CN109235086A - A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof - Google Patents
A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof Download PDFInfo
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- CN109235086A CN109235086A CN201811304967.3A CN201811304967A CN109235086A CN 109235086 A CN109235086 A CN 109235086A CN 201811304967 A CN201811304967 A CN 201811304967A CN 109235086 A CN109235086 A CN 109235086A
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- Prior art keywords
- spare
- vinyltriethoxysilane
- printing adhesive
- adhesive
- deionized water
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Abstract
The invention discloses a kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof, the component material of the vinyltriethoxysilane sealing end printing adhesive includes: butyl acrylate, acrylonitrile, styrene, acrylic acid, vinyltriethoxysilane, acrylamide, peregal, lauryl sodium sulfate, ammonium hydroxide and deionized water.The vinyltriethoxysilane blocks printing adhesive, without using excessive precision instrument, and the reaction condition of high request is not needed, preparation cost is lower, and preparation efficiency is high, cause monomer reaction into polymer using persulfide, so that the adhesive made is free of toxicity, it can be safe to use, and the fastness of the adhesive is good, it is more wear-resisting, meet ecological, environmental protective requirement, is worth of widely use.
Description
Technical field
The present invention relates to chemical technology field, specially a kind of vinyltriethoxysilane sealing end printing adhesive and its
Preparation method.
Background technique
Adhesive is one of most important auxiliary material, using extremely wide in packaging operation, adhesive be have it is viscous
Property substance, by its viscosity can by two kinds separate material link together, there are many type of adhesive, and adhesive is really
The various stress material general names for making identical or different material connect or be bonded, mainly there is liquid, paste and solid-state three types.
Traditional continuously or semi-continuously emulsion polymerization, finally obtained lotion molecule are complicated, it is easy to cause in adhesive
The reaction of portion's ingredient, causes adhesive itself to contain a small amount of toxicity adhesion effect bad, and molecular structure complexity causes production cost
It increases.
Summary of the invention
The purpose of the present invention is to provide a kind of vinyltriethoxysilane to block printing adhesive and preparation method thereof,
To solve traditional continuously or semi-continuously emulsion polymerization mentioned above in the background art, finally obtained lotion molecule is complicated,
It easily causes adhesive internal component to react, causes adhesive itself to contain a small amount of toxicity adhesion effect bad, and molecule knot
The problem of structure complexity causes production cost to increase.
To achieve the above object, the invention provides the following technical scheme: a kind of vinyltriethoxysilane blocks stamp
Adhesive, the component material of vinyltriethoxysilane sealing end printing adhesive include: butyl acrylate, acrylonitrile,
Styrene, acrylic acid, vinyltriethoxysilane, acrylamide, peregal, lauryl sodium sulfate, ammonium hydroxide and deionization
Water.
Preferably, the mixing ratio by weight between each component are as follows:
Preferably, the vinyltriethoxysilane sealing end printing adhesive is prepared by following procedure:
(1) by butyl acrylate, acrylonitrile, styrene, acrylic acid, acrylamide, peregal, lauryl sodium sulfate,
Ammonium hydroxide and deionized water are put into emulsification filling according to component proportion, and deionized water dispersion is added, spare；
(2) step (1) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(3) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(4) step (3) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(5) it takes step (4) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(6) it takes step (5) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(7) 1h, cooling discharge are kept the temperature.
Compared with prior art, the beneficial effects of the present invention are:
1. preparation method of the present invention is relatively simple, without using excessive precision instrument, and the reaction item of high request is not needed
Part, preparation cost is lower, and preparation efficiency is high；
2. material needed for preparation method of the present invention itself is free of toxicity, and reacts between each material and do not generate toxicity, make
Cause monomer reaction into polymer with persulfide, so that the adhesive made is free of toxicity, it can be safe to use, and the bonding
The fastness of agent is good, more wear-resisting, meets ecological, environmental protective requirement, is worth of widely use；
3. adhesive prepared by the present invention is safe and reliable, and quality itself is softer, therefore can be applicable to require very high
Underwear, bedding etc., the scope of application is wider.
Specific embodiment
The embodiment of the present application blocks printing adhesive and preparation method thereof by providing a kind of vinyltriethoxysilane,
Solves traditional continuously or semi-continuously emulsion polymerization, finally obtained lotion molecule is complicated, it is easy to cause inside adhesive
Ingredient reaction, causes adhesive itself to contain a small amount of toxicity adhesion effect bad, and molecular structure complexity causes production cost to add
Big problem.
The present invention provides a kind of technical solution: a kind of vinyltriethoxysilane sealing end printing adhesive, vinyl three
The component material that Ethoxysilane blocks printing adhesive includes: butyl acrylate, acrylonitrile, styrene, acrylic acid, vinyl
Triethoxysilane, acrylamide, peregal, lauryl sodium sulfate, ammonium hydroxide and deionized water.
Preferably, the mixing ratio by weight between each component are as follows:
Preferably, vinyltriethoxysilane sealing end printing adhesive is prepared by following procedure:
(1) by butyl acrylate, acrylonitrile, styrene, acrylic acid, acrylamide, peregal, lauryl sodium sulfate,
Ammonium hydroxide and deionized water are put into emulsification filling according to component proportion, and deionized water dispersion is added, spare；
(2) step (1) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(3) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(4) step (3) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(5) it takes step (4) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(6) it takes step (5) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(7) 1h, cooling discharge are kept the temperature.
In the present invention, monomer reaction is caused at polymer, to obtain nontoxic bonding by using persulfide
Agent, and the bonding effect of adhesive is more preferable.
It is clearly and completely described below in conjunction with the technical solution in the embodiment of the present invention, it is clear that described reality
Applying example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without making creative work belongs to what the present invention protected
Range.
Embodiment one:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
In the present embodiment, vinyltriethoxysilane can improve the dispersion performance of adhesive, tear to improve it
Resistance to spalling, and the adhesive property of rubber and metal, fabric can be improved, keep adhesive effect more preferable.
Embodiment two:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
In the present embodiment, polyacrylamide is water soluble polymer, has good flocculability, can reduce liquid
Frictional resistance between body keeps viscous and effect more preferable to increase the viscosity of the adhesive.
Embodiment three:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
In the present embodiment, by the formulated component of vinyltriethoxysilane and acrylamide, effectively make the bonding
More wear-resisting at the adhesion of agent, service life is wider.
Example IV:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
In the present embodiment, by matching above, the effective humidity resistance and surface smoothness for improving product improves production
Product qualification rate.
Embodiment five:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
In the present embodiment, by matching above, while so that adhesive is had excellent adhering, quality is more soft, makes it
It can be suitable for exigent underwear, bedding etc., the scope of application is wider.
Embodiment six:
A kind of preparation method of vinyltriethoxysilane sealing end printing adhesive, includes the following steps:
(1) each raw material is weighed respectively by following mass percents:
(2) all raw materials in step (1) in addition to silane are put into emulsification filling, deionized water dispersion is added, it is standby
With；
(3) step (2) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
Mix seal after 20min it is spare；
(4) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(5) step (4) is taken to give over to spare solution, by 1/3 emulsion and initiator be added directly into four-hole boiling flask into
Row reaction keeps the temperature 30min, spare；
(6) it takes step (5) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, standby
With；
(7) it takes step (6) to give over to spare solution, vinyltriethoxysilane coupling agent, about 10min drop is slowly added dropwise
It is complete；
(8) 1h, cooling discharge are kept the temperature.
It is larger by the adhesive hardness matched above in the present embodiment, suitable for the bonding of the materials such as plate, and
Bonding effect is more preferable.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
1. a kind of vinyltriethoxysilane blocks printing adhesive, it is characterised in that: the vinyltriethoxysilane
The component material for blocking printing adhesive includes: butyl acrylate, acrylonitrile, styrene, acrylic acid, vinyl triethoxyl silicon
Alkane, acrylamide, peregal, lauryl sodium sulfate, ammonium hydroxide and deionized water.
2. a kind of vinyltriethoxysilane according to claim 1 blocks printing adhesive, it is characterised in that: each
Mixing ratio by weight between component is,
3. a kind of vinyltriethoxysilane according to claim 2 blocks printing adhesive, it is characterised in that: described
Vinyltriethoxysilane, which blocks printing adhesive, to be prepared by following procedure:
(1) by butyl acrylate, acrylonitrile, styrene, acrylic acid, acrylamide, peregal, lauryl sodium sulfate, ammonium hydroxide
It is put into emulsification filling with deionized water according to component proportion, deionized water dispersion is added, it is spare；
(2) step (1) is given over to spare deionized water dispersion to be dispersed with stirring with mixing speed for 2800r/min, is stirred
It is sealed after 20min spare；
(3) portions of de-ionized water and a small amount of emulsifier are put to four-hole boiling flask, is heated to 80 DEG C using water-bath, it is spare；
(4) it takes step (3) to give over to spare solution, 1/3 emulsion and initiator is added directly into four-hole boiling flask and carried out instead
It answers, keeps the temperature 30min, it is spare；
(5) it takes step (4) to give over to spare solution, remaining 2/3 emulsion and initiator is slowly added dropwise, about 2h is dripped off, spare；
(6) it takes step (5) to give over to spare solution, vinyltriethoxysilane coupling agent is slowly added dropwise, about 10min is dripped off；
(7) 1h, cooling discharge are kept the temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811304967.3A CN109235086A (en) | 2018-11-05 | 2018-11-05 | A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811304967.3A CN109235086A (en) | 2018-11-05 | 2018-11-05 | A kind of vinyltriethoxysilane sealing end printing adhesive and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110330592A (en) * | 2019-07-29 | 2019-10-15 | 安徽天润化学工业股份有限公司 | A kind of preparation method for making fragrant adhesive polyacrylamide |
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| US5219969A (en) * | 1991-07-12 | 1993-06-15 | Basf Aktiengesellschaft | Crosslinked copolymers with crosslinkable groups based on acrylic or methacrylic acid, preparation thereof and use thereof |
| CN102718921A (en) * | 2012-06-18 | 2012-10-10 | 百利合化工（中山）有限公司 | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof |
| CN107604698A (en) * | 2017-09-26 | 2018-01-19 | 安踏（中国）有限公司 | A kind of manufacture craft of concentrator, fabric and fabric |
| CN107619449A (en) * | 2017-06-10 | 2018-01-23 | 合肥聚合辐化技术有限公司 | A kind of environment-friendly type high solid content and low viscosity acrylic resin and preparation method thereof |
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2018
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US5219969A (en) * | 1991-07-12 | 1993-06-15 | Basf Aktiengesellschaft | Crosslinked copolymers with crosslinkable groups based on acrylic or methacrylic acid, preparation thereof and use thereof |
| CN102718921A (en) * | 2012-06-18 | 2012-10-10 | 百利合化工（中山）有限公司 | Adhesive emulsion for environment-friendly textile gilding printing paste and preparation method thereof |
| CN107619449A (en) * | 2017-06-10 | 2018-01-23 | 合肥聚合辐化技术有限公司 | A kind of environment-friendly type high solid content and low viscosity acrylic resin and preparation method thereof |
| CN107604698A (en) * | 2017-09-26 | 2018-01-19 | 安踏（中国）有限公司 | A kind of manufacture craft of concentrator, fabric and fabric |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110330592A (en) * | 2019-07-29 | 2019-10-15 | 安徽天润化学工业股份有限公司 | A kind of preparation method for making fragrant adhesive polyacrylamide |
| CN110330592B (en) * | 2019-07-29 | 2021-07-30 | 安徽天润化学工业股份有限公司 | Preparation method of polyacrylamide for fragrant adhesive |
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Application publication date: 20190118 |
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