CN103343051B - Fragrance composition - Google Patents
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- CN103343051B CN103343051B CN201310279408.2A CN201310279408A CN103343051B CN 103343051 B CN103343051 B CN 103343051B CN 201310279408 A CN201310279408 A CN 201310279408A CN 103343051 B CN103343051 B CN 103343051B
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- flavor compositions
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- isopropyl
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0069—Heterocyclic compounds
- C11B9/0096—Heterocyclic compounds containing at least two different heteroatoms, at least one being nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/003—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing less than six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
- Seasonings (AREA)
Abstract
Provided is a fragrance composition having a natural rose aroma with freshness, sweetness, and softness, which is hardly reproduced by combining aroma components conventionally known as rose aromas. Also provided is a fragrance composition having excellent rose-like naturalness, freshness, and richness. More specifically, provided are: a fragrance composition, having added thereto 2-isopropyl-4-methylthiazole alone or in combination with rose oxide; a method of manufacturing the same; and a method of imparting an aroma to a fragrance composition, the method including adding 2-isopropyl-4-methylthiazole to a base fragrance composition having a rose-like aroma as a main aroma. Also provided are: a rose-like fragrance composition, having added thereto methyl epijasmonate alone or in combination with 2-isopropyl-4-methylthiazole; a method of manufacturing the same; and a method of imparting an aroma to a fragrance composition, the method including adding methyl epijasmonate alone or in combination with 2-isopropyl-4-methylthiazole to a base fragrance composition having a rose-like aroma as a main aroma.
Description
The divisional application that the application is the applying date is on March 1st, 2010, application number is " 201080010823.2 ", denomination of invention is the application of " flavor compositions ".
Technical field
What the present invention relates to is flavor compositions, especially relates to the flavor compositions with the such excellent aroma of rose.
Background technology
The fragrance of rose is deserved to be called the outstanding fragrance of " king in spending ", is just used in a variety of manners from before thousands of year.Since ancient times, which kind of the fragrance of rose do not have be the fragrance being better than natural rose, therefore, in order to obtain the fragrance of the representative and senior rose of most, and in cosmetic composition etc., be mixed with the natural rose essential extracted from natural rose (petal) also used.Such natural rose essential except from B.C. ancient times just with enjoy fragrance object and by except use, also by as medicinal or be used in sacrifice ceremony etc.This natural rose essential is extract from the petal of pink damask rose (Rosa damascena) class or moss rose (Rosa centifolia) class etc. in ancient times, and be made up of the main component the in so-called fragrance of Rose type " ancient times ", but, its fragrance is from not changing up to now at that time, being the intense flavors with dense slightly sweet taste, is in the past or its fragrance does not all change now.
On the other hand, by with the original seed of above-mentioned pink damask rose class or moss rose class etc. for parent, then, except the natural hybridization between original seed, also have for cultivating as appreciating with the artificial hybridization active after 19th-century of outstanding kind, the kind quantity of rose has also occurred that the burst almost reaching 20000 more than thousand kinds of degree increases, and the fragrance of rose also there occurs large change thereupon.In so-called " modern distance education system (Modern Rose) ", known has the fragrant Chinese rose (Tea Rose) of tea or the fragrant Chinese rose (Hybrid Tea Rose) of hybridization tea etc.Recently, what be developed out by genetic manipulation take blueness as being also popular by the blue moon (Blue moon) etc. spending or be called as blue series rose of homophony.About the flavour ingredient of rose, be Geraniol, geraniol, rose oxide, 2 phenylethyl alcohol etc., carried out Aroma analysis up to now, there will be a known hundreds of flavour ingredient.
In addition, as Rose type essence, there will be a known the situation (with reference to patent documentation 1) mixing 2-methylthiazol in the Rose type essence of pink damask rose class or moss rose class.
" 2-isopropyl-4-methyl thiazole " in the present invention there will be a known and be included in situation in tea, tropical fruit durian, yeast extract (with reference to non-patent literature 1 ~ 2) at occurring in nature, and is mainly used in as flavoring ingredients in the seasoning composition of edible meat type or tropical fruit type.
But, from the aroma characteristic of this compound, do not learn the utilizability of the flavour ingredient as spices.
Certainly, also from the aroma component of rose, the report that 2-isopropyl-4-methyl thiazole is such has not been found at present.
In addition, as Rose type essence, there will be a known and mix Flower of Arabian Jasmine oil condition (with reference to non-patent literature 3) in the Rose type essence of moss rose class.
" table methyl jasmonate " in the present invention, there will be a known at the flavour ingredient of occurring in nature as jasmine absolute (Jasmine absolute) (with reference to non-patent literature 4 ~ 6), orchid (with reference to non-patent literature 7) etc., being included in the situation in the fruits such as oranges and tangerines (lemon) (with reference to non-patent literature 8 ~ 9) in addition, being mainly used in spices use or food flavouring use to give jasmine type fragrance.Such as, there will be a known the situation (with reference to patent documentation 2) used as the active ingredient of Japan's orchid type flavor compositions by table methyl jasmonate.
But, from the aroma characteristic of this compound, do not learn the utilizability as Rose type aroma component.Certainly, also do not found at present to show the such report of methyl jasmonate from the aroma component of rose.
In addition, as in the aroma component of domestic rose, there is the report of " methyl jasmonate " of the steric isomer as table methyl jasmonate, but, also do not found that this compound, i.e. " table methyl jasmonate " are as the such report of the aroma component of rose (with reference to non-patent literature 10) up to now.
Patent documentation
Patent documentation 1: Japanese Unexamined Patent Publication 2006-219413 publication
Patent documentation 2: Japanese Unexamined Patent Publication 3-284618 publication
Non-patent literature
Non-patent literature 1:Hugo Weenen et al., J.Agric.Food Chem., 1996,44, p.3291-3293
Non-patent literature 2:Jennifer M.Ames, American Chemical SocietySymposium series, 1994,564 (SULFUR COMPOUNDS IN FOODS), p.147-159
Non-patent literature 3: special permission Room publication known conventional techniques collection spices III portion perfuming cosmetic spices P482
Non-patent literature 4: print rattan unit one work " " supplement revised edition " synthetic perfume chemistry and knowledge of goods " chemical industry day newspaper office 675-677 page on March 22nd, 2005
Non-patent literature 5:FLAVOR AND FRAGRANCE JOURNAL, VOL.16,161-163 (2001)
Non-patent literature 6:FLAVOR AND FRAGRANCE JOURNAL, VOL.1,115-119 (1986)
Non-patent literature 7:Agric.Biol.Chem., 54 (4), 1029-1033, (1990)
Non-patent literature 8:J.Agric.Food Chem., 2008,56,5475-5479
Non-patent literature 9:J.Agric.Food Chem., 1984,32,1001-1003
Non-patent literature 10:FLAVOR AND FRAGRANCE JOURNAL, VOL.5,115-120 (1990)
Summary of the invention
Therefore, even if composition known at present for the fragrance as rose is combined, be also difficult to pure and fresh, the fragrant and mellow fragrance that reproduction rose has, seeking the method realized always.Therefore, the object of the invention is to, provide a kind of and there is the flavor compositions of natural rose scent having freshness, fragrant and sweet sense, soft texture.
In addition, reproduce the outstanding natural sense having that rose has, pure and fresh, fragrant and mellow fragrance is difficult, seeking the method realized always.Therefore, the object of the invention is to, provide a kind of and there is outstanding Rose type natural sense, pure and fresh, fragrant and mellow flavor compositions.
The present inventors in order to the result solving above-mentioned prior art problem and repeatedly inquire into are, find by using as the aroma component in Flos Rosae Rugosae quintessence oil by the composition 2-isopropyl-4-methyl thiazole understood not individually or together add with rose oxide, can create the natural rose scent with freshness, fragrant and sweet sense, soft texture, this fragrance makes people remember the rose of blue series.
That is, the present invention comprises following content.
(1) with the addition of the flavor compositions that 2-isopropyl-4-methyl thiazole is feature.
(2) be flavor compositions described in above-mentioned (1) of Rose type fragrance.
(3) described in above-mentioned (1) or (2) flavor compositions, is characterized in that, with the addition of 2-isopropyl-4-methyl thiazole and rose oxide.
(4) flavor compositions described in any one of above-mentioned (1) ~ (3), it is characterized in that, the interpolation concentration of the 2-isopropyl-4-methyl thiazole in flavor compositions is 0.1ppm ~ 5000ppm.
(5) flavor compositions described in any one of above-mentioned (1) ~ (4), it is characterized in that, the 2-isopropyl-4-methyl thiazole in flavor compositions and the ratio of mixture of rose oxide are in the scope of 1: 1 ~ 1: 250.
(6) to the adding method of the fragrance of flavor compositions, it is characterized in that, in the perfume base flavor compositions being homophony with Rose type fragrance, add 2-isopropyl-4-methyl thiazole.
(7) adding method of described in above-mentioned (6) fragrance, it is characterized in that, the interpolation concentration of the 2-isopropyl-4-methyl thiazole in flavor compositions is 0.1ppm ~ 5000ppm.
(8) adding method of described in above-mentioned (6) or (7) fragrance, it is characterized in that, fragrance is more than one the fragrance texture selected from freshness, fragrant and sweet sense and soft texture.
(9) be the perfuming cosmetic of feature, medicine part outer article or groceries with flavor compositions described in any one being mixed with above-mentioned (1) ~ (5).
(10) to add the manufacture method of the flavor compositions that 2-isopropyl-4-methyl thiazole is feature.
(11) flavor compositions is manufacture method described in above-mentioned (10) of Rose type fragrance.
(12) described in above-mentioned (10) or (11) manufacture method, is characterized in that, adds 2-isopropyl-4-methyl thiazole and rose oxide.
(13) manufacture method described in any one of above-mentioned (10) ~ (12), it is characterized in that, the interpolation concentration of the 2-isopropyl-4-methyl thiazole in flavor compositions is 0.1ppm ~ 5000ppm.
(14) manufacture method described in any one of above-mentioned (10) ~ (13), it is characterized in that, the 2-isopropyl-4-methyl thiazole in flavor compositions and the ratio of mixture of rose oxide are in the scope of 1: 1 ~ 1: 250.
In addition, the present inventors find, as the aroma component in Flos Rosae Rugosae quintessence oil can create have outstanding Rose type natural sense, pure and fresh, fragrant and mellow fragrance not by the component list methyl jasmonate understood by adding.
That is, the present invention comprises following content.
(15) with to the addition of table methyl jasmonate be feature Rose type flavor compositions (but, as table methyl jasmonate interpolation form and only add the natural jasmine fragrance containing table methyl jasmonate situation except).
(16) described in above-mentioned (15) Rose type flavor compositions, is characterized in that, with the addition of table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
(17) described in above-mentioned (15) or (16) Rose type flavor compositions, it is characterized in that, the interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm.
(18) Rose type flavor compositions described in any one of above-mentioned (15) ~ (17), it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100: 1 ~ 1: 500.
