CN105482745A - Aqueous dry lamination adhesive and preparation method thereof - Google Patents
Aqueous dry lamination adhesive and preparation method thereof Download PDFInfo
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- CN105482745A CN105482745A CN201510877431.0A CN201510877431A CN105482745A CN 105482745 A CN105482745 A CN 105482745A CN 201510877431 A CN201510877431 A CN 201510877431A CN 105482745 A CN105482745 A CN 105482745A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses an aqueous dry lamination adhesive and a preparation method thereof. Raw materials of the aqueous dry lamination adhesive comprise styrene, butyl acrylate, isooctyl acrylate, acrylonitrile, N-methylolacrylamide, hydroxyethyl acrylate, acrylic acid, rosin, potassium persulfate, sodium dodecylbenzene sulfonate, isooctyl phenol polyoxyethylene ether, sodium bicarbonate, deionized water, ammonia water, a wetting agent and antifoaming agent. Aqueous latex with a core-shell structure is prepared through a segmented polymerization technology, so functional groups make a substrate and a plastic film be fully bonded, and polymer molecular chains are self-crosslinked, thereby the adhesion and the peeling strength of the substrate are improved, the adhesive has excellent initial adhesion, pressure sensitivity and covering ability, the excellent leveling property and the dynamic wetability of the adhesive make a laminated product have brilliant gloss, and the adhesive can be widely used in paper plastic lamination.
Description
Technical field
The present invention relates to a kind of package printing material, be specifically related to a kind of waterborne dry-type laminated adhesive and preparation method thereof.
Background technology
Dry type laminated adhesive is film one deck sizing agent on a plastic film in paper lamination process; then solvent in this sizing agent or moisture content is removed through the dry baking tunnel of laminating machine; bind with paper printed matter under hot pressing state again, printed matter be attractive in appearance, bright to reach, waterproof, antifouling, increase the provide protections such as the physical strength of paper product, wear-resisting, folding, resistance to chemical attack.Existing composite film material is divided into bright film, Matte film two kinds, and bright film requires level and smooth light, excellent, the non-foaming not delamination of sticking power, and Matte film requires that lid powder ability is strong.At present, the laminated adhesive ACRYLIC EMULSION of typical polymerization can not take into account the requirement of sticking power, first viscous force and stripping strength, usually needs allotment complementary.
Summary of the invention
The present invention is directed to the problems referred to above, a kind of waterborne dry-type laminated adhesive and preparation method thereof is provided.
The technical solution used in the present invention is as follows:
A kind of waterborne dry-type laminated adhesive, it is characterized in that, raw material is made up of following component, the parts by weight of its component are as follows: vinylbenzene 45-65 part, butyl acrylate 90-125 part, Isooctyl acrylate monomer 25-40 part, vinyl cyanide 5-8 part, N hydroxymethyl acrylamide 4-6 part, Hydroxyethyl acrylate 1-5 part, vinylformic acid 3-8 part, rosin 10-25 part, Potassium Persulphate 0.8-2.0 part, dodecylbenzene naphthenic acid sodium 0.8-2.0 part, octane-iso base phenol polyethenoxy ether 3-4.8 part, sodium bicarbonate 0.3-0.5 part, deionized water 200-250 part, ammoniacal liquor 2-4 part, wetting agent 1-3 part, defoamer 1-2 part.
Described rosin is viscosity increaser, can provide good original viscosity, pressure-sensitive and low-temperature adhesion performance.
Described wetting agent is the nonionic organic alkoxy alcohol surfactants with dynamic moisture effect, non-ionic type alkyne diol and the Virahol composition of described defoamer to be mass ratio be 1:1.
A preparation method for waterborne dry-type laminated adhesive, is characterized in that, is made up of following steps:
(1) 25-30 part vinylbenzene, 40-55 part butyl acrylate, 1-5 part Hydroxyethyl acrylate and 0-5 part vinyl cyanide are mixed, obtain mix monomer solution A; 4-6 part N hydroxymethyl acrylamide, 3-8 part vinylformic acid and 20-50 part deionized water are mixed, obtains mix monomer B solution; By 20-35 part vinylbenzene, 50-70 part butyl acrylate, 25-40 part Isooctyl acrylate monomer, 5-8 part vinyl cyanide and 10-25 part rosin mix, and obtain mix monomer C solution;
(2) mix monomer B solution in the step (1) of mix monomer solution A, 10%-15% in the step (1) of 180-200 part deionized water, 3-4.8 part octane-iso base phenol polyethenoxy ether, 0.8-2.0 part dodecylbenzene naphthenic acid sodium, 10%-15% is joined in reactor, stir and obtain mixing solutions after being warming up to 70 ± 2 DEG C, and 0.3-0.5 part sodium bicarbonate and 0.2-0.4 part Potassium Persulphate are added in reactor, control temperature, at 75 ± 1 DEG C, reacts 20-30min;
(3) temperature of reaction kettle is risen to 81 ± 1 DEG C, drip residue mix monomer solution A obtained in step (1), 25%-30% B solution, be dissolved with the aqueous solution of 0.2-0.6 part Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1.5-2h, continue constant temperature in 81 ± 1 DEG C, be incubated 0.5 hour;
(4) continue to be incubated in 81 ± 1 DEG C, drip mix monomer C solution obtained in step (1), remaining B solution and be dissolved with the aqueous solution of 0.4-1.0 part Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1-1.5h, continue constant temperature in 81 ± 1 DEG C, be incubated 1 hour;
(5) lower the temperature, when question response still temperature is down to 40 DEG C, with strainer filtering, add 2-4 part ammoniacal liquor, finally add 1-3 part wetting agent and 1-2 part defoamer stirs, obtain waterborne dry-type laminated adhesive.
The present invention compared with prior art, beneficial effect is: the waterborne dry-type laminated adhesive of preparation adopts the preparation of sectional type polymerization technique to have the water-based latex of nucleocapsid structure, can carry and make the bonding of functional group base material plastic film more fully, also can make, between polymer molecular chain, self-crosslinking occurs simultaneously, thus the sticking power improved base material and stripping strength, there is excellent original viscosity, pressure-sensitive and lid powder ability, the levelling of its excellence and dynamic wettability make the product gloss after overlay film bright-coloured, can be widely used in paper overlay film.
Embodiment
For enabling above-mentioned purpose, the feature and advantage of the application more become apparent, below in conjunction with embodiment, the application is described in further detail.
Embodiment 1:
The preparation method of this routine waterborne dry-type laminated adhesive is prepared as follows:
(1) by 25 parts of vinylbenzene, 40 parts of butyl acrylates and 2 parts of Hydroxyethyl acrylates mix, and obtain mix monomer solution A; 4 parts of N-methylol acryloyls, 3.5 parts of vinylformic acid and 20 parts of deionized waters mix, and obtain mix monomer B solution; 20 parts of vinylbenzene, 55 parts of butyl acrylates, 35 parts of Isooctyl acrylate monomers, 5 parts of vinyl cyanide and 12 parts of rosin mix, and obtain mix monomer C solution;
(2) mix monomer A in the step (1) of 180 parts of deionized waters, 3 parts of octane-iso base phenol polyethenoxy ethers, 0.8 part of dodecylbenzene naphthenic acid sodium and 10%-15% and B solution are joined in reactor, stir and obtain mixing solutions after being warming up to 70 ± 2 DEG C, and 0.3 part of buffer reagent and 0.2 part of Potassium Persulphate are added in reactor, control temperature, at 75 ± 1 DEG C, reacts 20-30min;
(3) temperature of reaction kettle is risen to 81 ± 1 DEG C, drip residue mix monomer solution A obtained in step (1), 25%-30% B solution and be dissolved with the aqueous solution of 0.3 part of Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1.5-2h, continue constant temperature in 81 ± 1 DEG C, be incubated 0.5 hour;
(4) continue to be incubated in 81 ± 1 DEG C, drip mix monomer C solution obtained in step (1), remaining B solution and be dissolved with the aqueous solution of 0.4 part of Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, and time for adding is controlled be added dropwise to complete in 1-1.5h, continue constant temperature in 81 ± 1 DEG C, be incubated 1 hour;
(5) lower the temperature, when question response still temperature is down to 40 DEG C, with strainer filtering, add 2 parts of ammoniacal liquor, finally add 1.5 parts of wetting agents and 1.2 parts of defoamers stir, obtain waterborne dry-type laminated adhesive.
Embodiment 2:
The preparation method of this routine waterborne dry-type laminated adhesive is prepared as follows:
(1) by 28 parts of vinylbenzene, 48 parts of butyl acrylates, 3 parts of Hydroxyethyl acrylates and 3 parts of vinyl cyanide mix, and obtain mix monomer solution A; 5 parts of N-methylol acryloyls, 6 parts of vinylformic acid and 40 parts of deionized waters mix, and obtain mix monomer B solution; 25 parts of vinylbenzene, 65 parts of butyl acrylates, 25 parts of Isooctyl acrylate monomers, 6 parts of vinyl cyanide and 15 parts of rosin mix, and obtain mix monomer C solution;
(2) mix monomer A in the step (1) of 200 parts of deionized waters, 4.0 parts of octane-iso base phenol polyethenoxy ethers, 1.4 parts of dodecylbenzene naphthenic acid sodium and 10%-15% and B solution are joined in reactor, stir and obtain mixing solutions after being warming up to 70 ± 2 DEG C, and 0.4 part of buffer reagent and 0.3 part of Potassium Persulphate are added in reactor, control temperature, at 75 ± 1 DEG C, reacts 20-30min;
(3) temperature of reaction kettle is risen to 81 ± 1 DEG C, drip residue mix monomer solution A obtained in step (1), 25%-30% B solution and be dissolved with the aqueous solution of 0.5 part of Potassium Persulphate, in dropping process, reactor constant temperature controls to be added dropwise to complete in 1.5-2h in 81 ± 1 DEG C of time for addings, continue constant temperature in 81 ± 1 DEG C, be incubated 0.5 hour;
(4) continue to be incubated in 81 ± 1 DEG C, drip mix monomer C solution obtained in step (1), remaining B solution and be dissolved with the aqueous solution of 0.7 part of Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1-1.5h, continue constant temperature in 81 ± 1 DEG C, be incubated 1 hour;
(5) lower the temperature, when question response still temperature is down to 40 DEG C, with strainer filtering, add 2-4 part ammoniacal liquor, finally add 2 parts of wetting agents and 1.5 parts of defoamers stir, obtain waterborne dry-type laminated adhesive.
Embodiment 3:
The preparation method of this routine waterborne dry-type laminated adhesive is prepared as follows:
(1) by 30 parts of vinylbenzene, 55 parts of butyl acrylates, 5 parts of Hydroxyethyl acrylates and 5 parts of vinyl cyanide mix, and obtain mix monomer solution A; 6 parts of N-methylol acryloyls, 8 parts of vinylformic acid and 50 parts of deionized waters mix, and obtain mix monomer B solution; 35 parts of vinylbenzene, 75 parts of butyl acrylates, 40 parts of Isooctyl acrylate monomers, 8 parts of vinyl cyanide and 25 parts of rosin mix, and obtain mix monomer C solution;
(2) mix monomer A in the step (1) of 220 parts of deionized waters, 4.8 parts of octane-iso base phenol polyethenoxy ethers, 1.8 parts of dodecylbenzene naphthenic acid sodium and 10%-15% and B solution are joined in reactor, stir and obtain mixing solutions after being warming up to 70 ± 2 DEG C, and 0.5 part of buffer reagent and 0.4 part of Potassium Persulphate are added in reactor, control temperature, at 75 ± 1 DEG C, reacts 20-30min;
(3) temperature of reaction kettle is risen to 81 ± 1 DEG C, drip residue mix monomer solution A obtained in step (1), 25%-30% B solution and be dissolved with the aqueous solution of 0.8 part of Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1.5-2h, continue constant temperature in 81 ± 1 DEG C, be incubated 0.5 hour;
(4) drip mix monomer C solution obtained in step (1), remaining B solution and be dissolved with the aqueous solution of 1.0 parts of Potassium Persulphates, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1-1.5h, continues constant temperature in 81 ± 1 DEG C, is incubated 1 hour;
(5) lower the temperature, when question response still temperature is down to 40 DEG C, with strainer filtering, add 4 parts of ammoniacal liquor, finally add 3 parts of wetting agents and 2 parts of defoamers stir, obtain waterborne dry-type laminated adhesive.
After testing, its technical indicator of waterborne dry-type laminated adhesive of the present invention is as shown in the table:
As shown above, waterborne dry-type laminated adhesive of the present invention, compared with existing waterborne dry-type laminated adhesive, has better sticking power and stripping strength, and lid powder ability also has lifting.
Claims (4)
1. a waterborne dry-type laminated adhesive, it is characterized in that, raw material is made up of following component, the parts by weight of its component are as follows: vinylbenzene 45-65 part, butyl acrylate 90-125 part, Isooctyl acrylate monomer 25-40 part, vinyl cyanide 5-8 part, N hydroxymethyl acrylamide 4-6 part, Hydroxyethyl acrylate 1-5 part, vinylformic acid 3-8 part, rosin 10-25 part, Potassium Persulphate 0.8-2.0 part, dodecylbenzene naphthenic acid sodium 0.8-2.0 part, octane-iso base phenol polyethenoxy ether 3-4.8 part, sodium bicarbonate 0.3-0.5 part, deionized water 200-250 part, ammoniacal liquor 2-4 part, wetting agent 1-3 part, defoamer 1-2 part.
2. a kind of waterborne dry-type laminated adhesive as claimed in claim 1, is characterized in that, described rosin is viscosity increaser.
3. a kind of waterborne dry-type laminated adhesive as claimed in claim 1, it is characterized in that, described wetting agent is the nonionic organic alkoxy alcohol surfactants with dynamic moisture effect, non-ionic type alkyne diol and the Virahol composition of described defoamer to be mass ratio be 1:1.
4. the preparation method of a kind of waterborne dry-type laminated adhesive as claimed in claim 1, is characterized in that, be made up of following steps:
(1) 25-30 part vinylbenzene, 40-55 part butyl acrylate, 1-5 part Hydroxyethyl acrylate and 0-5 part vinyl cyanide are mixed, obtain mix monomer solution A; 4-6 part N hydroxymethyl acrylamide, 3-8 part vinylformic acid and 20-50 part deionized water are mixed, obtains mix monomer B solution; By 20-35 part vinylbenzene, 50-70 part butyl acrylate, 25-40 part Isooctyl acrylate monomer, 5-8 part vinyl cyanide and 10-25 part rosin mix, and obtain mix monomer C solution;
(2) mix monomer B solution in the step (1) of mix monomer solution A, 10%-15% in the step (1) of 180-200 part deionized water, 3-4.8 part octane-iso base phenol polyethenoxy ether, 0.8-2.0 part dodecylbenzene naphthenic acid sodium, 10%-15% is joined in reactor, stir and obtain mixing solutions after being warming up to 70 ± 2 DEG C, and 0.3-0.5 part sodium bicarbonate and 0.2-0.4 part Potassium Persulphate are added in reactor, control temperature, at 75 ± 1 DEG C, reacts 20-30min;
(3) temperature of reaction kettle is risen to 81 ± 1 DEG C, drip residue mix monomer solution A obtained in step (1), 25%-30% B solution, be dissolved with the aqueous solution of 0.2-0.6 part Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1.5-2h, continue constant temperature in 81 ± 1 DEG C, be incubated 0.5 hour;
(4) continue to be incubated in 81 ± 1 DEG C, drip mix monomer C solution obtained in step (1), remaining B solution and be dissolved with the aqueous solution of 0.4-1.0 part Potassium Persulphate, in dropping process, reactor constant temperature is in 81 ± 1 DEG C, time for adding controls to be added dropwise to complete in 1-1.5h, continue constant temperature in 81 ± 1 DEG C, be incubated 1 hour;
(5) lower the temperature, when question response still temperature is down to 40 DEG C, with strainer filtering, add 2-4 part ammoniacal liquor, finally add 1-3 part wetting agent and 1-2 part defoamer stirs, obtain waterborne dry-type laminated adhesive.
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| CN201510877431.0A CN105482745B (en) | 2015-12-04 | 2015-12-04 | A kind of waterborne dry-type laminated adhesive and preparation method thereof |
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| CN201510877431.0A CN105482745B (en) | 2015-12-04 | 2015-12-04 | A kind of waterborne dry-type laminated adhesive and preparation method thereof |
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| CN105482745B CN105482745B (en) | 2017-11-07 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221618A (en) * | 2016-08-23 | 2016-12-14 | 广州昊江新材料有限公司 | A kind of Adhesive composition and its preparation method and application |
| CN106634722A (en) * | 2016-12-13 | 2017-05-10 | 鹤山市知墨印刷粘合材料有限公司 | Waterborne laminated adhesive and preparation method thereof |
| CN107345121A (en) * | 2017-06-30 | 2017-11-14 | 常州创索新材料科技有限公司 | A kind of overlay film adhesive and preparation method thereof |
| CN109536086A (en) * | 2018-11-14 | 2019-03-29 | 南通高盟新材料有限公司 | Bi-component waterborne styrene-acrylic emulsion adhesive and preparation method thereof for boiling packaging |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101284978A (en) * | 2008-05-06 | 2008-10-15 | 东莞市高埗星宇粘合剂厂 | Waterborne dry-type laminated adhesive and polymerization method threreof |
| CN102492380A (en) * | 2011-12-04 | 2012-06-13 | 汕头市中乾网络科技有限公司 | Paper and plastic laminating adhesive |
| CN104263292A (en) * | 2014-09-03 | 2015-01-07 | 台州学院 | Water-based laminated adhesive and preparation method thereof |
-
2015
- 2015-12-04 CN CN201510877431.0A patent/CN105482745B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101284978A (en) * | 2008-05-06 | 2008-10-15 | 东莞市高埗星宇粘合剂厂 | Waterborne dry-type laminated adhesive and polymerization method threreof |
| CN102492380A (en) * | 2011-12-04 | 2012-06-13 | 汕头市中乾网络科技有限公司 | Paper and plastic laminating adhesive |
| CN104263292A (en) * | 2014-09-03 | 2015-01-07 | 台州学院 | Water-based laminated adhesive and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221618A (en) * | 2016-08-23 | 2016-12-14 | 广州昊江新材料有限公司 | A kind of Adhesive composition and its preparation method and application |
| CN106634722A (en) * | 2016-12-13 | 2017-05-10 | 鹤山市知墨印刷粘合材料有限公司 | Waterborne laminated adhesive and preparation method thereof |
| CN106634722B (en) * | 2016-12-13 | 2019-04-30 | 鹤山市知墨印刷粘合材料有限公司 | A kind of aqueous laminated adhesive and preparation method thereof |
| CN107345121A (en) * | 2017-06-30 | 2017-11-14 | 常州创索新材料科技有限公司 | A kind of overlay film adhesive and preparation method thereof |
| CN109536086A (en) * | 2018-11-14 | 2019-03-29 | 南通高盟新材料有限公司 | Bi-component waterborne styrene-acrylic emulsion adhesive and preparation method thereof for boiling packaging |
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| CN105482745B (en) | 2017-11-07 |
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