CN109487593B - Mucilage for printing and dyeing and preparation method thereof - Google Patents
Mucilage for printing and dyeing and preparation method thereof Download PDFInfo
- Publication number
- CN109487593B CN109487593B CN201811341098.1A CN201811341098A CN109487593B CN 109487593 B CN109487593 B CN 109487593B CN 201811341098 A CN201811341098 A CN 201811341098A CN 109487593 B CN109487593 B CN 109487593B
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- stirring
- printing
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5221—Polymers of unsaturated hydrocarbons, e.g. polystyrene polyalkylene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of printing and dyeing, and provides a printing and dyeing adhesive cement aiming at the problem of easy fading, which comprises the following components: acrylic resin; ethylene-vinyl acetate copolymer emulsion; trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); talc powder; BA powder; a dispersant; a thickener; an anti-tack agent; and (3) a curing initiator. A preparation method of the mucilage for printing and dyeing comprises the following steps: (1) adding acrylic resin and ethylene-vinyl acetate copolymer emulsion into a container, and stirring; (2) adding trimethylolpropane-tri (3- (2-methylaziridinyl) propionate), a curing initiator, a dispersing agent, propylene glycol and an anti-sticking agent while stirring; (3) adding talcum powder, matting powder and BA powder, and stirring; (4) adding emulsifier and thickener, and stirring; (5) grinding and packaging. The trimethylolpropane-tri (3- (2-methylaziridine) propionate) and the dye form insoluble color, so that the washing fastness of the printed pattern is high.
Description
Technical Field
The invention relates to the technical field of printing and dyeing, in particular to a mucilage for printing and dyeing and a preparation method thereof.
Background
In order to satisfy the requirement of beauty, the clothes are usually made to have various colors and patterns on the appearance by printing and dyeing.
Because the coating that forms after printing and dyeing usually has the color, and for the environmental protection, the dyestuff adopts water-soluble dyestuff usually, simultaneously because the coating is attached to on dress surface for the coating is difficult to the parallel and level with dress surface, makes the coating protruding in dress surface, and then makes dress easily dissolve in water and the cooperation friction at abluent in-process dyestuff, produces the condition of losing color easily, consequently still improves the space.
Disclosure of Invention
Aiming at the defects in the prior art, the first purpose of the invention is to provide the mucilage for printing and dyeing, which has the advantage of higher washing color fastness.
In order to achieve the purpose, the invention provides the following technical scheme:
the mucilage for printing and dyeing comprises the following components in percentage by mass:
40-45 parts of acrylic resin;
8-11 parts of ethylene-vinyl acetate copolymer emulsion;
0.1-0.5 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate);
4-4.5 parts of talcum powder;
4-5 parts of BA powder;
0.3-0.8 part of dispersant;
0.1-0.5 part of thickening agent;
3-3.5 parts of an anti-sticking agent;
0.01-0.05 part of curing initiator.
By adopting the technical scheme, the ethylene-vinyl acetate copolymer emulsion is used as a base material, and the better miscibility of the ethylene-vinyl acetate copolymer emulsion is utilized to ensure that all substances are easy to disperse uniformly; acrylic resin is used as a main material, and a curing initiator is matched to initiate the acrylic resin to be cured and crosslinked, so that the printed and dyed coating is adhered to the surface of the clothes; trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) is added to crosslink the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) with acrylic resin and ethylene-vinyl acetate copolymer emulsion into a network shape, so that the adhesive cement can be stably adhered to the surface of clothes after being printed and dyed on the clothes, and meanwhile, the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) and dye form insoluble colored matters, so that the printed and dyed pattern has high washing fastness and is not easy to damage due to contact with the outside; by adding the talcum powder and the anti-sticking agent, the pattern printed by the adhesive cement is smoother and brighter, and the hand feeling is smoother; the BA powder is filled to generate a covering effect, so that the printed and dyed pattern is better in color development and better in printing and dyeing quality; by adding the dispersing agent, the mucilage is easier to rapidly and uniformly stir, the processing efficiency is improved, the energy consumption is reduced, and the cost is controlled.
The invention is further configured to: the dispersant is a sodium polycarboxylate salt.
By adopting the technical scheme, the sodium polycarboxylate is used as the dispersing agent, so that the dispersing agent and the main material both have carboxyl, the compatibility is good, and the dispersing effect is good.
The invention is further configured to: the thickening agent comprises one or two of PTF thickening agent and PA thickening agent.
By adopting the technical scheme, the thickening effect is better by adopting one or more of the PTF thickening agent and the PA thickening agent, so that the printing and dyeing pattern is clear in outline, bright in color and high in color yield.
The invention is further configured to: the anti-sticking agent is a silicon wax anti-sticking agent.
By adopting the technical scheme, the anti-sticking effect is better by adopting the silicon wax anti-sticking agent, and the anti-sticking agent is easy to disperse, so that the printed and dyed pattern is smoother.
The invention is further configured to: the curing initiator is cobalt naphthenate.
By adopting the technical scheme, the cobalt naphthenate is used as the curing initiator to ensure that the catalytic curing effect is better, the curing speed of the adhesive cement is higher, and the printing and dyeing operation efficiency is improved.
The invention is further configured to: the material also comprises the following raw materials in parts by weight:
0.4-0.8 part of matting powder.
By adopting the technical scheme, the matting powder is added, so that the surface gloss of the coating can be effectively reduced, the reflection of light is reduced, the light pollution is reduced, and the clothes are more natural and beautiful.
The invention is further configured to: the paint also comprises the following components in parts by mass:
2.3-2.7 parts of propylene glycol.
By adopting the technical scheme, the propylene glycol is added, so that the components are more easily and uniformly dispersed, the processing efficiency is improved, and the energy consumption is reduced.
The invention is further configured to: the paint also comprises the following components in parts by mass:
0.25-0.3 part of emulsifier.
By adopting the technical scheme, the raw materials are more stable by adding the emulsifier, and are not easy to delaminate and separate out, so that the stability of the mucilage is higher.
Aiming at the defects in the prior art, the second purpose of the invention is to provide a preparation method of the mucilage for printing and dyeing, which has the advantage that the printed patterns are not easy to wear.
In order to achieve the purpose, the invention provides the following technical scheme:
the preparation method of the mucilage for printing and dyeing comprises the following steps:
(1) adding acrylic resin and ethylene-vinyl acetate copolymer emulsion into a container, and stirring at the rotating speed of 800-;
(2) adding trimethylolpropane-tri (3- (2-methylaziridinyl) propionate), a curing initiator, a dispersing agent, propylene glycol and an anti-sticking agent while stirring;
(3) adding talcum powder, matting powder and BA powder, and stirring at the rotating speed of 1000-1500 r/min;
(4) adding an emulsifier and a thickener, and stirring at the rotating speed of 600-800 r/min;
(5) grinding and packaging.
By adopting the technical scheme, the trimethylolpropane-tris (3- (2-methylaziridine) propionate) is added, so that after the dye is added into the mucilage, the dye and the trimethylolpropane-tris (3- (2-methylaziridine) propionate) form insoluble colored matters, the dye is not easy to dissolve in water in the cleaning process, and the color fastness of the printed and dyed coating is high; the dispersing agent and the propylene glycol are added firstly, then the talcum powder, the matting powder and the BA powder are added, so that the powder which is difficult to disperse is rapidly and uniformly dispersed under the action of the dispersing agent and the propylene glycol, and finally the emulsifier and the thickening agent are added to ensure that the dispersed components are in a stable state and are difficult to aggregate, delaminate and separate out, thereby improving the stability of the mucilage.
In conclusion, the invention has the following beneficial effects:
1. trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) is crosslinked into a network shape with acrylic resin and ethylene-vinyl acetate copolymer emulsion by adding trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), so that the adhesive cement can be stably adhered to the surface of clothes after being printed on the clothes, and is not easy to damage due to contact with the outside;
2. meanwhile, trimethylolpropane-tris (3- (2-methylaziridine) propionate) and the dye form insoluble color, so that the washing fastness of the printed pattern is high;
3. by adding the talcum powder and the anti-sticking agent, the pattern printed and dyed by the adhesive cement is smoother and brighter, and the hand feeling is smoother.
Detailed Description
The present invention will be described in further detail with reference to examples.
In the following examples, the sodium polycarboxylate was a sodium polycarboxylate dispersant of type HX-5040 from Weifanghu chemical Co., Ltd;
in the following examples, PA thickener from Shanghai Taiwan chemical company, Ltd;
in the following examples, PTF thickener having model number JC-1510 from Jingchu-sourced New Material Co., Ltd, Dongguan was used;
in the following examples, the silicone wax type antisticking agent was GY-896, model number, available from Guangzhou silicon chemical Co., Ltd.
In the following examples, cobalt naphthenate was prepared according to model 61789-51-3 of photometric chemical reagents GmbH;
in the following examples, the matting powder was a large pore volume silica gel matting powder from fomak (guangzhou) materials science and technology ltd;
in the following examples, the emulsifier used was EM-50, model number, available from Guangdong Yinyi beautification science, Inc.
Example 1
The mucilage for printing and dyeing comprises the following components in parts by weight:
40 parts of acrylic resin; 8 parts of ethylene-vinyl acetate copolymer; 0.1 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.5 parts of talcum powder; 5 parts of BA powder; 0.8 part of sodium polycarboxylate; 0.07 part of PTF thickening agent; PA thickener 0.03; 3 parts of a silicon wax anti-sticking agent; 0.01 part of cobalt naphthenate; 0.4 part of matting powder; 2.7 parts of propylene glycol; 0.3 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 40kg of acrylic resin and 8kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) adding 0.1kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.01kg of cobalt naphthenate, 0.8kg of sodium polycarboxylate, 2.7kg of propylene glycol and 3kg of silicon wax anti-sticking agent while stirring, and stirring at the rotating speed of 800r/min for 5min after all the materials are added;
(3) 4.5kg of talcum powder, 0.4kg of extinction powder and 5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.3kg of emulsifier, 0.07kg of PTF thickener and 0.03kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Example 2
The mucilage for printing and dyeing comprises the following components in parts by weight:
43 parts of acrylic resin; 10 parts of ethylene-vinyl acetate copolymer; 0.3 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.24 part of PTF thickening agent; PA thickener 0.13; 3.2 parts of a silicon wax anti-sticking agent; 0.03 part of cobalt naphthenate; 0.6 part of matting powder; 2.5 parts of propylene glycol; 0.28 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 43kg of acrylic resin and 10kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) adding 0.3kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.03kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.5kg of propylene glycol and 3kg of silicon wax anti-sticking agent while stirring, and stirring at the rotating speed of 800r/min for 5min after all the materials are added;
(3) 4.2kg of talcum powder, 0.6kg of extinction powder and 4.5kg of BA powder are added, and after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.28kg of emulsifier, 0.24kg of PTF thickener and 0.13kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Example 3
The mucilage for printing and dyeing comprises the following components in parts by weight:
45 parts of acrylic resin; 11 parts of ethylene-vinyl acetate copolymer; 0.5 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4 parts of talcum powder; 5 parts of BA powder; 0.8 part of sodium polycarboxylate; 0.3 part of PTF thickening agent; PA thickener 0.2; 3.5 parts of a silicon wax anti-sticking agent; 0.05 part of cobalt naphthenate; 0.8 part of matting powder; 2.7 parts of propylene glycol; 0.25 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) adding 45kg of acrylic resin and 11kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 1000r/min for 5 min;
(2) 0.5kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.05kg of cobalt naphthenate, 0.8kg of sodium polycarboxylate, 2.7kg of propylene glycol and 3.5kg of silicon wax anti-sticking agent are added while stirring, and the materials are stirred for 5min at the rotating speed of 800r/min after all the materials are added;
(3) 4kg of talcum powder, 0.8kg of matting powder and 5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1500r/min, and the stirring is carried out for 10 min;
(4) adding 0.25kg of emulsifier, 0.3kg of PTF thickener and 0.2kg of PA thickener, reducing the rotating speed to 800r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Example 4
The mucilage for printing and dyeing comprises the following components in parts by weight:
45 parts of acrylic resin; 11 parts of ethylene-vinyl acetate copolymer; 0.1 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.2 part of PTF thickening agent; PA thickener 0.1; 3.1 parts of a silicon wax anti-sticking agent; 0.05 part of cobalt naphthenate; 0.5 part of matting powder; 2.6 parts of propylene glycol; 0.27 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) adding 45kg of acrylic resin and 11kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) 0.1kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.05kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.6kg of propylene glycol and 3.1kg of silicon wax anti-sticking agent are added while stirring, and the materials are stirred for 5min at the rotating speed of 800r/min after all the materials are added;
(3) 4.2kg of talcum powder, 0.5kg of extinction powder and 4.5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.27kg of emulsifier, 0.2kg of PTF thickener and 0.1kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Example 5
The mucilage for printing and dyeing comprises the following components in parts by weight:
40 parts of acrylic resin; 8 parts of ethylene-vinyl acetate copolymer; 0.5 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.2 part of PTF thickening agent; 0.1 part of PA thickening agent; 3.1 parts of a silicon wax anti-sticking agent; 0.01 part of cobalt naphthenate; 0.5 part of matting powder; 2.6 parts of propylene glycol; 0.27 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 40kg of acrylic resin and 8kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) 0.5kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.01kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.6kg of propylene glycol and 3.1kg of silicon wax anti-sticking agent are added while stirring, and the materials are stirred for 5min at the rotating speed of 800r/min after all the materials are added;
(3) 4.2kg of talcum powder, 0.5kg of extinction powder and 4.5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.27kg of emulsifier, 0.2kg of PTF thickener and 0.1kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Comparative example 1
The mucilage for printing and dyeing comprises the following components in parts by weight:
40 parts of acrylic resin; 8 parts of ethylene-vinyl acetate copolymer; 1 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.2 part of PTF thickening agent; PA thickener 0.1; 3.1 parts of a silicon wax anti-sticking agent; 0.01 part of cobalt naphthenate; 0.5 part of matting powder; 2.6 parts of propylene glycol; 0.27 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 40kg of acrylic resin and 8kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) adding 1kg of trimethylolpropane-tri (3- (2-methylaziridinyl) propionate), 0.01kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.6kg of propylene glycol and 3.1kg of silicon wax anti-sticking agent while stirring, and stirring at the rotating speed of 800r/min for 5min after all the materials are added;
(3) 4.2kg of talcum powder, 0.5kg of extinction powder and 4.5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.27kg of emulsifier, 0.2kg of PTF thickener and 0.1kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Comparative example 2
The mucilage for printing and dyeing comprises the following components in parts by weight:
40 parts of acrylic resin; 8 parts of ethylene-vinyl acetate copolymer; 5 parts of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate); 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.2 part of PTF thickening agent; PA thickener 0.1; 3.1 parts of a silicon wax anti-sticking agent; 0.01 part of cobalt naphthenate; 0.5 part of matting powder; 2.6 parts of propylene glycol; 0.27 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 40kg of acrylic resin and 8kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) 5kg of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate), 0.01kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.6kg of propylene glycol and 3.1kg of silicon wax anti-sticking agent are added while stirring, and the mixture is stirred for 5min at the rotating speed of 800r/min after all the materials are added;
(3) 4.2kg of talcum powder, 0.5kg of extinction powder and 4.5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.27kg of emulsifier, 0.2kg of PTF thickener and 0.1kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Comparative example 3
The mucilage for printing and dyeing comprises the following components in parts by weight:
40 parts of acrylic resin; 8 parts of ethylene-vinyl acetate copolymer; 4.2 parts of talcum powder; 4.5 parts of BA powder; 0.6 part of sodium polycarboxylate; 0.2 part of PTF thickening agent; PA thickener 0.1; 3.1 parts of a silicon wax anti-sticking agent; 0.01 part of cobalt naphthenate; 0.5 part of matting powder; 2.6 parts of propylene glycol; 0.27 part of emulsifier.
The preparation method of the mucilage for printing and dyeing comprises the following specific steps:
(1) putting 40kg of acrylic resin and 8kg of ethylene-vinyl acetate copolymer emulsion into a stirring kettle, and stirring at the rotating speed of 800r/min for 5 min;
(2) 0.01kg of cobalt naphthenate, 0.6kg of sodium polycarboxylate, 2.6kg of propylene glycol and 3.1kg of silicon wax anti-sticking agent are added while stirring, and the mixture is stirred for 5min at the rotating speed of 800r/min after all the components are added;
(3) 4.2kg of talcum powder, 0.5kg of extinction powder and 4.5kg of BA powder are added, after the addition is finished, the rotating speed is increased to 1000r/min, and the stirring is carried out for 10 min;
(4) adding 0.27kg of emulsifier, 0.2kg of PTF thickener and 0.1kg of PA thickener, reducing the rotating speed to 600r/min, and stirring for 5 min;
(5) and (4) performing grinding processing through grinding equipment, and then discharging and packaging.
Experiment 1
The colorfastness to washing of the printing and dyeing pastes prepared in the examples and comparative examples was tested according to GB/T12490-2014 color fastness to washing in the family and the business of textile color fastness tests.
5kg of dyes of red, yellow and blue colors were added to the pastes for printing and dyeing prepared in examples and comparative examples, respectively, and after stirring them uniformly, the pastes for printing and dyeing were printed on cotton cloth to perform tests, and the test results are shown in Table 1.
TABLE 1
According to table 1, the washing fastness of the printing and dyeing coating printed on the cotton cloth is obviously improved after the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) is added, and when the dosage of the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) reaches 1.5 percent of the total amount of the acrylic resin and the ethylene-vinyl acetate copolymer emulsion, the washing fastness of the printing and dyeing coating printed on the cotton cloth reaches the highest 5 grades, and the washing fastness of the printing and dyeing coating printed on the cotton cloth by the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) cannot be continuously improved by continuously increasing the dosage of the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate).
Meanwhile, when the dosage of the trimethylolpropane-tris (3- (2-methylaziridine) propionate) reaches 0.18 percent of the total amount of the acrylic resin and the ethylene-vinyl acetate copolymer emulsion, the washing fastness of the printing and dyeing coating of three colors printed and dyed on the cotton cloth reaches 4 grades, and if the dosage of the trimethylolpropane-tris (3- (2-methylaziridine) propionate) is reduced, the effect of improving the washing fastness of the printing and dyeing mucilage is poor.
Therefore, when the input amount of the acrylic resin is controlled to be 40-45 parts and the input amount of the ethylene-vinyl acetate copolymer emulsion is controlled to be 8-11 parts, the input amount of the trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) is controlled to be 0.1-0.5 part, so that the washing color fastness of the printing and dyeing mucilage can be better improved, the cost is controlled, and the waste of raw materials is avoided.
Experiment 2
The printing pastes prepared in examples and comparative examples were tested for tensile shear strength (MPa) according to GB/T7124-2008 "determination of tensile shear strength of adhesive" (rigid material vs. rigid material).
TABLE 2
As can be seen from table 2, the addition of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) increased the tensile shear strength of the cement, and the tensile shear strength of the cement gradually increased as the amount of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) added increased, and the effect of increasing the amount of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate) to 1.5% of the total amount of the acrylic resin and ethylene-vinyl acetate copolymer emulsion was low.
The embodiments of the present invention are preferred embodiments of the present invention, and the scope of the present invention is not limited by these embodiments, so: all equivalent changes made according to the structure, shape and principle of the invention are covered by the protection scope of the invention.
Claims (7)
1. The mucilage for printing and dyeing is characterized in that: the composition comprises the following components in percentage by mass:
40-45 parts of acrylic resin;
8-11 parts of ethylene-vinyl acetate copolymer emulsion;
0.1-0.5 part of trimethylolpropane-tris (3- (2-methylaziridinyl) propionate);
4-4.5 parts of talcum powder;
4-5 parts of BA powder;
0.3-0.8 part of dispersant;
0.1-0.5 part of thickening agent;
3-3.5 parts of an anti-sticking agent;
0.01-0.05 part of curing initiator;
the curing initiator is cobalt naphthenate;
0.25-0.3 part of emulsifier.
2. The dope according to claim 1, wherein: the dispersant is a sodium polycarboxylate salt.
3. The dope according to claim 2, wherein: the thickening agent comprises one or two of PTF thickening agent and PA thickening agent.
4. The dope according to claim 3, wherein: the anti-sticking agent is a silicon wax anti-sticking agent.
5. The sizing agent for textile printing according to any one of claims 1 to 4, wherein: the material also comprises the following raw materials in parts by weight:
0.4-0.8 part of matting powder.
6. The dope according to claim 5, wherein: the paint also comprises the following components in parts by mass:
2.3-2.7 parts of propylene glycol.
7. A process for producing the paste for printing and dyeing according to claim 6, characterized by comprising: the method comprises the following steps:
(1) adding acrylic resin and ethylene-vinyl acetate copolymer emulsion into a container, and stirring at the rotating speed of 800-;
(2) adding trimethylolpropane-tri (3- (2-methylaziridinyl) propionate), a curing initiator, a dispersing agent, propylene glycol and an anti-sticking agent while stirring;
(3) adding talcum powder, matting powder and BA powder, and stirring at the rotating speed of 1000-1500 r/min;
(4) adding an emulsifier and a thickener, and stirring at the rotating speed of 600-800 r/min;
(5) grinding and packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811341098.1A CN109487593B (en) | 2018-11-12 | 2018-11-12 | Mucilage for printing and dyeing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811341098.1A CN109487593B (en) | 2018-11-12 | 2018-11-12 | Mucilage for printing and dyeing and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109487593A CN109487593A (en) | 2019-03-19 |
| CN109487593B true CN109487593B (en) | 2021-04-27 |
Family
ID=65695774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811341098.1A Active CN109487593B (en) | 2018-11-12 | 2018-11-12 | Mucilage for printing and dyeing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109487593B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111206441B (en) * | 2020-02-25 | 2022-05-13 | 东莞威冠服饰工艺有限公司 | Gold stamping paste and manufacturing method thereof |
| CN111254725A (en) * | 2020-02-25 | 2020-06-09 | 东莞威冠服饰工艺有限公司 | Bronzing-imitating paste and manufacturing method thereof |
| CN114250635A (en) * | 2021-12-08 | 2022-03-29 | 深圳特朗商实业有限公司 | Self-help printing material and preparation method thereof |
| CN114316808A (en) * | 2021-12-31 | 2022-04-12 | 烟台泰盛精化科技有限公司 | Acrylate structural adhesive and preparation method and application thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6022115B2 (en) * | 1977-05-30 | 1985-05-31 | 共同印刷株式会社 | Paste-like aqueous composition containing sublimable dye |
| CN101187178A (en) * | 2007-10-25 | 2008-05-28 | 杨剑侠 | Hot stamping preventing mucilage |
| CN101948555B (en) * | 2010-09-30 | 2013-08-21 | 东莞长联新材料科技股份有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102643452B (en) * | 2011-02-16 | 2013-06-12 | 中国中化股份有限公司 | Method for improving aziridine cross-linking agent stability |
| CN102720074A (en) * | 2012-06-18 | 2012-10-10 | 百利合化工（中山）有限公司 | Environment-friendly adhesive cement for printing of three-dimensional thick textile plates and preparation and application of environment-friendly adhesive cement |
| CN103255646B (en) * | 2013-05-14 | 2015-05-20 | 广州市盛勤实业有限公司 | Bronzing pulp and preparation method thereof |
| CN105442348A (en) * | 2014-09-15 | 2016-03-30 | 珠海保税区天然宝杰数码科技材料有限公司 | Digital printing active ink |
-
2018
- 2018-11-12 CN CN201811341098.1A patent/CN109487593B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109487593A (en) | 2019-03-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109487593B (en) | Mucilage for printing and dyeing and preparation method thereof | |
| CN105113285B (en) | A kind of pulp-shaped dispersed dyes and preparation method and application | |
| CN102321984B (en) | High-gloss washing resistant environmental-friendly print paste and preparation method thereof | |
| CN100547153C (en) | A kind of environmental protection type dye printing paste without steaming and washing | |
| TWI525234B (en) | Cold-transfer printing method using dispersion dye | |
| CN102978975A (en) | Printing paste preparation and printing process thereof | |
| CN105839405B (en) | A kind of chlorine-resistant elevator and preparation method and application | |
| CN105111363A (en) | Function prepolymer and preparation method and application thereof | |
| WO2013086863A1 (en) | Spared sizing direct spray reactive dye ink | |
| CN108624126B (en) | Bi-component silk-screen glass printing ink and preparation and use methods thereof | |
| CN107385979A (en) | A kind of ink-jet printed technique of corn yarn carpet | |
| CN109736104B (en) | Indigo pulp dyeing process for all-cotton fabric | |
| CN102677486A (en) | Formaldehyde-free pigment printing covering white slurry, preparation method and application thereof | |
| CN102505527B (en) | Rubber cement for improving printing rubbing color fastness and dryness and preparation method thereof | |
| CN106349811A (en) | Six-color full-color soft printing ink and preparation method thereof | |
| CN106948191B (en) | The black printed slurry of SM | |
| CN101070039A (en) | Five-colour handicraft decoration, spray-drawing and oil-painting cloth and making technology | |
| CN104878622A (en) | Processing method for improving hand feel of coat-printed textiles | |
| CN102031705A (en) | Coating printing paste | |
| CN105461857B (en) | A kind of preparation method of living polymer dispersant | |
| CN109385918B (en) | White glue for printing and dyeing and preparation method thereof | |
| CN112661895B (en) | Preparation method of chemical crosslinking type monodisperse colored latex particles | |
| CN107119471A (en) | A kind of reactive dye discharge printing process based on ink-jet printed technology | |
| CN106749863A (en) | A kind of imitative reactive coating printing adhesive and preparation method thereof, application process | |
| CN104894893A (en) | Processing method for color-deepening and brightening of pigment printed textiles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |