CN103355743A - Preparation and application of crop waste cigarette filter additive carrier materials - Google Patents
Preparation and application of crop waste cigarette filter additive carrier materials Download PDFInfo
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- CN103355743A CN103355743A CN2013103543734A CN201310354373A CN103355743A CN 103355743 A CN103355743 A CN 103355743A CN 2013103543734 A CN2013103543734 A CN 2013103543734A CN 201310354373 A CN201310354373 A CN 201310354373A CN 103355743 A CN103355743 A CN 103355743A
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Abstract
Disclosed is preparation and application of crop waste cigarette filter additive carrier materials. The carrier materials use crop waste such as crop straw, or corncob, or peanut shells or cane trash as raw materials, the processes of washing, offensive odor removing, drying, smashing and sieving are conducted in sequence, and finally the crop waste cigarette filter additive carrier materials are prepared. After the carrier materials are loaded with cigarette harm reduction agents or flavoring agents directly or chemical modification is conducted, the carrier materials are added into a cigarette filtering rod so that a binary or multielement composite filtering bar can be achieved, and the crop waste cigarette filter additive carrier materials are applied to cigarette filters and have the advantages of reducing harmful ingredients of cigarette smoke, adding fragrance, improving smoking quality and the like. The crop waste cigarette filter additive carrier materials further have the advantages that crop waste materials are provided with porous structures, and the crop waste cigarette filter additive carrier materials are rich in cellulose, hemicellulose, lignin and the like, wide in source, simple in production technology, low in cost, environmentally friendly, capable of facilitating recycling of the waste and the like, thereby being excellent cigarette filter additive carrier materials.
Description
Technical field
The invention belongs to technical field of cigarettes, relate to cigarette filter, specifically a kind of preparation and application of agricultural waste material class cigarette filter-tip additive agent carrier material.
Background technology
Existing cigarette filter-tip additive agent carrier mostly is inorganic porous material and the high-molecular porous material of chemical synthesis, such as active carbon, silica gel, Woelm Alumina, molecular sieve, mesopore material, ion exchange resin etc.Patent US 5909736 has prepared cigarette filter-tip additive agent take active carbon as carrier by dipping hemoglobin or attached transferrins, hydrogen peroxide, protoporphyrin and cytochromes.Patent CN 1883320 is take active carbon as carrier, and active ingredient is wherein extracted in selection and the plant that tobacco has affiliation, is applied to and makes material supplemented active carbon on the active carbon.Patent CN 101669678 is take porous materials such as diatomite, silica, resin, hydroxyapatite, zeolite, polyvinyl acetate, shitosans as carrier, by carrying out different surface chemical modifications, obtain containing the modified porous material of different basic groups, this material is added on cigarette filter rod, can reduce the determination of hydrogen cyanide in mainstream cigarette smoke burst size more than 30%, simultaneously the sucking quality of cigarette do not had a negative impact.Patent CN 1682614 is take active carbon, diatomite or molecular sieve as carrier, load algal polysaccharides or derivatives thereof, prepared cigarette filter-tip additive agent, it can reach 20%～63% to the alkoxy free group inhibiting rate, simultaneously tar is also had certain scavenging action.Patent CN102838795A provides a kind of cigarette filter additive resin carrier, it is to be that the essence microcapsule of 1-8%, the converted starch of 20-60%, the resin of 30-70%, the plasticizer of 1-3% and the toner of 0.01-0.05% prepare according to squeeze technology for forming by mass percent, it had both kept resin and had easily finalized the design, can prepare quickly and easily the advantage of various shapes, and can be when sucking cigarette abundant release additives fragrance.Above-mentioned these cigarette additives or additive carrier have played certain effect to lowering harm and decreasing coking, but these materials also exist loaded down with trivial details, the complex process of preparation, cost higher, affect the problem such as cigarette odor-absorbing, so be not used widely.
In recent years, the natural plant kind material some reports also occurred as the filter tip additive carrier aspect.Patent CN101167601A is take one or more of pipe tobacco or expanded cut tobacco, tobacco stem shred or expanding tobacco stem, reconstituted tobacoo as carrier, the a certain proportion of flavouring agent of load or (with) the lowering harm and decreasing coking agent makes cigarette additive, be applied in the cigarette composite filter tip.Patent CN 100479681C as cigarette filter-tip additive agent and additive carrier, has tealeaves the Chemical Components in Cigarette Smoke of coordination, increases cigarette flavor, abirritate, improves the smoking property of cigarette quality.Patent CN 101317695B is take fresh pomelo peel as raw material, make required sorbing material through processing, it has good toughness, is conducive to the moulding of filter stick and the manufacturing of cigarette, can not cause the wearing and tearing of equipment, and can effectively reduce the harmful components such as tar, NNK, benzo [a] pyrene.But at present, for natural plant material as the research of cigarette additive carrier seldom, because floristics is numerous, character is different, therefore be necessary further to seek the natural plant kind filter tip additive carrier material with better characterization of adsorption, to satisfy the demand of cigarette industry.
China is large agricultural country, a large amount of miscellaneous agricultural waste materials of annual generation, and this has caused huge pressure to environment, and only has a small amount of agricultural waste material to obtain effective utilization at present.Therefore, rationally utilize the agricultural waste material can not only environmental contamination reduction, and the development that will facilitate economic and social.So far with agricultural waste material as the cigarette filter-tip additive agent carrier material, yet there are no open report.
Summary of the invention
Purpose of the present invention just is being based on above-mentioned current condition and preparation and the application of a kind of agricultural waste material class cigarette filter-tip additive agent carrier material of providing.
Agricultural waste material among the present invention is agricultural crop straw, corncob, peanut shell or bagasse; Described agricultural crop straw is maize straw, wheat stalk, broomcorn straw, rice straw or sesame stalk.
Invention mechanism of the present invention is: on microstructure, described agricultural waste material material has loose structure, and this has given them and has had certain characterization of adsorption, is conducive to remove the harmful components in the flue gas; This class material also is rich in cellulose, hemicellulose and lignin etc. in addition, the physical arrangement that has and the chemical characteristic of the discarded composition material of this class, for its load harm reduction agent, flavouring agent or further carry out chemical modification good basic condition is provided, and this also is prerequisite as carrier material institute.
The objective of the invention is to be achieved through the following technical solutions:
A kind of agricultural waste material class cigarette filter-tip additive agent carrier material is take agricultural waste material as raw material, makes by the following method:
(1) agricultural waste material is cleaned, to remove impurity and dirt.
The material that (2) will clean dries, and then steams 10～60 minutes at 100 ℃～150 ℃, then stores 2～5 hours, to remove the assorted gas in the material.
(3) material is carried out drying, baking temperature is 60～100 ℃, and dry rear material moisture control is 10%～14%.
(4) dried material is pulverized, and sieved with 20～100 purpose sieves, collect 20～100 purpose material granules, namely obtain agricultural waste material class cigarette filter-tip additive agent carrier material.
Among the present invention, when selecting maize straw, broomcorn straw, sesame stalk or corncob to prepare the filter tip additive carrier material, first spongy layer is wherein removed, be carried out according to above-mentioned preparation method again.
Agricultural waste material class cigarette filter-tip additive agent carrier material among the present invention, its application mode is: directly load harm reduction agent or flavouring agent, also can further carry out chemical modification, then join in the cigarette filter rod, make binary or multi-element composite filter stick.
The invention has the advantages that described agricultural waste material class material has loose structure and is rich in cellulose, hemicellulose and lignin etc., it is good cigarette filter-tip additive agent carrier material, and described material has, and wide material sources, production technology are simple, with low cost, environmental protection, also have the advantages such as recycling that promote discarded object.In addition, with agricultural waste material class carrier material load harm reduction agent, flavouring agent or after carrying out chemical modification, be applied to cigarette filter, have and reduce the cigarette smoke harmful components, increase fragrance matter, improve the advantage such as suction quality.
The specific embodiment
This is described further invention below in conjunction with embodiment, but the scope of the invention is not limited to these embodiment.
Embodiment1
Spongy layer in the middle of the maize straw is removed, then water cleans to remove impurity and dirt, after drying, steamed 30 minutes at 130 ℃, then stored 3 hours, next material is dried to moisture content 10%～14% at 75 ℃, pulverize, and sieve with 20～100 purpose sieves, collect 20～100 purpose corn stalk pelletses, get final product.
Embodiment 2
Choose wheat stalk, water cleans to remove impurity and dirt, after drying, steamed 20 minutes at 110 ℃, then stored 4 hours, next material is dried to moisture content 10%～14% at 80 ℃, pulverize, and sieve with 20～100 purpose sieves, collect 20～100 purpose wheat stalk particles, get final product.
Embodiment3
Corncob is carried out middle spongy layer to be removed, water cleans to remove impurity and dirt, after drying, steamed 20 minutes at 120 ℃, then stored 2 hours, next material is dried to moisture content 10%～14% at 80 ℃, pulverize, and sieve with 20～100 purpose sieves, collect 20～100 purpose corn cob granules, get final product.
Embodiment4
Choose peanut shell, water cleans to remove impurity and dirt, after drying, steamed 20 minutes at 140 ℃, then stored 5 hours, next material is dried to moisture content 10%～14% at 80 ℃, pulverize, and sieve with 20～100 purpose sieves, collect 20～100 purpose peanut shell granulars, get final product.
Embodiment5
Choose bagasse, water cleans to remove impurity and dirt, after drying, steams 50 minutes at 135 ℃, then stored 3 hours, and next material was dried to moisture content 10%～14% at 70 ℃, pulverize, and sieve with 20～100 purpose sieves, collect 20～100 purpose bagasse, get final product.
Application example1
The corn cob granule load harm reduction agent protoporphyrin for preparing (protoporphyrin consumption be corn cob granule quality 1.0%) is joined in the filter stick (addition is that 10mg/ props up) and prepares binary compound filter candle, then make cigarette.The smoke test result shows: the CO burst size obviously reduces in the cigarette mainstream flue gas.Smoking result shows, the fragrance harmony, and flue gas is soft, free from extraneous odour, and non-stimulated, pleasant impression is cleaner.
Application example2
With the peanut shell granular load flavouring agent damascenone for preparing (flavouring agent consumption be peanut shell granular quality 0.5%), join in the filter stick (addition is that 6mg/ props up) and prepare binary compound filter candle, then make cigarette.Smoking result shows, the perfume quantity abundance, and the fragrance harmony, flue gas is soft, free from extraneous odour, and non-stimulated, pleasant impression is cleaner, returns sweet better.
Application example3
The corn cob granule for preparing is carried out chemical modification, introduce aminated reagent, then it is joined in the filter stick (addition is that 15mg/ props up) and prepare binary compound filter candle, then make cigarette.The smoke test result shows: the carbonyl compound burst size obviously reduces in the cigarette mainstream flue gas.Smoking result shows, the fragrance harmony, and free from extraneous odour, non-stimulated, pleasant impression is cleaner.
Claims (5)
1. the preparation of an agricultural waste material class cigarette filter-tip additive agent carrier material is characterized in that: be take agricultural waste material as raw material, make by the following method:
(1) agricultural waste material is cleaned, to remove impurity and dirt;
The material that (2) will clean dries, and then steams 10～60 minutes at 100 ℃～150 ℃, then stores 2～5 hours, to remove the assorted gas in the material;
(3) material is carried out drying, baking temperature is 60～100 ℃, and dry rear material moisture control is 10%～14%;
(4) dried material is pulverized, and sieved with 20～100 purpose sieves, collect 20～100 purpose material granules, namely obtain agricultural waste material class cigarette filter-tip additive agent carrier material.
2. the preparation of agricultural waste material class cigarette filter-tip additive agent carrier material according to claim 1, it is characterized in that: described agricultural waste material is agricultural crop straw, corncob, peanut shell or bagasse.
3. the preparation of agricultural waste material class cigarette filter-tip additive agent carrier material according to claim 2 is characterized in that: described agricultural crop straw is maize straw, wheat stalk, broomcorn straw, rice straw or sesame stalk.
4. according to claim 2 or the preparation of 3 described agricultural waste material class cigarette filter-tip additive agent carrier materials, it is characterized in that: when selecting maize straw, broomcorn straw, sesame stalk or corncob to prepare the filter tip additive carrier material, first spongy layer is wherein removed.
5. the application of an agricultural waste material class cigarette filter-tip additive agent carrier material as claimed in claim 1, it is characterized in that, with the agent of the direct load Harm reduction techniques of this carrier material, flavouring agent or after chemical modification, add in the cigarette filter rod, make binary or multi-element composite filter stick.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103689791A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Peanut shell particle composite tip |
| CN103689797A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Modified peanut shell porous material and application thereof in cigarettes |
| CN103689792A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Corncob particle composite filter tip |
| CN103689793A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Modified corncob porous material and application thereof in cigarettes |
| CN103876283A (en) * | 2014-03-04 | 2014-06-25 | 湖南中烟工业有限责任公司 | Filter stick composite additive with coffee or cocoa flavor and preparation method and application thereof |
| CN103876286A (en) * | 2014-03-04 | 2014-06-25 | 湖南中烟工业有限责任公司 | Filter rod particle additive with coffee or cocoa flavor and preparation method and application thereof |
| CN104432508A (en) * | 2014-11-25 | 2015-03-25 | 云南还原医学生物科技有限公司 | Method for manufacturing cigarette holder through discarded tobacco stem |
| CN107433187A (en) * | 2017-07-25 | 2017-12-05 | 滁州卷烟材料厂 | A kind of filter tip for being used to adsorb heavy metal in cigarette smoke |
| CN110150740A (en) * | 2019-06-14 | 2019-08-23 | 孙庆雄 | A kind of corncob cigarette and preparation method thereof |
| CN110419777A (en) * | 2019-08-12 | 2019-11-08 | 云南中烟新材料科技有限公司 | A kind of preparation method of cigarette class active carbon particle |
| CN113481756A (en) * | 2021-06-29 | 2021-10-08 | 河南中烟工业有限责任公司 | Free radical scavenging composition and preparation method and application thereof |
| CN115053985A (en) * | 2022-07-20 | 2022-09-16 | 湖北中烟工业有限责任公司 | Filter tip rod for cigarette and preparation method thereof |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103689792B (en) * | 2013-12-03 | 2015-04-08 | 红云红河烟草(集团)有限责任公司 | Corncob particle composite filter tip |
| CN103689797A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Modified peanut shell porous material and application thereof in cigarettes |
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| CN103689793A (en) * | 2013-12-03 | 2014-04-02 | 红云红河烟草(集团)有限责任公司 | Modified corncob porous material and application thereof in cigarettes |
| CN103689797B (en) * | 2013-12-03 | 2015-04-08 | 红云红河烟草(集团)有限责任公司 | Modified peanut shell porous material and application thereof in cigarettes |
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| CN103689791B (en) * | 2013-12-03 | 2015-04-08 | 红云红河烟草(集团)有限责任公司 | Peanut shell particle composite tip |
| CN103689793B (en) * | 2013-12-03 | 2015-04-08 | 红云红河烟草(集团)有限责任公司 | Modified corncob porous material and application thereof in cigarettes |
| CN103876286A (en) * | 2014-03-04 | 2014-06-25 | 湖南中烟工业有限责任公司 | Filter rod particle additive with coffee or cocoa flavor and preparation method and application thereof |
| CN103876283A (en) * | 2014-03-04 | 2014-06-25 | 湖南中烟工业有限责任公司 | Filter stick composite additive with coffee or cocoa flavor and preparation method and application thereof |
| CN103876283B (en) * | 2014-03-04 | 2016-02-10 | 湖南中烟工业有限责任公司 | Filter stick compound additive with coffee or cocoa flavor and its preparation method and application |
| CN103876286B (en) * | 2014-03-04 | 2016-06-08 | 湖南中烟工业有限责任公司 | A kind of filter rod particulate additive with coffee or cocoa flavor and its preparation method and application |
| CN104432508A (en) * | 2014-11-25 | 2015-03-25 | 云南还原医学生物科技有限公司 | Method for manufacturing cigarette holder through discarded tobacco stem |
| CN104432508B (en) * | 2014-11-25 | 2017-06-20 | 云南还原医学生物科技有限公司 | A kind of method for making cigarette holder using discarded tobacco rod |
| CN107433187A (en) * | 2017-07-25 | 2017-12-05 | 滁州卷烟材料厂 | A kind of filter tip for being used to adsorb heavy metal in cigarette smoke |
| CN110150740A (en) * | 2019-06-14 | 2019-08-23 | 孙庆雄 | A kind of corncob cigarette and preparation method thereof |
| CN110419777A (en) * | 2019-08-12 | 2019-11-08 | 云南中烟新材料科技有限公司 | A kind of preparation method of cigarette class active carbon particle |
| CN110419777B (en) * | 2019-08-12 | 2022-05-31 | 云南中烟新材料科技有限公司 | Preparation method of activated carbon granules for cigarettes |
| CN113481756A (en) * | 2021-06-29 | 2021-10-08 | 河南中烟工业有限责任公司 | Free radical scavenging composition and preparation method and application thereof |
| CN115053985A (en) * | 2022-07-20 | 2022-09-16 | 湖北中烟工业有限责任公司 | Filter tip rod for cigarette and preparation method thereof |
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Application publication date: 20131023 |