(19) be the perfuming cosmetic of feature, medicine part outer article or groceries with Rose type flavor compositions described in any one mixing above-mentioned (15) ~ (18).
(20) a kind of adding method of the fragrance to flavor compositions, it is characterized in that, in the perfume base flavor compositions being homophony with Rose type fragrance add table methyl jasmonate (but, as table methyl jasmonate interpolation form and only add containing table methyl jasmonate natural jasmine fragrance situation except).
(21) adding method of described in above-mentioned (20) fragrance to flavor compositions, is characterized in that, in the perfume base flavor compositions being homophony with Rose type fragrance, adds table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
(22) adding method of described in above-mentioned (20) or (21) fragrance, it is characterized in that, the interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm.
(23) adding method of fragrance described in any one of above-mentioned (20) ~ (22), it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100: 1 ~ 1: 500.
(24) adding method of fragrance described in any one of above-mentioned (20) ~ (23), it is characterized in that, fragrance is more than one the fragrance texture selected from natural sense, freshness and fragrant and mellow sense.
(25) with the manufacture method of to add table methyl jasmonate be feature Rose type flavor compositions (but, as table methyl jasmonate interpolation form and only add the natural jasmine fragrance containing table methyl jasmonate situation except).
(26) manufacture method of described in above-mentioned (25) Rose type flavor compositions, is characterized in that, with the addition of table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
(27) manufacture method of described in above-mentioned (25) or (26) Rose type flavor compositions, it is characterized in that, the interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm.
(28) manufacture method of Rose type flavor compositions described in any one of above-mentioned (25) ~ (27), it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100: 1 ~ 1: 500.
invention effect
Adopting words of the present invention, by adding 2-isopropyl-4-methyl thiazole, can obtain being endowed the flavor compositions of natural fragrance with freshness, fragrant and sweet sense, soft texture.
And then, by adding 2-isopropyl-4-methyl thiazole in the perfume base flavor compositions being homophony with Rose type fragrance, can obtain being imparted the flavor compositions of natural fragrance with freshness, fragrant and sweet sense, soft texture further.
In addition, adopting words of the present invention, by adding table methyl jasmonate, can obtain being endowed the flavor compositions of fragrance with natural sense, freshness and fragrant and mellow sense.
And then, by adding table methyl jasmonate in the perfume base flavor compositions being homophony with Rose type fragrance, can obtain being imparted the flavor compositions of fragrance with natural sense, freshness and fragrant and mellow sense further.
Embodiment
Below, the present invention is described in detail.
1) flavor compositions containing 2-isopropyl-4-methyl thiazole
The feature of flavor compositions of the present invention is, with the addition of 2-isopropyl-4-methyl thiazole (2-Isopropyl-4-methyl thiazole).By adding 2-isopropyl-4-methyl thiazole in perfume base flavor compositions (Base ffagrancecomposition), outstanding Rose type fragrance can be brewed.
[fragrance component]
The 2-isopropyl-4-methyl thiazole used in the present invention is known compound, and known method can be utilized to manufacture.In addition, this compound is the compound commercially sold, therefore, it is possible to easily obtain.
Up to now, also do not found that this compound, namely 2-isopropyl-4-methyl thiazole are as the such report of the aroma component of rose.
In addition, add rose oxide (Rose oxide) outside 2-isopropyl-4-methyl thiazole again, then the magnificent natural sense that rose has improves further.
That is, in flavor compositions of the present invention, be more preferably the material that with the addition of 2-isopropyl-4-methyl thiazole and rose oxide.
Rose oxide is known compound, and known method can be utilized to manufacture.In addition, this compound is the compound commercially sold, therefore, it is possible to easily obtain.
[blending ratio]
In perfume base flavor compositions, add 2-isopropyl-4-methyl thiazole, then can give the natural sense with pure and fresh (fresh), fragrant and sweet (sweet), soft texture to fragrance.It adds concentration is preferably 0.1ppm ~ 5000ppm as the ultimate density in perfume base flavor compositions, is more preferably 1ppm ~ 100ppm, is especially preferably 5ppm ~ 50ppm.
When the combined amount of 2-isopropyl-4-methyl thiazole is very few, then there is effect of the present invention not by situation about playing, on the other hand, the balance that then there is fragrance time too much is deteriorated, fruity sense grow peach as maturation or tropical fruit thus with have rose the natural sense of pure and fresh, fragrant and sweet, soft texture that has situation about differing greatly.
In addition, if in flavor compositions of the present invention so add rose oxide, be then endowed the natural sense of green grass type (green), floral type in fragrance.Its addition, the 2-isopropyl-4-methyl thiazole in preferred flavor compositions and the ratio of mixture of rose oxide are in the scope of 1: 1 ~ 1: 250, are more preferably 1: 2 ~ 1: 10, are especially preferably 1: 3 ~ 1: 8.
Then there is above-mentioned effect when the ratio of mixture of rose oxide is very few not by situation about playing, on the other hand, the balance that then there is fragrance time too much is deteriorated, situation about differing greatly with the natural sense with pure and fresh, fragrant and sweet, the soft texture that rose has.
[fragrance adding method and manufacture method to flavor compositions]
Rose scent that the flavor compositions that the present invention relates to has form the brute force and the succinct fragrance of enthusiasm and the fragrant rose (Tea Rose) of tea simultaneously with pink damask rose (Damask Rose) even high gracefulness fragrance feature, the fragrance of uniqueness that do not have without him.
That is, in the present invention, by adding 2-isopropyl-4-methyl thiazole in the perfume base flavor compositions being homophony with Rose type fragrance, adding 2-isopropyl-4-methyl thiazole and rose oxide by being more preferably combination, fragrance can be given to flavor compositions, especially can give the soft of freshness, fragrant and sweet sense, soft texture etc. and natural fragrance texture.
About the preferred interpolation concentration of the 2-isopropyl-4-methyl thiazole in the adding method of the fragrance to flavor compositions of the present invention and ratio of mixture when using rose oxide simultaneously, as describing of above flavor compositions for the present invention.
In addition, in the present invention, " perfume base flavor compositions " is part and parcel for essence, refer to become colored fragrance, fruit the essence of skeleton of all kinds fragrance such as fragrance, the fragrance of oranges and tangerines, the fragrance of vanilla, refer to the characteristic in order to give all aromatics to flavor compositions (essence used in finished product) and the essence used.
As the perfume base flavor compositions used in the present invention, preferably there is the material of Rose type fragrance, such as, can enumerate the material comprising Geraniol, geraniol, phenylethyl alcohol, Linaool, rhodinol, meraneine, citronellyl acetate, Eugenol.
In addition, as the manufacture method of the flavor compositions that the present invention relates to, have no particular limits except adding 2-isopropyl-4-methyl thiazole, can usual method be adopted.
In flavor compositions of the present invention, only otherwise destroy the balance of fragrance, the solvent of ethanol, dipropylene glycol, diethyl phthalate, propylene glycol, triethyl citrate, peruscabin, glycerine, glycerine triacetate etc. can also be used.In addition, can as required and the known flavor confect thing such as mixed solubilizers, stablizer, antioxidant, UV light absorber, tinting material.
In addition, as in order to form flavor compositions of the present invention by other fragrance components used together with 2-isopropyl-4-methyl thiazole, both can be natural perfume also can be synthetic perfume, such as, can enumerate Linaool, Geraniol, rose oxide, vernol, 2 phenylethyl alcohol, γ-hexalactone etc.
And then, by adding 2-isopropyl-4-methyl thiazole in the perfume base flavor compositions being homophony with Rose type fragrance, can obtain by the flavor compositions imparting the natural fragrance with pure and fresh, fragrant and sweet, soft texture further.
The flavor compositions that the present invention relates to, can be applied to the makeup such as perfume, Gu Longshui, skin cream, emulsion, foundation cream, the agent of the clean body such as soap, body wash, in the perfuming cosmetic of the Hair grooming makeup such as shampoo, conditioner, hair conditioner etc.
In addition, also can be used in the medicine part outer articles (quasi drug) such as balneation agent, hair dye, in the groceries of space spray, spraying type perfume compound, line spices, clothes etc. etc.
The addition of flavor compositions of the present invention to above-mentioned perfuming cosmetic, medicine part outer article or groceries etc. is not particularly limited, (interpolation) amount equal with the addition of common flavor compositions can be mixed in various perfuming cosmetic, medicine part outer article or groceries, that is, usually to mixing (interpolation) 0.001 ~ 100 quality % (mass percent) left and right such as perfuming cosmetic, medicine part outer article, foreign material.
2) flavor compositions containing table methyl jasmonate
In addition, the feature of flavor compositions of the present invention is, with the addition of table methyl jasmonate.By adding table methyl jasmonate in perfume base flavor compositions, outstanding Rose type fragrance can be brewed.
[fragrance component]
In the present invention, be used as " the table methyl jasmonate " of " along body " of methyl jasmonate (Methyl jasmonate).In addition, the synthetics of general methyl jasmonate is based on " anti-body " (with reference to non-patent literature 4).
At this, table methyl jasmonate (Methyl epijasmonate) be two side chains of pentamethylene ring at methyl jasmonate joint portion on there is the compound of suitable body structure, specifically, it is the compound represented with " 1; 2-cis-3-oxo-2 α-[(Z)-pentenyl]-1 α-cyclopentaneacetic acid methyl esters (methyl1,2-cis-3-oxo-2 α-[(Z)-2-pentenyl]-1 α-cyclopentaneacetate) ".
Up to now, also do not find to show methyl jasmonate as the such report of the flavour ingredient of rose.
Table methyl jasmonate is known compound, and known method can be utilized to manufacture.
As the table methyl jasmonate used in the present invention, such as, can be used in synthesis methyl jasmonate the material of the amount that improve table methyl jasmonate (along body).Specifically, the containing ratio preferably showing methyl jasmonate (along body) is more than 5%, more preferably more than 10%, and be further preferably more than 15%, be especially preferably more than 20%.
In addition, such compound is the compound commercially sold, therefore, it is possible to easily obtain.As the synthetic table methyl jasmonate that improve the amount of table methyl jasmonate that market is sold, such as, can exemplify out " ZEPPIN (registered trademark) " (table methyl jasmonate amount is 20 ~ 23%) " Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) system " etc.In addition, the material utilizing the manufacture method of the epimerization height containing ratio material of known methyl jasmonate (such as with reference to Japanese Patent No. 2857628 publication (epimer amount is 6 ~ 8%)) to obtain can be used.
In addition, outside table methyl jasmonate, also add 2-isopropyl-4-methyl thiazole, then the beautiful feeling that has of rose or natural sense improve further.
That is, in flavor compositions of the present invention, preferably with the addition of the material of table methyl jasmonate and 2-isopropyl-4-methyl thiazole further.
2-isopropyl-4-methyl thiazole is known compound, and known method can be utilized to manufacture.In addition, this compound is the compound commercially sold, therefore, it is possible to easily obtain.
