CN103351200B - A kind of Marine organism calcium magnesium fertilizer - Google Patents

A kind of Marine organism calcium magnesium fertilizer Download PDF

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Publication number
CN103351200B
CN103351200B CN201310296462.8A CN201310296462A CN103351200B CN 103351200 B CN103351200 B CN 103351200B CN 201310296462 A CN201310296462 A CN 201310296462A CN 103351200 B CN103351200 B CN 103351200B
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preparation
subsequent use
fertilizer
marine organism
calcium
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CN103351200A (en
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吴锦华
候宪文
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Guangxi Wei Heng Ecological Agriculture Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

Disclosed by the invention is a kind of Marine organism calcium magnesium fertilizer.Existing ca and mg fertilizer, be utilize chemical process to prepare mostly, nutrient is single, and long-term application easily causes the hardening soil, reduces soil quality, is unfavorable for the Sustainable development of agricultural.Oyster shell whiting preparation that the present invention takes (1); (2) extra large ore powder prepares; (3) old bittern prepares; (4) shrimp pond is clay standby; (5) polypeptide amino acid liquid preparation; (6) the fertile preparation of mixing; (7) measure such as biological calcium fertiliser containing magnesium preparation, has produced Marine organism calcium magnesium fertilizer, has had (1) bionical degree high, complexing better effects if; (2) raw material sources are wide, and preparation cost is low, and production process does not form secondary pollution; (3) biological activity is higher, and nutrient more comprehensively; (4) use range is wider, can be used as acidic soil conditioner and uses, also can make aquaculture water quality improving agent, rich water agent uses; (5) feature of side reaction minimizing.

