touchstone ore extraction is come out; Described broken screening is cleaned and is, the Irish touchstone ore with exploitation is come out carries out the fragmentation screening with palate crushed stone machine, filters out the particulate state of 6-13mm, cleans up with clear water; Described picking be, the Irish touchstone ore of rinsing well spread out dried, and through artificial careful picking, the particle or the assorted stone foreign material of foreign peoples that will have the corrosion spot are rejected; Described feeding intake is that with the Irish touchstone ore input loading hopper of select, the enforcement autocontrol mode is delivered to its leakage in the stove at regular time and quantity successively; Described intensification is founded and is, qualified Irish touchstone ore is heated two above hot spots of furnace kiln body device in stove; The Irish touchstone ore is founded to heat up in the process at stove and is reached 1430 ℃-1700 ℃, and the Irish touchstone ore particles impels solution further to merge homogenizing through the full and uniform fusing of high temperature; Get rid of bubble; Component diffusion, Irish touchstone ore become high plastic state by solid-state gradually, and wriggling cross flow is in platinum rhodium bushing groove; The cooling of described silk root is, respectively installs a water circulation type nozzle shield at the upper and lower of platinum rhodium bushing, makes solution reach the viscoelastic state of suitable wire-drawing shape fast; Described bushing wire drawing is, with viscoelastic state solution through the platinum rhodium bushing through small opening moment moulding, under the drawing wire machine tension, form fiber, the bushing temperature is controlled between 1210 ℃-1275 ℃; Described fog curing is that below bushing, the attenuating zone of baster top is provided with micro-sprayer; With clear water fiber is carried out fog curing, viscoelastic attitude fiber is changed into rapidly solidify attitude, play the curing enhancement; Avoid collision friction between the fiber, the adhesion fracture of wire; Described infiltration is that fiber is provided with baster midway at pulling process, adorns treating compound in the baster, the fiber of pulling out in time is coated with to roll to soak into handles; It is that fiber is wrapped on the cylinder of drawing wire machine through the gathering roll boundling under the traction of drawing wire machine again that described boundling twines; Described baking yarn is that the fiber that draws out is in time sent into the baking of heating in the baking yarn case; The treating compound that fiber surface is adhered to evenly spreads film forming, and moisture content obtains evaporation, and fiber is further gained in strength; Storing time 1-2 hour, temperature was controlled between 110 ℃-135 ℃; Describedly move back and be, baked raw yarn is moved back separate Split Down, form complete high-strength pure basalt continuous fiber; Described inspection after construction is that the high-strength pure basalt continuous fiber of Split Down is done the breaking tenacity check.
Described high-strength pure basalt continuous fiber production technique, its described treating compound is: silane, epoxy and polyester Polyurethane, nonionic, positively charged ion.
Claims (2)
1. high-strength pure basalt continuous fiber production technique; Master operation by select, quarry, broken screening is cleaned, pick, feed intake, heat up found, the cooling of silk root, bushing wire drawing, fog curing, infiltration, boundling twine, dry by the fire yarn, move back also and inspection after construction; It is characterized in that: described selecting is as single component raw material with a kind of natural basalt; Natural basalt is selected the crystalloid even structure for use, and purity is high, acid modulus: the MK=(Sio2+Al2o3)/(Cao+Mgo) of basic oxide compound; The acid modulus of basic oxide compound remains in the 4.3-5.8 scope, and Fe2o3+Feo is controlled between the 8-15% simultaneously.
2. high-strength pure basalt continuous fiber production technique according to claim 1; It is characterized in that: described quarrying is according to selecting definite ore deposit point and aspect position thereof, to adopt the mining excavating equipment; Take through peeling off, selected Irish touchstone ore extraction is come out; Described broken screening is cleaned and is, the Irish touchstone ore with exploitation is come out carries out the fragmentation screening with palate crushed stone machine, filters out the particulate state of 6-13mm, cleans up with clear water; Described picking be, the Irish touchstone ore of rinsing well spread out dried, and through artificial careful picking, the particle or the assorted stone foreign material of foreign peoples that will have the corrosion spot are rejected; Described feeding intake is that with the Irish touchstone ore input loading hopper of select, the enforcement autocontrol mode is delivered to its leakage in the stove at regular time and quantity successively; Described intensification is founded and is, qualified Irish touchstone ore is heated two above hot spots of furnace kiln body device in stove; The Irish touchstone ore is founded to heat up in the process at stove and is reached 1430 ℃-1700 ℃, and the Irish touchstone ore particles impels solution further to merge homogenizing through the full and uniform fusing of high temperature; Get rid of bubble; Component diffusion, Irish touchstone ore become high plastic state by solid-state gradually, and wriggling cross flow is in platinum rhodium bushing groove; The cooling of described