CN106543804A - It is difficult the heat sublimation ink of skinning - Google Patents

It is difficult the heat sublimation ink of skinning Download PDF

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Publication number
CN106543804A
CN106543804A CN201610945250.1A CN201610945250A CN106543804A CN 106543804 A CN106543804 A CN 106543804A CN 201610945250 A CN201610945250 A CN 201610945250A CN 106543804 A CN106543804 A CN 106543804A
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CN
China
Prior art keywords
parts
heat sublimation
skinning
difficult
sublimation ink
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610945250.1A
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Chinese (zh)
Inventor
戚裕
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Suzhou Jigu New Material Co Ltd
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Suzhou Jigu New Material Co Ltd
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Priority to CN201610945250.1A priority Critical patent/CN106543804A/en
Publication of CN106543804A publication Critical patent/CN106543804A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/108—Hydrocarbon resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/14—Printing inks based on carbohydrates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof

Abstract

The invention discloses a kind of heat sublimation ink for being difficult skinning, is grouped into by each group of following parts by weight：15 20 parts of heat sublimation dyestuff, 38 parts of normal propyl alcohol, 26 parts of acrylic acid, 46 parts of casein, 18 parts of sodium alginate, 2.5 6 parts of chlorinated polypropylene dispersion, 1.5 3 parts of sagging inhibitor, 1.2 3.6 parts of pearlescent pigment, 35 parts of hydroethyl acrylate, 2.5 6 parts of pyromellitic acid dianhydride, 0.2 1 parts of preservative, 20 30 parts of soft water.The heat sublimation ink moderate drying speed of the present invention, therefore, will not be in printing surface skining, scumming.

Description

It is difficult the heat sublimation ink of skinning
Technical field
The present invention relates to Thermal-printing Technology field, and in particular to a kind of heat sublimation ink for being difficult skinning.
Background technology
The rate of drying of heat sublimation ink affects its tack, and with the increase of drying time, its tackness gradually increases To maximum, then drop to zero, if ink dried speed is quickly, ink can be in printing surface skining, scumming.
The content of the invention
Goal of the invention：The invention aims to make up the deficiency of existing investigative technique, there is provided one kind is difficult skinning Heat sublimation ink.
Technical scheme：A kind of heat sublimation ink for being difficult skinning, is grouped into by each group of following parts by weight：Heat sublimation contaminates Material 15-20 parts, normal propyl alcohol 3-8 parts, acrylic acid 2-6 parts, casein 4-6 parts, sodium alginate 1-8 parts, chlorinated polypropylene dispersion 2.5-6 parts, sagging inhibitor 1.5-3 parts, pearlescent pigment 1.2-3.6 parts, propenoic acid beta-hydroxy ethyl ester 3-5 parts, pyromellitic acid dianhydride 2.5-6 parts, preservative 0.2-1 parts, soft water 20-30 parts.
Preferably, described sagging inhibitor is tetrafluoroethene emulsion.
Preferably, described preservative is p-Hydroxybenzoate.
Preferably, described ink pH is 6.5-7.0.
Preferably, the first dryness of described ink is 10-15mm/15s, 25 DEG C.
A kind of preparation method of the heat sublimation ink for being difficult skinning, comprises the following steps：
1) heat sublimation dyestuff, normal propyl alcohol, acrylic acid are put in enamel reaction still, cover charging aperture, drive reflux condenser, Heat temperature raising, is slowly added into propenoic acid beta-hydroxy ethyl ester during to 65 DEG C, and charging aperture is covered after adding, and is kept for 65-70 DEG C, stirs 2.5- 3h so as to be completely dissolved；
2), when being cooled to 55 DEG C, casein, sodium alginate, chlorinated polypropylene dispersion, PMA are slowly uniformly added into Dianhydride, sampling and testing pH value after reaction 1h, no longer changes to 9；
3) sagging inhibitor, pearlescent pigment, preservative are added, stirs, be warmed up to 80-90 DEG C, after keeping 0.5h；
4) pH is finally adjusted to 6.5-7.0, plus soft water stirs.
7. a kind of use of heat sublimation ink, it is characterised in that：Heat sublimation ink is stirred and pass through after 3min flying print Machine is sprayed onto on paper or thin film.
Beneficial effect：The heat sublimation ink moderate drying speed of the present invention, therefore, will not be in printing surface skining, scumming.
Specific embodiment：
Embodiment 1：
A kind of heat sublimation ink for being difficult skinning, is grouped into by each group of following parts by weight：15 parts of heat sublimation dyestuff, just 3 parts of propanol, 2 parts of acrylic acid, 4 parts of casein, 1 part of sodium alginate, 2.5 parts of chlorinated polypropylene dispersion, 1.5 parts of sagging inhibitor, 1.2 parts of pearlescent pigment, 3 parts of propenoic acid beta-hydroxy ethyl ester, 2.5 parts of pyromellitic acid dianhydride, 0.2 part of preservative, 20 parts of soft water.Preservative For p-Hydroxybenzoate.Ink pH is 6.5-7.0.The first dryness of ink be 10-15mm/15s, 25 DEG C.
The preparation method of above-mentioned heat sublimation ink, comprises the following steps：
1) heat sublimation dyestuff, normal propyl alcohol, acrylic acid are put in enamel reaction still, cover charging aperture, drive reflux condenser, Heat temperature raising, is slowly added into propenoic acid beta-hydroxy ethyl ester during to 65 DEG C, and charging aperture is covered after adding, and is kept for 65-70 DEG C, stirs 2.5- 3h so as to be completely dissolved；
2), when being cooled to 55 DEG C, casein, sodium alginate, chlorinated polypropylene dispersion, PMA are slowly uniformly added into Dianhydride, sampling and testing pH value after reaction 1h, no longer changes to 9；
3) sagging inhibitor, pearlescent pigment, preservative are added, stirs, be warmed up to 80-90 DEG C, after keeping 0.5h；
4) pH is finally adjusted to 6.5-7.0, plus soft water stirs.
The using method of above-mentioned heat sublimation ink, by heat sublimation ink stir 3min after by high-speed printer be sprayed onto paper or On person's thin film.
Embodiment 2：
A kind of heat sublimation ink for being difficult skinning, is grouped into by each group of following parts by weight：20 parts of heat sublimation dyestuff, just 8 parts of propanol, 6 parts of acrylic acid, 6 parts of casein, 8 parts of sodium alginate, 6 parts of chlorinated polypropylene dispersion, 3 parts of sagging inhibitor, pearly-lustre 3.6 parts of pigment, 5 parts of propenoic acid beta-hydroxy ethyl ester, 6 parts of pyromellitic acid dianhydride, 1 part of preservative, 30 parts of soft water.Sagging inhibitor is tetrafluoro Vac emulsion, preservative is p-Hydroxybenzoate, and ink pH is 6.5-7.0, and the first dryness of ink is 10-15mm/15s, 25 ℃。
The preparation method of above-mentioned heat sublimation ink, comprises the following steps：
1) heat sublimation dyestuff, normal propyl alcohol, acrylic acid are put in enamel reaction still, cover charging aperture, drive reflux condenser, Heat temperature raising, is slowly added into propenoic acid beta-hydroxy ethyl ester during to 65 DEG C, and charging aperture is covered after adding, and is kept for 65-70 DEG C, stirs 2.5- 3h so as to be completely dissolved；
2), when being cooled to 55 DEG C, casein, sodium alginate, chlorinated polypropylene dispersion, PMA are slowly uniformly added into Dianhydride, sampling and testing pH value after reaction 1h, no longer changes to 9；
3) sagging inhibitor, pearlescent pigment, preservative are added, stirs, be warmed up to 80-90 DEG C, after keeping 0.5h；
4) pH is finally adjusted to 6.5-7.0, plus soft water stirs.
A kind of using method of heat sublimation ink, by heat sublimation ink stir 3min after by high-speed printer be sprayed onto paper or On person's thin film.
Embodiment 3：
A kind of heat sublimation ink for being difficult skinning, is grouped into by each group of following parts by weight：16 parts of heat sublimation dyestuff, just 6 parts of propanol, 3 parts of acrylic acid, 5 parts of casein, 7 parts of sodium alginate, 3 parts of chlorinated polypropylene dispersion, 2 parts of sagging inhibitor, pearly-lustre 3 parts of pigment, propenoic acid beta-hydroxy ethyl ester 3-5 parts, 5 parts of pyromellitic acid dianhydride, 0.8 part of preservative, 25 parts of soft water.
The preparation method of above-mentioned heat sublimation ink, comprises the following steps：
1) heat sublimation dyestuff, normal propyl alcohol, acrylic acid are put in enamel reaction still, cover charging aperture, drive reflux condenser, Heat temperature raising, is slowly added into propenoic acid beta-hydroxy ethyl ester during to 65 DEG C, and charging aperture is covered after adding, and is kept for 65-70 DEG C, stirs 2.5- 3h so as to be completely dissolved；
2), when being cooled to 55 DEG C, casein, sodium alginate, chlorinated polypropylene dispersion, PMA are slowly uniformly added into Dianhydride, sampling and testing pH value after reaction 1h, no longer changes to 9；
3) sagging inhibitor, pearlescent pigment, preservative are added, stirs, be warmed up to 80-90 DEG C, after keeping 0.5h；
4) pH is finally adjusted to 6.5-7.0, plus soft water stirs.
The using method of above-mentioned heat sublimation ink, by heat sublimation ink stir 3min after by high-speed printer be sprayed onto paper or On person's thin film.

Claims (7)

1. a kind of heat sublimation ink for being difficult skinning, it is characterised in that：It is grouped into by each group of following parts by weight：Heat sublimation contaminates Material 15-20 parts, normal propyl alcohol 3-8 parts, acrylic acid 2-6 parts, casein 4-6 parts, sodium alginate 1-8 parts, chlorinated polypropylene dispersion 2.5-6 parts, sagging inhibitor 1.5-3 parts, pearlescent pigment 1.2-3.6 parts, propenoic acid beta-hydroxy ethyl ester 3-5 parts, pyromellitic acid dianhydride 2.5-6 parts, preservative 0.2-1 parts, soft water 20-30 parts.
2. the heat sublimation ink of skinning is difficult as claimed in claim 1, it is characterised in that：Described sagging inhibitor is tetrafluoro second Alkene emulsion.
3. the heat sublimation ink of skinning is difficult as claimed in claim 1, it is characterised in that：Described preservative is para hydroxybenzene Formic acid esters.
4. the heat sublimation ink of skinning is difficult as claimed in claim 1, it is characterised in that：Described ink pH is 6.5-7.0.
5. the heat sublimation ink of skinning is difficult as claimed in claim 1, it is characterised in that：The first dryness of described ink is 10-15mm/15s, 25 DEG C.
6. a kind of preparation method of the heat sublimation ink for being difficult skinning, it is characterised in that：Comprise the following steps：
1) heat sublimation dyestuff, normal propyl alcohol, acrylic acid are put in enamel reaction still, cover charging aperture, drive reflux condenser, heated Heat up, during to 65 DEG C, be slowly added into propenoic acid beta-hydroxy ethyl ester, after adding, cover charging aperture, kept for 65-70 DEG C, stir 2.5-3h, It is completely dissolved which；
2), when being cooled to 55 DEG C, casein, sodium alginate, chlorinated polypropylene dispersion, pyromellitic acid dianhydride are slowly uniformly added into, Sampling and testing pH value after reaction 1h, no longer changes to 9；
3) sagging inhibitor, pearlescent pigment, preservative are added, stirs, be warmed up to 80-90 DEG C, after keeping 0.5h；
4) pH is finally adjusted to 6.5-7.0, plus soft water stirs.
7. a kind of using method of the heat sublimation ink for being difficult skinning, it is characterised in that：Heat sublimation ink is stirred and lead to after 3min Cross high-speed printer to be sprayed onto on paper or thin film.
CN201610945250.1A 2016-10-26 2016-10-26 It is difficult the heat sublimation ink of skinning Pending CN106543804A (en)

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Application Number Priority Date Filing Date Title
CN201610945250.1A CN106543804A (en) 2016-10-26 2016-10-26 It is difficult the heat sublimation ink of skinning

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610945250.1A CN106543804A (en) 2016-10-26 2016-10-26 It is difficult the heat sublimation ink of skinning

Publications (1)

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CN106543804A true CN106543804A (en) 2017-03-29

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585589A (en) * 2012-03-07 2012-07-18 深圳市墨库图文技术有限公司 Thermal sublimation ink as well as direct printing technology and equipment
CN103289473A (en) * 2013-07-01 2013-09-11 深圳市墨库图文技术有限公司 Dye-sublimation ink and preparation method thereof
CN103834234A (en) * 2012-11-26 2014-06-04 江苏格美高科技发展有限公司 Disperse dye ink for cotton fabric inkjet printing and preparation method thereof
CN105348919A (en) * 2015-12-22 2016-02-24 中国科学院福建物质结构研究所 Thermal transfer printing inkjet ink composition and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585589A (en) * 2012-03-07 2012-07-18 深圳市墨库图文技术有限公司 Thermal sublimation ink as well as direct printing technology and equipment
CN103834234A (en) * 2012-11-26 2014-06-04 江苏格美高科技发展有限公司 Disperse dye ink for cotton fabric inkjet printing and preparation method thereof
CN103289473A (en) * 2013-07-01 2013-09-11 深圳市墨库图文技术有限公司 Dye-sublimation ink and preparation method thereof
CN105348919A (en) * 2015-12-22 2016-02-24 中国科学院福建物质结构研究所 Thermal transfer printing inkjet ink composition and preparation method thereof

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Application publication date: 20170329

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