CN105767837A - Cooling agent composition, essence containing the cooling agent composition and application thereof - Google Patents
Cooling agent composition, essence containing the cooling agent composition and application thereof Download PDFInfo
- Publication number
- CN105767837A CN105767837A CN201610118403.5A CN201610118403A CN105767837A CN 105767837 A CN105767837 A CN 105767837A CN 201610118403 A CN201610118403 A CN 201610118403A CN 105767837 A CN105767837 A CN 105767837A
- Authority
- CN
- China
- Prior art keywords
- coolant compositions
- essence
- oil
- cooling agent
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/56—Flavouring or bittering agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Food Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Cosmetics (AREA)
- Confectionery (AREA)
Abstract
The invention discloses a cooling agent composition, an essence containing the cooling agent composition and an application thereof. The cooling agent composition is composed of polyglutamic acids and a cooling agent; and the molecular weight of the polyglutamic acids is more than 1 million Dalton and the cooling agent is oil-soluble, The cooling agent composition can be used in food of candy, cakes, drinks, etc., can also be used in oral care products of toothpastes, mouthwash, etc., and can also be used in daily necessities of cosmetics, liquid shampoo, etc. The cooling agent composition has a longer staying time in skin and oral cavity and does not have a bitter taste or other adverse stimuli even in a larger addition amount.
Description
Technical field
The present invention provides a kind of compositions, is specifically related to a kind of coolant compositions, essence containing coolant compositions and application thereof.Said composition can produce full, balanced, lasting cool feeling in the oral cavity of human body and throat.Said composition can be used in the food such as confection, cake, beverage, it may also be used in the oral care implement such as toothpaste, collutory, it may also be used in the daily living article such as cosmetics, shampoo.
Background technology
Traditionally, for toothpaste, confection, beverage, Nicotiana tabacum L., poultice, cosmetics etc., to the skin of people, oral cavity, throat with the freshener of nice and cool sensation and cold refreshing sensation: MENTHOL is widely used, but MENTHOL has defect lasting not in the holding capacity of cooling effect, if and increase consumption time, strengthen cooling effect, but consequently also with disadvantageous bitter sense.
In order to make up the simple weak point using MENTHOL, do and much made great efforts synthesize other various cooling compounds and study the compositions of various cooling compounds.
Publication number CN1950057A discloses menthol derivative and the coolant compositions containing menthol derivative component.Application number 93106070 relate to ketal compound and menthol, the compositions of contracting amide.German patent application the 2339661st discloses aromatic composition, including the menthol esters of menthol or different ring carboxylic acids.Japanese Patent Application Laid-Open No.47-16648 relate to N-replacement-p-terpane-3-Carboxylamide.Japanese Patent Application Laid-Open No.61-194049 relate to 1-menthyl-3-hydroxybutyl compound.
German patent application the 2608226th discloses a kind of compositions, and it shows a kind of physiological cooling effect.
Acetic acid menthol ester and menthyl lactate are cooling compounds best in this announcement.Publication number CN1084387A relates to the coolant compositions formed containing ketal and menthol, carbonyl amide a kind of or their mixture.Relating to a class coolant compositions in publication number CN1179094A, this based composition includes the compositions of a kind of suitable carrier, a kind of dihydroxylic alcohols and freshener composition.Application publication number CN102558036A provides coolant compositions that is a kind of composite by amide of mint type derivant and N-ethyl-2-isopropyl-5-methyl-cyclohexyl alkane amide and that obtain.Relate to a kind of coolant compositions for confection in Authorization Notice No. CN101119643B, menthol and at least one physiological cooling agents selected from N-p-menthane carbosamided, acyclic carboxamides, the menthyl succinate replaced and combination thereof are merged by said composition.Above-mentioned single freshener has a degree of cooling effect, but still unsatisfactory in the persistency of cooling effect.
Existing coolant compositions, although improve the persistency of cooling effect to a certain extent, but duration is still unsatisfactory, and existing coolant compositions is relatively costly, is unfavorable for application.The reason causing problem above is: on the one hand, and existing freshener is not enough in the persistency of cooling effect；On the other hand, for the freshener in oral cavity along with the flowing of saliva, can slowly reduce residual quantity in the oral cavity, thus causing that cooling effect enduring quality weakens.
Summary of the invention
It is an object of the invention to overcome the defect of above-mentioned prior art, it is provided that a kind of novel coolant compositions, said composition has the sustainability of the nice and cool or cold refreshing sensation of excellence, and will not bring undesirable stimulation, particularly stink and bitterness.
For realizing the purpose of the present invention, technical scheme is as follows:
The novel freshener compositions that the present invention relates to is made up of polyglutamic acid and freshener, molecular weight > 1,000,000 dalton of described polyglutamic acid, and described freshener is oil-soluble, it is preferable that 120-150 ten thousand dalton.
The principle of the application polyglutamic acid effect is: macromole polyglutamic acid can be formed and be similar to porous membrane structure as agar, adsorbs freshener, and membrane structure can be adsorbed on hair or oral cavity epidermis, and the release time of freshener is extended.At cosmetic field, polyglutamic acid is made water-retaining agent, generally can select micromolecular composition, be so more convenient for absorbing.
Wherein polyglutamic acid accounting in the composition is 50-98%wt, and the best accounts for as 80-95%wt.
The application find oil-soluble freshener can use composite with polyglutamic acid, improve its persistence.Especially by polyglutamic acid, N-ethyl-L-menthyl Methanamide (hereinafter referred to as WS-3) and N-(ethoxycarbonylmethyl group)-to alkane-3-Methanamide (hereinafter referred to as WS-5) three composite time, refrigerant sense duration is at most.
Wherein polyglutamic acid accounting in the composition is 50-98%, and the best accounts for as 80-95%, and all the other are N-ethyl-L-menthyl Methanamide and N-(ethoxycarbonylmethyl group)-to alkane-3-Methanamide；
Wherein, N-ethyl-L-menthyl Methanamide and N-(ethoxycarbonylmethyl group)-to the mass ratio of alkane-3-Methanamide are 0.5:1～5:1, and optimal proportion is 1:1～3:1；
Polyglutamic acid involved in the present invention is the biopolymer using microbe fermentation method to prepare, molecular weight > 1,000,000 dalton, it is preferable that 120-150 ten thousand dalton；Having excellent water solublity, superpower adsorptivity and biodegradability, catabolite is non-harmful glutamic acid, is a kind of excellent environment-friendly type macromolecule material.
WS-3 involved in the present invention, from Millennium company of the U.S., is a kind of several subdiaphanous white crystals, cool dose of the system being mainly used in medicine, mouth care, confection.It can produce that more impact, pure and fresh, lasting fragrance, and its mouthfeel threshold values is 200ppb (puts in mouth with Tetefol bar and record).
WS-5 involved in the present invention, from Millennium company of the U.S., one white crystal, cool dose of the system being mainly used in mouth care, confection, has the cool feeling more lasting than MENTHOL
The novel freshener compositions that the present invention relates to is by polyglutamic acid, N-ethyl-L-menthyl Methanamide, N-(ethoxycarbonylmethyl group)-form alkane-3-Methanamide three is composite.The refrigerant sense persistency of the coolant compositions of the present invention is good, is better than existing freshener.
Present invention also offers a kind of essence containing described coolant compositions, described coolant compositions content in essence is 0.001～40%wt.Preferably, described coolant compositions content in essence is 0.1～30%wt.
Described essence also includes more than one in quintessence oil, spice or perfume preservative.
Described quintessence oil includes but not limited to more than one in mentha piperita oil, Oleum Menthae Rotundifoliae, asia peppermint oil, Fructus Citri Limoniae oil, oleum Citri sinensis, Oleum Anisi Stellati, trans-anethole or wintergreen oil；Described spice includes but not limited to more than one in phenylethyl alcohol, methyl phenyl carbinyl acetate, acetaminol, rose oxide, linalool, muscone or benzaldehyde；Described perfume preservative includes but not limited to more than one in propylene glycol, glycerol, butanediol, hexanediol, triethyl citrate, diethyl phthalate, MCT Oil.
Present invention also offers the application in beverage, confection, cosmetics, oral care implement, showering agent or medicine of the described essence.
It addition, the application that present invention also offers in the beverage of described coolant compositions, confection, cosmetics, oral care implement, showering agent or medicine.
