CN101921504A - Sublimation ink for industrial nozzle - Google Patents
Sublimation ink for industrial nozzle Download PDFInfo
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- CN101921504A CN101921504A CN 201010280050 CN201010280050A CN101921504A CN 101921504 A CN101921504 A CN 101921504A CN 201010280050 CN201010280050 CN 201010280050 CN 201010280050 A CN201010280050 A CN 201010280050A CN 101921504 A CN101921504 A CN 101921504A
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- ink
- heat sublimation
- sublimation
- industrial nozzle
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Abstract
The invention relates to sublimation ink for an industrial nozzle, which is suitable for large format inkjet printer with the industrial nozzle. The ink at least comprises sublimation dye, dispersant, organic solvent and water, wherein the viscosity of the ink is 8 to 15 centipoises, and is prepared by mixing and grinding the sublimation dye and the dispersant, adding a proper amount of wetting agent, adjuvant and deionized water, and then stirring. The ink is used for matching with the industrial nozzle to print textiles, has the characteristic of good environmental conservation and has no harm to skin.
Description
Technical field
The present invention relates to be used for the heat sublimation ink of industrial nozzle, this ink is applicable to the wide format ink jet printer with industrial nozzle, particularly implement the pattern print job on the polyester chemical fiber fabric at textiles, pass through direct heating, pattern is sublimate on the cloth, need not to implement the intermediate transfer step, not only environmental protection but also be applicable to industrialized production by offset medium.
Background technology
Ink-jet printer is with the customization that heat sublimation ink is bright in luster owing to it, resolving power is high, flexible operation is widely used in personalized product, and cup, crystal, T-shirt of various different patterns etc. are arranged as transfer printing.Heat sublimation ink generally needs offset medium to be mated could implement transfer printing, therefore its range of application generally is confined to small-sized ink-jet printer, cooperate the Seiko, the industrial nozzles such as Xaar, Konica that require almost not to have suitability to no offset medium, so that can not realize large batch of industrial production in textile field.
In recent years, along with improving constantly of domestic ink-jet printer production technology, occurred the wide format ink jet printer of various brands successively, the textiles that is used for heat sublimation ink is printed.These ink-jet printers use industrial nozzles such as Seiko, Xaar, Konica mostly, and its jet speed is fast, high efficiency, and be furnished with heating unit, need not to carry out transfer printing can sublimate directly to pattern on the recording medium.These ink-jet printers use solvent-based inks as its photographic developer mostly, and it pollutes big, can cause bigger negative impact to environment.As the Chinese patent publication number is that the patent documentation of CN101245204A discloses a kind of thermal sublimation digit printing ink-jet writing ink and preparation method.This heat sublimation ink is applied in and has Xaar, on the large-scale piezoelectric type digital decorating machine of industrial nozzles such as Spectra, but this ink is solvent-based inks, its organic solvent content 60～90%, and be the extremely strong material of volatility, unfriendly to environment, especially environmental pollution is very big when print ad flag, banner; During the ready-made clothes of swimming suit that wears next to the skin in printing and so on, very big to skin damage.
Summary of the invention
Be difficult to problem with industrial nozzle coupling at above-mentioned heat sublimation solvent-based inks, the heat sublimation ink that provides a kind of ink-jet printer to use is provided the object of the invention, and this ink can directly be implemented the heat sublimation operation, and is all harmless to environment and skin.
For reaching to above-mentioned purpose, the invention provides a kind of water miscible heat sublimation ink, it is applicable to the wide format ink jet printer with industrial nozzle.This ink contains sublimation dye, dispersion agent, organic solvent and water at least, and its viscosity is 8～15 centipoises.
This ink scheme preferably is that its viscosity is 8～12 centipoises.
Aforementioned heat sublimation ink, the content of its organic solvent are chosen as 25～40 weight %, and preferred content range is 30～40 weight %.This organic solvent is selected from least a in aliphatic alcohols such as ethylene glycol, glycol ether, triglycol, propylene glycol, the glycerine.
Aforementioned heat sublimation ink, the content of its water are chosen as 50～65 weight %, and preferred content scope 1～30 weight %, more excellent content range are 1～10 weight %.
Aforementioned heat sublimation ink, its content as the sublimation dye that tinting material uses is chosen as 1.5～6 weight %, to obtain good colorrendering quality.Preferred sublimation dye comprises: be selected from EX-SF DISPERSE BLUE EX-SF 300 14,28,56,60,72,73,77,334,336 at least a that cyan is formed in public being used in present technique field; Be selected from public being used in present technique field and form Disperse Red 4,22,55,59,60,146,152,191,302 at least a of magenta ink; Be selected from public being used in present technique field and form DISPERSE YELLOW 51,54,60,64,65,82,98,119,160,211 at least a of yellow ink.
Aforementioned heat sublimation ink, its dispersant are chosen as 0.5～10 weight %.This dispersion agent is selected from the xylogen that has hydrophilic radical, in the sulfonated lignin any.The xylogen that preferably has hydrophilic radical is the hydroxylation xylogen.The hydroxylation xylogen is selected from any in phenolic group xylogen, hydroxyl xylogen, the carboxyl xylogen.Sulfonated lignin are sodium lignosulfonate.
Aforementioned heat sublimation ink, at least a in also comprises surfactant, acidity-basicity regulator, the antiseptic-germicide.Its tensio-active agent is selected from any in nonionogenic tenside, anion surfactant, the zwitterionics.Its acidity-basicity regulator is selected from any in sodium hydroxide, potassium hydroxide, ammoniacal liquor, triethylamine, trolamine, acetic acid, the lactic acid.Its antiseptic-germicide is PROXEL GXL.
Be difficult to industrial nozzle coupling, and contaminate environment when print ad flag, banner the problem of injury skin when printing ready-made clothes next to the shin at existing solvent-borne type heat sublimation ink.Heat sublimation ink of the present invention adopts water-based system, and primary solvent is a water, and to environment and human body close friend, application prospect is more extensive, and can realize good coupling with existing industrial nozzle.
Embodiment
Describe heat sublimation ink of the present invention below in detail.
Heat sublimation ink of the present invention is in order to method preparation down, and various batchings are all used commercially available industrial pure material in the process for preparation, and the purity of water is deionized water:
Get the sublimation dye and the dispersion agent of predetermined amount, mixing the back uses diameter to grind dispersion 20 hours as the zirconium pearl of 0.1mm in sand mill, the gained dispersion liquid is removed and puts into reactor, add certain amount of organic solvent, tensio-active agent, antiseptic-germicide and deionized water more successively, stir after 60 minutes under the room temperature, with 0.45 μ membrane filtration, promptly get heat sublimation ink.
Composition according to various embodiments of the present invention ink in the table 1, with sublimation dye and dispersant, using diameter to grind as the zirconium pearl of 0.1mm in sand mill disperseed 20 hours, the gained dispersion liquid is removed and puts into reactor, add a certain amount of wetting agent, auxiliary agent and deionized water more successively, stir after 60 minutes under the room temperature,, promptly get heat sublimation ink with 0.45 μ membrane filtration.Table 2 shows the viscosity test result of ink of the present invention.Table 3 shows the printing fluency measurement result of ink of the present invention.
Table 1 ink of the present invention is formed situation (each component concentration unit: weight percent)
Table 2 ink viscosity test result (this table embodiment numbers ascending corresponding one by one with table 1 numbering)
| The embodiment numbering | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 |
| Viscosity (centipoise) | 8.75 | 8.98 | 9.13 | 9.28 | 9.35 | 8.75 | 9.01 | 8.72 | 8.78 |
Get each chromatic ink 500ml of the present invention, print having on the textile inkjet printer of industrial nozzle, to detect the printing fluency of ink.Print media is the polyester chemical fiber fabric, and print result sees Table 3.
Ink fluency assessment method is:
A level: print 500ml continuously, print smooth no white line;
B level: print 500ml continuously, palpus cleaning industrial nozzle number of times in the print procedure≤3 times;
C level: print 500ml continuously, palpus cleaning industrial nozzle number of times in the print procedure 〉=4 times.
Table 3 ink printed fluency measurement result (this table embodiment numbers ascending corresponding one by one with table 1 numbering)
| The embodiment numbering | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 |
| Fluency) | B | B | A | A | A | B | A | B | A |
Claims (6)
1. heat sublimation ink comprises sublimation dye, dispersion agent, organic solvent and water, it is characterized in that described ink viscosity is 8～15 centipoises.
2. according to the described heat sublimation ink of claim 1, it is characterized in that described ink viscosity is 8～12 centipoises.
3. according to claim 1 or 2 described heat sublimation inks, it is characterized in that the content of described organic solvent in described ink is 25～40 weight %, described organic solvent is selected from least a of ethylene glycol, glycol ether, triglycol, propylene glycol, glycerine.
4. according to the described heat sublimation ink of claim 3, it is characterized in that the content of described organic solvent in described ink is 30～40 weight %.
5. according to the described heat sublimation ink of claim 4, the content that it is characterized in that described water is 50～65 weight %.
6. according to the described heat sublimation ink of claim 5, it is characterized in that the content of described sublimation dye in described ink is 1～30 weight %.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010280050 CN101921504A (en) | 2010-09-14 | 2010-09-14 | Sublimation ink for industrial nozzle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010280050 CN101921504A (en) | 2010-09-14 | 2010-09-14 | Sublimation ink for industrial nozzle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101921504A true CN101921504A (en) | 2010-12-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010280050 Pending CN101921504A (en) | 2010-09-14 | 2010-09-14 | Sublimation ink for industrial nozzle |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585589A (en) * | 2012-03-07 | 2012-07-18 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
| CN103289473A (en) * | 2013-07-01 | 2013-09-11 | 深圳市墨库图文技术有限公司 | Dye-sublimation ink and preparation method thereof |
| CN103450740A (en) * | 2013-09-29 | 2013-12-18 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
| CN103497588A (en) * | 2013-09-30 | 2014-01-08 | 深圳市墨库图文技术有限公司 | Textile dye sublimation ink and preparation method thereof |
| CN106349817A (en) * | 2016-09-29 | 2017-01-25 | 苏州吉谷新材料有限公司 | Quick-dry heat sublimation ink |
| CN106566312A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Anticorrosion and sterilization sublimation ink |
| CN106567266A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Thermal dye-sublimation printed bamboo product, and preparation method thereof |
| CN106566310A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Thermal sublimation ink with scale inhibition function |
| CN106675203A (en) * | 2016-12-15 | 2017-05-17 | 苏州吉谷新材料有限公司 | Thermal sublimation ink with stable performances |
| CN106752301A (en) * | 2016-11-15 | 2017-05-31 | 苏州吉谷新材料有限公司 | Heat sublimation ink and preparation method thereof |
| CN106835778A (en) * | 2016-11-15 | 2017-06-13 | 苏州吉谷新材料有限公司 | Heat sublimation ink of weaving and preparation method thereof |
| CN107129721A (en) * | 2017-05-24 | 2017-09-05 | 安徽正洁高新材料股份有限公司 | A kind of heat sublimation ink based on compounding dispersed black dye and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85107346A (en) * | 1985-09-17 | 1987-09-02 | 厦门市科学技术局 | Colored ink for transferring and printing method |
| CN1258702A (en) * | 1998-12-30 | 2000-07-05 | 张元明 | Subliming heat-transfer planographic ink and its making process and application |
| CN101245204A (en) * | 2008-04-02 | 2008-08-20 | 上海英威喷墨科技有限公司 | Thermal sublimation digit printing ink-jet writing ink and preparation method |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
-
2010
- 2010-09-14 CN CN 201010280050 patent/CN101921504A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85107346A (en) * | 1985-09-17 | 1987-09-02 | 厦门市科学技术局 | Colored ink for transferring and printing method |
| CN1258702A (en) * | 1998-12-30 | 2000-07-05 | 张元明 | Subliming heat-transfer planographic ink and its making process and application |
| CN101245204A (en) * | 2008-04-02 | 2008-08-20 | 上海英威喷墨科技有限公司 | Thermal sublimation digit printing ink-jet writing ink and preparation method |
| CN101709177A (en) * | 2009-12-03 | 2010-05-19 | 上海英威喷墨科技有限公司 | Waterborne digital ink-jet printing sublimation ink and preparation method thereof |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585589A (en) * | 2012-03-07 | 2012-07-18 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
| CN102585589B (en) * | 2012-03-07 | 2013-12-11 | 深圳市墨库图文技术有限公司 | Thermal sublimation ink as well as direct printing technology and equipment |
| CN103289473A (en) * | 2013-07-01 | 2013-09-11 | 深圳市墨库图文技术有限公司 | Dye-sublimation ink and preparation method thereof |
| CN103450740B (en) * | 2013-09-29 | 2015-07-08 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
| CN103450740A (en) * | 2013-09-29 | 2013-12-18 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
| CN103497588A (en) * | 2013-09-30 | 2014-01-08 | 深圳市墨库图文技术有限公司 | Textile dye sublimation ink and preparation method thereof |
| CN103497588B (en) * | 2013-09-30 | 2015-05-20 | 深圳市墨库图文技术有限公司 | Textile dye sublimation ink and preparation method thereof |
| CN106349817A (en) * | 2016-09-29 | 2017-01-25 | 苏州吉谷新材料有限公司 | Quick-dry heat sublimation ink |
| CN106566312A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Anticorrosion and sterilization sublimation ink |
| CN106567266A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Thermal dye-sublimation printed bamboo product, and preparation method thereof |
| CN106566310A (en) * | 2016-11-04 | 2017-04-19 | 苏州吉谷新材料有限公司 | Thermal sublimation ink with scale inhibition function |
| CN106752301A (en) * | 2016-11-15 | 2017-05-31 | 苏州吉谷新材料有限公司 | Heat sublimation ink and preparation method thereof |
| CN106835778A (en) * | 2016-11-15 | 2017-06-13 | 苏州吉谷新材料有限公司 | Heat sublimation ink of weaving and preparation method thereof |
| CN106675203A (en) * | 2016-12-15 | 2017-05-17 | 苏州吉谷新材料有限公司 | Thermal sublimation ink with stable performances |
| CN107129721A (en) * | 2017-05-24 | 2017-09-05 | 安徽正洁高新材料股份有限公司 | A kind of heat sublimation ink based on compounding dispersed black dye and preparation method thereof |
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Application publication date: 20101222 |