CN103261098B - 表面改性的氧化锆纳米粒子 - Google Patents
表面改性的氧化锆纳米粒子 Download PDFInfo
- Publication number
- CN103261098B CN103261098B CN201180061279.9A CN201180061279A CN103261098B CN 103261098 B CN103261098 B CN 103261098B CN 201180061279 A CN201180061279 A CN 201180061279A CN 103261098 B CN103261098 B CN 103261098B
- Authority
- CN
- China
- Prior art keywords
- group
- ligand
- zirconia
- nanoparticles
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C259/00—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups
- C07C259/04—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups without replacement of the other oxygen atom of the carboxyl group, e.g. hydroxamic acids
- C07C259/06—Compounds containing carboxyl groups, an oxygen atom of a carboxyl group being replaced by a nitrogen atom, this nitrogen atom being further bound to an oxygen atom and not being part of nitro or nitroso groups without replacement of the other oxygen atom of the carboxyl group, e.g. hydroxamic acids having carbon atoms of hydroxamic groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/24—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/25—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/24—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/29—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/60—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Graft Or Block Polymers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061426169P | 2010-12-22 | 2010-12-22 | |
| US61/426,169 | 2010-12-22 | ||
| PCT/US2011/064617 WO2012087665A2 (en) | 2010-12-22 | 2011-12-13 | Surface-modified zirconia nanoparticles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103261098A CN103261098A (zh) | 2013-08-21 |
| CN103261098B true CN103261098B (zh) | 2015-05-20 |
Family
ID=46314756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180061279.9A Expired - Fee Related CN103261098B (zh) | 2010-12-22 | 2011-12-13 | 表面改性的氧化锆纳米粒子 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9139670B2 (enExample) |
| EP (1) | EP2655257A4 (enExample) |
| JP (2) | JP2014509291A (enExample) |
| KR (1) | KR101898746B1 (enExample) |
| CN (1) | CN103261098B (enExample) |
| WO (1) | WO2012087665A2 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9139670B2 (en) * | 2010-12-22 | 2015-09-22 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
| WO2013130247A1 (en) | 2012-02-28 | 2013-09-06 | 3M Innovative Properties Company | Composition comprising surface modified high index nanoparticles suitable for optical coupling layer |
| US9477354B2 (en) | 2012-11-16 | 2016-10-25 | 3M Innovative Properties Company | Conductive trace hiding materials, articles, and methods |
| US9862124B2 (en) | 2014-07-18 | 2018-01-09 | 3M Innovative Properties Company | Multilayer optical adhesives and methods of making same |
| KR101579384B1 (ko) * | 2014-10-24 | 2015-12-22 | 인하대학교 산학협력단 | 고유전율 절연재료의 제조방법 및 이를 포함하는 다이오드소자 |
| CN108369301B (zh) | 2015-12-09 | 2021-02-05 | 3M创新有限公司 | 光学叠堆 |
| CN108473826B (zh) | 2016-01-15 | 2021-01-15 | 3M创新有限公司 | 光学粘合剂 |
| US20200325348A1 (en) * | 2016-06-27 | 2020-10-15 | 3M Innovative Properties Company | Compositions comprising nanoparticles functionalized with an alpha-hydroxy acid or salt, articles, and methods |
| KR102400691B1 (ko) * | 2016-07-18 | 2022-05-23 | 에이제트 일렉트로닉 머티어리얼스 (룩셈부르크) 에스.에이.알.엘. | Led 밀봉 물질용 제형 |
| KR102428052B1 (ko) * | 2016-12-23 | 2022-08-01 | 이보클라 비바덴트 아게 | 소결 거동이 조정된 다층 산화물 세라믹체 |
| CN113727956B (zh) * | 2019-02-05 | 2023-02-21 | 伊利可创镁业有限公司 | 用于形成纳米陶瓷的氧化锆分散体 |
| US10570063B1 (en) | 2019-02-05 | 2020-02-25 | Magnesium Elektron Limited | Zirconia dispersion for use in forming nano ceramics |
| KR102837685B1 (ko) | 2019-11-01 | 2025-07-23 | 삼성디스플레이 주식회사 | 양자점-함유 복합체, 이를 포함한 발광 소자, 광학 부재 및 장치 |
| JP7522606B2 (ja) * | 2020-08-17 | 2024-07-25 | 株式会社日本触媒 | 金属酸化物ナノ粒子、金属酸化物ナノ粒子を含む組成物及びその硬化物 |
| CN112574471B (zh) * | 2020-11-17 | 2022-06-07 | 中化石化销售有限公司 | 超支化聚合物改性无机纳米成核剂及其制备方法和应用 |
| KR20220100760A (ko) | 2021-01-08 | 2022-07-18 | 삼성디스플레이 주식회사 | 양자점-함유 물질, 이를 포함한 조성물 및 전자 장치 |
| CN113912792B (zh) * | 2021-11-08 | 2023-12-15 | 东莞市光志光电有限公司 | 一种高折射率纳米氧化锆复合树脂的制备方法及其应用 |
| CN114735749A (zh) * | 2022-05-06 | 2022-07-12 | 山东国瓷功能材料股份有限公司 | 表面处理的氧化锆纳米粉体、氧化锆分散液及应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007104312A2 (en) * | 2006-03-13 | 2007-09-20 | Dentofit A/S | Composite material, in particular a dental filling material |
| CN101132989A (zh) * | 2004-12-30 | 2008-02-27 | 3M创新有限公司 | 氧化锆粒子 |
| CN101638222A (zh) * | 2009-05-25 | 2010-02-03 | 中国科学院等离子体物理研究所 | 羧酸化学改性金属氧化物纳米颗粒的制备方法 |
| WO2010085427A1 (en) * | 2009-01-22 | 2010-07-29 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6680338B2 (en) | 1998-02-06 | 2004-01-20 | Darwin Discovery Ltd. | Hydroxamic and carboxylic acid derivatives |
| US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| NL1016779C2 (nl) | 2000-12-02 | 2002-06-04 | Cornelis Johannes Maria V Rijn | Matrijs, werkwijze voor het vervaardigen van precisieproducten met behulp van een matrijs, alsmede precisieproducten, in het bijzonder microzeven en membraanfilters, vervaardigd met een dergelijke matrijs. |
| US7901656B2 (en) * | 2003-03-21 | 2011-03-08 | Wayne State University | Metal oxide-containing nanoparticles |
| US7282272B2 (en) * | 2003-09-12 | 2007-10-16 | 3M Innovative Properties Company | Polymerizable compositions comprising nanoparticles |
| DE102004009287A1 (de) * | 2004-02-26 | 2005-09-15 | Institut Für Neue Materialien Gem. Gmbh | Amphiphile Nanopartikel |
| US7156911B2 (en) | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
| US7297810B2 (en) | 2004-12-30 | 2007-11-20 | 3M Innovative Properties Company | High refractive index monomers for optical applications |
| KR20080075495A (ko) * | 2005-11-05 | 2008-08-18 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 고굴절률 및 반사방지 코팅을 포함하는 광학 필름 |
| US7981949B2 (en) | 2006-05-23 | 2011-07-19 | 3M Innovative Properties Company | Curable hydrophilic compositions |
| US20100184887A1 (en) * | 2007-07-02 | 2010-07-22 | Basf Se | Hybrid nanoparticles |
| US20090105437A1 (en) | 2007-10-19 | 2009-04-23 | 3M Innovative Properties Company | High refractive index pressure-sensitive adhesives |
| US8647510B2 (en) | 2007-12-28 | 2014-02-11 | 3M Innovative Properties Company | Method of making zirconia-containing nanoparticles |
| JP5632122B2 (ja) * | 2008-06-17 | 2014-11-26 | 株式会社日本触媒 | 複合粒子、樹脂組成物、及び、その硬化物 |
| JP2010085427A (ja) * | 2008-09-29 | 2010-04-15 | Tpo Displays Corp | 液晶表示装置及びその製造方法 |
| CN102405267A (zh) | 2009-03-09 | 2012-04-04 | 3M创新有限公司 | 用于丙烯酸系粘合剂的氮丙啶交联剂 |
| US8512464B2 (en) | 2009-12-02 | 2013-08-20 | 3M Innovative Properties Company | Functionalized zirconia nanoparticles and high index films made therefrom |
| US9139670B2 (en) | 2010-12-22 | 2015-09-22 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
-
2011
- 2011-12-13 US US13/991,578 patent/US9139670B2/en active Active
- 2011-12-13 KR KR1020137018863A patent/KR101898746B1/ko not_active Expired - Fee Related
- 2011-12-13 WO PCT/US2011/064617 patent/WO2012087665A2/en not_active Ceased
- 2011-12-13 JP JP2013546206A patent/JP2014509291A/ja active Pending
- 2011-12-13 CN CN201180061279.9A patent/CN103261098B/zh not_active Expired - Fee Related
- 2011-12-13 EP EP11850535.3A patent/EP2655257A4/en not_active Withdrawn
-
2016
- 2016-10-21 JP JP2016207129A patent/JP6336546B2/ja not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101132989A (zh) * | 2004-12-30 | 2008-02-27 | 3M创新有限公司 | 氧化锆粒子 |
| WO2007104312A2 (en) * | 2006-03-13 | 2007-09-20 | Dentofit A/S | Composite material, in particular a dental filling material |
| WO2010085427A1 (en) * | 2009-01-22 | 2010-07-29 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
| CN101638222A (zh) * | 2009-05-25 | 2010-02-03 | 中国科学院等离子体物理研究所 | 羧酸化学改性金属氧化物纳米颗粒的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9139670B2 (en) | 2015-09-22 |
| US20130338251A1 (en) | 2013-12-19 |
| KR101898746B1 (ko) | 2018-09-13 |
| WO2012087665A2 (en) | 2012-06-28 |
| JP6336546B2 (ja) | 2018-06-06 |
| JP2014509291A (ja) | 2014-04-17 |
| EP2655257A2 (en) | 2013-10-30 |
| CN103261098A (zh) | 2013-08-21 |
| KR20130132547A (ko) | 2013-12-04 |
| WO2012087665A3 (en) | 2012-08-09 |
| JP2017061693A (ja) | 2017-03-30 |
| EP2655257A4 (en) | 2016-10-19 |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150520 Termination date: 20201213 |