Description

A kind of Marine organism calcium magnesium fertilizer
Technical field
What the present invention relates to is a kind of Marine organism calcium magnesium fertilizer, belongs to technical field prepared by bio-organic fertilizer.
Background technology
Chinese first soil conditioner (ca and mg fertilizer) industry development summit in 2012 is held in Beijing, participant expert thinks due to acid chemical fertilizer year after year, the excessive use of agricultural chemicals and unreasonable use, the reasons such as industrial pollution acid rain increases the weight of, cause south China 14 province, district, the serious meta-acid of city's soil, the ratio that pH is less than 6.5 expands 65% to by 52% before 30 years, soil meta-acid, calcium magnesium plasma easily runs off, add that southern rainwater is more, crop is caused generally to lack calcium, the moderate-elements such as magnesium, have a strong impact on the yield and quality of crop, soil acidification, degenerate and become the important factor affecting agriculture production and ecotope.Existing ca and mg fertilizer, utilize chemical process to prepare mostly, or the recycling of Chemicals residue, nutrient is single, long-term application easily causes the hardening soil, reduce soil quality, be unfavorable for the Sustainable development of agricultural, therefore research and development also suitably use a kind of biological organic calcium fertiliser containing magnesium, can improve and stable soil pH value, can supplement calcium magnesium element again, to promotion crop yield, stable yields, improving quality of agricultural product has important reality and far-reaching significance.
Summary of the invention
The object of this invention is to provide a kind of Marine organism calcium magnesium fertilizer, the plurality of raw materials such as the shell of seashells, extra large ore, bittern and raw fish are utilized to prepare a kind of marine organism type organic calcium fertiliser containing magnesium, solve the problem of soil acidification, degeneration, the nutrient overcome existing for existing ca and mg fertilizer is single, easily cause the hardening soil, reduce the deficiency of soil quality.
Object of the present invention, is achieved by following technical proposals, a kind of Marine organism calcium magnesium fertilizer, prepares primarily of following method:
(1) oyster shell whiting preparation: the shell getting seashells, shake after dryness in the sun the coarse grain being broken into particle diameter 1-2 centimetre, obtains shell meal for subsequent use;
(2) extra large ore powder prepares: get on the beach of seashore or the tankage being used as material of construction of bay exploitation, particle diameter is the particulate of 0.1-10 millimeter, obtains extra large ore powder for subsequent use;
(3) old bittern prepares: get seawater after evaporating, concentrate and evaporating brine, obtain the bittern that concentration is not less than 28.5o, be namely commonly called as old bittern for subsequent use;
(4) shrimp pond is clay standby: get the mud in fish, shrimp, crab seawater aquaculturing pond, dries and is 20-35% and is broken into particle diameter to be that the coarse grain of 1-5 millimeter is for subsequent use to water content;
(5) polypeptide amino acid liquid preparation: get the juice after low-value small fish or processing of aquatic products, internal organ and tankage thereof, to add weight percentage be the activity of 0.1-1% is that the proteolytic enzyme of 20-100 units/gram carries out enzymolysis, enzymolysis 48-120 hour, obtain being rich in polypeptide, dipeptides aminoacids solution for subsequent use;
(6) the fertile preparation of mixing: get oyster shell whiting 30-50 part by weight, sea ore powder 20-40 part, pond sludge 15-30 part, gets 10-100 hundred million/gram of silicate bacteria 0.1-1 parts, above-mentioned raw materials mixes, the ratio of the solid-to-liquid ratio 3-5:1 of by weight/volume, adds old bittern and mixes, pile fermentation 10-20 days, pile fermentation 5-10 days is continued after turning, be dried to water content 6-10%, be ground into 20-100 order fine powder, obtain mixing fertile for subsequent use;
(7) biological calcium fertiliser containing magnesium preparation: the ratio of the solid-to-liquid ratio 6-10:1 of by weight/volume, adds polypeptide amino acid liquid and stirs complexing, surface modification, granulate, be dried to water content 15-25% and get final product in mixing fertilizer.
Take the present invention of above-mentioned measure, there is following features:
(1) bionical degree is high, complexing better effects if: at occurring in nature, shell-fish is mainly the mucus of polypeptide, dipeptide material by the major ingredient in health, carried out the multiple nutrients material such as calcium, magnesium, zinc, silicon of enrichment surrounding enviroment by the nanoaperture of housing, promote the increase of housing or natural pearls.The present invention's principle accordingly just, selects raw material self to have to inhale the nanoaperture storing function comparatively by force and the nano crack formed in crushing process carries out biological adsorption.By the organic matter of electronegative ion in bittern old in raw material and shrimp pond mud, the ionic adsorption complexing formed between the inorganic cations such as the inorganic anions such as chlorine, bromine, iodine, silicon and calcium, magnesium, sodium, potassium, finally by there is each electronegative carboxyl of polypeptide protein long-chain of anion surface activity to positive electricity nutrient ion complexings again such as calcium, magnesium, zinc in raw material polypeptide amino acid liquid, absorption exchanges, and then the nutrient such as calcium, magnesium, silicon, zinc that enrichment tool complex state more easily absorbs, not easily leaching loss under rainy condition.
(2) raw material sources are wide, and preparation cost is low, and production process does not form secondary pollution.
(3) biological activity is higher, and nutrient more comprehensively, outside the medium trace element such as deliming, magnesium, zinc, silicon, is rich in natural organic nutrient such as nitrogen, phosphorus, potassium and amino acid, humic acids etc.
(4) use range is wider, can be used as acidic soil conditioner and uses, and also can do to like calcium, and happiness magnesium crop trace element supplement uses, and also can make aquaculture water quality improving agent, rich water agent uses.
(5) side reaction reduces, and in the present invention, the alkaline matter such as calcium carbonate, calcium oxide eases up to the side effect of effective object, and avoid lime, alkaline residue quasi-alkali material being when too much using or use inequality, the soil compaction caused increases the weight of or local crop damage phenomenon.
Concrete result of use such as following example application illustrates:
(1) cane planting is applied the present invention to, and compare with conventional composite fertilizer, 150 mu of sugarcanes are selected to compare test, wherein use 120 kg of the present invention and make base manure for 100 mu every mu, use calcium superphosphate of equal value for all the other 50 mu and make base manure, plant latter three months test group and control group and all impose with 30 kilograms, the urea of same brand and same quantity, potassium sulfate 20 kilograms, year-end survey is produced, use sugarcane of the present invention, on average every mu is increased production 700 kilograms, and stimulation ratio reaches 12%.
(2) peanut cultivation is applied the present invention to, and compare with calcium superphosphate, 25 mu of peanuts are selected to compare test, wherein use the present invention 80 kilograms and make base manure for 20 mu every mu, use equivalent calcium superphosphate for all the other 5 mu and make base manure, carry out results contrast after results, use experimental plot of the present invention than the contrast field of using calcium superphosphate, on average every mu is increased production 32 kilograms, and stimulation ratio reaches 15%.
Embodiment
Embodiment 1
Preparation process:
(1) oyster shell whiting preparation: get 5000 kilograms of pearl shells, shake after dryness in the sun and be broken into the coarse grain that particle diameter is 0.1-1 centimetre, obtain shell meal for subsequent use;
(2) extra large ore powder prepares: getting 4000 kilograms of seabeaches, to coat the ore particle powder tankage of exploitation for subsequent use;
(3) old bittern prepares: get the bittern of separating out after evaporating brine in 2500 kilograms of salt pans, the old bittern obtaining concentration 28.5o is for subsequent use;
(4) shrimp pond is clay standby: get the mud in 3000 kilograms of fishes, prawn farm ponds, dries and is 20-35% and is broken into particle diameter to be that the coarse grain of 1 millimeter is for subsequent use to water content;
(5) polypeptide amino acid liquid preparation: add the juice 600 kilograms after processing of aquatic products after getting 400 kilograms low trash fishes rubbings, adding 5 kilograms of activity is that the proteolytic enzyme of 50 units/gram carries out enzymolysis, enzymolysis 48 hours, obtains being rich in the amino liquid of polypeptide, dipeptides and amino acid whose polypeptide for subsequent use;
(6) the fertile preparation of mixing: get oyster shell whiting 5000 kilograms, sea ore powder 4000 kilograms, 3000 kilograms, shrimp pond sludge, gets the silicate bacteria 20 kilograms of 1,000,000,000/gram, after above-mentioned raw materials mixing, add 2500 kilograms of old bittern and mix, pile fermentation 20 days, continues pile fermentation 10 days, is dried to water content and is no more than 10% after turning, be ground into 40 order fine powders, obtain mixing fertile for subsequent use;
(7) biological calcium fertiliser containing magnesium preparation: add 1000 kilograms of polypeptide amino acid liquid and stir in mixing fertilizer, to obtain final product.
Embodiment 2
Preparation process:
(1)-(4) are identical with embodiment 1;
(5) polypeptide amino acid liquid preparation: add the juice 600 kilograms after processing of aquatic products after getting 400 kilograms low trash fishes rubbings, adding 5 kilograms of activity is that the proteolytic enzyme of 100 units/gram carries out enzymolysis, enzymolysis 72 hours, obtains being rich in the amino liquid of polypeptide, dipeptides and amino acid whose polypeptide for subsequent use;
(6) the fertile preparation of mixing: get oyster shell whiting 5000 kilograms, sea ore powder 4000 kilograms, 3000 kilograms, shrimp pond sludge, gets the silicate bacteria 10 kilograms of 10,000,000,000/gram, after above-mentioned raw materials mixing, add 2000 kilograms of old bittern and mix, pile fermentation 20 days, continues pile fermentation 10 days, is dried to water content and is no more than 10% after turning, be ground into 40 order fine powders, obtain mixing fertile for subsequent use;
(7) biological calcium fertiliser containing magnesium preparation: add 1000 kilograms of polypeptide amino acid liquid and stir in mixing fertilizer, to obtain final product.

Claims (1)

1. a Marine organism calcium magnesium fertilizer, is characterized in that described Marine organism calcium magnesium fertilizer is prepared primarily of following method:
(1) oyster shell whiting preparation: the shell getting seashells, shake after dryness in the sun the coarse grain being broken into particle diameter 1-2 centimetre, obtains shell meal for subsequent use;
(2) extra large ore powder prepares: get on the beach of seashore or the tankage being used as material of construction of bay exploitation, particle diameter is the particulate of 0.1-10 millimeter, obtains extra large ore powder for subsequent use;
(3) old bittern prepares: get seawater after evaporating, concentrate and evaporating brine, obtain the bittern that concentration is not less than 28.5o, be namely commonly called as old bittern for subsequent use;
(4) shrimp pond is clay standby: get the mud in fish, shrimp, crab seawater aquaculturing pond, dries and is 20-35% and is broken into particle diameter to be that the coarse grain of 1-5 millimeter is for subsequent use to water content;
(5) the aminoacids solution preparation of polypeptide, dipeptides: get the juice after low-value small fish or processing of aquatic products, internal organ and tankage thereof, to add weight percentage be the activity of 0.1-1% is that the proteolytic enzyme of 20-100 units/gram carries out enzymolysis, enzymolysis 48-120 hour, obtain being rich in polypeptide, dipeptides aminoacids solution for subsequent use;
(6) the fertile preparation of mixing: get oyster shell whiting 30-50 part by weight, sea ore powder 20-40 part, shrimp pond mud 15-30 part, gets 10-100 hundred million/gram of silicate bacteria 0.1-1 parts, above-mentioned raw materials mixes, the ratio of the solid-to-liquid ratio 3-5:1 of by weight/volume, adds old bittern and mixes, pile fermentation 10-20 days, pile fermentation 5-10 days is continued after turning, be dried to water content 6-10%, be ground into 20-100 order fine powder, obtain mixing fertile for subsequent use;
(7) biological calcium fertiliser containing magnesium preparation: the ratio of the solid-to-liquid ratio 6-10:1 of by weight/volume, adds polypeptide, the aminoacids solution of dipeptides stirs, surface modification, granulate, be dried to water content 15-25% and get final product in mixing fertilizer.
CN201310296462.8A 2013-07-16 2013-07-16 A kind of Marine organism calcium magnesium fertilizer Active CN103351200B (en)

