CN105238147A - Marine coating with high weather resistance and manufacturing method thereof - Google Patents
Marine coating with high weather resistance and manufacturing method thereof Download PDFInfo
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- CN105238147A CN105238147A CN201510605540.7A CN201510605540A CN105238147A CN 105238147 A CN105238147 A CN 105238147A CN 201510605540 A CN201510605540 A CN 201510605540A CN 105238147 A CN105238147 A CN 105238147A
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- 238000000576 coating method Methods 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 11
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 11
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 9
- 239000004411 aluminium Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 244000226021 Anacardium occidentale Species 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 235000020226 cashew nut Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 6
- 229960002217 eugenol Drugs 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 6
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 6
- 239000010466 nut oil Substances 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 244000166124 Eucalyptus globulus Species 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 238000010073 coating (rubber) Methods 0.000 abstract description 2
- 239000007822 coupling agent Substances 0.000 abstract description 2
- 238000006056 electrooxidation reaction Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 125000006414 CCl Chemical group ClC* 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a marine coating with high weather resistance. The coating is prepared by mixing and dissolving chlorinated rubber and vinyl acetate resin, and adding coupling-agent-coated modified nanometer magnesium hydroxide and other effective auxiliary agents at the same time; and all the components are uniformly dispersed and draw on each other's strength. Due to the composition of a C-Cl bond with great polarity, weather resistance and flame retardation performance of the coating are increased, and the disadvantages of great brittleness, low toughness, poor adhesion on a substrate and the like of a chlorinated rubber coating are improved; meanwhile, added metal aluminum powder can significantly improve permeability and electrochemical corrosion resistance of the coating so as to effectively enhance durability and weather resistance of ships. The coating provided by the invention has the advantages of simple preparation process, few synthetic steps; and a film obtained after coating of the coating on a ship bottom is smooth and compact, does not fall off, has high glossiness and shows significant resistance reducing performance in water.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high-weatherability marine finish and preparation method thereof.
Background technology
Compared with land natural condition, the bacterium etc. in the impact of the temperature of the ultraviolet in ocean environment, salt fog, temperature and humidity, seawater and flow velocity, dissolved oxygen of seawater and saltiness, wave, the shock of floating matter, marine organisms, ocean bottom soil all can cause the corrosion of steel beam column to some extent.Boats and ships are in the corrosive environment of this harshness for a long time; make steel beam column erosion rate very fast; address this problem and need to develop a kind of novel ship paint in the above position of planking load water line or hull bottom; form the impact that layer protective layer reduces the oceanic climate corrosion of strong variations, and this coating needs to possess following characteristic: good ornamental, resistance to sea atmosphere corrosion, resistance to tanning by the sun property, salt fog resistance, high adhesive force and good snappiness etc.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of high-weatherability marine finish and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high-weatherability marine finish, is made up of the raw material of following weight part: chlorinated rubber 36-38, vinyl acetate resin 20-22, aluminium powder 6-8, allylguaiacol 4-6, cashew nut oil 8-10, zinc sulfate 1-2, kaolin 2-3, nano-sized magnesium hydroxide 3-5, anilinomethyl triethoxysilane 9-11, polypropylene fibre 5-7, weak strength flour 4-6, eucalyptus extracts 0.3-0.6, propyl carbinol 12-14, dimethylbenzene 55-58, compact agent 1-3.
Described compact agent is made up of following raw materials in part by weight: nano titanium oxide 4-5, yttrium element 0.1-0.15, Sodium hexametaphosphate 99 1-2, nano titanium carbide 0.2-0.3, neopentyl glycol 6-8, TriMethylolPropane(TMP) 2-3, vulcabond 3-4, dipropylene glycol 12-13, ethanol 30-40, its preparation method is by neopentyl glycol, TriMethylolPropane(TMP), nano titanium oxide joins in ethanol, be warming up to 60-75 DEG C, dispersed with stirring 40-50 minute, then, add vulcabond, Sodium hexametaphosphate 99, stir 40-60 minute, be warming up to 85-95 DEG C again, add other surplus stock, stir 2-3 hour, cool rear grinding and get final product.
The making method of described a kind of high-weatherability marine finish, comprises the following steps:
(1) nano-sized magnesium hydroxide is joined in propyl carbinol, ultrasonic disperse 30-50 minute, add anilinomethyl triethoxysilane, be warming up to 85-95 DEG C, add aluminium powder, weak strength flour maintenance temperature stirring reaction 3-6 hour, be cooled to room temperature and obtain coating modification nano-sized magnesium hydroxide through centrifugation, washing drying;
(2) allylguaiacol, cashew nut oil are mixed and heated to 105-120 ° of C, are cooled to 60-70 DEG C and add polypropylene fibre, kaolin stirring and evenly mixing, with 600-800 rev/min of grinding distribution 20 minutes;
(3) chlorinated rubber, vinyl acetate resin and dimethylbenzene being dropped into stirring in high mixer makes it dissolve, add step (1) material high-speed dispersion 2-4 hour, leave standstill 30-50 minute, add step (2) material and other remaining components high speed dispersion 1-2 hour, be ground to fineness with conoidal mill and reach 40 μm of dischargings.
Advantage of the present invention is: the present invention by chlorinated rubber and vinyl acetate resin miscible, add the nano-sized magnesium hydroxide through coupling agent coating modification and other effective auxiliary agent simultaneously, be uniformly dispersed between each composition, mutually learn from other's strong points to offset one's weaknesses, owing to constituting the larger C-Cl key of polarity, not only increasing the weathering resistance of coating and flame retardant properties, to also improve chlorinated rubber coating fragility large, toughness is low, to defects such as the poor adhesive force of base material, and add the perviousness resistance to electrochemical corrosion energy that metallic aluminium powder can significantly improve coating, effective weather resistance and weathering resistance improving boats and ships, Paint preparation technology of the present invention is simple, synthesis step is few, be coated on hull bottom gained photocatalytic coating film to slip and closely not come off, glossiness is high fall in water significantly resistive.
Embodiment
A kind of high-weatherability marine finish, is made up of the raw material of following weight part: chlorinated rubber 36, vinyl acetate resin 20, aluminium powder 6, allylguaiacol 4, cashew nut oil 8, zinc sulfate 1, kaolin 2, nano-sized magnesium hydroxide 3, anilinomethyl triethoxysilane 9, polypropylene fibre 5, weak strength flour 4, eucalyptus extracts 0.3, propyl carbinol 12, dimethylbenzene 55, compact agent 1.
Described compact agent is made up of following raw materials in part by weight: nano titanium oxide 5, yttrium element 0.1, Sodium hexametaphosphate 99 1, nano titanium carbide 0.3, neopentyl glycol 7, TriMethylolPropane(TMP) 2, vulcabond 4, dipropylene glycol 12, ethanol 37, its preparation method is by neopentyl glycol, TriMethylolPropane(TMP), nano titanium oxide joins in ethanol, be warming up to 60-75 DEG C, dispersed with stirring 40-50 minute, then, add vulcabond, Sodium hexametaphosphate 99, stir 40-60 minute, be warming up to 85-95 DEG C again, add other surplus stock, stir 2-3 hour, cool rear grinding and get final product.
The making method of described a kind of high-weatherability marine finish, comprises the following steps:
(1) nano-sized magnesium hydroxide is joined in propyl carbinol, ultrasonic disperse 30 minutes, adds anilinomethyl triethoxysilane, is warming up to 85 DEG C, add aluminium powder, weak strength flour keeps temperature stirring reaction 3 hours, be cooled to room temperature and obtain coating modification nano-sized magnesium hydroxide through centrifugation, washing drying;
(2) allylguaiacol, cashew nut oil are mixed and heated to 105 ° of C, are cooled to 60 DEG C and add polypropylene fibre, kaolin stirring and evenly mixing, with 600 revs/min of grinding distributions 20 minutes;
(3) chlorinated rubber, vinyl acetate resin and dimethylbenzene being dropped into stirring in high mixer makes it dissolve, add step (1) material high-speed and disperse 2 hours, leave standstill 30 minutes, add step (2) material and other remaining component high speed dispersion 1 hour, be ground to fineness with conoidal mill and reach 40 μm of dischargings.
The technical parameter index of the marine finish using the present invention to produce is as follows:
(1) glossiness: 96;
(2) salt fog 720h paint film non-foaming, do not come off, non-corrosive;
(3) the light aging resisting experiment of 700h, coatingsurface flawless, efflorescence and loss of gloss grade all≤1 grade.
Claims (2)
1. a high-weatherability marine finish, it is characterized in that, be made up of the raw material of following weight part: chlorinated rubber 36-38, vinyl acetate resin 20-22, aluminium powder 6-8, allylguaiacol 4-6, cashew nut oil 8-10, zinc sulfate 1-2, kaolin 2-3, nano-sized magnesium hydroxide 3-5, anilinomethyl triethoxysilane 9-11, polypropylene fibre 5-7, weak strength flour 4-6, eucalyptus extracts 0.3-0.6, propyl carbinol 12-14, dimethylbenzene 55-58, compact agent 1-3, described compact agent is made up of following raw materials in part by weight: nano titanium oxide 4-5, yttrium element 0.1-0.15, Sodium hexametaphosphate 99 1-2, nano titanium carbide 0.2-0.3, neopentyl glycol 6-8, TriMethylolPropane(TMP) 2-3, vulcabond 3-4, dipropylene glycol 12-13, ethanol 30-40, its preparation method is by neopentyl glycol, TriMethylolPropane(TMP), nano titanium oxide joins in ethanol, be warming up to 60-75 DEG C, dispersed with stirring 40-50 minute, then, add vulcabond, Sodium hexametaphosphate 99, stir 40-60 minute, be warming up to 85-95 DEG C again, add other surplus stock, stir 2-3 hour, cool rear grinding and get final product.
2. the making method of a kind of high-weatherability marine finish according to claim 1, is characterized in that comprising the following steps:
(1) nano-sized magnesium hydroxide is joined in propyl carbinol, ultrasonic disperse 30-50 minute, add anilinomethyl triethoxysilane, be warming up to 85-95 DEG C, add aluminium powder, weak strength flour maintenance temperature stirring reaction 3-6 hour, be cooled to room temperature and obtain coating modification nano-sized magnesium hydroxide through centrifugation, washing drying;
(2) allylguaiacol, cashew nut oil are mixed and heated to 105-120 ° of C, are cooled to 60-70 DEG C and add polypropylene fibre, kaolin stirring and evenly mixing, with 600-800 rev/min of grinding distribution 20 minutes;
(3) chlorinated rubber, vinyl acetate resin and dimethylbenzene being dropped into stirring in high mixer makes it dissolve, add step (1) material high-speed dispersion 2-4 hour, leave standstill 30-50 minute, add step (2) material and other remaining components high speed dispersion 1-2 hour, be ground to fineness with conoidal mill and reach 40 μm of dischargings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510605540.7A CN105238147A (en) | 2015-09-22 | 2015-09-22 | Marine coating with high weather resistance and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510605540.7A CN105238147A (en) | 2015-09-22 | 2015-09-22 | Marine coating with high weather resistance and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105238147A true CN105238147A (en) | 2016-01-13 |
Family
ID=55035983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510605540.7A Withdrawn CN105238147A (en) | 2015-09-22 | 2015-09-22 | Marine coating with high weather resistance and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105238147A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109226407A (en) * | 2018-09-06 | 2019-01-18 | 盐城都亭汽车部件有限公司 | Stamping device is used in a kind of production of auto parts and components |
| CN109467970A (en) * | 2018-09-30 | 2019-03-15 | 镇江宝海船舶五金有限公司 | A kind of coating and preparation method thereof applied in marine anchor chain |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN102250518A (en) * | 2011-06-17 | 2011-11-23 | 天津中油渤星工程科技有限公司 | Double-rubber anti-corrosion coating and preparation method thereof |
-
2015
- 2015-09-22 CN CN201510605540.7A patent/CN105238147A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN102250518A (en) * | 2011-06-17 | 2011-11-23 | 天津中油渤星工程科技有限公司 | Double-rubber anti-corrosion coating and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 杨保祥等: "《钛基材料制造》", 31 January 2015, 冶金工业出版社 * |
| 童佳民等: "《高校建筑消防 上》", 31 January 2012, 青岛出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109226407A (en) * | 2018-09-06 | 2019-01-18 | 盐城都亭汽车部件有限公司 | Stamping device is used in a kind of production of auto parts and components |
| CN109467970A (en) * | 2018-09-30 | 2019-03-15 | 镇江宝海船舶五金有限公司 | A kind of coating and preparation method thereof applied in marine anchor chain |
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Application publication date: 20160113 |
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