[blending ratio]
In perfume base flavor compositions, add table methyl jasmonate, then give natural sense, freshness and fragrant and mellow sense to fragrance.
Its addition, the interpolation concentration of the table methyl jasmonate in preferred flavor compositions is 0.1ppm ~ 1000ppm, is more preferably 0.2ppm ~ 200ppm, is especially preferably 2ppm ~ 20ppm.Then there is effect of the present invention when combined amount is very few not by situation about playing, on the other hand, the balance that then there is fragrance time too much is deteriorated, the situation that the natural sense had with rose, freshness and fragrant and mellow sense differ greatly.
In addition, in flavor compositions of the present invention and then add 2-isopropyl-4-methyl thiazole, then give the natural sense with pure and fresh, fragrant and sweet, the soft texture that rose has to fragrance further.Its addition, the ratio of mixture of the table methyl jasmonate in preferred flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100: 1 ~ 1: 500, be more preferably in the scope of 10: 1 ~ 1: 10, be especially preferably in the scope of 2: 1 ~ 1: 5.
When the combined amount of 2-isopropyl-4-methyl thiazole is very few, then there is above-mentioned effect not by situation about playing, on the other hand, the balance that then there is fragrance time too much is deteriorated, the situation that the natural sense had with rose, freshness and fragrant and mellow sense differ greatly.
[fragrance adding method and manufacture method to flavor compositions]
In the present invention, by interpolation table methyl jasmonate in the perfume base flavor compositions being homophony with Rose type fragrance, by being more preferably combination interpolation table methyl jasmonate and 2-isopropyl-4-methyl thiazole, fragrance can be given to flavor compositions, especially can give the soft fragrance of natural sense, freshness and fragrant and mellow sense etc.
About the ratio of mixture in the preferred interpolation concentration to the table methyl jasmonate in the fragrance adding method of flavor compositions of the present invention and when using 2-isopropyl-4-methyl thiazole simultaneously, as describing of above flavor compositions for the present invention.
In addition, " perfume base flavor compositions " is herein part and parcel for essence, refer to become colored fragrance, fruit the essence of various types of skeleton such as fragrance, the fragrance of oranges and tangerines, the fragrance of vanilla, refer to the characteristic in order to give all aromatics to flavor compositions (essence used in finished product) and the essence used.
As the perfume base flavor compositions used in the present invention, preferably to have the material of the such fragrance of rose, such as, can enumerate the material comprising Geraniol, geraniol, phenylethyl alcohol, Linaool, rhodinol, meraneine, citronellyl acetate, Eugenol.
In addition, as the manufacture method of the flavor compositions that the present invention relates to, have no particular limits except interpolation table methyl jasmonate, can usual method be adopted.
In flavor compositions of the present invention, only otherwise destroy the balance of fragrance, the solvent of ethanol, dipropylene glycol, diethyl phthalate, propylene glycol, triethyl citrate, peruscabin, glycerine, glycerine triacetate etc. can also be used.In addition, can mixed solubilizers, stablizer, antioxidant, UV light absorber, tinting material etc. are known as required flavor confect thing.
In addition, other fragrance components used together with 2-isopropyl-4-methyl thiazole as using to manufacture flavor compositions of the present invention, with above-mentioned table methyl jasmonate, both can be natural perfume also can be synthetic perfume, such as, can enumerate Linaool, Geraniol, rose oxide, vernol, 2 phenylethyl alcohol, γ-hexalactone etc.
And then, by adding table methyl jasmonate in the perfume base flavor compositions being homophony with Rose type fragrance, can obtain being imparted the flavor compositions of fragrance with natural sense, delicate fragrance sense and fragrant and mellow sense further.
[product]
Flavor compositions of the present invention can be applied to the makeup of perfume, Gu Longshui, skin cream, emulsion, foundation cream etc., the clean body agent of soap, body wash etc., in the perfuming cosmetic of the Hair grooming makeup such as shampoo, conditioner, hair conditioner etc.
In addition, also can be used in the medicine part outer article of balneation agent etc., in the groceries of space spray, spraying type perfume compound, line spices, clothes etc. etc.
The addition of flavor compositions of the present invention to above-mentioned perfuming cosmetic, medicine part outer article or groceries etc. is not particularly limited, (interpolation) amount equal with the addition of common flavor compositions can be mixed in various perfuming cosmetic, medicine part outer article or groceries, that is, usually to mixing (interpolation) 0.001 ~ 100 quality % (mass percent) left and right such as perfuming cosmetic, medicine part outer article, groceries.
Embodiment
Below, the present invention is described in further detail for embodiment, but therefore the present invention is not subject to any restriction.As long as no special record, combined amount represents mass parts.
" embodiment 1 " flavor compositions containing 2-isopropyl-4-methyl thiazole
The effect test of [test example 1-1] 2-isopropyl-4-methyl thiazole
(1) Rose type perfume base flavor compositions
Rose type perfume base flavor compositions has been prepared by common method according to following formula.
< Formulation Example 1-1>
(2) evaluation of fragrance
In the perfume base flavor compositions of Formulation Example 1-1, test preparation example 1-1-1 ~ test example 1-1-10 by the ultimate density interpolation 2-isopropyl-4-methyl thiazole that can become shown in table 1, and carried out the evaluation of fragrance.The mean value of evaluation result is represented in Table 1.
In addition, the evaluation of fragrance is evaluated experts by three and is pressed and state judgement criteria and carry out.
4: there is very outstanding Rose type nature fragrance.
3: there is outstanding Rose type nature fragrance.
