CN102718921A - Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof - Google Patents
Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof Download PDFInfo
- Publication number
- CN102718921A CN102718921A CN2012102007006A CN201210200700A CN102718921A CN 102718921 A CN102718921 A CN 102718921A CN 2012102007006 A CN2012102007006 A CN 2012102007006A CN 201210200700 A CN201210200700 A CN 201210200700A CN 102718921 A CN102718921 A CN 102718921A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- environment
- gold stamping
- printing paste
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses adhesive emulsion for environment-friendly textile gilding printing paste and a preparation method thereof. The emulsion consists of the following components in percentage by weight: 0.5-3% of emulsifier, 30-50% of soft monomer, 6-15% of hard monomer, 2-5% of functional monomer, 0.1-0.3% of initiator, 40-60% of deionized water and 0.5-2% of neutralizer. The adhesive is prepared into gilding paste and is used for bonding textile gilding foil; and the shortcomings of the products on the market of low net operability, hard handfeel, unsatisfactory firmness, easy color losing after washing, environmental pollution and the like are overcome. Through the invention, the prepared adhesive has excellent initial viscosity and sustained viscosity and good water resistance, and can realize good adhesive force against different textile fabrics; and meanwhile, the adhesive has good cohesion permanent viscosity, is environment-friendly without releasing toxic substances such as formaldehyde and the like, and does not contain the alkylphenol additives. The adhesive emulsion disclosed by the invention is suitable for the cold and hot gilding technology of manual or mechanical printing, is easy to operate, and has soft handfeel, no sand hole and high yield.
Description
Technical field
The present invention relates to the gold stamping printing paste of a kind of environment-friendly type textiles with adhesive agent emulsion and preparation method thereof.
Background technology
The gold stamping printing paste of textiles is at present than a kind of characteristic printing coating of popular, it be a kind of easy to use, suitability strong, the novel printing method that has wide range of applications.Its chromatography is accurate, the clear exquisiteness of decorative pattern, handiness are strong, both can be mass-produced, but also small serial production also can be printed patterns such as Freehandhand-drawing, the gold stamping font of new Year scroll, and carry out local stamp.Gold stamping slurry is to utilize tackiness agent, auxiliary agent etc. synthetic; Through half tone gold stamping slurry is undertaken the printing of on stock; Through (cold) hot pressing of fitting, electrochemical aluminum foil (gold stamping film) and polyester film are peeled off and are bonding on the stock, make and form a kind of gorgeous luxurious special-effect on the stock.It can be a kind of through the gold stamping printing technology that carries out the solid phase transfer of (cold) hot pressing.The technical process of gold stamping slurry printing is: picture and text egative film → system wire mark version → print gold stamping slurry → thermoprint → finished product, so the gold stamping method of wire mark is a kind of easy, bronzing method cheaply.
In the gold stamping stamp of textiles, the textiles stock to reach good gold stamping feel, washing fastness good, do not shrink, good springiness, do not need too high boiling hot pressure temperature, key is gold stamping slurry, the main gordian technique of gold stamping slurry is tackiness agent.This just requires the synthesis of acrylic ester adhesive agent emulsion to have good tack, gathers in stronger to hold viscous force and peel off greatly, makes the gold stamping slurry can be gold stamping under the situation of room temperature.This tackiness agent is configured to gold stamping slurry, is used for the gold stamping paper tinsel of bonded fiber fabric, it is poor to solve on the market product gambling net operation property, Boardy Feeling, shortcomings such as that the not good wash water of firmness is prone to is eclipsed, not environmental protection.Though Chinese invention patent application CN 101474932A discloses a kind of method for printing bronzing paper, it does not relate to the preparation of gold stamping slurry and the preparation method of relevant tackiness agent thereof.
Summary of the invention
Purpose of the present invention is the deficiency that exists to prior art, provides that a kind of working method is simple, the gold stamping printing paste of environment-friendly type textiles of each item excellent performance is used adhesive agent emulsion.
Another object of the present invention is that the preparation method of the gold stamping printing paste of a kind of above-mentioned environment-friendly type textiles with adhesive agent emulsion will be provided.
The technical solution adopted for the present invention to solve the technical problems is:
The gold stamping printing paste of a kind of environment-friendly type textiles is used adhesive agent emulsion, it is characterized in that: it mainly is that feedstock production by following mass percent forms: emulsifying agent 0.5% ~ 3%, soft monomer 30% ~ 50%, hard monomer 6% ~ 15%, functional monomer 2% ~ 5%, initiator 0.1% ~ 0.3%, deionized water 40% ~ 60%, neutralizing agent 0.5% ~ 2%.
Described emulsifying agent is a sodium lauryl sulphate.
Described soft monomer is one or more mixtures in Bing Xisuandingzhi, Isooctyl acrylate monomer, ethyl propenoate, the vinyl neodecanoate.
Described hard monomer is one or more mixtures in vinylbenzene, ɑ-vinyl toluene, TEB 3K, methyl acrylate, the vinyl acetate.
Functional monomer is two or more a mixture in methylacrylic acid, vinylformic acid, methylene-succinic acid, vinylformic acid-2-hydroxyl second fat, acrylic amide, rosin, vinyl triethoxyl siloxanes, the vinyl trimethoxy siloxanes.
Described initiator is a kind of in Potassium peroxide 85 or the ammonium persulphate.
Described neutralizing agent is a kind of in ammoniacal liquor or the trolamine.
A kind of method for preparing the gold stamping printing paste of above-mentioned environment-friendly type textiles with adhesive agent emulsion is characterized in that may further comprise the steps:
A, in advance emulsification: emulsifying agent is dissolved in 1/3~2/3 the deionized water, stirs, add soft monomer, hard monomer, functional monomer, stir, obtain pre-emulsion;
B, dissolving initiator: with the part deionized water dissolving in the component, it is for use to be made into initiator solution with the initiator in the component;
C, preparation emulsion: in the four-hole boiling flask that has whisking appliance, TM, condensation reflux unit and Dropping feeder; Add balance of deionized water; 2% ~ 10% of the pre-emulsion that makes in the steps A; 20 ~ 50% of the initiator solution total amount that makes among the step B stirs and is warming up to 75 ~ 85 ℃, reaction 10 ~ 30min; Begin to drip the pre-emulsion of surplus and the initiator solution of surplus; 2 ~ 4h dropwises; Be warming up to 85 ~ 90 ℃ of insulation slaking 1 ~ 2h after all dropwising, be cooled to below 40 ℃, after the adding neutralizing agent is regulated pH value to 7.0 ~ 8.0; Filter discharging with 120 order gauzes, obtain the gold stamping printing paste of environmental protection textiles and use adhesive agent emulsion.
The invention has the beneficial effects as follows: tackiness agent of the present invention is the aqueous, environmental protective product, and as solvent, the formaldehydeless toxicant that waits discharges no induced by alkyl hydroxybenzene additive with water; The tack of tackiness agent is with to hold viscosity good, and water-tolerant can have good firmness to different textile cloths, gathers in this tackiness agent simultaneously that to hold viscous force good, and 60 ℃ of saponification washing 3h do not come off; Be applicable to the hot and cold gilding technology of manual or mechanical stamp, easy to operate, soft, no sand holes, yield rate is high.
Below in conjunction with embodiment the present invention is further specified.
Embodiment
Below in conjunction with practical implementation example explanation the inventive method, umber related among the embodiment is mass parts.
Embodiment 1
Formula rate by table 1 takes by weighing raw material.
Table 1
The preparation method of present embodiment may further comprise the steps:
A, emulsifier sodium lauryl sulfate is dissolved in 30.0% deionized water, stirs, add soft monomer, hard monomer, functional monomer stirs, and obtains pre-emulsion;
It is for use that B, the deionized water with 10% are made into initiator solution with the ammonium persulphate dissolving;
C, in reactor drum, add the surplus deionized water, get 5% of the pre-emulsion that makes in the steps A and add in the reactor drum, be warming up to 78 ℃, add 20% of the initiator solution that makes among the step B, reaction 20min also is warming up to 80 ℃; Begin to drip the remaining pre-emulsion and the initiator solution of surplus; 3.5h dropwise, be warming up to 85 ℃ of insulation slaking 2h after all dropwising, be cooled to below 45 ℃; Add in the ammoniacal liquor be 7.0-8.0 to the pH value after; Filter discharging with 120 order gauzes, obtain solid content and be 51% acrylic ester emulsion, be the gold stamping printing paste of environment-friendly type textiles of the present invention and use adhesive agent emulsion.
Embodiment 2
Formula rate by table 2 takes by weighing raw material.
Table 2
The preparation method of present embodiment may further comprise the steps:
A, emulsifier sodium lauryl sulfate is dissolved in 30.0% deionized water, stirs, add soft monomer, hard monomer, functional monomer, stir, obtain pre-emulsion;
It is for use that B, the deionized water with 10% are made into initiator solution with the ammonium persulphate dissolving;
C, in reactor drum, add the surplus deionized water, get 5% of the pre-emulsion that makes in the steps A and add in the reactor drum, be warming up to 78 ℃, add 20% of the initiator solution that makes among the step B, reaction 20min also is warming up to 80 ℃; Begin to drip the remaining pre-emulsion and the initiator solution of surplus; 4h dropwises, and is warming up to 85 ℃ of insulation slaking 2h after all dropwising, and is cooled to below 45 ℃; Add in the ammoniacal liquor be 7.0-8.0 to the pH value after; Filter discharging with 120 order gauzes, obtain solid content and be 55% acrylic ester emulsion, be the gold stamping printing paste of environment-friendly type textiles of the present invention and use adhesive agent emulsion.
Embodiment 3
Formula rate by table 3 takes by weighing raw material.
The preparation method of present embodiment may further comprise the steps:
A, emulsifier sodium lauryl sulfate is dissolved in 30.0% deionized water, stirs, add soft monomer, hard monomer, functional monomer stirs, and obtains pre-emulsion;
It is for use that B, the deionized water with 10% are made into initiator solution with the ammonium persulphate dissolving;
C, in reactor drum, add the surplus deionized water, get 5% of the pre-emulsion that makes in the steps A and add in the reactor drum, be warming up to 78 ℃, add 20% of the initiator solution that makes among the step B, reaction 20min also is warming up to 80 ℃; Begin to drip the remaining pre-emulsion and the initiator solution of surplus; 3h dropwises; Be warming up to 85 ℃ of insulation slaking 1.5h after all dropwising, be cooled to below 45 ℃, add in the ammoniacal liquor be 7.0-8.0 to the pH value after; Filter discharging with 120 order gauzes, obtain solid content and be 47% acrylic ester emulsion.Be the gold stamping printing paste of environment-friendly type textiles of the present invention and use adhesive agent emulsion.
Table 3
Embodiment 4
Formula rate by table 4 takes by weighing raw material.
The preparation method of present embodiment may further comprise the steps:
A, emulsifier sodium lauryl sulfate is dissolved in 30.0% deionized water, stirs, add soft monomer, hard monomer, functional monomer stirs, and obtains pre-emulsion;
It is for use that B, the deionized water with 10% are made into initiator solution with the ammonium persulphate dissolving;
C, in reactor drum, add the surplus deionized water, get 5% of the pre-emulsion that makes in the steps A and add in the reactor drum, be warming up to 78 ℃, add 20% of the initiator solution that makes among the step B, reaction 20min also is warming up to 80 ℃; Begin to drip the remaining pre-emulsion and the initiator solution of surplus; 2.5h dropwise; Be warming up to 85 ℃ of insulation slaking 1.5h after all dropwising, be cooled to below 45 ℃, add in the ammoniacal liquor be 7.0-8.0 to the pH value after; Filter discharging with 120 order gauzes, obtain solid content and be 45% acrylic ester emulsion.Be the gold stamping printing paste of environment-friendly type textiles of the present invention and use adhesive agent emulsion.
Table 4
The application implementation example
The gold stamping printing paste of environment-friendly type textiles that embodiment 2 is prepared from carries out the performance test contrast with adhesive agent emulsion and tackiness agent in the market, result such as table 5:
Table 5
Test item | Embodiment 2 | Product on the market |
PH | 7.5 | 8.2 |
Viscosity | 11000cps | 1000cps |
Solid content | 47.1% | 40.2% |
Formaldehyde content | Fail to detect | 513ppm |
Gambling net property (silk-screen 4h) | Do not gamble net | The gambling net |
Feel | Soft | Hard slightly |
Ambient operation property | Can | Need the blanching operation |
The wash water firmness (60 ℃, 2h) | Do not fade more than three times | Fade for twice |
Claims (8)
1. the gold stamping printing paste of environment-friendly type textiles is used adhesive agent emulsion, it is characterized in that: it mainly is that feedstock production by following mass percent forms: emulsifying agent 0.5% ~ 3%, soft monomer 30% ~ 50%, hard monomer 6% ~ 15%, functional monomer 2% ~ 5%, initiator 0.1% ~ 0.3%, deionized water 40% ~ 60%, neutralizing agent 0.5% ~ 2%.
2. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, and it is characterized in that: described emulsifying agent is a sodium lauryl sulphate.
3. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, it is characterized in that: described soft monomer is one or more mixtures in Bing Xisuandingzhi, Isooctyl acrylate monomer, ethyl propenoate, the vinyl neodecanoate.
4. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, it is characterized in that: described hard monomer is one or more mixtures in vinylbenzene, ɑ-vinyl toluene, TEB 3K, methyl acrylate, the vinyl acetate.
5. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, it is characterized in that: functional monomer is two or more a mixture in methylacrylic acid, vinylformic acid, methylene-succinic acid, vinylformic acid-2-hydroxyl second fat, acrylic amide, rosin, vinyl triethoxyl siloxanes, the vinyl trimethoxy siloxanes.
6. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, it is characterized in that: described initiator is a kind of in Potassium peroxide 85 or the ammonium persulphate.
7. the gold stamping printing paste of a kind of environment-friendly type textiles according to claim 1 is used adhesive agent emulsion, it is characterized in that: described neutralizing agent is a kind of in ammoniacal liquor or the trolamine.
8. the gold stamping printing paste of a kind of environment-friendly type textiles as claimed in claim 1 is characterized in that may further comprise the steps with the preparation method of adhesive agent emulsion:
A, in advance emulsification: emulsifying agent is dissolved in 1/3~2/3 the deionized water, stirs, add soft monomer, hard monomer, functional monomer, stir, obtain pre-emulsion;
B, dissolving initiator: with the part deionized water dissolving in the component, it is for use to be made into initiator solution with the initiator in the component;
C, preparation emulsion: in the four-hole boiling flask that has whisking appliance, TM, condensation reflux unit and Dropping feeder; Add balance of deionized water; 2% ~ 10% of the pre-emulsion that makes in the steps A; 20 ~ 50% of the initiator solution total amount that makes among the step B stirs and is warming up to 75 ~ 85 ℃, reaction 10 ~ 30min; Begin to drip the pre-emulsion of surplus and the initiator solution of surplus; 2 ~ 4h dropwises; Be warming up to 85 ~ 90 ℃ of insulation slaking 1 ~ 2h after all dropwising, be cooled to below 40 ℃, after the adding neutralizing agent is regulated pH value to 7.0 ~ 8.0; Filter discharging with 120 order gauzes, obtain the gold stamping printing paste of environmental protection textiles and use adhesive agent emulsion.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2012102007006A CN102718921A (en) | 2012-06-18 | 2012-06-18 | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2012102007006A CN102718921A (en) | 2012-06-18 | 2012-06-18 | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN102718921A true CN102718921A (en) | 2012-10-10 |
Family
ID=46944807
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2012102007006A Pending CN102718921A (en) | 2012-06-18 | 2012-06-18 | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102718921A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103255646A (en) * | 2013-05-14 | 2013-08-21 | 广州市盛勤实业有限公司 | Bronzing pulp and preparation method thereof |
CN103450409A (en) * | 2013-08-26 | 2013-12-18 | 华中师范大学 | Environment-friendly styrene-acrylic emulsion with ultra-low VOC (Volatile Organic Compound) content and preparation method thereof |
CN103756601A (en) * | 2014-01-07 | 2014-04-30 | 佛山市三水灏诚合成树脂有限公司 | Gold and silver powder adhesive, preparation method thereof, wallpaper and textiles |
CN104497776A (en) * | 2014-02-21 | 2015-04-08 | 井冈山大学 | Reinforcement protection agent for mud wall and attached mortar layer surface slogans and preparation method thereof |
CN104628933A (en) * | 2015-02-10 | 2015-05-20 | 东莞长联新材料科技股份有限公司 | Environment-friendly anti-oxidation printing adhesive for glitter paste and gold and silver power and preparation method thereof |
CN107012696A (en) * | 2017-04-10 | 2017-08-04 | 江苏亨德利纺织印染有限公司 | Waterborne suede slurry for cotton flannelette and preparation method thereof and application method |
CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
CN108360273A (en) * | 2018-02-05 | 2018-08-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of processing method of metallic Chinese flax fabric |
CN108411651A (en) * | 2018-03-20 | 2018-08-17 | 惠州长联新材料科技有限公司 | A kind of gold stamping slurry and its preparation method and application |
CN109098022A (en) * | 2018-08-16 | 2018-12-28 | 浙江美格机械股份有限公司 | A kind of application method of transfer printing carrier coating and the coating |
CN109183452A (en) * | 2018-09-04 | 2019-01-11 | 黄敏 | The preparation of pseudomonas aeruginosa extractive from fermentative and the application in dyeing and printing adhesive agent |
CN109235086A (en) * | 2018-11-05 | 2019-01-18 | 合肥聚合辐化技术有限公司 | A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof |
CN109320665A (en) * | 2018-10-08 | 2019-02-12 | 浙江科峰新材料有限公司 | A kind of preparation method of research of silicone modified coating printing adhesive |
CN111171238A (en) * | 2020-03-04 | 2020-05-19 | 中山市天益聚合物有限公司 | Environment-friendly core-shell structure acrylate emulsion for textiles and preparation method thereof |
CN111802695A (en) * | 2020-06-06 | 2020-10-23 | 浙江本科特水松纸有限公司 | Gold stamping type tipping paper and preparation method thereof |
CN113351057A (en) * | 2021-07-05 | 2021-09-07 | 南京君越化工有限公司 | Adhesive for textile gold stamping printing paste, preparation method and device |
CN114013196A (en) * | 2021-11-25 | 2022-02-08 | 绍兴柯桥众恒烫金有限公司 | Electrochemical aluminum transfer gold stamping process |
CN117229448A (en) * | 2023-10-16 | 2023-12-15 | 波司登羽绒服装有限公司 | Aqueous acrylic emulsion for gold stamping |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005139340A (en) * | 2003-11-07 | 2005-06-02 | Nippon Carbide Ind Co Inc | Aqueous composition of acrylic copolymer for textile printing |
CN101368342A (en) * | 2008-09-16 | 2009-02-18 | 江南大学 | Core-shell type paint dyeing and printing adhesive agent emulsion and preparation method thereof |
CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
CN102154852A (en) * | 2011-01-12 | 2011-08-17 | 百利合化工(中山)有限公司 | Textile machinery printing pigment binding agent and manufacturing method thereof |
CN102344522A (en) * | 2011-06-25 | 2012-02-08 | 百利合化工(中山)有限公司 | Environment-friendly printing platen adhesive emulsion and preparation method thereof |
-
2012
- 2012-06-18 CN CN2012102007006A patent/CN102718921A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005139340A (en) * | 2003-11-07 | 2005-06-02 | Nippon Carbide Ind Co Inc | Aqueous composition of acrylic copolymer for textile printing |
CN101368342A (en) * | 2008-09-16 | 2009-02-18 | 江南大学 | Core-shell type paint dyeing and printing adhesive agent emulsion and preparation method thereof |
CN101748617A (en) * | 2008-12-05 | 2010-06-23 | 上海洁润丝新材料股份有限公司 | Anti-sticking soft dope printing adhesive and preparation method |
CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
CN102154852A (en) * | 2011-01-12 | 2011-08-17 | 百利合化工(中山)有限公司 | Textile machinery printing pigment binding agent and manufacturing method thereof |
CN102344522A (en) * | 2011-06-25 | 2012-02-08 | 百利合化工(中山)有限公司 | Environment-friendly printing platen adhesive emulsion and preparation method thereof |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103255646A (en) * | 2013-05-14 | 2013-08-21 | 广州市盛勤实业有限公司 | Bronzing pulp and preparation method thereof |
CN103255646B (en) * | 2013-05-14 | 2015-05-20 | 广州市盛勤实业有限公司 | Bronzing pulp and preparation method thereof |
CN103450409A (en) * | 2013-08-26 | 2013-12-18 | 华中师范大学 | Environment-friendly styrene-acrylic emulsion with ultra-low VOC (Volatile Organic Compound) content and preparation method thereof |
CN103450409B (en) * | 2013-08-26 | 2016-01-13 | 华中师范大学 | Environment-friendly type benzene emulsion of a kind of zero VOC content and preparation method thereof |
CN103756601A (en) * | 2014-01-07 | 2014-04-30 | 佛山市三水灏诚合成树脂有限公司 | Gold and silver powder adhesive, preparation method thereof, wallpaper and textiles |
CN103756601B (en) * | 2014-01-07 | 2016-01-20 | 佛山市三水灏诚合成树脂有限公司 | Metal(lic)powder tackiness agent and preparation method thereof and wallpaper, textiles |
CN104497776A (en) * | 2014-02-21 | 2015-04-08 | 井冈山大学 | Reinforcement protection agent for mud wall and attached mortar layer surface slogans and preparation method thereof |
CN104497776B (en) * | 2014-02-21 | 2017-05-10 | 井冈山大学 | Reinforcement protection agent for mud wall and attached mortar layer surface slogans and preparation method thereof |
CN104628933A (en) * | 2015-02-10 | 2015-05-20 | 东莞长联新材料科技股份有限公司 | Environment-friendly anti-oxidation printing adhesive for glitter paste and gold and silver power and preparation method thereof |
CN107012696A (en) * | 2017-04-10 | 2017-08-04 | 江苏亨德利纺织印染有限公司 | Waterborne suede slurry for cotton flannelette and preparation method thereof and application method |
CN107880208A (en) * | 2017-12-12 | 2018-04-06 | 杭州龙驹合成材料有限公司 | A kind of gold stamping slurry emulsion and preparation method thereof |
CN108360273A (en) * | 2018-02-05 | 2018-08-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of processing method of metallic Chinese flax fabric |
CN108411651A (en) * | 2018-03-20 | 2018-08-17 | 惠州长联新材料科技有限公司 | A kind of gold stamping slurry and its preparation method and application |
CN108411651B (en) * | 2018-03-20 | 2020-09-11 | 惠州长联新材料科技有限公司 | Slurry for gold stamping and preparation method and application thereof |
CN109098022A (en) * | 2018-08-16 | 2018-12-28 | 浙江美格机械股份有限公司 | A kind of application method of transfer printing carrier coating and the coating |
CN109183452A (en) * | 2018-09-04 | 2019-01-11 | 黄敏 | The preparation of pseudomonas aeruginosa extractive from fermentative and the application in dyeing and printing adhesive agent |
CN109320665A (en) * | 2018-10-08 | 2019-02-12 | 浙江科峰新材料有限公司 | A kind of preparation method of research of silicone modified coating printing adhesive |
CN109320665B (en) * | 2018-10-08 | 2021-08-06 | 浙江科峰有机硅有限公司 | Preparation method of organic silicon modified pigment printing adhesive |
CN109235086A (en) * | 2018-11-05 | 2019-01-18 | 合肥聚合辐化技术有限公司 | A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof |
CN111171238A (en) * | 2020-03-04 | 2020-05-19 | 中山市天益聚合物有限公司 | Environment-friendly core-shell structure acrylate emulsion for textiles and preparation method thereof |
CN111802695A (en) * | 2020-06-06 | 2020-10-23 | 浙江本科特水松纸有限公司 | Gold stamping type tipping paper and preparation method thereof |
CN113351057A (en) * | 2021-07-05 | 2021-09-07 | 南京君越化工有限公司 | Adhesive for textile gold stamping printing paste, preparation method and device |
CN114013196A (en) * | 2021-11-25 | 2022-02-08 | 绍兴柯桥众恒烫金有限公司 | Electrochemical aluminum transfer gold stamping process |
CN117229448A (en) * | 2023-10-16 | 2023-12-15 | 波司登羽绒服装有限公司 | Aqueous acrylic emulsion for gold stamping |
CN117229448B (en) * | 2023-10-16 | 2024-07-26 | 波司登羽绒服装有限公司 | Aqueous acrylic emulsion for gold stamping |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102718921A (en) | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof | |
CN103225215B (en) | Environmental protection fire retardation type textile printing coating material and preparation method thereof | |
CN102344522B (en) | Environment-friendly printing platen adhesive emulsion and preparation method thereof | |
CN105463882B (en) | A kind of gold stamping slurry and preparation method thereof | |
CN101748617B (en) | Anti-sticking soft dope printing adhesive and preparation method | |
CN102619102B (en) | Embossed printing paste for velvet fabric and preparation method thereof | |
CN104004473A (en) | Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper | |
CN102154852A (en) | Textile machinery printing pigment binding agent and manufacturing method thereof | |
CN102330363B (en) | Temperature-sensitive printing color paste and color-temperature clothing | |
CN102619104B (en) | Active coating imitating printing adhesive and preparation method thereof | |
CN102838953A (en) | Aqueous acrylate emulsion adhesive for paper pearl powder, and preparation method thereof | |
CN103756601B (en) | Metal(lic)powder tackiness agent and preparation method thereof and wallpaper, textiles | |
CN103436129A (en) | Water-based wallpaper polystyrene foam and preparation method thereof as well as wallpaper | |
CN103088674B (en) | Bright film printing paste and preparation method thereof | |
CN102504090A (en) | Binder used for pigment printing of textiles and preparation method thereof | |
CN108411651A (en) | A kind of gold stamping slurry and its preparation method and application | |
CN102532386A (en) | Styrene-acrylate emulsion for primary coating of coating paper | |
CN102643590B (en) | Water-based paint and preparation method thereof | |
CN107083118B (en) | A kind of special-purpose aqueous fiber coating of thermal transfer and preparation method thereof | |
CN105482738A (en) | Special paper-plastic waterborne adhesive for high-speed laminator | |
CN103396746B (en) | A kind of high-performance water-based pressure sensitive adhesive and preparation method thereof | |
CN101942772A (en) | Low-formaldehyde soaping-resistant adhesive for textile pigment printing and preparation method thereof | |
CN103146326A (en) | Emulsion type acrylic ester adhesive for anti-yellowing polishing membrane and preparation method thereof | |
CN103132387B (en) | Leatherette paper dip-dying solution and preparation method of the same | |
CN105482745A (en) | Aqueous dry lamination adhesive and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121010 |