CN103255646B - Bronzing pulp and preparation method thereof - Google Patents

Bronzing pulp and preparation method thereof Download PDF

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Publication number
CN103255646B
CN103255646B CN201310177685.2A CN201310177685A CN103255646B CN 103255646 B CN103255646 B CN 103255646B CN 201310177685 A CN201310177685 A CN 201310177685A CN 103255646 B CN103255646 B CN 103255646B
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agent
gold stamping
parts
pulp
defoamer
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CN201310177685.2A
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CN103255646A (en
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梅立斌
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GUANGZHOU SHENGQIN INDUSTRIAL Co Ltd
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GUANGZHOU SHENGQIN INDUSTRIAL Co Ltd
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Abstract

The invention discloses bronzing pulp. The bronzing pulp is prepared from the following raw materials in parts by weight: 60-80 parts of acrylic ester emulsion, 2-6 parts of deionized water, 3-10 parts of a solvent, 1-5 parts of a stabilizer, 10-20 parts of EVA (Ethylene-Vinyl Acetate) hot melt adhesive powder, 0.5-3 parts of silica, 0.2-0.5 part of a polyurethane defoaming agent, 0.1-0.5 part of a pH regulator, 0.1-0.2 part of a preservative, 0.3-1 part of an emulsion wetting agent and 0.4-2 parts of a thickener. The bronzing pulp has the beneficial effects that the bronzing pulp is water-based pulp, the raw materials are easy to obtain and environment-friendly, the production is convenient, the technology is mature, and substances harmful to the environment can not be produced; and the bronzing pulp is soft in handfeel, firm in fastness, outstanding in resistance to tension fracture and diversified in application mode, enriches the styles of textiles, and endows the textiles with the noble quality.

Description

Gold stamping slurry and preparation method thereof
Technical field
The present invention relates to printing in textiles Material Field, be specially a kind of gold stamping slurry and preparation method thereof.
Background technology
Prior art in garment printing, the gold stamping mark becoming fashion because it is bright and glittering.But all the time, all there is Boardy Feeling, wash water fastness difference and the bronzing effect not gold stamping defect such as glittering like that on such as plastics in costume bronzing.Along with consumer is to the favor of bronzing effect, these problems are also just more and more outstanding.Therefore client's these problems in the urgent need to address.
Summary of the invention
For the deficiency that above-mentioned prior art exists, the object of this invention is to provide a kind of soft, fastness is firm, and tension splits the gold stamping slurry of superior.
Another object of the present invention is to provide a kind of preparation method of above-mentioned gold stamping slurry.
To achieve these goals, the technical solution adopted in the present invention is: gold stamping slurry, is made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 60-80,
Deionized water 2-6,
Solvent 3-10,
Stabilizing agent 1-5,
Hot-melt adhesive powder 10-20,
Silica 0.5-3,
Defoamer 0.2-0.5,
PH adjusting agent 0.1-0.5,
Preservative agent 0.1-0.2,
Emulsification wetting agent 0.3-1,
Thickener 0.4-2.
Described acrylic acid ester emulsion is the aqueous acrylic emulsion that Ahmedabad rich Industrial Co., Ltd. in Shuande, Foshan City produces, and its model is 1070HA.
Described solvent can be ethylene glycol.
Described stabilizing agent can be epoxidized soybean oil.
Described hot-melt adhesive powder is EVA hot-melt adhesive powder.
Described preservative agent can be isothiazolinone.
Described pH adjusting agent is ammoniacal liquor or NaOH.
Described emulsification wetting agent can be poly(ethylene oxide) phenolic ether, polyethylene glycol glycerol condensation polymer, and preferred German enlightening is high dispers715W.
Described thickener can be PTF thickener.
Described defoamer is polyurethane defoamer or product type is the defoamer of BYK-025.
The preparation method of gold stamping slurry, its step is as follows: by the acrylic acid ester emulsion of the above parts by weight, deionized water input cylinder, EVA hot-melt adhesive powder and silica is slowly added under stirring state, add solvent, stabilizing agent, defoamer, pH adjusting agent, preservative agent and emulsification wetting agent again, then grind through grinder, filter and collect, dropping into thickener and carry out thickening.
Compared with prior art, the invention has the beneficial effects as follows: be water paste, raw material is easy to get, environmental protection is easy to make, does not produce environmental toxic harmful substances; Have soft, fastness is firm, and tension splits superior, and application mode variation, has enriched textiles style; The gold stamping excellent wash water fastness of textiles and glittering outward appearance can be given, embody the quality that weaving is noble.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
Gold stamping slurry, be made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 61,
Deionized water 3,
Solvent 4,
Stabilizing agent 2,
Hot-melt adhesive powder 11,
Silica 0.6,
Defoamer 0.3,
PH adjusting agent 0.2,
Preservative agent 0.12,
Emulsification wetting agent 0.4;
Thickener 0.5.
Embodiment 2
Gold stamping slurry, be made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 79,
Deionized water 5,
Solvent 9,
Stabilizing agent 4,
Hot-melt adhesive powder 19,
Silica 2.9,
Defoamer 0.45,
PH adjusting agent 0.45,
Preservative agent 0.19,
Emulsification wetting agent 0.9
Thickener 1.9.
Embodiment 3
Gold stamping slurry, be made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 67,
Deionized water 3,
Solvent 7,
Stabilizing agent 2,
Hot-melt adhesive powder 18,
Silica 1,
Defoamer 0.4,
PH adjusting agent 0.3,
Preservative agent 0.15,
Emulsification wetting agent 0.6,
Thickener 0.8.
Embodiment 4
Gold stamping slurry, be made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 70,
Deionized water 4,
Solvent 6,
Stabilizing agent 3,
Hot-melt adhesive powder 15,
Silica 2,
Defoamer 0.4,
PH adjusting agent 0.3,
Preservative agent 0.15,
Emulsification wetting agent 0.7,
Thickener 1.2.
Described acrylic acid ester emulsion is the aqueous acrylic emulsion that Ahmedabad rich Industrial Co., Ltd. in Shuande, Foshan City produces, and its model is 1070HA.Described solvent can be ethylene glycol.Described stabilizing agent can be epoxidized soybean oil.Described hot-melt adhesive powder is EVA hot-melt adhesive powder.Described preservative agent can be isothiazolinone.Described pH adjusting agent is ammoniacal liquor or NaOH.Described emulsification wetting agent can be poly(ethylene oxide) phenolic ether, polyethylene glycol glycerol condensation polymer, and preferred German enlightening is high dispers715W.Described thickener can be PTF thickener.Described defoamer is polyurethane defoamer or product type is the defoamer of BYK-025.
The preparation method of gold stamping slurry, its step is as follows: by the acrylic acid ester emulsion of the above parts by weight, deionized water input cylinder, EVA hot-melt adhesive powder and silica is slowly added under stirring state, add solvent, stabilizing agent, defoamer, pH adjusting agent, preservative agent and emulsification wetting agent again, then grind through grinder, filter and collect, dropping into thickener and carry out thickening.Wherein, EVA hot-melt adhesive powder and silica slowly add hot-melt adhesive powder and silica while stirring under 400-800rpm/min rotating speed, grinder ground 800-1000 order net, drops into thickener, be thickened to viscosity 37000-57000 centipoise.
After testing, the present invention has soft, and fastness is firm, and it is well a lot of that tension splits the current existing product of Performance Ratio, and can give the gold stamping excellent wash water fastness of textiles and glittering outward appearance, embodies the quality that weaving is noble.
Above-described embodiment is the present invention's preferably embodiment; but be not merely restricted to the described embodiments; change, the modification done under other any does not deviate from Spirit Essence of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be all included within protection scope of the present invention.

Claims (8)

1. gold stamping slurry, is characterized in that, is made up of the raw material comprising following parts by weight:
Acrylic acid ester emulsion 60-80,
Deionized water 2-6,
Solvent 3-10,
Stabilizing agent 1-5,
Hot-melt adhesive powder 10-20,
Silica 0.5-3,
Defoamer 0.2-0.5,
PH adjusting agent 0.1-0.5,
Preservative agent 0.1-0.2,
Emulsification wetting agent 0.3-1,
Thickener 0.4-2.
2. gold stamping slurry according to claim 1, is characterized in that: described acrylic acid ester emulsion is the aqueous acrylic emulsion that Ahmedabad rich Industrial Co., Ltd. in Shuande, Foshan City produces.
3. gold stamping slurry according to claim 1, is characterized in that: described solvent is ethylene glycol; Described stabilizing agent is epoxidized soybean oil.
4. gold stamping slurry according to claim 1, is characterized in that: described hot-melt adhesive powder is EVA hot-melt adhesive powder.
5. gold stamping slurry according to claim 1, is characterized in that: described preservative agent is isothiazolinone; Described pH adjusting agent is ammoniacal liquor or NaOH.
6. gold stamping slurry according to claim 1, is characterized in that: described emulsification wetting agent is poly(ethylene oxide) phenolic ether, polyethylene glycol glycerol condensation polymer.
7. gold stamping slurry according to claim 1, is characterized in that: described defoamer is polyurethane defoamer or product type is the defoamer of BYK-025.
8. according to the preparation method of any described gold stamping slurry of claim 1-7, it is characterized in that: its step is as follows: by the acrylic acid ester emulsion of the above parts by weight, deionized water input cylinder, EVA hot-melt adhesive powder and silica is slowly added under stirring state, add solvent, stabilizing agent, defoamer, pH adjusting agent, preservative agent and emulsification wetting agent again, then grind through grinder, filter and collect, dropping into thickener and carry out thickening.
CN201310177685.2A 2013-05-14 2013-05-14 Bronzing pulp and preparation method thereof Active CN103255646B (en)

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CN103255646B true CN103255646B (en) 2015-05-20

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104309347A (en) * 2014-10-30 2015-01-28 上海理工大学 Silk-screen printing based plate-free hot-stamping process
CN104725914A (en) * 2015-04-13 2015-06-24 叶光明 Golden artistic coating
CN104742550A (en) * 2015-04-13 2015-07-01 叶光明 Anti-static and brightening fabric transfer printing and hot stamping method
CN105433513A (en) * 2015-11-12 2016-03-30 刘光有 Gold stamped and diamond stamped elastic band
CN107083701A (en) * 2017-04-10 2017-08-22 江苏新瑞贝科技股份有限公司 A kind of environmental protection typed gold green onion slurry and preparation method thereof
CN109177553A (en) * 2018-09-28 2019-01-11 宁波创源文化发展股份有限公司 A kind of bronzing method combined with silk-screen printing
CN109487593B (en) * 2018-11-12 2021-04-27 广州市珠之江环保印花材料实业有限公司 Mucilage for printing and dyeing and preparation method thereof
CN110983825A (en) * 2019-11-19 2020-04-10 广州市盛勤实业有限公司 Water-based acrylate printing paste for gold stamping
CN111206441B (en) * 2020-02-25 2022-05-13 东莞威冠服饰工艺有限公司 Gold stamping paste and manufacturing method thereof
CN111254725A (en) * 2020-02-25 2020-06-09 东莞威冠服饰工艺有限公司 Bronzing-imitating paste and manufacturing method thereof
CN112323516B (en) * 2020-11-17 2022-12-13 宁波澳翔精细化工有限公司 Gold stamping paste with strong functionality and preparation method thereof
CN113832750B (en) * 2021-11-11 2023-11-17 东莞长联新材料科技股份有限公司 Gold stamping paste and preparation method and application thereof

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CN101187178A (en) * 2007-10-25 2008-05-28 杨剑侠 Hot stamping preventing mucilage
CN101659841A (en) * 2009-09-29 2010-03-03 陈铁旦 Hot melt adhesive
CN102718921A (en) * 2012-06-18 2012-10-10 百利合化工(中山)有限公司 Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof
CN102896927A (en) * 2012-10-19 2013-01-30 武汉虹之彩包装印刷有限公司 Novel alumite suitable for rotary gold stamping on ultraviolet (UV) glazing oil paper

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Publication number Priority date Publication date Assignee Title
JP2005139340A (en) * 2003-11-07 2005-06-02 Nippon Carbide Ind Co Inc Aqueous composition of acrylic copolymer for textile printing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101187178A (en) * 2007-10-25 2008-05-28 杨剑侠 Hot stamping preventing mucilage
CN101659841A (en) * 2009-09-29 2010-03-03 陈铁旦 Hot melt adhesive
CN102718921A (en) * 2012-06-18 2012-10-10 百利合化工(中山)有限公司 Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof
CN102896927A (en) * 2012-10-19 2013-01-30 武汉虹之彩包装印刷有限公司 Novel alumite suitable for rotary gold stamping on ultraviolet (UV) glazing oil paper

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