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104803714B (en) * 2014-01-27 2018-04-03 浙江华缔生物工程有限公司 Animal source waste converted products, its preparation method and application
CN104072280B (en) * 2014-06-13 2016-08-31 平和三平绿源生物技术有限公司 A kind of preparation method of chitin active calcium fertilizer
CN104788227A (en) * 2015-04-23 2015-07-22 国家海洋局第一海洋研究所 Marine organism fermentation fertilizer and preparation method thereof
CN105036952A (en) * 2015-08-04 2015-11-11 夏勇 Sea manure and preparation method thereof
CN105110909A (en) * 2015-08-05 2015-12-02 国家海洋局第一海洋研究所 Preparation method for marine biological calcium magnesium fertilizer
CN105481556A (en) * 2015-12-19 2016-04-13 青岛伟源达技术服务有限公司 Fermentation type globefish tail material soil conditioner
CN105753606A (en) * 2016-03-09 2016-07-13 广东海洋大学 Method of utilizing aquatic product viscera and oyster shells to prepare organic fertilizer
CN108558544A (en) * 2018-06-22 2018-09-21 砀山县绿源生态肥料有限公司 A kind of aquatic amino acid phosphorus calcareous fertilisers
CN117342896B (en) * 2023-12-04 2024-02-02 烟台凡西农业科技有限公司 Preparation method of marine mineral source silicon-calcium-magnesium fertilizer with soil anti-caking effect

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101803506A (en) * 2010-03-26 2010-08-18 浙江大学 Fertilizer applying mode for facility culture grapes
CN101851140A (en) * 2009-04-03 2010-10-06 中国科学院沈阳应用生态研究所 Environment-friendly fertilizer with marine bioactivity and use method thereof
CN101928188A (en) * 2009-06-19 2010-12-29 深圳市意可曼生物科技有限公司 Slow-release fertilizer with effect of soil remediation and remediation method of soil polluted by polycyclic aromatic hydrocarbons
CN102153393A (en) * 2011-05-06 2011-08-17 陈景河 Multielement fertilizer with marine organism calcium
CN102503650A (en) * 2011-09-02 2012-06-20 单茂莹 Amino acid chelated fertilizer and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851140A (en) * 2009-04-03 2010-10-06 中国科学院沈阳应用生态研究所 Environment-friendly fertilizer with marine bioactivity and use method thereof
CN101928188A (en) * 2009-06-19 2010-12-29 深圳市意可曼生物科技有限公司 Slow-release fertilizer with effect of soil remediation and remediation method of soil polluted by polycyclic aromatic hydrocarbons
CN101803506A (en) * 2010-03-26 2010-08-18 浙江大学 Fertilizer applying mode for facility culture grapes
CN102153393A (en) * 2011-05-06 2011-08-17 陈景河 Multielement fertilizer with marine organism calcium
CN102503650A (en) * 2011-09-02 2012-06-20 单茂莹 Amino acid chelated fertilizer and preparation method thereof

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Effective date of registration: 20170511

Address after: 536000, No. eight, Lane West, Henan Road, Haicheng District, the Guangxi Zhuang Autonomous Region, Beihai

Patentee after: Guangxi Wei Heng Ecological Agriculture Co., Ltd.

Address before: Tibet Road, Haicheng District of Beihai City Sanqing Park A the Guangxi Zhuang Autonomous Region 536000 building 1-401

Patentee before: Wu Jinhua

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