silk root is, respectively installs a water circulation type nozzle shield at the upper and lower of platinum rhodium bushing, makes solution reach the viscoelastic state of suitable wire-drawing shape fast; Described bushing wire drawing is, with viscoelastic state solution through the platinum rhodium bushing through small opening moment moulding, under the drawing wire machine tension, form fiber, the bushing temperature is controlled between 1210 ℃-1275 ℃; Described fog curing is that below bushing, the attenuating zone of baster top is provided with micro-sprayer; With clear water fiber is carried out fog curing, viscoelastic attitude fiber is changed into rapidly solidify attitude, play the curing enhancement; Avoid collision friction between the fiber, the adhesion fracture of wire; Described infiltration is that fiber is provided with baster midway at pulling process, adorns treating compound in the baster, the fiber of pulling out in time is coated with to roll to soak into handles; It is that fiber is wrapped on the cylinder of drawing wire machine through the gathering roll boundling under the traction of drawing wire machine again that described boundling twines; Described baking yarn is that the fiber that draws out is in time sent into the baking of heating in the baking yarn case; The treating compound that fiber surface is adhered to evenly spreads film forming, and moisture content obtains evaporation, and fiber is further gained in strength; Storing time 1-2 hour, temperature was controlled between 110 ℃-135 ℃; Describedly move back and be, baked raw yarn is moved back separate Split Down, form complete high-strength pure basalt continuous fiber; Described inspection after construction is that the high-strength pure basalt continuous fiber of Split Down is done the breaking tenacity check.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104057621A (en) * | 2014-07-03 | 2014-09-24 | 王力虎 | Rock wool production method |
| CN105331165A (en) * | 2015-11-03 | 2016-02-17 | 李明顺 | Production device and method for basalt flakes |
| CN106088356A (en) * | 2016-06-28 | 2016-11-09 | 四川点石玄武纤维科技有限公司 | A kind of method preparing basalt fibre screw |
| CN106116163A (en) * | 2016-06-28 | 2016-11-16 | 成都镭迪蒙科技有限公司 | A kind of preparation method of basalt fibre hawser |
| CN106113520A (en) * | 2016-06-28 | 2016-11-16 | 成都镭迪蒙科技有限公司 | A kind of preparation method of the corrosion-resistant compound built-in fitting of basalt fibre |
| CN106142293B (en) * | 2016-06-28 | 2018-07-06 | 四川点石玄武纤维科技有限公司 | A kind of preparation method of underground pipe gallery |
| CN108585525A (en) * | 2018-07-02 | 2018-09-28 | 浙江石金玄武岩纤维股份有限公司 | Basalt fibre and its production method applied to epoxy prepreg |
| CN109626824A (en) * | 2019-01-16 | 2019-04-16 | 河南光远新材料股份有限公司 | A kind of pre-treating method of glass fabric wire drawing |
| CN110747558A (en) * | 2019-10-10 | 2020-02-04 | 浙江石金玄武岩纤维股份有限公司 | Basalt fiber sewing thread for heat-insulation board and preparation method thereof |
| CN111023601A (en) * | 2019-12-10 | 2020-04-17 | 武汉中科先进技术研究院有限公司 | Application of basalt fiber fabric in photothermal conversion |
| CN111499209A (en) * | 2019-01-31 | 2020-08-07 | 四川思络普防护网工程有限公司 | Preparation process of basalt fiber for side slope protective net |
| CN112209622A (en) * | 2019-07-10 | 2021-01-12 | 贵州玄武岩新材料工程技术开发有限公司 | Basalt fiber monomer furnace wire drawing process |
| CN113831629A (en) * | 2021-11-03 | 2021-12-24 | 中科华坤(北京)科技有限公司 | High-strength basalt fiber 3d printing composite material |
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| CN1230526A (en) * | 1998-04-01 | 1999-10-06 | 鸡西市梨树区人民政府 | Continuous basalt fiber and its production technology |
| CN1210094A (en) * | 1998-09-17 | 1999-03-10 | 李洪安 | Method, apparatus and products of alkaliproof basalt fibers |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104057621A (en) * | 2014-07-03 | 2014-09-24 | 王力虎 | Rock wool production method |
| CN105331165A (en) * | 2015-11-03 | 2016-02-17 | 李明顺 | Production device and method for basalt flakes |
| CN106088356A (en) * | 2016-06-28 | 2016-11-09 | 四川点石玄武纤维科技有限公司 | A kind of method preparing basalt fibre screw |
| CN106116163A (en) * | 2016-06-28 | 2016-11-16 | 成都镭迪蒙科技有限公司 | A kind of preparation method of basalt fibre hawser |
| CN106113520A (en) * | 2016-06-28 | 2016-11-16 | 成都镭迪蒙科技有限公司 | A kind of preparation method of the corrosion-resistant compound built-in fitting of basalt fibre |
| CN106142293B (en) * | 2016-06-28 | 2018-07-06 | 四川点石玄武纤维科技有限公司 | A kind of preparation method of underground pipe gallery |
| CN108585525A (en) * | 2018-07-02 | 2018-09-28 | 浙江石金玄武岩纤维股份有限公司 | Basalt fibre and its production method applied to epoxy prepreg |
| CN109626824A (en) * | 2019-01-16 | 2019-04-16 | 河南光远新材料股份有限公司 | A kind of pre-treating method of glass fabric wire drawing |
| CN111499209A (en) * | 2019-01-31 | 2020-08-07 | 四川思络普防护网工程有限公司 | Preparation process of basalt fiber for side slope protective net |
| CN112209622A (en) * | 2019-07-10 | 2021-01-12 | 贵州玄武岩新材料工程技术开发有限公司 | Basalt fiber monomer furnace wire drawing process |
| CN110747558A (en) * | 2019-10-10 | 2020-02-04 | 浙江石金玄武岩纤维股份有限公司 | Basalt fiber sewing thread for heat-insulation board and preparation method thereof |
| CN111023601A (en) * | 2019-12-10 | 2020-04-17 | 武汉中科先进技术研究院有限公司 | Application of basalt fiber fabric in photothermal conversion |
| CN111023601B (en) * | 2019-12-10 | 2021-07-23 | 武汉中科先进技术研究院有限公司 | Application of basalt fiber fabric in photothermal conversion |
| CN113831629A (en) * | 2021-11-03 | 2021-12-24 | 中科华坤(北京)科技有限公司 | High-strength basalt fiber 3d printing composite material |
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Application publication date: 20120718 |