CN103361996A - Vinylchloride acrylonitrile copolymer/flame retardant viscose blended fabric - Google Patents
Vinylchloride acrylonitrile copolymer/flame retardant viscose blended fabric Download PDFInfo
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- CN103361996A CN103361996A CN2013103393169A CN201310339316A CN103361996A CN 103361996 A CN103361996 A CN 103361996A CN 2013103393169 A CN2013103393169 A CN 2013103393169A CN 201310339316 A CN201310339316 A CN 201310339316A CN 103361996 A CN103361996 A CN 103361996A
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- blended fabric
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- vinyon
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Abstract
The invention discloses a vinylchloride acrylonitrile copolymer/flame retardant viscose blended fabric. The blended fabric is prepared by blending 40-60 weight parts of vinylchloride acrylonitrile copolymer fiber and 40-60 weight parts of flame retardant viscose fiber. The blended fabric has high flame retardance and relatively low cost. In addition, the blended fabric is comfortable to wear and can be applied for protection series products.
Description
Technical field
The present invention relates to a kind of fabric, relate in particular to the BLENDED FABRIC of a kind of Vinyon N and anti-flaming viscose.
Background technology
Polyacrylic and polyester fiber is a kind of modified acrylic fibres, is that acrylonitrile monemer forms with the vinyl compound copolymerization that contains ignition-proof element, has similar fleecy feel and high flame retardant, and has acidproof and the chemically-resistant medicament.As a kind of functional fiber, in Japan and American-European countries, this fiber is widely used, and is used for household textiles, protective garment fabric, decorative textile product material etc.
The formal name used at school of polyacrylic and polyester fiber is veral.External trade name Vinyon.135 ℃ of softening points.0.42 N/spy's (4.2 grams of force per Denier) of intensity.Percentage elongation 25%.Elasticity is strong.Hydroscopicity is little.Electrical insulating property is high.As insulating materials and textile material.Got by dry spinning by vinyl chloride and acrylonitrile compolymer.Vinyl-chloride-containing 60%～40%, acrylonitrile 40%～60%.Main performance is between polyvinyl chloride fibre and acrylic fibers.More heat-resisting than polyvinyl chloride fibre, than more high resilience and anti-combustion of acrylic fibers.
The characteristics of polyacrylic and polyester fiber are as follows:
Outstanding fire resistance.---the natural fire resistance that possesses of fiber makes the fire-retardant requirement that material can be by various countries' harshness, even natural fibre blendedly still have a constant fire resistance with other.
Natural, soft feel.---polyacrylic and polyester fiber has the general softness of similar other natural fabric, natural feel, water absorbing properties and comfortableness.
Burning is without melting, shrinkage phenomenon.---Vinyon N garment material when burning be without shrinking and melting phenomenon, and only produce charing, effectively stopped to melt to drip burning to skin.
The chemical stability of material is good---and therefore acid and alkali resistance and other general organic and inorganic medicine are used for filter cloth material, special protecting clothing material and other industrial materials.
The dyeing material performance is good---lovely luster, and COLOR FASTNESS is good, and is sun-resistant, and the daylight illumination degrading is not obvious, can be used for parasols etc.
Summary of the invention
For the deficiencies in the prior art, technical problem to be solved by this invention provides the BLENDED FABRIC of a kind of Vinyon N and anti-flaming viscose.
Technical problem to be solved by this invention is achieved by the following technical solution:
The BLENDED FABRIC of a kind of Vinyon N and anti-flaming viscose is prepared from by the polyacrylic and polyester fiber of 40-60 weight portion and the Fire resistant viscose fiber blending of 40-60 weight portion.
Preferably,
Fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber in the described Fire resistant viscose fiber.
Described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
Concrete, in the present invention:
Described Fire resistant viscose fiber has good flame retardant effect, has good flexibility, can strengthen the dress ornament comfort property.
Described Fire resistant viscose fiber can adopt following method to be prepared from: fire retardant is mixed with viscose solution (claiming again rayon spinning liquid), wet spinning sprays the silk technological forming routinely, described fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber, described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
In the described fire retardant:
10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, and English name: 10-(2,5-Dihydroxyphenyl)-10H-9-oxa-10-phospha-phenantbrene-10-oxide, CAS number: 99208-50-1.
[the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate, CAS accession number: 20120-33-6, English name: 3-(Dimethylphosphono)-N-methylolpropionamide.
Three (2,3-dibromopropyl) fulminuric acid ester, English name: Flame retardant TBC, Chinese another name: fire retardant TBC, molecular formula: C
12H
15Br
6N
3O.
Described viscose solution is the sodium hydrate aqueous solution of cellulose sulfonate.Preferably, in the described viscose solution, the weight percent content of first fibre is 8-9%, and the weight percent content of NaOH is 4-6%, falling ball viscosity 50-60 second, degree of ripeness 10-14%.
The BLENDED FABRIC of Vinyon N of the present invention and anti-flaming viscose can be carried out the shredding mixing with polyacrylic and polyester fiber and Fire resistant viscose fiber first, adopts industry universal method to make blended yarn, adopts conventional method to weave blended yarn again and forms fabric.
The BLENDED FABRIC of Vinyon N of the present invention and anti-flaming viscose has higher fire resistance, and comfortable and easy to wear, and cost is relatively cheap.
The BLENDED FABRIC of Vinyon N of the present invention and anti-flaming viscose can be applied to protect series of products.
The specific embodiment
The invention will be further described below in conjunction with embodiment.
Polyacrylic and polyester fiber, the Vinyon N that Shenyang sunlight chemical fibre trade Co., Ltd provides, oxygen index (OI) LOI value 31%.
Embodiment 1
Take by weighing: 50 kilograms of 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide; [3-[(methylol) amino]-3-carbonyl propyl group]-30 kilograms of dimethyl phosphonates; 20 kilograms of three (2,3-dibromopropyl) fulminuric acid esters mix and make composite flame-retardant agent.
Above-mentioned composite flame-retardant agent is mixed with viscose solution, and wet spinning spray silk technological forming can make described Fire resistant viscose fiber routinely, and the length of Fire resistant viscose fiber is 38mm.Wherein, the quality percentage composition of fire retardant is 7% in the control finished product Fire resistant viscose fiber, and the viscose solution in the described raw material, the weight percent content of first fibre are 8.5%, and the weight percent content of NaOH is 5%, falling ball viscosity 55 seconds, degree of ripeness 12%.
Take by weighing 50 kilograms of polyacrylic and polyester fibers, 50 kilograms of the above-mentioned Fire resistant viscose fiber that makes mix, and the shredding preliminary treatment is carded to the carded sliver at carding machine; Again on drawing frame and close and make ripe; Carry out drawing-off and twisting at Speed frames, blended yarn is made at last further draw twisting on fine spining machine, and yarn linear density is 39tex.Blended yarn is adopted large circle machine knitting device making method to weave, warp count is that 200/10cm, warp count are 200/10cm, finally makes the BLENDED FABRIC of Vinyon N and anti-flaming viscose again.
Embodiment 2
Substantially the same manner as Example 1, unique difference is, used fire retardant is 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 3
Substantially the same manner as Example 1, unique difference is, used fire retardant is [3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 4
Substantially the same manner as Example 1, unique difference is, used fire retardant is three (2, the 3-dibromopropyl) fulminuric acid ester, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.
Embodiment 5
Substantially the same manner as Example 1, unique difference is, used fire retardant is tricresyl phosphate (dimethylbenzene) ester, rather than by 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-the compound mixing fire retardant of dimethyl phosphonate and three (2,3-dibromopropyl) fulminuric acid ester three.Fire retardant tricresyl phosphate (dimethylbenzene) ester is the general fire retardant of the industry, and CAS accession number 25155-23-1 claims again xylenylphosphate.
Test case
The BLENDED FABRIC of the Fire resistant viscose fiber that respectively embodiment 1-5 is made and final finished product Vinyon N and anti-flaming viscose is carried out the fire resistance test.
| ? | Oxygen index (OI) LOI value, % |
| The Fire resistant viscose fiber that embodiment 1 makes | 29.4 |
| The Fire resistant viscose fiber that embodiment 2 makes | 28.5 |
| The Fire resistant viscose fiber that embodiment 3 makes | 28.4 |
| The Fire resistant viscose fiber that embodiment 4 makes | 27.6 |
| The Fire resistant viscose fiber that embodiment 5 makes | 28.0 |
| The flame-retarding blended fabric that embodiment 1 makes | 30.2 |
| The flame-retarding blended fabric that embodiment 2 makes | 29.7 |
| The flame-retarding blended fabric that embodiment 3 makes | 29.6 |
| The flame-retarding blended fabric that embodiment 4 makes | 29.3 |
| The Fire resistant viscose fiber that embodiment 5 makes | 29.5 |
The present invention is with 10-(2, the 5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide, [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate and three (2, the 3-dibromopropyl) these three kinds of composite uses of fire retardant of fulminuric acid ester, the flame retardant effect Synergistic has been obtained beyond thought excellent technique effect.
Claims (3)
1. the BLENDED FABRIC of a Vinyon N and anti-flaming viscose is characterized in that, is prepared from by the polyacrylic and polyester fiber of 40-60 weight portion and the Fire resistant viscose fiber blending of 40-60 weight portion.
2. the BLENDED FABRIC of Vinyon N as claimed in claim 1 and anti-flaming viscose is characterized in that, fire retardant accounts for the quality percentage composition 6-8% of described Fire resistant viscose fiber in the described Fire resistant viscose fiber.
3. the BLENDED FABRIC of Vinyon N as claimed in claim 2 and anti-flaming viscose is characterized in that, described fire retardant is comprised of following components in mass portion: 10-(2,5-dihydroxy phenyl)-10H-9-oxa--10-phospho hetero phenanthrene-10-oxide 40-60 part; [the 3-[(methylol) amino]-3-carbonyl propyl group]-dimethyl phosphonate 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 10-30 part.
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| CN201310339316.9A CN103361996B (en) | 2013-08-05 | 2013-08-05 | The BLENDED FABRIC of Vinyon N and anti-flaming viscose |
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| CN201310339316.9A CN103361996B (en) | 2013-08-05 | 2013-08-05 | The BLENDED FABRIC of Vinyon N and anti-flaming viscose |
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| CN103361996A true CN103361996A (en) | 2013-10-23 |
| CN103361996B CN103361996B (en) | 2015-11-18 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104630979A (en) * | 2015-02-10 | 2015-05-20 | 上海婉静纺织科技有限公司 | Acrylic fiber and spandex blended fabric |
| CN104630971A (en) * | 2015-02-10 | 2015-05-20 | 上海婉静纺织科技有限公司 | Vinylon modacrylic viscose blended fabric |
| CN108950783A (en) * | 2018-07-27 | 2018-12-07 | 株洲市万昌纺织有限公司 | The fire-retardant preparation method with scribbled |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040060119A1 (en) * | 2002-10-01 | 2004-04-01 | Spungold, Inc. | Composite fire barrier and thermal insulation fabric for mattresses and mattress foundations |
| CN200999282Y (en) * | 2006-12-07 | 2008-01-02 | 张志明 | Flame-proof core-spun yarn |
| CN101181661A (en) * | 2007-12-13 | 2008-05-21 | 中国人民解放军总后勤部军需装备研究所 | Multifunctional ventilating type protection material and preparation method thereof |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
-
2013
- 2013-08-05 CN CN201310339316.9A patent/CN103361996B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040060119A1 (en) * | 2002-10-01 | 2004-04-01 | Spungold, Inc. | Composite fire barrier and thermal insulation fabric for mattresses and mattress foundations |
| CN200999282Y (en) * | 2006-12-07 | 2008-01-02 | 张志明 | Flame-proof core-spun yarn |
| CN101181661A (en) * | 2007-12-13 | 2008-05-21 | 中国人民解放军总后勤部军需装备研究所 | Multifunctional ventilating type protection material and preparation method thereof |
| CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
| CN103012765A (en) * | 2012-12-08 | 2013-04-03 | 北京服装学院 | Preparation method for moisture-absorbing and flame-retardant polyester fiber |
Non-Patent Citations (3)
| Title |
|---|
| 同济大学普通化学及无机化学教研室编著: "《普通化学》", 31 August 1993, 同济大学出版社 * |
| 欧育湘主编: "《阻燃剂》", 30 September 2009, 国防工业出版社 * |
| 王涛等: "阻燃粘胶纤维/腈氯纶混纺织物的制备及性能研究", 《天津工业大学学报》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104630979A (en) * | 2015-02-10 | 2015-05-20 | 上海婉静纺织科技有限公司 | Acrylic fiber and spandex blended fabric |
| CN104630971A (en) * | 2015-02-10 | 2015-05-20 | 上海婉静纺织科技有限公司 | Vinylon modacrylic viscose blended fabric |
| CN108950783A (en) * | 2018-07-27 | 2018-12-07 | 株洲市万昌纺织有限公司 | The fire-retardant preparation method with scribbled |
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| CN103361996B (en) | 2015-11-18 |
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Inventor after: Wang Wei Inventor before: Yuan Juan |
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Effective date of registration: 20170505 Address after: 264200, Shandong District, Weihai City, Huancui Province sheep town Song Qu village project two District No. 1 office building Patentee after: Shandong thinking Textile Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T158 Patentee before: Shanghai Wanjing Textile Technology Co., Ltd. |
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Granted publication date: 20151118 Termination date: 20170805 |
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