CN103333643A - Adhesive agent for high pressure resistant paper boxes and preparation method thereof - Google Patents
Adhesive agent for high pressure resistant paper boxes and preparation method thereof Download PDFInfo
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- CN103333643A CN103333643A CN2013102087077A CN201310208707A CN103333643A CN 103333643 A CN103333643 A CN 103333643A CN 2013102087077 A CN2013102087077 A CN 2013102087077A CN 201310208707 A CN201310208707 A CN 201310208707A CN 103333643 A CN103333643 A CN 103333643A
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Abstract
The invention discloses an adhesive agent for high pressure resistance paper boxes and a preparation method thereof. The adhesive agent comprises following components: styrene acrylic emulsion, starch maize, nanometer level, titanium dioxide, zirconia, chloropropylene oxide, polydimethylsiloxane, phenyltriethoxysilane, triethylene tetramine, dodecencylsuccinic acid, sodium methyl silicate, methoxybutanol, and water. The preparation method adopts styrene acrylic emulsion and starch maize as the main materials. Through ozonation treatment of starch maize, good performances of starch maize are improved, and the compressive strength of the product is largely improved. Furthermore, the preparation method has the advantages of simple preparation method, low cost, and suitability for mass production.
Description
Technical field
The invention belongs to the tackiness agent preparing technical field, be specifically related to a kind of high resistance to compression carton and stick with glue agent and preparation method thereof.
Background technology
At present, the product of printing industry, material is a lot, quality in order to ensure wrapped product, prevent toxic substance, the application of wrapped product inferior, must get hold of the use of tackiness agent, starch adhesive more and more is subjected to the favor of carton production firm as environmentally friendly natural adhesive, but at present at the used starch adhesive of carton production industry, mainly be with starch, water, sodium hydroxide, starting material such as oxygenant are made, shortcoming is that rate of drying is slow, bonding strength is low, poor water resistance and storge quality instability etc., thus limited its application in the carton production industry to a certain extent.
Summary of the invention
The object of the present invention is to provide a kind of high resistance to compression carton to stick with glue agent and preparation method thereof.
The present invention adopts following technical scheme:
A kind of high resistance to compression carton sticks with glue agent, it is characterized in that the weight part of its constitutive material is: benzene emulsion 75-85, W-Gum 13-18, Nano titanium dioxide 23-28, zirconium white 8.0-10.0, epoxy chloropropane 1.0-1.2, polydimethylsiloxane 2.3-2.8, phenyl triethoxysilane 5.0-5.5, triethylene tetramine 15-17,12 rare basic Succinic Acid 0.7-0.9, sodium methyl silicate 11-13, methoxybutanol 2.8-3.5 and water 600-650.
Described high resistance to compression carton sticks with glue agent, it is characterized in that the weight part of its constitutive material is: benzene emulsion 80, W-Gum 15, Nano titanium dioxide 25, zirconium white 9.0, epoxy chloropropane 1.1, polydimethylsiloxane 2.5, phenyl triethoxysilane 5.2, triethylene tetramine 16,12 rare basic Succinic Acid 0.8, sodium methyl silicate 12, methoxybutanol 3.2 and water 620.
Described high resistance to compression carton sticks with glue the preparation method of agent, it is characterized in that may further comprise the steps:
(1) processing of W-Gum: the weight part by constitutive material took by weighing W-Gum, is added to the water, and is heated to 90-100 ℃, is incubated 10-20 minute, by ozone bubbling 30-40 minute;
(2) weight part by constitutive material takes by weighing other each constitutive material, with above-mentioned steps (1) mixing of materials, stirs, and is heated to 80-90 ℃, and restir reaction 1.0-1.5h obtains.
Beneficial effect of the present invention:
It is major ingredient that the present invention adopts benzene emulsion and W-Gum, by the ozone Oxidation Treatment to W-Gum, has improved the premium properties of W-Gum, improved the ultimate compression strength of product greatly, and preparation method of the present invention is simple, and cost is low, is fit to scale operation.
Embodiment
Embodiment 1: high resistance to compression carton sticks with glue agent, and the weight part of its constitutive material (jin) is: benzene emulsion 80, W-Gum 15, Nano titanium dioxide 25, zirconium white 9.0, epoxy chloropropane 1.1, polydimethylsiloxane 2.5, phenyl triethoxysilane 5.2, triethylene tetramine 16,12 rare basic Succinic Acid 0.8, sodium methyl silicate 12, methoxybutanol 3.2 and water 620.
High resistance to compression carton sticks with glue the preparation method of agent, may further comprise the steps:
(1) processing of W-Gum: the weight part by constitutive material took by weighing W-Gum, is added to the water, and is heated to 90-100 ℃, is incubated 10-20 minute, by ozone bubbling 30-40 minute;
(2) weight part by constitutive material takes by weighing other each constitutive material, with above-mentioned steps (1) mixing of materials, stirs, and is heated to 80-90 ℃, and restir reaction 1.0-1.5h obtains.
The tackiness agent that above-described embodiment 1 makes is used for carton performance data after testing:
Outward appearance: oyster white; Titre: 55-63 drips/minute; Time of drying 20-23min; Ultimate compression strength: 570-630Kgf; Pop strength: 4820Kpa/10min; Transfix intensity: 220Kgf.cm; Water tolerance: 〉=3.5h; Cost: 440 yuan/ton.
Claims (3)
1. one kind high resistance to compression carton sticks with glue agent, it is characterized in that the weight part of its constitutive material is: benzene emulsion 75-85, W-Gum 13-18, Nano titanium dioxide 23-28, zirconium white 8.0-10.0, epoxy chloropropane 1.0-1.2, polydimethylsiloxane 2.3-2.8, phenyl triethoxysilane 5.0-5.5, triethylene tetramine 15-17,12 rare basic Succinic Acid 0.7-0.9, sodium methyl silicate 11-13, methoxybutanol 2.8-3.5 and water 600-650.
2. high resistance to compression carton according to claim 1 sticks with glue agent, it is characterized in that the weight part of its constitutive material is: benzene emulsion 80, W-Gum 15, Nano titanium dioxide 25, zirconium white 9.0, epoxy chloropropane 1.1, polydimethylsiloxane 2.5, phenyl triethoxysilane 5.2, triethylene tetramine 16,12 rare basic Succinic Acid 0.8, sodium methyl silicate 12, methoxybutanol 3.2 and water 620.
3. a high resistance to compression carton as claimed in claim 1 sticks with glue the preparation method of agent, it is characterized in that may further comprise the steps:
(1) processing of W-Gum: the weight part by constitutive material took by weighing W-Gum, is added to the water, and is heated to 90-100 ℃, is incubated 10-20 minute, by ozone bubbling 30-40 minute;
(2) weight part by constitutive material takes by weighing other each constitutive material, with above-mentioned steps (1) mixing of materials, stirs, and is heated to 80-90 ℃, and restir reaction 1.0-1.5h obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310208707.7A CN103333643B (en) | 2013-05-30 | 2013-05-30 | A kind of high resistance platen case sticks with glue agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310208707.7A CN103333643B (en) | 2013-05-30 | 2013-05-30 | A kind of high resistance platen case sticks with glue agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103333643A true CN103333643A (en) | 2013-10-02 |
| CN103333643B CN103333643B (en) | 2016-05-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310208707.7A Active CN103333643B (en) | 2013-05-30 | 2013-05-30 | A kind of high resistance platen case sticks with glue agent and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103333643B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753083A (en) * | 2017-01-09 | 2017-05-31 | 广东绿之彩印刷科技股份有限公司 | A kind of wrapping paper adhesive and preparation method thereof |
| CN113733651A (en) * | 2021-09-06 | 2021-12-03 | 浙江捷成包装科技有限公司 | Corrugated carton with high pressure resistance and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05195493A (en) * | 1992-01-23 | 1993-08-03 | Nippon Zeon Co Ltd | Composition for coating paper |
| CN102850974A (en) * | 2012-09-29 | 2013-01-02 | 上海东升新材料有限公司 | Preparation method and application of papermaking coating styrene-acrylic latex |
| CN103102831A (en) * | 2012-12-10 | 2013-05-15 | 铜陵市松马食品包装机械制造有限责任公司 | Compound binder for corrugated board |
-
2013
- 2013-05-30 CN CN201310208707.7A patent/CN103333643B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05195493A (en) * | 1992-01-23 | 1993-08-03 | Nippon Zeon Co Ltd | Composition for coating paper |
| CN102850974A (en) * | 2012-09-29 | 2013-01-02 | 上海东升新材料有限公司 | Preparation method and application of papermaking coating styrene-acrylic latex |
| CN103102831A (en) * | 2012-12-10 | 2013-05-15 | 铜陵市松马食品包装机械制造有限责任公司 | Compound binder for corrugated board |
Non-Patent Citations (1)
| Title |
|---|
| 王世泰 等: "氧化淀粉及其复合胶粘剂的制备与性能研究", 《山东轻工业学院学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753083A (en) * | 2017-01-09 | 2017-05-31 | 广东绿之彩印刷科技股份有限公司 | A kind of wrapping paper adhesive and preparation method thereof |
| CN113733651A (en) * | 2021-09-06 | 2021-12-03 | 浙江捷成包装科技有限公司 | Corrugated carton with high pressure resistance and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103333643B (en) | 2016-05-11 |
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| C06 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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Address after: 233000 Bengbu City, Anhui province prosperous road, No. 558 Patentee after: ANHUI KING-AUTO ELECTRONIC TECHNOLOGY CO., LTD. Address before: 233000 Bengbu City, Anhui province prosperous road, No. 558 Patentee before: Anhui Qiaite Electronic Technology Co., Ltd. |
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| CP01 | Change in the name or title of a patent holder | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Adhesive agent for high pressure resistant paper boxes and preparation method thereof Effective date of registration: 20190823 Granted publication date: 20160511 Pledgee: Bengbu Branch of China Construction Bank Co., Ltd. Pledgor: ANHUI KING-AUTO ELECTRONIC TECHNOLOGY CO., LTD. Registration number: Y2019340000026 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |