CN103289473B - Dye-sublimation ink and preparation method thereof - Google Patents
Dye-sublimation ink and preparation method thereof Download PDFInfo
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- 238000000859 sublimation Methods 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 230000008022 sublimation Effects 0.000 claims abstract description 69
- 239000006185 dispersion Substances 0.000 claims abstract description 42
- 239000003960 organic solvent Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000000975 dye Substances 0.000 claims description 41
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- 239000013543 active substance Substances 0.000 claims description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 6
- 239000001045 blue dye Substances 0.000 claims description 6
- 239000001044 red dye Substances 0.000 claims description 6
- 239000001043 yellow dye Substances 0.000 claims description 6
- 238000005374 membrane filtration Methods 0.000 claims description 5
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims 12
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims 6
- 238000000034 method Methods 0.000 abstract description 14
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 238000007641 inkjet printing Methods 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 36
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 238000007639 printing Methods 0.000 description 10
- 229920001732 Lignosulfonate Polymers 0.000 description 8
- 230000033444 hydroxylation Effects 0.000 description 8
- 238000005805 hydroxylation reaction Methods 0.000 description 8
- 235000019357 lignosulphonate Nutrition 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- -1 polyoxyethylene Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 229920005552 sodium lignosulfonate Polymers 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 206010037660 Pyrexia Diseases 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
Abstract
The invention discloses dye-sublimation ink and a preparation method thereof. The dye-sublimation ink is adapted to and matched with sixth-generation Epson digital printer nozzle, and is low in cost. The dye-sublimation ink consists of the following components in percentage by mass: 10-40 percent of sublimation dye, 0.5-10 percent of a dispersing agent, 20-40 percent of an organic solvent, 30-60 percent of water, 0.5-2 percent of a surfactant and 0.05-0.2 percent of a preservative. The method for preparing the dye-sublimation ink comprises the following steps of: mixing and grinding the sublimation dye and the dispersing agent, thus obtaining a dispersion solution; adding the organic solvent, deionized water, the surfactant and the preservative into the dispersion solution, and stirring to obtain the dye-sublimation ink. Compared with the prior art, the dye-sublimation ink has high smoothness and stability, is well matched with and adapted to a sixth-generation Epson digital printer and can be used for large-format ink-jet printing of the printer with the sixth-generation Epson nozzle.
Description
Technical field
The present invention relates to a kind of printing ink ink and preparation method thereof, particularly a kind of ink for ink-jet print for Epson the 6th algebraic code printing press shower nozzle and preparation method thereof.
Background technology
Epson the 6th algebraic code printing press (a six generations machine) shower nozzle is single 360 spray orifices, 10 rows have 360 × 10=3600 spray orifice, monochromatic passage, and full accuracy can reach 2880dpi, can realize ten looks and print, be all to reach impeccable effect at color gamut or in precision.It is by controlling piezoquartz, and ink dot is realized controllability, reaches the minimum 3.5pl ink droplet of ink drop size, realizes the perfect adaptation of accuracy and runtime, also has in addition shower nozzle whether to stop up automatic detection function, has effectively ensured the perfection of the picture printing.It is also higher to the requirement of ink for ink-jet print on the other hand; on the market much originally on five generations machines the good ink for ink-jet print of print performance be applied on Epson six generations machine; often there will be and print broken string or plug phenomenon; cause print performance poor; the ink for ink-jet print of prior art is not good to adaptability and the matching of Epson six generations machine; the high-performance of a six generations machine be can not give full play to, very large inconvenience and loss brought to user.And six generations a machine-specific ink for ink-jet print price higher.
Summary of the invention
The object of this invention is to provide a kind of heat sublimation ink and preparation method thereof, the technical problem that solve is to adapt to and coupling Epson the 6th algebraic code printing press shower nozzle, and cost is low.
The present invention is by the following technical solutions: a kind of heat sublimation ink, is made up of following mass percent component: sublimation dye 10～40%, dispersion agent 0.5～10%, organic solvent 20～40%, water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%;
The dispersed blue dye of described sublimation dye employing composition cyan is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or for form the dispersive red dye of magenta ink be numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or for form the disperse yellow dye of yellow ink be numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin with hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--more than one in butyl ether of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of in nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and Surfynol465.
Sublimation dye of the present invention is 15～35%, and organic solvent is 26～38%, and water is 30～50%.
Water of the present invention is 35.4～43.4%.
Dispersion agent of the present invention adopts lignosulfonic acid sodium salt.
Sanitas of the present invention adopts Proxel GXL.
Sublimation dye of the present invention, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material, water is deionized water.
A preparation method for heat sublimation ink, comprises the following steps:
One, under room temperature, by mass percentage, by after sublimation dye 10～40% and dispersion agent 0.5～10% mixing, the zirconium pearl that uses diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2200～2800r/min, grinding distribution 24h, obtains dispersion liquid;
The dispersed blue dye of described sublimation dye employing composition cyan is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or for form the dispersive red dye of magenta ink be numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or for form the disperse yellow dye of yellow ink be numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin with hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate.
Two, in dispersion liquid, add organic solvent 20～40%, deionized water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%, rotating speed 2200～2800r/min, stirs after 60min, uses 0.22u membrane filtration, obtains heat sublimation ink;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--more than one in butyl ether of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of combinations in nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and Surfynol465.
Described sanitas adopts Proxel GXL;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
Method sublimation dye of the present invention is 15～35%, and organic solvent is 26～38%, and deionized water is 30～50%.
Method deionized water of the present invention is 35.4～43.4%.
Method powder of the present invention adopts lignosulfonic acid sodium salt.
Compared with prior art, heat sublimation ink has good fluency and stability in the present invention, and Epson the 6th algebraic code printing press is had to good matching and adaptability, and the large-format ink-jet that can be used for Epson six generations machine is printed.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Heat sublimation ink of the present invention, is made up of following mass percent component: sublimation dye 10～40%, dispersion agent 0.5～10%, organic solvent 20～40%, water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%.
Be preferably: sublimation dye 15～35%, organic solvent 26～38%, water 30～50%.
More preferably: water 35.4～43.4%.
Sublimation dye adopts the dyestuff of prior art: for form the dispersed blue dye of cyan be numbered 14,28,56,60,72,73,77,334,336 and 359 more than one; Or for form the dispersive red dye of magenta ink be numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or for form the disperse yellow dye of yellow ink be numbered 51,54,60,64,65,82,98,119,160 and 211 more than one.
Dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin with hydrophilic radical.Hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen, and lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10, and sulfonated lignin are sodium lignosulfonate.Be preferably lignosulfonic acid sodium salt.
Organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--more than one in butyl ether of methyl ether, glycol ether--methyl ether and glycol ether--.
Tensio-active agent adopts any one or two kinds of combination in nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and Surfynol465.
Sanitas adopts Proxel GXL.
Sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material, water is deionized water.
Heat sublimation ink of the present invention, viscosity is 3～7mPa.s, surface tension is 20～45mN/m, dissolved oxygen content DO value≤2PPM.Viscosity is 3～5mPa.s preferably, and surface tension is 20～40mN/m preferably.
The preparation method of heat sublimation ink of the present invention, comprises the following steps:
One, under room temperature (20 DEG C), by mass percentage, by after sublimation dye 10～40% and dispersion agent 0.5～10% mixing, in sand mill, use the zirconium pearl of diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2200～2800r/min, grinding distribution 24h, obtains dispersion liquid.
Two, dispersion liquid is put into reactor, add organic solvent 20～40%, deionized water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%, rotating speed 600～800r/min, stirs after 60min, uses 0.22u membrane filtration, obtains heat sublimation ink.
Be preferably: sublimation dye 15～35%, organic solvent 26～38%, deionized water 30～50%.
More preferably: deionized water 35.4～43.4%.
Sublimation dye adopts the dyestuff of prior art: for form the dispersed blue dye of cyan be numbered 14,28,56,60,72,73,77,334,336 and 359 more than one; Or for form the dispersive red dye of magenta ink be numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or for form the disperse yellow dye of yellow ink be numbered 51,54,60,64,65,82,98,119,160 and 211 more than one.
Dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin with hydrophilic radical.Hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen, and lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10, and sulfonated lignin are sodium lignosulfonate.Be preferably lignosulfonic acid sodium salt.
Organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--more than one in butyl ether of methyl ether, glycol ether--methyl ether and glycol ether--.
Tensio-active agent adopts any one or two kinds of combinations in nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and Surfynol465.
Sanitas adopts Proxel GXL.
Sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
The component of embodiment 1-3 and processing parameter are in table 1.
The heat sublimation ink of the embodiment 1-3 that the inventive method prepares, the digital viscometer of DV-II+Pro type for viscosity test, is set to 30 DEG C of & 60rpm; The full-automatic surface tension instrument of BZY-1 for surface tension, the test of adopting platinum plate method; Dissolved oxygen content DO value adopts the test of Hana HI9146 dissolved oxygen meter, and test result is in table 2.
Comparative example 1, adopts the blue fever transfer printing ink (martial prowess C) of Chinese Zhuhai martial prowess Fan Ling trade Co., Ltd, and by the identical method tested viscosity of embodiment 1-3, surface tension, dissolved oxygen content DO value, test result is in table 2.
Comparative example 2, adopting country of origin is Italy, retailer is the yellow heat sublimation ink (ten thousand exquisite Y) of the exquisite chemical industry of Kai Angwan (Shanghai) Co., Ltd., and by the identical method tested viscosity of embodiment 1-3, surface tension, dissolved oxygen content DO value, test result is in table 2.
As can be seen from Table 2, the viscosity of embodiment 1-3 is less than comparative example 1-2, surface tension is less than comparative example 1-2, DO value is less, viscosity and surface tension are low guarantees that ink has good mobility and the adaptability to shower nozzle, and the less bubble reducing to greatest extent in ink of DO value affects ink fluency in print procedure.
The heat sublimation ink of the embodiment 1-3 that the inventive method prepares and the ink of comparative example 1-2, get respectively 1000ml, printing with on six generations of Epson machine EPSON7710 ink-jet printers, to detect the printing fluency of ink.Print media is heat-transferring printing paper, and ink printed fluency test result is in table 3.
The assessment method of ink fluency test is:
A level: print continuously 1000ml, print smooth without broken string;
B level: print continuously 1000ml, print procedure interrupt line < 3 lattice;
C level: print continuously 1000ml, print procedure interrupt line >=3 lattice test printing fluency.
According to test result, illustrate that the heat sublimation ink that the inventive method prepares has good matching and adaptability, on Epson six generations machine, print and there is good fluency.
Component and the processing parameter of table 1 embodiment 1-3
The heat sublimation ink of table 2 embodiment 1-3 and comparative example 1-2 tested viscosity, surface tension, dissolved oxygen content DO value
The heat sublimation ink of table 3 embodiment 1-3 and comparative example 1-2 ink printed fluency test result
| Embodiment and comparative example | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Fluency test | A | A | A | C | C |
Claims (6)
1. a heat sublimation ink, it is characterized in that: described heat sublimation ink is made up of following mass percent component: sublimation dye 25%, dispersion agent NP-10 2%, organic solvent glycerine 15%, ethylene glycol--methyl ether 11%, propylene glycol 5%, deionized water 40.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL 0.1%;
Described sublimation dye adopts the dispersed blue dye of composition cyan to be numbered 359;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material.
2. a heat sublimation ink, it is characterized in that: described heat sublimation ink is made up of following mass percent component: sublimation dye 35%, dispersion agent NP-10 2%, organic solvent glycerine 15%, ethylene glycol--methyl ether 8%, propylene glycol 3%, deionized water 35.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL 0.1%;
Described sublimation dye adopts the dispersive red dye of composition magenta ink to be numbered 60;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material.
3. a heat sublimation ink, it is characterized in that: described heat sublimation ink is made up of following mass percent component: sublimation dye 15%, dispersion agent NP-10 2%, organic solvent glycerine 21%, ethylene glycol--methyl ether 12%, propylene glycol 5%, deionized water 43.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL 0.1%;
Described sublimation dye adopts the disperse yellow dye of composition yellow ink to be numbered 54;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material.
4. a preparation method for heat sublimation ink, comprises the following steps:
One, under room temperature, by mass percentage, after sublimation dye 25% and dispersion agent NP-10 2% are mixed, the zirconium pearl that uses diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2400r/min, grinding distribution 24h, obtains dispersion liquid;
Described sublimation dye adopts the dispersed blue dye of composition cyan to be numbered 359;
Two, in dispersion liquid, add organic solvent glycerine 15%, ethylene glycol--methyl ether 11%, propylene glycol 5%, deionized water 40.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL 0.1%, rotating speed 2600r/min, stirs after 60min, use 0.22u membrane filtration, obtain heat sublimation ink;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
5. a preparation method for heat sublimation ink, comprises the following steps:
One, under room temperature, by mass percentage, after sublimation dye 35% and dispersion agent NP-10 2% are mixed, the zirconium pearl that uses diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2400r/min, grinding distribution 24h, obtains dispersion liquid;
Described sublimation dye adopts the dispersive red dye of composition magenta ink to be numbered 60;
Two, in dispersion liquid, add organic solvent glycerine 15%, ethylene glycol--methyl ether 8%, propylene glycol 3%, deionized water 35.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL0.1%, rotating speed 2600r/min, stirs after 60min, use 0.22u membrane filtration, obtain heat sublimation ink;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
6. a preparation method for heat sublimation ink, comprises the following steps:
One, under room temperature, by mass percentage, after sublimation dye 15% and dispersion agent NP-10 2% are mixed, the zirconium pearl that uses diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2400r/min, grinding distribution 24h, obtains dispersion liquid;
Described sublimation dye adopts the disperse yellow dye of composition yellow ink to be numbered 54;
Two, in dispersion liquid, add organic solvent glycerine 21%, ethylene glycol--methyl ether 12%, propylene glycol 5%, deionized water 43.4%, tensio-active agent Surfynol 604 0.5%, Surfynol 465 1%, sanitas Proxel GXL 0.1%, rotating speed 2600r/min, stirs after 60min, use 0.22u membrane filtration, obtain heat sublimation ink;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
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| CN109487578A (en) * | 2018-12-04 | 2019-03-19 | 深圳市墨库图文技术有限公司 | Thief zone heat sublimation ink and preparation method thereof |
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| CN101245204A (en) * | 2008-04-02 | 2008-08-20 | 上海英威喷墨科技有限公司 | Thermal sublimation digit printing ink-jet writing ink and preparation method |
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| CN101921504A (en) * | 2010-09-14 | 2010-12-22 | 珠海保税区天然宝杰数码科技材料有限公司 | Sublimation ink for industrial nozzle |
| CN102585589B (en) * | 2012-03-07 | 2013-12-11 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
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| CN109487578A (en) * | 2018-12-04 | 2019-03-19 | 深圳市墨库图文技术有限公司 | Thief zone heat sublimation ink and preparation method thereof |
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