CN103319955A - High cover up low viscosity textile hand drawing mark pen ink, preparation method and application thereof - Google Patents
High cover up low viscosity textile hand drawing mark pen ink, preparation method and application thereof Download PDFInfo
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- CN103319955A CN103319955A CN2013101986329A CN201310198632A CN103319955A CN 103319955 A CN103319955 A CN 103319955A CN 2013101986329 A CN2013101986329 A CN 2013101986329A CN 201310198632 A CN201310198632 A CN 201310198632A CN 103319955 A CN103319955 A CN 103319955A
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Abstract
The invention belongs to the technical field of textile coating, and specifically relates to a high cover up textile hand drawing mark pen ink, and a preparation method and an application thereof. The high cover up low viscosity textile hand drawing mark pen ink comprises the following components of, by weight, 30-50 parts of a water borne self-crosslinking acrylic emulsion, 10-15 parts of titanium dioxide, 1-5 parts of an organic dispersant, 5-10 parts of color paste, 5-8 parts of a wetting agent, 10-20 parts of filling materials and 10-20 parts of water; and the preparation method comprises preparing a first premix, preparing a second premix, controlling the viscosity of a mixture and filtering a crude product. The invention also provides a related mark pen. According to the technical scheme provided by the invention, the water borne self-crosslinking acrylic emulsion for textile use is innovatively matched with the organic dispersant, the viscosity of pigment is effectively reduced, the pigment has excellent properties such as high cover up performance and high adhesive power and air drying solidification and the like, and therefore the pigment is especially suitable for being used as the ink of mark pen for textile use.
Description
Technical field
The invention belongs to the technical field of spinning coating, be specifically related to a kind of high covering textiles Freehandhand-drawing marker ink and its preparation method and application.
Background technology
Along with the popular textiles Freehandhand-drawing pigment that occurred later in 2000 of individual character Freehandhand-drawing DIY, be widely used in Freehandhand-drawing footwear, Freehandhand-drawing T-shirt, humanoid boudoir, Freehandhand-drawing wallet, Freehandhand-drawing cap, Freehandhand-drawing dress ornament, clothes and repair the fields such as look.
But present textiles Freehandhand-drawing pigment generally is pulpous state, can only pigment be imposed on the textiles by paintbrush, and is higher for the requirement of painting skill, can't adapt to the demand of ordinary populace new hand DIY Freehandhand-drawing, limited the development in this field.
The usage comparison of marker is simple and easy to carry, has a color beautiful aspect performance, painted convenient, with characteristics such as pen are frank, style of writing is obvious, but too high can't the imposing on the textiles by marker of viscosity of general textiles Freehandhand-drawing pigment.
And the opacifying power of existing marker and sticking power are than next poor of textiles Freehandhand-drawing pigment, therefore at present use marker to paint at the white ground of weaving, opacifying power is lower than 70% relatively, sometimes also needs the baking oven baking just can be cured and obtains corresponding sticking power.
Therefore demand developing the textiles Freehandhand-drawing pigment of a kind of low viscosity, high covering power, strong adhesion urgently, to satisfy the market requirement of DIY individual character Freehandhand-drawing on the textiles.
Summary of the invention
Technical problem to be solved by this invention is when reducing pigment viscosity, can't guarantee opacifying power high on yarn fabric and sticking power, in order to overcome above defective, provide a kind of high covering low viscosity textiles Freehandhand-drawing marker ink and its preparation method and application.
In order to solve the problems of the technologies described above, technical scheme provided by the invention is: the described high component that low viscosity textiles Freehandhand-drawing marker ink comprises following weight proportion that hides:
Described water-borne Self-Crosslinked Acrylic emulsion produces intermolecular cross-linking behind the normal temperature desiccation, and to the strong adhesion of fabric, water tolerance and stain resistance are all very desirable after applying.
Further, the described high kinematic viscosity that hides low viscosity textiles Freehandhand-drawing marker ink is 40~80 seconds ISO-3 cup elution times.
Further, described organic dispersing agent is polycarboxylic acid salt's dispersion agent.The narrow molecular weight distribution of described polycarboxylic acid salt's dispersion agent can the stable dispersion settlement prevention.
Further, described titanium dioxide is Rutile type Titanium Dioxide, and fineness is well easily disperseed strong covering power.
Further, described wetting agent is the nonionic wetting agent.Emulsifying effectiveness is better, and is good with the wettability of fiber textile.
Further, the median size of described mill base is 100~500 nanometers.Ultra-fine mill base can settlement prevention, is used in stifled nib in the marker.
Further, the second-order transition temperature of described water-borne Self-Crosslinked Acrylic emulsion is-30 ℃~0 ℃.The water-borne Self-Crosslinked Acrylic ester emulsion that second-order transition temperature control is-30 ℃~0 ℃ is made pigment and has well been taken into account the anti-sticking and not stiff performance of coating.
Further, described filler is more than one in calcium carbonate and the kaolin.
The present invention also provides the above-mentioned high preparation method who hides low viscosity textiles Freehandhand-drawing marker ink, and it may further comprise the steps:
1) with titanium dioxide, organic dispersing agent, mill base, wetting agent, filler and water mix and blend, obtains the first Preblend;
2) with filtering behind water-borne Self-Crosslinked Acrylic emulsion, wetting agent and the water mix and blend, obtain the second Preblend;
3) mix the first Preblend and the second Preblend, regulate the kinematic viscosity of control mixture 40~80 seconds ISO-3 cup elution times, obtain crude product;
4) crude product that step 3) is obtained filters, and filtrate is the described high low viscosity textiles Freehandhand-drawing pigment that hides.
Further, the control method of described step 3) kinematic viscosity is: if mixture movement viscosity height then adds the second Preblend, if the low thickening material that then adds of kinematic viscosity.
The present invention also provides a kind of marker, and the ink of described marker is the above-mentioned high low viscosity textiles Freehandhand-drawing marker ink that hides.
The invention provides technical scheme innovation collocation water-borne Self-Crosslinked Acrylic emulsion and the organic dispersing agent of weaving usefulness, effectively reduce the viscosity of pigment, and this pigment has high covering, high adhesive power, from premium propertiess such as solidization, makes it be particularly suitable as the ink that marker is used in weaving.
Embodiment
Below in conjunction with embodiment the present invention is described in detail:
Elution time testing method: according to international standard ISO2432-1993 " paint and varnish one usefulness efflux cup mensuration elution time "
Each raw material is the commercially available prod.
Embodiment 1
A kind of high covering low viscosity textiles Freehandhand-drawing marker ink, its composition of raw materials is:
The second-order transition temperature of described water-borne Self-Crosslinked Acrylic emulsion is-10 ℃.
1) with titanium dioxide, polycarboxylic acid salt's dispersion agent, mill base, non-ionic wetting agent, water-ground limestone, calcined kaolin and water mix and blend, obtains the first Preblend;
2) with filtering behind water-borne Self-Crosslinked Acrylic emulsion, non-ionic wetting agent and the water mix and blend, obtain the second Preblend;
3) mix the first Preblend and the second Preblend, the kinematic viscosity that records mixture be the ISO-3 cup elution time below 40 seconds, add thickening material after, measure kinematic viscosity and be the ISO-3 cup elution time at 40~80 seconds, obtain crude product;
4) crude product that step 3) is obtained filters, and filtrate is the described high low viscosity textiles Freehandhand-drawing pigment A that hides, and kinematic viscosity is that the ISO-3 cup elution time was at 40~80 seconds.
Embodiment 2
A kind of high covering low viscosity textiles Freehandhand-drawing pigment, its composition of raw materials is:
The second-order transition temperature of described water-borne Self-Crosslinked Acrylic emulsion is-20 ℃.
1) with titanium dioxide, polycarboxylic acid salt's dispersion agent, mill base, non-ionic wetting agent, water-ground limestone and water mix and blend, obtains the first Preblend;
2) with filtering behind water-borne Self-Crosslinked Acrylic emulsion, non-ionic wetting agent and the water mix and blend, obtain the second Preblend;
3) mix the first Preblend and the second Preblend, the kinematic viscosity that records mixture be the ISO-3 cup elution time at 40~80 seconds, obtain crude product;
4) crude product that step 3) is obtained filters, and filtrate is the described high low viscosity textiles Freehandhand-drawing pigment B that hides, and kinematic viscosity is that the ISO-3 cup elution time was at 40~80 seconds.
Embodiment 3
A kind of high covering low viscosity textiles Freehandhand-drawing marker ink, its composition of raw materials is:
The second-order transition temperature of described water-borne Self-Crosslinked Acrylic emulsion is-5 ℃.
1) with titanium dioxide, polycarboxylic acid salt's dispersion agent, mill base, non-ionic wetting agent, calcined kaolin and water mix and blend, obtains the first Preblend;
2) with filtering behind water-borne Self-Crosslinked Acrylic emulsion, non-ionic wetting agent and the water mix and blend, obtain the second Preblend;
3) mix the first Preblend and the second Preblend, record the ISO-3 cup elution time of mixture more than 80 seconds, add the second Preblend and dilute, obtain crude product;
4) crude product that step 3) is obtained filters, and filtrate is the described high low viscosity textiles Freehandhand-drawing pigment C that hides, and the ISO3 cup elution time was at 40~80 seconds.
After hiding the relative opacifying power test data of low viscosity textiles Freehandhand-drawing marker ink and inject marker, the height of embodiment 1~3 preparation imposes on sticking power test data on the pure cotton fabric shown in following table one:
Table one
Relative opacifying power testing method: EN ISO2814-2006 paint and varnish. the comparison of the contrast ratio of the coating of same type and color (hiding rare)
Adhesion test method: textile fabric paint adhesion test method among the mark Q/320583AYBB001-2011 of enterprise.
Claims (10)
2. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, kinematic viscosity is 40~80 seconds ISO-3 cup elution times.
3. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, described organic dispersing agent is polycarboxylic acid salt's dispersion agent.
4. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, described wetting agent is the nonionic wetting agent.
5. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, the median size of described mill base is 100~500 nanometers.
6. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, the second-order transition temperature of described water-borne Self-Crosslinked Acrylic emulsion is-30 ℃~0 ℃.
7. described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink according to claim 1 is characterized in that, described filler is more than one in calcium carbonate and the kaolin.
8. the preparation method of the arbitrary described a kind of high covering low viscosity textiles Freehandhand-drawing marker ink of claim 1~7 is characterized in that, may further comprise the steps:
1) with titanium dioxide, organic dispersing agent, mill base, wetting agent, filler and water mix and blend, obtains the first Preblend;
2) with filtering behind water-borne Self-Crosslinked Acrylic emulsion, wetting agent and the water mix and blend, obtain the second Preblend;
3) mix the first Preblend and the second Preblend, the kinematic viscosity of regulating the control mixture be the ISO3 cup elution time at 40~80 seconds, obtain crude product;
4) crude product that step 3) is obtained filters, and filtrate is the described high low viscosity textiles Freehandhand-drawing pigment that hides.
9. described preparation method according to claim 8 is characterized in that, the control method of kinematic viscosity is in the described step 3): if mixture movement viscosity height then adds the second Preblend, if the low thickening material that then adds of kinematic viscosity.
10. a marker is characterized in that, the ink of described marker is the arbitrary described high low viscosity textiles Freehandhand-drawing marker ink that hides of claim 1~7.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106479263A (en) * | 2015-08-31 | 2017-03-08 | 旭化成家庭用品株式会社 | Packaging material for food is with aqueous Writing utensil equipped |
JP2017115084A (en) * | 2015-12-25 | 2017-06-29 | 株式会社パイロットコーポレーション | Aqueous ink composition for writing instrument |
CN107083093A (en) * | 2017-05-11 | 2017-08-22 | 广州海鑫无纺布实业有限公司 | A kind of wood pulp cotton pastel drawing pigment and its production and use |
CN111117354A (en) * | 2019-12-31 | 2020-05-08 | 苏州雄鹰笔墨新材料有限公司 | Water-based propylene marker ink and preparation method thereof |
CN114316678A (en) * | 2022-02-24 | 2022-04-12 | 盐城工业职业技术学院 | Cloth painting water color pen coating ink and preparation method thereof |
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US20100015412A1 (en) * | 2006-11-10 | 2010-01-21 | Sun Chemical Corp. | Water based printing inks for nonwoven substrates |
CN102093780A (en) * | 2010-12-31 | 2011-06-15 | 东莞市佳景印刷材料有限公司 | Non-woven fabric environmental-protection water-based ink and preparation method thereof |
CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
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2013
- 2013-05-24 CN CN201310198632.9A patent/CN103319955B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20100015412A1 (en) * | 2006-11-10 | 2010-01-21 | Sun Chemical Corp. | Water based printing inks for nonwoven substrates |
CN102108224A (en) * | 2010-12-30 | 2011-06-29 | 周震 | Washable water-soluble ink for marker pens for painting on surfaces of plastic toys |
CN102093780A (en) * | 2010-12-31 | 2011-06-15 | 东莞市佳景印刷材料有限公司 | Non-woven fabric environmental-protection water-based ink and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106479263A (en) * | 2015-08-31 | 2017-03-08 | 旭化成家庭用品株式会社 | Packaging material for food is with aqueous Writing utensil equipped |
JP2017115084A (en) * | 2015-12-25 | 2017-06-29 | 株式会社パイロットコーポレーション | Aqueous ink composition for writing instrument |
CN107083093A (en) * | 2017-05-11 | 2017-08-22 | 广州海鑫无纺布实业有限公司 | A kind of wood pulp cotton pastel drawing pigment and its production and use |
CN111117354A (en) * | 2019-12-31 | 2020-05-08 | 苏州雄鹰笔墨新材料有限公司 | Water-based propylene marker ink and preparation method thereof |
CN114316678A (en) * | 2022-02-24 | 2022-04-12 | 盐城工业职业技术学院 | Cloth painting water color pen coating ink and preparation method thereof |
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