CN103342926A - Paint for polyolefin and preparation method thereof - Google Patents
Paint for polyolefin and preparation method thereof Download PDFInfo
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- CN103342926A CN103342926A CN 201310318011 CN201310318011A CN103342926A CN 103342926 A CN103342926 A CN 103342926A CN 201310318011 CN201310318011 CN 201310318011 CN 201310318011 A CN201310318011 A CN 201310318011A CN 103342926 A CN103342926 A CN 103342926A
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- Prior art keywords
- coating
- polyolefinic
- polyolefinic coating
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- 238000002360 preparation method Methods 0.000 title abstract description 11
- 229920000098 polyolefin Polymers 0.000 title description 7
- 239000003973 paint Substances 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims description 40
- 238000000576 coating method Methods 0.000 claims description 40
- 238000003756 stirring Methods 0.000 claims description 16
- -1 polypropylene Polymers 0.000 claims description 13
- 239000000049 pigment Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 8
- 239000002318 adhesion promoter Substances 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 7
- 230000007797 corrosion Effects 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- 230000002401 inhibitory effect Effects 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 230000003068 static effect Effects 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical group [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract description 3
- 239000002966 varnish Substances 0.000 abstract 6
- 239000002932 luster Substances 0.000 abstract 3
- 230000002349 favourable effect Effects 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses water-based double-component polyurethane finishing varnish and a preparation process thereof. The finishing varnish comprises a component A and a component B, wherein the component A comprises the following substances in percentage by mass: 72-80% of water-based acrylic resin, 0.2-0.5% of substrate wetting agent, 0.3-0.6% of thickening agent, 0.15-0.35% of pH regulator, 6-10% of cosolvent and 15-20% of water; and the component B is a curing agent. The water-based automobile finishing varnish disclosed by the invention is prepared by combining hydrophobic polybasic acid and polyalcohol; the relationship between the leveling property and the mass of the mixed components is especially favorable; the smaller the liquid drops dispersed in the water-based polyalcohol are, the higher the performance and luster of the cured varnish film are; and the mass of the finishing varnish is very suitable for being used for on-line automobile painting operation. According to the method disclosed by the invention, the defects of low room-temperature drying speed, not high hardness and low luster are solved; and the finishing varnish is environment-friendly, flame-retardant, high in room-temperature drying speed, high in hardness and favorable in luster.
Description
Technical field
The present invention relates to a kind of coating and preparation thereof, relate in particular to a kind of polyolefinic coating and preparation method thereof that is exclusively used in.
Background technology
Along with the automotive industry high speed development, automobile just develops towards lighting, intensive, ecology direction with novel material.Advantages such as polyolefine material is little owing to excellent mechanical property, easy-formation, proportion, price is low and reusable are widely used in automobile typical case component (collision bumper, dashboard, inside gadget etc.).Because the polyolefin alloy material surface energy is low, wetting ability is poor, usually adopt methods such as UV-irradiation, glow discharge, corona discharge, plasma gun processing and chromic acid processing that polyolefin plastics is carried out surface treatment at present, and then carry out application with coating, but poor effect.At the initial stage that the automotive plastic parts application is finished, general polyolefine can keep good adhesion property and weather resistance with coating, but along with vehicle uses for a long time, it is more and more serious that vehicle is subjected to the erosion meeting of the especially acid water quality of aqueous vapor.Therefore, coating is priming paint especially, must have the cohesive strength of the excellence that continues of medium ability such as excellent acid and alkali-resistance and plastic component.But, in recent years, existing polyolefine user coating, unstable properties can not satisfy polyolefin substrate application demand, is not suitable for the heavy industrialization application, and original chlorinated polyolefin resin that uses can not satisfy the construction of workability requirement, particularly inside gadget.
Because above-mentioned existing defective for polyolefinic coating existence, the inventor is based on being engaged in practical experience and the expertise that this type of product design manufacturing is enriched for many years, and the utilization of cooperation scientific principle, actively studied innovation, a kind of novel for polyolefinic coating in the hope of founding, make it have more practicality.Through constantly research, design, and after studying sample and improvement repeatedly, create the present invention who has practical value finally.
Summary of the invention
Main purpose of the present invention is, overcome existing defective for polyolefinic coating and preparation technology's existence thereof, and provide a kind of novel for polyolefinic coating and preparation technology thereof, antistatic, acid and alkali-resistance, workability are good, and preparation technology is simple, thereby be suitable for practicality more, and have the utility value on the industry.
The object of the invention to solve the technical problems realizes by the following technical solutions.According to the present invention propose a kind of for polyolefinic coating, described coating comprises following substances in parts by weight,
Aforesaid for polyolefinic coating, the acid of described unsaturated double-bond or acid anhydrides are the chlorinatedpolyolefins of sour modification.
Aforesaid for polyolefinic coating, described ester compound is chlorinatedpolyolefins alkane resin.
Aforesaid for polyolefinic coating, described filler is superfine talcum powder.
Aforesaid for polyolefinic coating, described cellulose ester is cellulose acetate butyrate 381-0.5.
Aforesaid for polyolefinic coating, described corrosion-inhibiting pigment is aluminium triphosphate, and described conducting pigment is graphitized carbon black.
Aforesaid for polyolefinic coating, described static inhibitor is rutile titanium dioxide.
Aforesaid for polyolefinic coating, described adhesion promoter is sour modified chlorinated alkene alkane.
Aforesaid for polyolefinic coating, described solvent is the mixture of N-BUTYL ACETATE and dimethylbenzene.
Prepare aforesaid this method of method for polyolefinic coating and comprise the steps,
(1) get the acid of chlorinated polypropylene, unsaturated double-bond or acid anhydrides, ester compound, Resins, epoxy is dissolved in the solvent, put into stirrer and stir;
(2) in the process that step (1) stirs, add filler, corrosion-inhibiting pigment, conducting pigment and static inhibitor gradually, after waiting to stir, join and be ground to fineness≤25um in the shredder;
(3) after to be ground the finishing, add cellulose ester, silane coupling agent and adhesion promoter successively, viscosity is adjusted in the back that stirs, and namely obtains target product.
By technique scheme, the present invention is used for polyolefinic coating and preparation technology has following advantage at least:
Of the present invention fast for polyolefinic coating surface drying, easily polishing, antistatic property is good, is zero level (cross-hatching) with substrate adhesion and supporting ply adhesion, and anti-boiling water, medium such as acidproof, alkaline-resisting are splendid, the workability excellence.
Color stuffing composite, that adopt excellent performance by several resins makes up, and is ground to suitable fineness, and finally the adjustment by viscosity obtains target product, and preparation technology is simple, and is easy to operate, and environmental friendliness is suitable for industrial application.
Stating bright only is the general introduction of technical solution of the present invention, for can clearer understanding technique means of the present invention, and can be implemented according to the content of specification sheets, below with preferred embodiment of the present invention describe in detail as after.
Embodiment
Reach technique means and the effect that predetermined goal of the invention is taked for further setting forth the present invention, be used for polyolefinic coating and preparation method thereof its embodiment, feature and effect thereof to what foundation the present invention proposed, describe in detail as after.
Embodiment 1
It is a kind of for polyolefinic coating that the present invention proposes, and comprises following substances in parts by weight,
Prepare the method for polyolefinic coating of the present invention, comprise the steps,
Chlorinatedpolyolefins, 2% chlorinatedpolyolefins alkane resin, 2% Resins, epoxy of at first getting 10% chlorinated polypropylene, 2% sour modification is dissolved in the solvent that the mixture of 47% N-BUTYL ACETATE and dimethylbenzene forms, and puts into stirrer and stirs 20～30 minutes;
Then, in the process that stirs, add 10% superfine talcum powder filler, 5% aluminium triphosphate corrosion-inhibiting pigment, 4% graphitized carbon black and 10% rutile titanium dioxide static inhibitor gradually, after waiting to stir, join and be ground to fineness≤25um in the shredder;
At last, after to be ground the finishing, add 2% cellulose acetate butyrate 381-0.5 cellulose ester, 4% silane coupling agent and 2% sour modified chlorinated alkene alkane adhesion promoter successively, viscosity is adjusted in the back that stirs, and namely obtains target product.
Embodiment 2
It is a kind of for polyolefinic coating that the present invention proposes, and comprises following substances in parts by weight,
Prepare the method for polyolefinic coating of the present invention, comprise the steps,
Chlorinatedpolyolefins, 1.5% chlorinatedpolyolefins alkane resin, 3% Resins, epoxy of at first getting 9% chlorinated polypropylene, 3% sour modification is dissolved in the solvent that the mixture of 47% N-BUTYL ACETATE and dimethylbenzene forms, and puts into stirrer and stirs 20～30 minutes;
Then, in the process that stirs, add 10% superfine talcum powder filler, 4% aluminium triphosphate corrosion-inhibiting pigment, 4% graphitized carbon black and 10% rutile titanium dioxide static inhibitor gradually, after waiting to stir, join and be ground to fineness≤25um in the shredder;
At last, after to be ground the finishing, add 2% cellulose acetate butyrate 381-0.5 cellulose ester, 4.5% silane coupling agent and 2% sour modified chlorinated alkene alkane adhesion promoter successively, viscosity is adjusted in the back that stirs, and namely obtains target product.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, though the present invention discloses as above with preferred embodiment, yet be not in order to limit the present invention, any those skilled in the art, in not breaking away from the technical solution of the present invention scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, in every case be the content that does not break away from technical solution of the present invention, any simple modification that foundation technical spirit of the present invention is done above embodiment, equivalent variations and modification all still belong in the scope of technical solution of the present invention.
Claims (10)
1. one kind is used for polyolefinic coating, and it is characterized in that: described coating comprises following substances in parts by weight
Chlorinated polypropylene 8 ~ 12%
The acid of unsaturated double-bond or acid anhydrides 2 ~ 3%
Ester compound 1.5 ~ 2%
Silane coupling agent 3 ~ 5%
Filler 9 ~ 11%
Cellulose ester 2 ~ 3%
Resins, epoxy 2 ~ 4%
Corrosion-inhibiting pigment 4 ~ 6%
Conducting pigment 3 ~ 5%
Static inhibitor 9 ~ 13%
Adhesion promoter 2 ~ 3%
Solvent 43 ~ 48%.
2. according to claim 1 for polyolefinic coating, it is characterized in that: the acid of described unsaturated double-bond or acid anhydrides are the chlorinatedpolyolefins of sour modification.
3. according to claim 1 for polyolefinic coating, it is characterized in that: described ester compound is chlorinatedpolyolefins alkane resin.
4. according to claim 1 for polyolefinic coating, it is characterized in that: described filler is superfine talcum powder.
5. according to claim 1 for polyolefinic coating, it is characterized in that: described cellulose ester is cellulose acetate butyrate 381-0.5.
6. according to claim 1 for polyolefinic coating, it is characterized in that: described corrosion-inhibiting pigment is aluminium triphosphate, and described conducting pigment is graphitized carbon black.
7. according to claim 1 for polyolefinic coating, it is characterized in that: described static inhibitor is rutile titanium dioxide.
8. according to claim 1 for polyolefinic coating, it is characterized in that: described adhesion promoter is sour modified chlorinated alkene alkane.
9. according to claim 1 for polyolefinic coating, it is characterized in that: described solvent is the mixture of N-BUTYL ACETATE and dimethylbenzene.
10. prepare each described method for polyolefinic coating of claim 1 ~ 9, it is characterized in that: this method comprises the steps,
(1) get the acid of chlorinated polypropylene, unsaturated double-bond or acid anhydrides, ester compound, Resins, epoxy is dissolved in the solvent, put into stirrer and stir;
(2) in the process that described step (1) stirs, add filler, corrosion-inhibiting pigment, conducting pigment and static inhibitor gradually, after waiting to stir, join and be ground to fineness≤25 um in the shredder;
(3) after to be ground the finishing, add cellulose ester, silane coupling agent and adhesion promoter successively, viscosity is adjusted in the back that stirs, and namely obtains target product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310318011.XA CN103342926B (en) | 2013-07-25 | 2013-07-25 | Paint for polyolefin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310318011.XA CN103342926B (en) | 2013-07-25 | 2013-07-25 | Paint for polyolefin and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103342926A true CN103342926A (en) | 2013-10-09 |
| CN103342926B CN103342926B (en) | 2017-05-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310318011.XA Active CN103342926B (en) | 2013-07-25 | 2013-07-25 | Paint for polyolefin and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103342926B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923546A (en) * | 2014-05-08 | 2014-07-16 | 铁岭永新涂料有限公司 | Matte black water-based plastic piece coating for automotive trim |
| CN103937361A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Ageing resistant automobile coating and preparation method thereof |
| CN104263100A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Scratch-resistant automobile paint and preparation method thereof |
| CN104263190A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Insulating resin coating and preparation method thereof |
| CN104774502A (en) * | 2015-04-29 | 2015-07-15 | 王金海 | Plastic printing ink with acid-base resistance property and preparation method thereof |
| CN104789034A (en) * | 2015-04-29 | 2015-07-22 | 王金海 | UV-aging-resistant plastic ink and preparation method thereof |
| CN108329790A (en) * | 2018-02-09 | 2018-07-27 | 苏州甫众塑胶有限公司 | A kind of preparation method of makrolon high adhesion force wear-resistant paint |
| CN110724433A (en) * | 2019-10-15 | 2020-01-24 | 江苏大亚新型包装材料有限公司 | Antifouling weather-resistant protective coating for reaction kettle equipment and preparation method thereof |
| CN111154374A (en) * | 2019-12-23 | 2020-05-15 | 广东东方一哥新材料股份有限公司 | Aqueous alkali-resistant aluminum foil gloss oil and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0450701A1 (en) * | 1990-04-05 | 1991-10-09 | John L. Armitage & Co. | Conductive coating composition |
| CN101260178B (en) * | 2008-02-22 | 2010-12-15 | 常州南京大学高新技术研究院 | Modified chlorinated polyolefin resin and preparing method thereof |
| CN101235239B (en) * | 2008-02-22 | 2010-12-29 | 江苏足迹涂料有限公司 | Special-purpose dope for polyolefin material |
| CN102086332B (en) * | 2009-12-03 | 2013-05-15 | 立邦涂料（中国）有限公司 | Coating composition for polyolefin substrate and coating and product thereof |
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2013
- 2013-07-25 CN CN201310318011.XA patent/CN103342926B/en active Active
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937361A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Ageing resistant automobile coating and preparation method thereof |
| CN103923546A (en) * | 2014-05-08 | 2014-07-16 | 铁岭永新涂料有限公司 | Matte black water-based plastic piece coating for automotive trim |
| CN104263100A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Scratch-resistant automobile paint and preparation method thereof |
| CN104263190A (en) * | 2014-08-27 | 2015-01-07 | 南京市荣达树脂有限公司 | Insulating resin coating and preparation method thereof |
| CN104263100B (en) * | 2014-08-27 | 2017-02-15 | 南京市荣达树脂有限公司 | Scratch-resistant automobile paint and preparation method thereof |
| CN104774502A (en) * | 2015-04-29 | 2015-07-15 | 王金海 | Plastic printing ink with acid-base resistance property and preparation method thereof |
| CN104789034A (en) * | 2015-04-29 | 2015-07-22 | 王金海 | UV-aging-resistant plastic ink and preparation method thereof |
| CN108329790A (en) * | 2018-02-09 | 2018-07-27 | 苏州甫众塑胶有限公司 | A kind of preparation method of makrolon high adhesion force wear-resistant paint |
| CN110724433A (en) * | 2019-10-15 | 2020-01-24 | 江苏大亚新型包装材料有限公司 | Antifouling weather-resistant protective coating for reaction kettle equipment and preparation method thereof |
| CN110724433B (en) * | 2019-10-15 | 2021-10-01 | 江苏大亚新型包装材料有限公司 | Antifouling weather-resistant protective coating for reaction kettle equipment and preparation method thereof |
| CN111154374A (en) * | 2019-12-23 | 2020-05-15 | 广东东方一哥新材料股份有限公司 | Aqueous alkali-resistant aluminum foil gloss oil and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103342926B (en) | 2017-05-03 |
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Effective date of registration: 20220412 Address after: No.8, Huangguan Road, high tech Zone, Anqing City, Anhui Province Patentee after: Anhui footprint New Material Technology Co.,Ltd. Address before: 213034, Changzhou, Jiangsu Province town of Jiang Zhang Industrial Park Patentee before: JIANGSU FOOTMARK PAINT CO.,LTD. |
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Effective date of registration: 20221221 Address after: No.8, Huangguan Road, high tech Zone, Anqing City, Anhui Province Patentee after: Anhui footprint New Material Technology Co.,Ltd. Address before: 213000 Baizhang, Chunjiang Town, Xinbei District, Changzhou City, Jiangsu Province Patentee before: JIANGSU FOOTMARK PAINT CO.,LTD. |
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Application publication date: 20131009 Assignee: SHANGHAI KINLITA CHEMICAL CO.,LTD. Assignor: Anhui footprint New Material Technology Co.,Ltd. Contract record no.: X2023980038928 Denomination of invention: A coating for polyolefins and its preparation method Granted publication date: 20170503 License type: Common License Record date: 20230807 |
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Denomination of invention: A coating for polyolefins and its preparation method Granted publication date: 20170503 Pledgee: Anqing rural commercial bank Limited by Share Ltd. Pledgor: Anhui footprint New Material Technology Co.,Ltd. Registration number: Y2024980000406 |
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