2: there is Rose type nature fragrance.
1: almost there is no the fragrance that rose is such.
[table 1]
Clearly can finding out from table 1, in order to form Rose type fragrance, preferably by the ultimate density that can become 0.1ppm ~ 5000ppm, 2-isopropyl-4-methyl thiazole being added to perfume base flavor compositions, more preferably 1 ~ 1000ppm, especially preferably 5ppm ~ 50ppm.
The effect test of [test example 1-2] rose oxide
In the perfume base flavor compositions of Formulation Example 1-1, test preparation example 1-2-1 ~ test example 1-2-7 by the ultimate density mixing rose oxide that can become shown in table 2, and the evaluation of fragrance has been carried out in the same manner as test example 1-1.The mean value of evaluation result is represented in table 2.
[table 2]
Clearly can find out from table 2, in order to form Rose type fragrance, perfume base flavor compositions preferably be added to rose oxide by the ultimate density that can become 5ppm ~ 5000ppm, is more preferably 50ppm ~ 500ppm.
The merging effect test of [test example 1-3] 2-isopropyl-4-methyl thiazole and rose oxide
In the perfume base flavor compositions of Formulation Example 1-1, so that the ultimate density mixing 2-isopropyl-4-methyl thiazole shown in table 3 and rose oxide and test preparation example 1-3-1 ~ test example 1-3-10 can be become, and carry out the evaluation of fragrance in the same manner as test example 1-1.The mean value of evaluation result is represented in table 3.
[table 3]
The ratio of mixture of #2-isopropyl-4-methyl thiazole and rose oxide
As can be clearly seen from Table 3, be form Rose type fragrance, the ratio of mixture of 2-isopropyl-4-methyl thiazole and rose oxide with preferably 1: 1 ~ 1: 250, more preferably 1: 2 ~ 1: 10, especially preferably 1: 3 ~ 1: 8.
The effectiveness comparison of [test example 1-4] 2-isopropyl-4-methyl thiazole and 2-methylthiazol
(1) Rose type perfume base flavor compositions
The Rose type perfume base flavor compositions according to following formulated.
< Formulation Example 1-2>
(2) evaluation of fragrance
In the perfume base flavor compositions of Formulation Example 1-2, prepare and be mixed with in ratio shown in table 4 the sample A (check plot) that the sample B of 1% solution (solvent is dipropylene glycol (DPG)) of 2-isopropyl-4-methyl thiazole, the sample C being mixed with 1% solution (solvent is DPG) of 2-methylthiazol and substituted thiazole are mixed with DPG.
With sample A district in contrast, compare containing the sample B of 2-isopropyl-4-methyl thiazole of the 0.005% and sample C containing the 2-methylthiazol of 0.005%, and carried out the evaluation of fragrance by seven evaluation experts according to following judgement criteria.The mean value of evaluation result is represented in table 4.
5: impart very outstanding natural sense, freshness, fragrant and mellow sense.
4: impart outstanding natural sense, freshness, fragrant and mellow sense.
3: impart natural sense outstanding a little, freshness, fragrant and mellow sense.
2: impart natural sense, freshness, fragrant and mellow sense.
1: to no effect.
[table 4]
| Composition | Sample A | Sample B | Sample C |
| The composition of Formulation Example 1-2 | 995 | 995 | 995 |
| Dipropylene glycol (DPG | 5 | - | - |
| 2-isopropyl-4-methyl thiazole (1%DPG solution) | - | 5 | - |
| 2-methylthiazol (1%DPG solution) | - | - | 5 |
| Fragrance is evaluated | 1.0 | 4.9 | 2.6 |
As can be clearly seen from Table 4, the sample B being mixed with 2-isopropyl-4-methyl thiazole has been endowed very outstanding natural sense, freshness, fragrant and mellow sense.On the other hand, the sample C being mixed with 2-methylthiazol has been endowed natural sense, freshness, fragrant and mellow sense, but, grade comparatively quite low compared with sample B.
[test example 1-5] stability test
The concentration making the flavor compositions of test example 1-3-5 by 5% is dissolved in 95% ethanol, and respectively at 0 DEG C and 40 DEG C the material taken care of after three months investigated the stability of fragrance.
Consequently, to the material of the flavor compositions that with the addition of 2-isopropyl-4-methyl thiazole and rose oxide keeping at 40 DEG C and the material of keeping at 0 DEG C with just dissolve after flavor compositions soon compare, do not find the change of fragrance, maintain good fragrance.
[Production Example 1-1] astringent
Astringent is obtained according to following formula by common method.
[Production Example 1-2] protective skin cream
Protective skin cream is obtained according to following formula by common method.
[Production Example 1-3] emulsion
Emulsion is obtained according to following formula by common method.
[Production Example 1-4] takes care of hair film
Following compositions is undertaken mixing by common method and has prepared hair care film.
[Production Example 1-5] shampoo
Following compositions is undertaken mixing by common method and has prepared shampoo.
[Production Example 1-6] bathliquid
The bathliquid according to following formulated.That is, utilize V-mixer the following compositions except flavor compositions stirred complete evenly after, add flavor compositions, be stirred well to further evenly and obtain bathliquid.
[Production Example 1-7] gel fragrance
The gel fragrance according to following formulated.That is, carrageenin, propylene glycol and propylparaben are being mixed and while stirring, is adding deionized water, and be heated to about 80 DEG C while being carried out reposefully stirring.Then, be cooled to about 65 DEG C, while homogenizer stirs it with 3000rpm in use, add flavor compositions and after being formed as homogeneous phase, pouring in the container of regulation, after naturally cooling, obtain perfume compound.
