CN102817254B - Cold-transfer printing digital proofing method - Google Patents

Cold-transfer printing digital proofing method Download PDF

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Publication number
CN102817254B
CN102817254B CN201210261528.5A CN201210261528A CN102817254B CN 102817254 B CN102817254 B CN 102817254B CN 201210261528 A CN201210261528 A CN 201210261528A CN 102817254 B CN102817254 B CN 102817254B
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ink
cold
transfer printing
jet
printing
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CN201210261528.5A
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CN102817254A (en
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钟博文
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长胜纺织科技发展(上海)有限公司
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Abstract

The invention discloses a cold-transfer printing digital proofing method. The cold-transfer printing digital proofing method comprises the following steps of carrying out computer drawing according to a customer's sample or a sample manuscript, printing ink-jet ink on a base paper by an ink-jet printer to obtain a cold-transfer printing paper, carrying out cold-transfer printing, and carrying out cold pad batch fixation to obtain a sample which is used as a standard sample after determination, wherein the ink-jet printer is an industrial multicolor piezoelectric ink-jet printer; the base paper of the cold-transfer printing paper is a paper coated with a polymer compound insulating layer; and the ink-jet ink comprises water soluble dye, a wetting agent, an antiseptic, a thickener, a permeating agent, a conditioning agent and deionized water. The cold-transfer printing digital proofing method realizes the combination of an ink-jet printing technology and a cold-transfer printing technology and realizes cold-transfer printing proofing well.

Description

The digital specimen method of cold-transfer printing
Technical field
The present invention relates to the stamp field of dyeing industry in textile industry, specifically refer to a kind of digital specimen method of cold-transfer printing.The digital specimen method of cold-transfer printing is the method that cold-transfer printing technology and ink-jet printed technology combine, and can improve the work efficiency of cold-transfer printing.Shorten the plate-making time, make client's sample manuscript directly be converted into digital image by scanner, textile printing and ecommerce are combined.
Background technology
Ink-jet printedly from ink-jet word is printed, slowly change and come, ink-jet printed have very large relevance with textiles.Ink jet printing (Ink-jet Printing) appears at 1878, until nineteen fifty-one Siemens company is transformed into liquid ink the art applications patent of ink droplet, by 1964 by a special board, can control the size of ink droplet and the speed of ejection, form the blank of ink jet printer, Hertz in 1967 develop the ink-jet table printing machine of continous mode, and Here it is at present at the ink-jet printer of industrial use.Within 1966, Siemens releases piezoelectric ink jet printer (Piezoelectric Drop-on-Demand Ink-jet Printing), Canon in 1979 release the ink-jet printer (Drop-on-Demand Ink-jet Printing) of Thermal, be called Bubble Ink-jet Printing, HP in 1984 also release the ink-jet printer (Drop-on-Demand Ink-jet Printing) of Thermal.Ink-jet printer (Ink-jet Printing) is divided into two large classes substantially, a class is (Continuous) continous mode, and another kind of is (Drop-on-Demand) controllable.Continuous Ink-jet Printing continuous inkjet printer is mainly used in industrial aspect, the surface of paper, metal and the plastic cement such as such as Print Label, ticket, carton; Its advantage is that speed is fast, and the smoothness of material surface is also not bery important, has sizable distance, so unaffected by the thickness of printed material material between shower nozzle and material; Shortcoming is that resolution is not very high, is conventionally used in material surface coarse, that not bery focus on resolution.At present continuous inkjet printer Continuous Ink-jet Printing develops two kinds of two-way deflection (Binary Deflection) and multidirectional skews (Multiple Deflection), is all the principle of utilizing voltage generation deflection; The mode ink supply of the former ink-jet and not ink-jet when not charged when charged, after the ejection of the latter's ink droplet, through high pressure deflect board, can control the direction of deflection, and can more accurately reach the place that needs ink-jet, uncharged ink droplet imports ink guide tank, recyclable re-using.
Ink-jet printed is a kind of novel digital application technology, and it is the method for application Computerized ink-jetting printer mimeograph documents, dye ink is directly printed on textiles by the pattern of computer design, thereby realizes ink-jet printed.Ink-jet printed technique has lot of advantages, and for example stamp process is fast, and it is convenient that flower type changes, and pattern is true to nature, easy to use, can adapt to current many kinds of small lot printing technology, and stamp sample technique.But ink-jet printed also band is served shortcoming, is mainly that printing cost is high, in ink-jetting process the maintaining of ink-jet printed head more difficult, and the ink-jet printed mass production method that is not suitable with.Current transfering printing technology is the method that adopts transfer printing paper transfer printing, has advantages of environmental protection and energy-conservation stamp, is a kind of stamp new technology with promotional value.But the sample technique of transfer printing also adopts more traditional method, need to be through style design, plate-making, the mode that engraving etc. are identical with conventional stamp sample, with printing machine, dye ink is printed on transfer paper again, then is transferred on textiles, after client confirms, could print again full-page proof.Because the sample of cold-transfer printing only needs the PRINTED FABRIC of minute quantity, adopt conventional stamp sample mode to cause out sample cost large, and time consumption and energy consumption.Therefore, if can adopt mode ink-jet printed and that transfer printing combines to print sample, can either save cost, can save time again and quick delivery.For example, but known ink-jet printing ink and ink-jet printed technique thereof also cannot adapt to cold-transfer printing technique at present:
1. patent of invention " 200510047731.2 ", be entitled as " a kind of purposes of active dye as ink-jet printing ink ", discloses the ink-jet printed purposes of REACTIVE DYES and the formula of REACTIVE DYES.
2. patent of invention " 98103230.3 " and " 98103229.X ", exercise question is all " method of according to ink jet printing, textile material being carried out stamp ", discloses water miscible REACTIVE DYES ink-jet ink, is especially applicable to cellulosic fibre material stamp.
3. patent of invention " 98127147.2 ", be entitled as " ink-jet printing method of textile fiber material ", disclose the one that textile fiber material uses and contained at least one DISPERSE DYES, the water-based of a kind of anionic copolymer and/or a kind of nonionic block polymer and/or a kind of dispersant prints China ink to be printed, and relates to the Yin Mo that contains these components.
4. patent of invention " 02133084.0 ", is entitled as " ink of waterproof ink-jet printing, air brushing and ink-jet printing of fabric ", discloses the dyestuff with carboxymethyl group is manufactured for ink, and the component of dye ink is dye matrix and H +, N2 +, K +, NH 4 +, Li +deng.When ink-jet, under heat, electromagnetic radiation or the microwave action of nozzle, part dyestuff decarboxylize forms water-soluble dye.
5. patent of invention " 200510097007.0 ", be entitled as " a kind of for ink-jet printed nano grade polymer micro-emulsion and manufacture method thereof ", disclose a kind of soft monomer butyl acrylate taking high-load as the synthetic ink-jet ink of main polymerization single polymerization monomer, pigment particles can be attached on textile fabric securely.
6. patent of invention " 200410013291.4 ", be entitled as " water miscible pigment ink-jetting printing ink ", disclose a kind of ink-jet printing ink being formed by pigment, water-miscible organic solvent, deionized water, preservative agent, self-crosslinking acrylic resin, surfactant, wetting agent, pH adjusting agent.
7. patent of invention " 200510040115.4 ", be entitled as " a kind of ink-jet printing ink and preparation method thereof ", disclosing one is that dispersant and sticking agent are prepared pigment ink-jet inks by polyocarboxy acid type high-molecular copolymer, and pigment dispersing agent and sticking agent are made to same component.
8. patent of invention " 200510092005.1 ", be entitled as " a kind of nanometer painting ink-jetting printing oil ink and preparation method thereof ", a kind of jetted ink is disclosed, by cross-linked polymer fine latex, deionized water, water-miscible organic solvent, the preservative agent of pigment microcapsules, humectant, surfactant and pH adjusting agent form.
9. patent of invention " 00102155.9 ", be entitled as " thermal transfer print ink for colour printer ", disclose one and formed jetted ink by heat sublimation dyestuff and pigment, aqueous binder, lubricant, pyrophosphoric acid, potassium and defoamer, can be used for heat transfer printing paper.
In addition, each major company of the world has carried out a series of research to ink-jet printed with dyestuff in recent years, and has recommended a series of for ink-jet printed REACTIVE DYES.SUMITOMO CHEMICAL company has delivered many about ink-jet printed result of study and patent by REACTIVE DYES, proposed to be specifically designed to the REACTIVE DYES that cotton fiber textile inkjet printing is used, these dye structures are simple, synthetic conveniently, properties all can meet ink-jet printed requirement.Meanwhile, each company also constantly releases ink-jet printed REACTIVE DYES commodity, for example: Stork and Zeneca company have developed the highly purified Procion P type dye for ink-jet printed use cooperatively; The Cibacron MI ink series of Ciba company has 8 kinds, is specially adapted to the ink-jet printed of piezoelectric type and thermal bubble jet technology; The Jettex R type REACTIVE DYES of DYStar company is made up of 13 kinds; Jettex Rink has 9 kinds, is through the REACTIVE DYES of purifying and special disposal is crossed.
Above-mentioned these ink-jet printing inks are all to adopt ink-jet printer directly required pattern to be printed on and to be printed on fabric, therefore, inadaptable being printed on made cold transfer printing paper on paper, even if wherein some ink-jet printing ink can be printed on paper, be only applicable to heat transfer printing paper, cannot make practical cold transfer printing paper, more cannot realize cold-transfer printing technique, can not be completed the requirement of cold-transfer printing sample.Therefore need a kind of dye ink that is applicable to the ink-jet printed use of cold transfer, in conjunction with digital ink-jet printed technology used, could complete smoothly the digital sample work of cold-transfer printing.
Summary of the invention
Cannot adapt to print the requirement of cold transfer printing paper in order to solve existing ink-jet printing ink, current ink-jet printed Method of printing does not meet the demand of cold-transfer printing sample technique yet, adopt a kind of ink-jet printed digital specimen method combining with cold-transfer printing technology in order to overcome the present invention of these difficult problems, in conjunction with the use of water-soluble dye type ink-jet ink, can solve the task of the digital sample of cold-transfer printing.
The present invention is that the method that solves the digital sample of above-mentioned technical barrier cold-transfer printing used is: the digital specimen method of cold-transfer printing is according to client's sample or sample manuscript, carry out computer graphics, press the made pattern input ink-jet printer of computer, on base paper at cold transfer printing paper, be printed as cold transfer printing paper through printing of inkjet printer with ink-jet ink, by cold transfer printing paper with by the closely sealed cold-transfer printing that carries out of seal textiles, make sample textiles through cold dome fixation, determine that through client or technical staff sample forms standard specimen.
In the digital specimen method of this cold-transfer printing:
A. described ink-jet printer is industrial polychrome ink-jet piezoelectric type printer;
B. the base paper of described cold transfer printing paper is the paper that scribbles macromolecular compound separation layer;
C. described ink-jet ink is water-soluble active or ACID DYES ink-jet printing ink, by mass percentage formula:
Water-soluble active or ACID DYES are 10%-25%,
Humectant is 1%-4.5%,
Preservative agent is 0.001%-0.1%,
Thickener is 2%-8%,
Bleeding agent is 0.5%-3%,
Conditioning agent is 0.1%-0.5%,
Adjust to 100% by deionized water;
D. described cold-transfer printing is the decalcomania on cold transfer printing paper to be transferred to be printed on textiles under workshop natural temperature and pressure; Described cold dome fixation is by plastic sheeting and the decalcomania face of transfer printing textiles is laminating, and is jointly wound into spool, and under the natural temperature of workshop, slow rotation is carried out fixation.
In addition,, when described inkjet printing is used the printing fabric width < 1m of base paper of cold transfer printing paper, adopt 60-90g/m 2blank sheet of paper; While printing fabric width>=1m, adopt 90-120g/m 2blank sheet of paper.Described ink-jet printer is industrial 4-6 look ink-jet piezoelectric type printer; While adopting 4 color ink-jet printing ink, be yellow, carmetta, cyan and black; While adopting 6 color ink-jet printing ink, be yellow, carmetta, cyan, black, orange and golden; Reach >=600dpi of the resolution of piezoelectric type printer, can clean cleaning with nonwoven fabric and clean shower nozzle.First water-soluble active or ACID DYES are rolled dyestuff to be ground 3--4 time with grinder, rear employing porcelain ball mill is rotated grinding, goes out after machine cylinder with 2000 eye mesh screens filtrations, dyestuff fineness≤0.2 μ m.
Humectant in described ink-jet printing ink is N methyl pyrrolidone, or glycerol, makes the dyestuff in the ink-jet printing ink on shower nozzle week edge that withered obstruction can not occur in 24 hours.Described ink-jet printed with the preservative agent in ink be Sodium Benzoate, the pot-life of ink-jet printing ink reaches three months, can preserve nine months to 1 year under sealing condition.Described ink-jet printed with the thickener in ink be xanthan gum, make the viscosity of ink-jet printing ink be controlled at 4cp and more than, ink-jet printing ink can seepage.Described ink-jet printed with the bleeding agent in ink be polyethylene glycol, ethanol and JFC bleeding agent, make the COLOR FASTNESS of the sample textiles after cold dome fixation reach 3-4 level.Described ink-jet printed with the conditioning agent in ink be sodium dihydrogen phosphate and sodium hydrogen phosphate, pH value reaches 7-8.
The present invention is mainly how inkjet technology to be directly applied in the stamp sample work of textiles by the operational characteristic of cold-transfer printing, and to really realize the SAMPLE METHOD of digit printing, ink-jet printing ink is the key technology that realizes the digital specimen method of cold-transfer printing.First ink-jet printing ink of the present invention can be applicable to ink-jet printer and normally use, this ink-jet printing ink can become cold transfer printing paper Paper Printing, and can solve cold transfer printing paper and by the rate of transform between seal fabric and the problem of dye uptake, make last stamp sample product reach standard.
The digital specimen method of cold-transfer printing of the present invention is a kind of ink-jet printed digital specimen method combining with cold-transfer printing technology, can better solve the sample task of cold-transfer printing.The digital specimen method of cold-transfer printing of the present invention and traditional stamp specimen method relatively have many good qualities.The firstth, can small lot sample, product can be realized delivery on the same day or immediate delivery, and Neng Dui city field boundary demand is made fast reaction.The secondth, without color separation, plate-making, the color matching process such as size mixing, greatly to simplify to produce and prepared, all technological parameters of drawing a design all record and are stored in computer, are the foundation of batch production in the future.The 3rd is to adopt four or six Essential colour, can form 1,670 ten thousand kinds of colors being transferred on fabric in theory, is that the stamp of one edition of the same colour of tradition is incomparable.The 4th is that transfer process is discharged without residual slurry, does not need steam, and production process noise is less, and discharge of wastewater is very low, is a kind of process for cleanly preparing.
Brief description of the drawings
Below in conjunction with drawings and Examples, patent of the present invention is described further.
Fig. 1 is the process chart of the digital specimen method of cold-transfer printing.
Detailed description of the invention:
Embodiment 1.
A kind of method of digital sample of all-cotton fabric cold-transfer printing.
All-cotton fabric specification: the textile poplin cloth of 40 × 40 133 × 72 145/147Cm (57/58 inch)
As shown in Figure 1, its process flow comprises sample, computer graphics, printing, transfer printing paper, cold-transfer printing, fixation, sample and standard specimen to the digital specimen method of cold-transfer printing.The method of the digital sample of cold-transfer printing first will be according to client's sample or sample manuscript, carry out computer graphics, press computer institute pattern access ink-jet printer, on base paper at cold transfer printing paper, be printed as cold transfer printing paper through printing of inkjet printer with ink-jet printing ink, by cold transfer printing paper with by the closely sealed cold-transfer printing that carries out of seal textiles, make sample textiles through cold dome fixation, determine sample through client or technical staff, finally form standard specimen.
In the digital specimen method of cold-transfer printing, the ink of ink-jet printed use is a kind of dye-type ink-jet ink, and is a kind of water-soluble dye ink-jet printing ink, by mass percentage formula:
Water-soluble dye is REACTIVE DYES, accounts for 25%,
Humectant is N methyl pyrrolidone, accounts for 4%,
Preservative agent is Sodium Benzoate, accounts for 0.1%,
Thickener is xanthan gum (VANZAN), accounts for 4%,
Bleeding agent is used JFC bleeding agent for weaving, accounts for 3%,
Conditioning agent is sodium dihydrogen phosphate and sodium hydrogen phosphate, accounts for 0.3%,
Adjust to 100% by deionized water.
When use, should first the REACTIVE DYES of commercial dye class be rolled dyestuff to be ground 3-4 time with three-roll grinder,
Rear employing porcelain ball mill is rotated grinding, makes porcelain ball and dyestuff mutually clash into pulverizing, and the time is 4-6 hour, goes out after machine cylinder and filters with 2000 eye mesh screens, makes dyestuff fineness≤0.2 μ m, then this dyestuff and above-mentioned all the other material homopolymerizations is uniformly mixed.
Add various auxiliary agents to make water-soluble dye ink-jet printing ink show good performance, survey as follows:
4% N methyl pyrrolidone humectant makes the dyestuff in the ink-jet printing ink on printer head week edge that withered obstruction not occur in 24 hours;
1% Sodium Benzoate preservative agent makes the pot-life of ink-jet printing ink reach three months to six months;
4% xanthan gum (VANZAN) thickener makes the viscosity of ink-jet printing ink be controlled at 3-4cp, and when inkjet printing, Seepage does not occur ink-jet printing ink;
3% weaving makes the COLOR FASTNESS of the sample textiles after cold dome fixation reach 3 grades with JFC bleeding agent;
It is 7.5 left and right that 3% sodium dihydrogen phosphate and sodium hydrogen phosphate conditioning agent make the ink-jet printed pH value with ink.
Ink-jet printer adopts favour Pu 4-6 look industrial inkjet piezoelectric type printer, and reach >=600dpi of the resolution of printer can clean cleaning shower nozzle with nonwoven fabric; When the present embodiment adopts 6 look inkjet printing, be yellow, carmetta, cyan, black, orange and golden ink-jet printing ink.
The base paper of cold transfer printing paper scribbles the paper that the patent No. " 200610026581.1 " is entitled as " pigment release agent for cold transfer printing paper " described separation layer; The printing fabric width of base paper is 1.2m, adopts 90g/m 2blank sheet of paper.
Cold-transfer printing technique is under the natural temperature of workshop, adopts a pair of transfer printing mode that adds knobbling rolls that the decalcomania on cold transfer printing paper is transferred to and is printed on textiles.Cold dome fixation is by plastic sheeting and the decalcomania face of transfer printing textiles is laminating, and is jointly wound into spool, and under the natural temperature of workshop, slow rotation is carried out fixation for 48 hours.
Embodiment 2.
A kind of method of digital sample of Tynex fabric cold-transfer printing:
Tynex crape burlap, blending ratio is (65/35)
The digital specimen method of Tynex crape linen cold-transfer printing is identical with above-described embodiment 1, and wherein concrete difference is:
Water-soluble dye is ACID DYES, accounts for 22%,,
Humectant is glycerol, accounts for 4%,
Preservative agent is Sodium Benzoate, accounts for 0.1%.
Thickener is xanthan gum (VANZAN), accounts for 3%.
Bleeding agent is polyethylene glycol, 2%.
Conditioning agent is sodium dihydrogen phosphate and sodium hydrogen phosphate, accounts for 0.3%, and making the ink-jet printed pH value with ink is 7.8 left and right.
Adjust to 100% by deionized water;
The printing fabric width of base paper is 0.95m, adopts 60g/m 2blank sheet of paper.

Claims (9)

1. a digital specimen method for cold-transfer printing, comprises sample, computer graphics, printing, transfer printing paper, cold-transfer printing, fixation, sample and standard specimen operation, it is characterized in that:
The digital specimen method of cold-transfer printing is according to client's sample or sample manuscript, carry out computer graphics, press computer institute pattern input ink-jet printer, on base paper at cold transfer printing paper, be printed as cold transfer printing paper through printing of inkjet printer with ink-jet ink, by cold transfer printing paper with by the closely sealed cold-transfer printing that carries out of seal textiles, make sample textiles through cold dome fixation, determine that through client or technical staff sample forms standard specimen;
Wherein:
A. described ink-jet printer is industrial polychrome ink-jet piezoelectric type printer;
B. the base paper of described cold transfer printing paper is the paper that scribbles macromolecular compound separation layer;
C. described ink-jet ink is water-soluble active or ACID DYES ink-jet printing ink, by mass percentage formula:
Water-soluble active or ACID DYES are 10%-25%,
Humectant is 1%-4.5%,
Preservative agent is 0.001%-0.1%,
Thickener is 2%-8%,
Bleeding agent is 0.5%-3%,
Conditioning agent is 0.1%-0.5%,
Adjust to 100% by deionized water;
D. described cold-transfer printing is the decalcomania on cold transfer printing paper to be transferred to be printed on textiles under workshop natural temperature and pressure; Described cold dome fixation is by plastic sheeting and the decalcomania face of transfer printing textiles is laminating, and is jointly wound into spool, and under the natural temperature of workshop, slow rotation is carried out fixation.
2. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
When described inkjet printing is used the printing fabric width < 1m of base paper of cold transfer printing paper, adopt 60-90g/m 2blank sheet of paper; While printing fabric width>=1m, adopt 90-120g/m 2blank sheet of paper.
3. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
Described ink-jet printer is industrial 4-6 look ink-jet piezoelectric type printer, while adopting 4 color ink-jet printing ink, is yellow, carmetta, cyan and black; While adopting 6 color ink-jet printing ink, be yellow, carmetta, cyan, black, orange and golden; Reach >=600dpi of the resolution of piezoelectric type printer, can clean cleaning with nonwoven fabric and clean shower nozzle.
4. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
First described water-soluble active or ACID DYES are rolled dyestuff to be ground 3-4 time with grinder, rear employing porcelain ball mill is rotated grinding, goes out after machine cylinder with 2000 eye mesh screens filtrations, dyestuff fineness≤0.2 μ m.
5. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
Humectant in described ink-jet printing ink is N methyl pyrrolidone, or glycerol, makes the dyestuff in the ink-jet printing ink on shower nozzle week edge that withered obstruction can not occur in 24 hours.
6. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
Described ink-jet printed with the preservative agent in ink be Sodium Benzoate, the pot-life of ink-jet printing ink reaches three months, can preserve nine months to 1 year under sealing condition.
7. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
Described ink-jet printed with the thickener in ink be xanthan gum, make the viscosity of ink-jet printing ink be controlled at 4cp and more than, ink-jet printing ink can seepage.
8. the digital specimen method of cold-transfer printing according to claim 1, is characterized in that:
Described ink-jet printed with the bleeding agent in ink be polyethylene glycol, ethanol and JFC bleeding agent, make the COLOR FASTNESS of the sample textiles after cold dome fixation reach 3-4 level.
9. the digital specimen method of cold-transfer printing according to claim 4, is characterized in that:
Described ink-jet printed with the conditioning agent in ink be sodium dihydrogen phosphate and sodium hydrogen phosphate, pH value reaches 7-8.
CN201210261528.5A 2012-07-26 2012-07-26 Cold-transfer printing digital proofing method CN102817254B (en)

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