CN103351510B - 一种彩色抗氧化聚乙烯电缆料及其制备方法 - Google Patents
一种彩色抗氧化聚乙烯电缆料及其制备方法 Download PDFInfo
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- CN103351510B CN103351510B CN201310243579.XA CN201310243579A CN103351510B CN 103351510 B CN103351510 B CN 103351510B CN 201310243579 A CN201310243579 A CN 201310243579A CN 103351510 B CN103351510 B CN 103351510B
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- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 18
- -1 polyethylene Polymers 0.000 title claims abstract description 18
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 17
- 238000012986 modification Methods 0.000 claims abstract description 10
- 230000004048 modification Effects 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 8
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims abstract description 8
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 7
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 7
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims abstract description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 7
- 239000010937 tungsten Substances 0.000 claims abstract description 7
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 5
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 5
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims abstract description 4
- OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000019738 Limestone Nutrition 0.000 claims abstract description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000006028 limestone Substances 0.000 claims abstract description 4
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229940126062 Compound A Drugs 0.000 claims description 6
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 4
- 229940075507 glyceryl monostearate Drugs 0.000 claims 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims 2
- 235000021355 Stearic acid Nutrition 0.000 abstract description 7
- 125000005456 glyceride group Chemical group 0.000 abstract description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 7
- 239000008117 stearic acid Substances 0.000 abstract description 7
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000003063 flame retardant Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
项 目 | 单 位 | 本发明电缆料 |
原始拉伸强度 | MPa 不小于 | 18.00 |
原始断裂伸长率 | % 不小于 | 630 |
耐158℃×168h老化后 | ||
断裂强度 | MPa 不小于 | 17 |
断裂伸长率 | % 不小于 | 610 |
20℃体积电阻率 | Ω·m | 1.0×1014 |
200℃热稳定时间 | Min | 60 |
Claims (2)
Priority Applications (1)
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CN201310243579.XA CN103351510B (zh) | 2013-06-19 | 2013-06-19 | 一种彩色抗氧化聚乙烯电缆料及其制备方法 |
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CN201310243579.XA CN103351510B (zh) | 2013-06-19 | 2013-06-19 | 一种彩色抗氧化聚乙烯电缆料及其制备方法 |
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CN103351510A CN103351510A (zh) | 2013-10-16 |
CN103351510B true CN103351510B (zh) | 2015-11-18 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103554619A (zh) * | 2013-10-31 | 2014-02-05 | 合肥得润电子器件有限公司 | 一种汽车线束用改性低密度聚乙烯绝缘料 |
CN103756085A (zh) * | 2013-12-10 | 2014-04-30 | 芜湖佳诚电子科技有限公司 | 一种用于轨道交通的无卤阻燃防虫蛀电缆线及其制备方法 |
CN105504460A (zh) * | 2016-02-29 | 2016-04-20 | 萧县明智电子有限公司 | 一种耐潮防白蚁直埋电缆料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061027A (zh) * | 2010-12-10 | 2011-05-18 | 南京聚隆科技股份有限公司 | 纳米蒙脱土滑石粉滚塑级交联聚乙烯复合材料及制备方法 |
CN102702609A (zh) * | 2012-07-04 | 2012-10-03 | 浙江明筑新材料有限公司 | 一种用于仿生藤的聚乙烯复合材料 |
CN102911416A (zh) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | 一种核电站用控制电缆料及其制备方法 |
CN102977605A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种硅橡胶交联阻燃电缆料及其制备方法 |
CN103059396A (zh) * | 2012-12-18 | 2013-04-24 | 滁州凯凯建筑节能有限公司 | 聚乙烯/cpe包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 |
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2013
- 2013-06-19 CN CN201310243579.XA patent/CN103351510B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061027A (zh) * | 2010-12-10 | 2011-05-18 | 南京聚隆科技股份有限公司 | 纳米蒙脱土滑石粉滚塑级交联聚乙烯复合材料及制备方法 |
CN102702609A (zh) * | 2012-07-04 | 2012-10-03 | 浙江明筑新材料有限公司 | 一种用于仿生藤的聚乙烯复合材料 |
CN102911416A (zh) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | 一种核电站用控制电缆料及其制备方法 |
CN102977605A (zh) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | 一种硅橡胶交联阻燃电缆料及其制备方法 |
CN103059396A (zh) * | 2012-12-18 | 2013-04-24 | 滁州凯凯建筑节能有限公司 | 聚乙烯/cpe包覆椰壳粉颗粒粒子共混发泡材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
聚合填充型超高分子质量聚乙烯复合材料的结构与性能;魏文杰等;《中国塑料》;19980930;第12卷(第5期);20-25 * |
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