" embodiment 2 ": the flavor compositions containing table methyl jasmonate
[test example 2-1] shows the effect test of methyl jasmonate
(1) Rose type perfume base flavor compositions
Rose type perfume base flavor compositions has been prepared by common method according to following formula.
< Formulation Example 2-1>
(2) evaluation of fragrance
In the perfume base flavor compositions 995 parts of Formulation Example 2-1, using the only dipropylene glycol (DPG) (sample A) as solvent, a large amount of methyl jasmonate (" ZEPPIN* " containing table methyl jasmonate, Japan ゼ Caiン Co., Ltd. (ZEON CORPORATION) system) 1%DPG solution (sample B), the 1%DPG solution (sample C) of methyl jasmonate (Off ァ ィ Le メ bis-ッ ヒ S.A. (Firmenich S.A.) product), the 1%DPG solution (sample D) of jasmine absolute (Jasmine absolute) adds 5 parts respectively, and carried out the evaluation of fragrance.The mean value of evaluation result is represented in table 5.
* the methyl jasmonate (Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) products catalogue 2008 the 44th page) containing 20 ~ 23% table methyl jasmonates
In addition, evaluate expert by seven and carry out the evaluation of fragrance according to following judgement criteria.
5: impart the such natural sense of very outstanding rose, freshness, fragrant and mellow sense.
4: impart the such natural sense of outstanding rose, freshness, fragrant and mellow sense.
3: impart the such natural sense of rose outstanding a little, freshness, fragrant and mellow sense.
2: impart the such natural sense of rose, freshness, fragrant and mellow sense.
1: to no effect.
[table 5]
As can be clearly seen from Table 5, in Rose type perfume base flavor compositions, a large amount of sample B containing table methyl jasmonate has been endowed very outstanding Rose type natural sense, freshness, fragrant and mellow sense.
On the other hand, the sample C being mixed with the methyl jasmonate that chemical structure is similar to is not endowed enough freshnesss, fragrant and mellow sense, and fragrance glamour is not enough.
In addition, although be mixed with and contain table methyl jasmonate and the sample D of known jasmine absolute with trace and be endowed dense and there is the fragrance of a flower fragrance of sense of fulfillment (Voluminousness), be also not sufficient to the fragrance giving rose characteristic.
[test example 2-2] shows the effect test of methyl jasmonate
(1) Rose type perfume base flavor compositions
Rose type perfume base flavor compositions has been prepared by common method according to following formula.
< Formulation Example 2-2>
(2) evaluation of fragrance
In the perfume base flavor compositions of Formulation Example 2-2, the ultimate density shown in table 6 can be become by table methyl jasmonate and add a large amount of methyl jasmonate (" ZEPPIN* " Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) system) test preparation example 2-2-1 ~ test example 2-2-12 containing table methyl jasmonate, and carry out the evaluation of fragrance.The mean value of evaluation result is represented in table 6.
* the methyl jasmonate (Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) products catalogue 2008 the 44th page) containing 20 ~ 23% table methyl jasmonates
In addition, evaluate expert by seven and carry out the evaluation of fragrance according to following judgement criteria.
5: impart the such natural sense of very outstanding rose, freshness, fragrant and mellow sense.
4: impart the such natural sense of outstanding rose, freshness, fragrant and mellow sense.
3: impart the such natural sense of rose outstanding a little, freshness, fragrant and mellow sense.
2: impart the such natural sense of rose, freshness, fragrant and mellow sense.
1: to no effect.
[table 6]
* the amount of the table methyl jasmonate in " ZEPPIN " is set to 20% epimer amount (ultimate density) when calculating
As can be clearly seen from Table 6, in order to form Rose type fragrance, table methyl jasmonate is preferably 0.1ppm ~ 1000ppm in perfume base flavor compositions, is more preferably 0.2 ~ 200ppm, is especially preferably 2ppm ~ 20ppm.
The combined effect that [test example 2-3] shows methyl jasmonate and 2-isopropyl-4-methyl thiazole is tested
In the perfume base flavor compositions of Formulation Example 2-2, by the ultimate density shown in table 7 can be become, the methyl jasmonate (" ZEPPIN* " Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) system) in a large number containing table methyl jasmonate is carried out mixed preparing test example 2-3-1 ~ test example 2-3-10 with 2-isopropyl-4-methyl thiazole, and carried out the evaluation of fragrance in the same manner as test example 2-1.The mean value of evaluation result is represented in table 7.
* the methyl jasmonate (Japanese ゼ Caiン Co., Ltd. (ZEON CORPORATION) products catalogue 2008 the 44th page) containing 20 ~ 23% table methyl jasmonates
In addition, evaluate expert by seven and the evaluation of the test example 2-3-1 for the mixing identical with test example 2-2-7 is set to 5, and carried out the evaluation of fragrance according to following judgement criteria.
9: impart the such natural sense of very outstanding rose, freshness, fragrant and mellow sense.
8: impart the such natural sense of outstanding rose, freshness, fragrant and mellow sense.
7: impart the such natural sense of rose outstanding a little, freshness, fragrant and mellow sense.
6: impart the such natural sense of rose, freshness, fragrant and mellow sense.
5: to no effect (=equal with the most high praise of test example 2-2).
[table 7]
* the amount of the table methyl jasmonate in " ZEPPIN " is set to 20% epimer amount (ultimate density) when calculating
# shows the ratio of mixture of methyl jasmonate and 2-isopropyl-4-methyl thiazole
As can be clearly seen from Table 7, in order to very outstanding Rose type natural sense, pure and fresh, fragrant and mellow fragrance can be given, the ratio of mixture of table methyl jasmonate and 2-isopropyl-4-methyl thiazole is preferably 100: 1 ~ 1: 500, is more preferably 10: 1 ~ 1: 10, is especially preferably 2:1 ~ 1: 5.
[test example 2-4] stability test
The concentration making the flavor compositions of test example 2-3-6 by 5% to be dissolved in 95% ethanol and the stability of the fragrance of material have passed through three months at 0 DEG C, 40 DEG C after is investigated.
Consequently, the flavor compositions that with the addition of table methyl jasmonate, without large change, maintains good fragrance.
[Production Example 2-1] astringent
Except according to except following formula, obtain astringent by common method.
[Production Example 2-2] protective skin cream
Except according to except following formula, obtain protective skin cream by common method.
[Production Example 2-3] emulsion
Except according to except following formula, obtain emulsion by common method.
[Production Example 2-4] shampoo
Except according to except following formula, obtain shampoo by common method.
[Production Example 2-5] bathliquid
First, utilizing V-mixer the following compositions except spices (flavor compositions) to be stirred to evenly, adding following spices (flavor compositions), being stirred well to further evenly and obtaining bathliquid.
[Production Example 2-6] gel fragrance
According to following formula carrageenin, propylene glycol and propylparaben carried out mixing and adding deionized water while stirring, and be heated to about 80 DEG C while being carried out reposefully stirring.Then, be cooled to about 65 DEG C, while utilizing homogenizer to stir it with 3000rpm, add following spices (flavor compositions) and after being formed as homogeneous phase, pouring in the container of regulation, after naturally cooling, obtain perfume compound.
industrial utilizes possibility
High, that the there is Rose type excellent aroma flavor compositions of hobby property can be obtained by the present invention.
Flavor compositions of the present invention, the perfuming cosmetic of perfume, makeup, clean body agent, Hair grooming makeup etc. can be used in, or the medicine part outer article of balneation agent, hair dye etc., in the groceries of space spray, line spices, clothes etc. etc., can hobby be improved.
Claims (11)
1. a Rose type flavor compositions, is characterized in that, with the addition of table methyl jasmonate, but, as table methyl jasmonate interpolation form and only add containing table methyl jasmonate natural jasmine fragrance situation except,
The interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm,
Table methyl jasmonate is 1,2-cis-3-oxo-2 α-[(Z)-pentenyl]-1 α-cyclopentaneacetic acid methyl esters.
2. Rose type flavor compositions as claimed in claim 1, is characterized in that, with the addition of table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
3. Rose type flavor compositions as claimed in claim 2, it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100:1 ~ 1:500.
4. perfuming cosmetic, medicine part outer article or groceries, is characterized in that, hybrid right requires the Rose type flavor compositions described in any one of 1 ~ 3.
5. the adding method to the fragrance of flavor compositions, it is characterized in that, table methyl jasmonate is added in the perfume base flavor compositions being homophony with Rose type fragrance, but, as table methyl jasmonate interpolation form and only add containing table methyl jasmonate natural jasmine fragrance situation except
The interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm,
Table methyl jasmonate is 1,2-cis-3-oxo-2 α-[(Z)-pentenyl]-1 α-cyclopentaneacetic acid methyl esters.
6. the adding method to the fragrance of flavor compositions as claimed in claim 5, is characterized in that, in the perfume base flavor compositions being homophony with Rose type fragrance, adds table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
7. the adding method of fragrance as claimed in claim 6, it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100:1 ~ 1:500.
8. the adding method of the fragrance as described in any one of claim 5 ~ 7, is characterized in that, fragrance is more than one the fragrance texture selected from natural sense, freshness and fragrant and mellow sense.
9. a manufacture method for Rose type flavor compositions, is characterized in that, add table methyl jasmonate, but, as table methyl jasmonate interpolation form and only add containing table methyl jasmonate natural jasmine fragrance situation except,
The interpolation concentration of the table methyl jasmonate in Rose type flavor compositions is 0.1ppm ~ 1000ppm,
Table methyl jasmonate is 1,2-cis-3-oxo-2 α-[(Z)-pentenyl]-1 α-cyclopentaneacetic acid methyl esters.
10. the manufacture method of Rose type flavor compositions as claimed in claim 9, is characterized in that, with the addition of table methyl jasmonate and 2-isopropyl-4-methyl thiazole.
The manufacture method of 11. Rose type flavor compositions as claimed in claim 10, it is characterized in that, the ratio of mixture of the table methyl jasmonate in Rose type flavor compositions and 2-isopropyl-4-methyl thiazole is in the scope of 100:1 ~ 1:500.
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| EP2931236A2 (en) | 2012-12-14 | 2015-10-21 | The Procter & Gamble Company | Antiperspirant and deodorant compositions |
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| DE102015217868A1 (en) * | 2015-09-17 | 2017-03-23 | Henkel Ag & Co. Kgaa | Perfume composition with odor modulator compounds to increase fragrance intensity |
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| EP2687587A1 (en) | 2014-01-22 |
| EP2687587B1 (en) | 2017-01-04 |
| WO2010101099A1 (en) | 2010-09-10 |
| US20130253076A1 (en) | 2013-09-26 |
| KR101500918B1 (en) | 2015-03-12 |
| US8791059B2 (en) | 2014-07-29 |
| CN103343051A (en) | 2013-10-09 |
| ES2492676T3 (en) | 2014-09-10 |
| KR101470062B1 (en) | 2014-12-05 |
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