Compared with prior art, the invention has the beneficial effects as follows:
(1) owing to the polyglutamic acid of macromole has good absorption property, freshener composition being helped in the residual at the position such as skin, oral mucosa, loose structure can adsorb freshener simultaneously, promotes the progressively release of freshener.
(2) present invention is found by test of many times, and WS-3 and WS-5 and polyglutamic acid have good associativity, compare other fresheners, and both fresheners retention time in skin with oral cavity is longer.
(3) polyglutamic acid, WS-3 and WS-5 are composite by certain ratio, have good cooling effect, and this three has synergy, and the cooling effect of use more composite than independent a kind of freshener and polyglutamic acid significantly improves.
(4) even if coolant compositions addition involved in the present invention is relatively big, without producing hardship sense or other pessimal stimulations, this is also a big advantage of the present invention.
Detailed description of the invention
Below by being embodied as example, the present invention is described in further details.
Embodiment 1
The embodiment of coolant compositions: (unit is mass percent)
| Composition | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Polyglutamic acid | 85 | 90 | 90 |
| WS-3 | 10 | 7.5 | 5 |
| WS-5 | 5 | 2.5 | 5 |
[preparation method of coolant compositions]:
By WS-3 and WS-5 heating for dissolving；
Add polyglutamic acid, stir 5min
Mixture is cooled in ice bath room temperature, to obtain final product.
[sensory evaluation of embodiment]
Evaluated by oral cavity and the coolant compositions of embodiment 1,2,3 and the cooling perception lasts of MENTHOL are evaluated.Evaluation methodology is as follows:
This evaluation test is random, double blinding, comparison, parallel sensory evaluation test；
This evaluation adopts the sensory evaluation group of specialty to complete, and this sensory evaluation group, by through training and consisting of 7 people examined, has the sense organ of acumen, it is possible to objectively the refrigerant sense of product is evaluated, marking.
Preparation concentration is 20ppm, the aqueous solution 1000ml containing coolant compositions every kind obtained and MENTHOL.
Member's every kind of solution of rinsing the mouth 10ml of sensory evaluation group 15 seconds, discharge solution, evaluating refrigerant sense at that moment, that time is defined as 0min, at 5min, 15min, 25min, 35min, 45min, 60min, 75min, 90min, refrigerant sense is marked respectively later.Scoring score value is 10 score values, and the refrigerant sense of 0=disappears, and 10=is very strong.
During testing, evaluation personnel can not drink water and take food；
[embodiment Analyses Methods for Sensory Evaluation Results]
The test result of refrigerant sense is as shown in the table:
7 bit test personnel evaluate composite coolant compositions and have an excellent refrigerant sense, embodiment 1, embodiment 2, embodiment 3 cooling perception lasts degree be significantly higher than MENTHOL.Composite freshener persistence can reach more than 1 hour, and the refrigerant persistence of common freshener MENTHOL only has 15min effect.
Embodiment 4
[sensory evaluation of embodiment]
Evaluated by oral cavity and the coolant compositions of embodiment 1, polyglutamic acid and WS-5 (mass ratio 17:2) composite, polyglutamic acid and WS-3 (mass ratio 17:1) cooling perception lasts composite, WS-5 and WS-3 are evaluated.Evaluation methodology is as follows:
This evaluation test is random, double blinding, comparison, parallel sensory evaluation test；
This evaluation adopts the sensory evaluation group of specialty to complete, and this sensory evaluation group, by through training and consisting of 7 people examined, has the sense organ of acumen, it is possible to objectively the refrigerant sense of product is evaluated, marking.
Preparation concentration is 20ppm, the aqueous solution 1000ml containing coolant compositions every kind obtained.
Member's every kind of solution of rinsing the mouth 10ml of sensory evaluation group 15 seconds, discharge solution, evaluating refrigerant sense at that moment, that time is defined as 0min, at 5min, 15min, 25min, 35min, 45min, 60min, 75min, 90min, refrigerant sense is marked respectively later.Scoring score value is 10 score values, and the refrigerant sense of 0=disappears, and 10=is very strong.
During testing, evaluation personnel can not drink water and take food；
[embodiment Analyses Methods for Sensory Evaluation Results]
The test result of refrigerant sense is as shown in the table:
7 bit test personnel evaluate composite coolant compositions and have excellent refrigerant sense, upper table can draw, after WS-5 is composite with polyglutamic acid, effect is better than single WS-5；The interpolation of visible polyglutamic acid extends the persistency of refrigerant sense, especially when polyglutamic acid, WS-3 and WS-5 three are composite the refrigerant sense persistence of (embodiment 1) be significantly higher than that polyglutamic acid is composite with WS-3 and polyglutamic acid and WS-5 composite, it is possible to prove that WS-3 and WS-5 has synergism.
In the present invention, composite coolant compositions can be added directly in various product such as essence, beverage and confection, cosmetics, oral care implement, showering agent and medicine.Further, composite coolant compositions can be charged first in flavor compositions, to obtain the essence containing coolant compositions, then can be added in product by the essence that comprise coolant compositions.
The component being configured to essence together with the coolant compositions of the present invention includes the spice of various synthesis, natural essential oil, synthesis edible vegetable oil, animal perfume material etc..Such as widely used mentha piperita oil, Oleum Menthae Rotundifoliae, asia peppermint oil, Fructus Citri Limoniae oil, oleum Citri sinensis, Oleum Anisi Stellati, trans-anethole, wintergreen oil in oral care implement essence；Such as widely used phenylethyl alcohol, methyl phenyl carbinyl acetate, acetaminol, rose oxide, linalool, benzaldehyde, muscone etc. in cosmetic product essence.Can further include one or more the perfume preservative often used in essence.The example of perfume preservative includes propylene glycol, glycerol, butanediol, hexanediol, triethyl citrate, diethyl phthalate, MCT Oil etc..
In the essence containing coolant compositions, the content of coolant compositions can suitably adjust, the kind of this use scope depending on essence and other components thereof.Usually, coolant compositions is 0.001-40% relative to the content of whole essence combination in mass, it is preferred to 0.1-30% in mass, it is particularly preferred to for 1%-20% in mass.
The coolant compositions of the present invention can separately as freshener, or the form with the essence containing coolant compositions joins in various product, brings consumer with refrigerant sensation.These products have beverage, confection, cosmetics, oral care implement, showering agent, medicine etc..
The coolant compositions of the present invention or the essence comprising these coolant compositions give the confection of refrigerant sense and the concrete instance of beverage, it is not specially limited in this, comprise beverage, as: fruit drink, milk beverage, soda pop, sports drink, drinks；Confection, as: chewing gum, peppermint candy, pressed candy, chocolate etc..
The coolant compositions of the present invention or the essence comprising these coolant compositions give the cosmetics of refrigerant sense or the concrete instance of articles for daily use, including fragrance product, Basic skin care products, cosmetic hair, soap, bath foam, abluent, deodorization and aromatic, anthelmintic, toothpaste, collutory, dentifrice, mouth washes etc..
Effect according to the refrigerant sense having needed for product, it is possible to suitably regulate the amount of the coolant compositions counting or being supplied to product, to provide this product cooling sensation.Generally, the amount adding or providing of coolant compositions, relative to the quality of product, it is preferable that be 0.01-5% in mass, it is more preferable to be 0.1-2% in mass.
Embodiment 4
Oral care implement essence containing coolant compositions
With conventional method, producing oral care implement essence by formula as below, in formula, formula ratio is in mass parts.
<composition>
| Component | Formula ratio |
| Mentha piperita oil | 25 |
| 65% Oleum Menthae Rotundifoliae | 17.5 |
| Trans-anethole | 10 |
| 80% eucalyptus oil | 6.5 |
| Thymol | 1 |
| L-Mentholum | 30 |
| Embodiment 1 coolant compositions | 10 |
Embodiment 5
Toothpaste containing coolant compositions
According to following formula, the coolant compositions of the embodiment 2 by adding 1% prepares toothpaste.This toothpaste has refrigerant sense, and the persistence of refrigerant sense can keep 30min.
<formulation of tooth-paste>
The embodiment 6 shampoo containing coolant compositions
According to formula as below, preparing shampoo by adding the coolant compositions implementing 3 of 0.8%, this shampoo has refrigerant sense, and refrigerant sense persistency is good.
<shampoo formula>
The announcement of book and instruction according to the above description, above-mentioned embodiment can also be modified and revise by those skilled in the art in the invention.Therefore, the invention is not limited in detailed description of the invention disclosed and described above, should also be as some modifications and changes of the present invention falling in the scope of the claims of the present invention.Although additionally, employ some specific terms in this specification, but these terms are intended merely to convenient explanation, and the present invention does not constitute any restriction.
Claims (10)
1. a coolant compositions, it is characterised in that be made up of polyglutamic acid and freshener；Molecular weight > 1,000,000 dalton of described polyglutamic acid, described freshener is oil-soluble.
2. coolant compositions according to claim 1, it is characterised in that the percentage by weight of described polyglutamic acid is 50-98%.
3. coolant compositions according to claim 1 and 2, it is characterised in that described freshener is N-ethyl-L-menthyl Methanamide and N-(ethoxycarbonylmethyl group)-both alkane-3-Methanamides is composite.
4. coolant compositions according to claim 3, it is characterised in that described N-ethyl-L-menthyl Methanamide and N-(ethoxycarbonylmethyl group)-to the mass ratio of alkane-3-Methanamide are 0.5:1～5:1.
5. the essence containing coolant compositions described for one of claim 1-4, it is characterised in that described coolant compositions content in essence is 0.001～40%wt.
6. essence according to claim 5, it is characterised in that described coolant compositions content in essence is 0.1～30%wt.
7. the essence according to claim 5 or 6, it is characterised in that also include in quintessence oil, spice or perfume preservative more than one.
8. essence according to claim 7, it is characterised in that described quintessence oil is more than one in mentha piperita oil, Oleum Menthae Rotundifoliae, asia peppermint oil, Fructus Citri Limoniae oil, oleum Citri sinensis, Oleum Anisi Stellati, trans-anethole or wintergreen oil；Described spice is more than one in phenylethyl alcohol, methyl phenyl carbinyl acetate, acetaminol, rose oxide, linalool, muscone or benzaldehyde；Described perfume preservative is more than one in propylene glycol, glycerol, butanediol, hexanediol, triethyl citrate, diethyl phthalate, MCT Oil.
9. one of claim 5-8 described essence application in beverage, confection, cosmetics, oral care implement, showering agent or medicine.
10. the application in the beverage of the described coolant compositions of one of claim 1-4, confection, cosmetics, oral care implement, showering agent or medicine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118403.5A CN105767837B (en) | 2016-03-02 | 2016-03-02 | A kind of coolant compositions, the essence containing coolant compositions and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118403.5A CN105767837B (en) | 2016-03-02 | 2016-03-02 | A kind of coolant compositions, the essence containing coolant compositions and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105767837A true CN105767837A (en) | 2016-07-20 |
| CN105767837B CN105767837B (en) | 2018-10-19 |
Family
ID=56387753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610118403.5A Active CN105767837B (en) | 2016-03-02 | 2016-03-02 | A kind of coolant compositions, the essence containing coolant compositions and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105767837B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106974845A (en) * | 2017-03-21 | 2017-07-25 | 广州满庭芳实业有限公司 | Essence combination and preparation method and application |
| CN107028779A (en) * | 2017-03-13 | 2017-08-11 | 广州薇美姿实业有限公司 | A kind of coolant compositions and its application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275887A (en) * | 1997-09-18 | 2000-12-06 | Wm.雷格利Jr.公司 | Chewing gum containing physiological cooling agents |
| JP2005029513A (en) * | 2003-07-07 | 2005-02-03 | Kobayashi Pharmaceut Co Ltd | Breath cool-refreshing preparation and method for producing the same |
| CN101238203A (en) * | 2005-06-21 | 2008-08-06 | 高砂香料工业株式会社 | Flavor and fragrance composition |
| EP1835815B1 (en) * | 2004-12-29 | 2013-08-28 | Wm. Wrigley Jr. Company | Combinations of cooling agents for use in confections |
| WO2014054737A1 (en) * | 2012-10-05 | 2014-04-10 | 小川香料株式会社 | Powdery refreshing composition |
| CN105079798A (en) * | 2015-09-15 | 2015-11-25 | 孟庆蕾 | Pharmaceutical composition for treating syndrome of retention of lung phlegm-heat in infants and preparation method of pharmaceutical composition |
-
2016
- 2016-03-02 CN CN201610118403.5A patent/CN105767837B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275887A (en) * | 1997-09-18 | 2000-12-06 | Wm.雷格利Jr.公司 | Chewing gum containing physiological cooling agents |
| JP2005029513A (en) * | 2003-07-07 | 2005-02-03 | Kobayashi Pharmaceut Co Ltd | Breath cool-refreshing preparation and method for producing the same |
| EP1835815B1 (en) * | 2004-12-29 | 2013-08-28 | Wm. Wrigley Jr. Company | Combinations of cooling agents for use in confections |
| CN101238203A (en) * | 2005-06-21 | 2008-08-06 | 高砂香料工业株式会社 | Flavor and fragrance composition |
| WO2014054737A1 (en) * | 2012-10-05 | 2014-04-10 | 小川香料株式会社 | Powdery refreshing composition |
| CN105079798A (en) * | 2015-09-15 | 2015-11-25 | 孟庆蕾 | Pharmaceutical composition for treating syndrome of retention of lung phlegm-heat in infants and preparation method of pharmaceutical composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107028779A (en) * | 2017-03-13 | 2017-08-11 | 广州薇美姿实业有限公司 | A kind of coolant compositions and its application |
| CN107028779B (en) * | 2017-03-13 | 2021-02-19 | 广州舒客实业有限公司 | Toothpaste containing algefacient composition |
| CN106974845A (en) * | 2017-03-21 | 2017-07-25 | 广州满庭芳实业有限公司 | Essence combination and preparation method and application |
| CN106974845B (en) * | 2017-03-21 | 2021-02-23 | 广州满庭芳实业有限公司 | Essence composition and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105767837B (en) | 2018-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101238203B (en) | Flavor and fragrance composition | |
| JP5698120B2 (en) | Warm composition | |
| JP6556811B2 (en) | Organic compounds | |
| KR101448283B1 (en) | A Composition of a Bubble Dentifrice and the Method of Making it | |
| TWI233782B (en) | Composition for deodoring tobacco smell, deodorant for tobacco smell, and cigarette and tobacco package with reduced side-stream smoke smell | |
| JP5912482B2 (en) | Menthol-containing mixture | |
| CN103168907B (en) | Refrigerant enhancing composition | |
| CN101282707A (en) | Cooling compositions including menthyl esters | |
| WO2012165406A1 (en) | Psychic energizer agent and psychic energizer composition | |
| CN102573769B (en) | Dentifrice composition | |
| JP2002088391A (en) | Method for reinforcing smell and persistence of perfume and reinforcing agent | |
| JP4360654B1 (en) | Perfume citrus flavor enhancer | |
| JP6316825B2 (en) | Chewing gum | |
| EP2404987B1 (en) | Fragrance compositions | |
| KR20130122987A (en) | Body odor improving agent for ingestion into body, beverage/food using the same, and method for improvement body odor | |
| JP2009179711A (en) | Deodorant for tobacco smell | |
| CN108524356A (en) | A kind of medicated toothpaste and preparation method thereof containing francolin leaf extract | |
| CN105767837A (en) | Cooling agent composition, essence containing the cooling agent composition and application thereof | |
| JP7379055B2 (en) | Composition for suppressing thermal deterioration of citral and method for suppressing thermal deterioration | |
| KR101490114B1 (en) | Perfume Composition Using an Essential Oil Extract of Acorus gramineus and an Essential Oil Extract of Torreya nucifera | |
| JP5016233B2 (en) | Dentifrice | |
| CN112315833A (en) | Composite strong cooling agent applied to toothpaste essence | |
| JP7155943B2 (en) | Liquid oral compositions and oral spray formulations | |
| JP6625775B2 (en) | Autonomic nervous modulator | |
| JP6249588B2 (en) | Oral composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180903 Address after: 510900 -26, No. 339 Heng Jiang Road, Conghua suburb street, Guangzhou, Guangdong (first to four floors of C building) Applicant after: Guangzhou Mantingfang Industry Co. Ltd. Address before: 510130 Guangdong province Guangzhou city Liwan District Sha noodles North Street 103 Applicant before: GUANGZHOU MANTINGFANG FRAGRANCES CO., LTD. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |