CN104371466A - Water-based colourful slice coating and preparation method thereof - Google Patents

Water-based colourful slice coating and preparation method thereof Download PDF

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Publication number
CN104371466A
CN104371466A CN201410627028.8A CN201410627028A CN104371466A CN 104371466 A CN104371466 A CN 104371466A CN 201410627028 A CN201410627028 A CN 201410627028A CN 104371466 A CN104371466 A CN 104371466A
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CN
China
Prior art keywords
water
sliver
multicolor finish
control
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410627028.8A
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Chinese (zh)
Inventor
许栋
戴殿峰
陈勇桦
胡小萍
边界
易丽君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGXI JINGXIN PAINT INDUSTRY CO LTD
Original Assignee
JIANGXI JINGXIN PAINT INDUSTRY CO LTD
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Publication date
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Priority to CN201410627028.8A priority Critical patent/CN104371466A/en
Publication of CN104371466A publication Critical patent/CN104371466A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Abstract

The invention discloses water-based colourful slice coating and a preparation method thereof. The water-based colourful slice coating is prepared from the following components by mass percent: 1-3% of a film formation auxiliary, 0.1-0.15% of a pH value conditioning agent, 30-40% of emulsion, 30-40% of water, 0.1-0.2% of a wetting agent, 1-1.5% of propylene glycol, 0.1-0.2% of a sterilization preservative, 0.2-0.3% of a defoaming agent, 1-2% of a thickening agent and 20-25% of compound slice. The prepared water-based colourful coating is high in durability and has highly vivid stone-like effect and high durability using effect, manual ageing resistance of the water-based colourful coating is five times of standard manual ageing resistance, the preparation method is simple, and production cost is low.

Description

Water-based sliver multicolor finish and preparation method thereof
technical field:
The present invention relates to water-borne coatings and preparation method thereof, particularly relate to a kind of water-based sliver multicolor finish and preparation method thereof.
background technology:
Along with development and the refinement of domestic coating industry, market is also more and more outstanding for special functional requirement, and the requirement wherein for the water-soluble colorful coating of imitative stone effect is also day by day urgent.But current most of producer is only confined to the emphasis for imitative stone effect, and the emphasis for the high-durability of stone material is extremely short of.And client really pursues is the stone-intimating construction finishing material that appearance effect and durable degree match.
How to produce the coating with the stone-intimating construction finishing material that appearance effect and durable degree match, to meet this type of market requirement, and have the height durable water-based sliver multicolor finish having high imitative stone effect true to nature and the durable result of use of height concurrently simultaneously.
summary of the invention:
The present invention discloses a kind of water-soluble colorful coating and preparation method thereof, its water-soluble colorful coating produced is the height durable water-based sliver multicolor finish having high imitative stone effect true to nature and the durable result of use of height concurrently, and its artificial ageing-resistant performance, reaches 5 times of standard, preparation method is simple, and cost of manufacture is low.
A kind of water-soluble colorful coating of the present invention, comprises following quality and forms than component:
Film coalescence aid 1-3%,
PH value regulator 0.1-0.15%,
Emulsion 30-40%,
Water 30-40%,
Wetting agent 0.1-0.2%,
Propylene glycol 1-1.5%,
Fungicidal preservative 0.1-0.2%,
Defoamer 0.2-0.3%,
Thickening material 1-2%,
Compound sliver 20-25%;
Described film coalescence aid is alcohol ester 12.
A kind of water-soluble colorful coating of the present invention, pH value regulator described in it is AMP-95 or AMP-95 and/or oxysuccinic acid; Be preferably AMP-95.
Emulsion of the present invention is preferably fluorine-silicon modified acrylic emulsion.
This emulsion is preferably special, can with compound sliver can be friendly compatible emulsion, in weathering resistance He in alkali-resistivity, have particular requirement.
Wetting agent of the present invention is common aqueous wetting agent, and described wetting agent is preferably PE-100.
Fungicidal preservative of the present invention is efficient fungicidal preservative, as the A26 etc. of German Shu Mei.
Compound sliver of the present invention is the colorful compound sliver of sliver, is preferably the lightweight compound sliver of the high durable of shades of colour collocation.
A kind of method preparing water-based sliver multicolor finish of the present invention, carry out as follows:
1) first compound sliver is made slurry,
2) water, emulsion, wetting agent, propylene glycol, fungicidal preservative, defoamer are dropped into and be placed in whipping appts, control under lower-speed state, stir 2-3 minute, reach uniform state, then add film coalescence aid and pH value regulator neutralization slowly, make alkaline mixed solution;
3) under lower-speed state, to stir and slow in 2 gradually) add the thickening material of formula ratio in the alkaline mixed solution of step, thickening is stirred, and forms mixed phase;
4) 3) after step adds thickening material, high-speed stirring is carried out to formation mixed phase, and to control stirring velocity be more than 800 revs/min, controls churning time 15-20 minute, make the g., jelly-like that mixed phase reaches even, unified;
5) by 1) the compound sliver slurry that makes of step, and 4) the g., jelly-like material made of step is uniformly mixed, and controls stirring velocity, mix under Ultra-Low Speed state, control mixing time 15-20 minute, make water-soluble colorful coating.
The method preparing water-based sliver multicolor finish of the present invention, preferably the stirring velocity of the described whipping appts of control is its stirring velocity of control at lower-speed state is 500-600 rev/min, and Ultra-Low Speed state is its stirring velocity of control is 50-100 rev/min.
Method of the present invention, controls 2) to control its pH be 8-10 to alkaline mixed solution described in step.
The present invention's water used preferably adopts deionized water.
Each component raw material of the present invention is all by commercially available acquisition.
Fungicidal preservative as used in the present invention adopts inorganic or organic bactericide sanitas, as the hypochlorite of inorganic fungicidal preservative, and clorox, potassium etc.Organic bactericide sanitas as the MBT of organosulfur, 2,2 two bromo-malonamide nitriles of organic bromine; BTT of heterogeneous ring compound etc.
Fungicidal preservative of the present invention, also can be efficient fungicidal preservative, as the A26 etc. of German Shu Mei company; Defoamer, can select polyethers defoamer, or mineral oil defoaming agent, as the NXZ etc. of Japanese Nuo Puke company; Thickening material, selects the thickening material etc. that synthetic macromolecular compound is as swelling in alkali such as the ASE-60 of LG-DOW.
Defoamer, also can select polyethers defoamer, and high-carbon alcohols is if anions and canons tensio-active agent and nonionogenic tenside etc. are as Laurate alcohol ester phenylacetate etc.
Thickening material, also can select synthetic macromolecular compound as polyvinyl alcohol, styrene-butadiene rubber(SBR) etc.; The white carbon black of inorganic thickening agent or wilkinite, diatomite etc.
The present invention's compound sliver used is preferably colorful compound sliver, can select a kind of 1-12 ㎜ size, and thickness is the softness of 0.3 ㎜ and resilient irregular molectron, all uses natural inorganic elements material composition.
To the construction usage method of height of the present invention durable water-based sliver multicolor finish be: packaged for the invention described above height durable water-based sliver multicolor finish product is loaded spray gun special after stirring, start air compressor machine, make spray pressure control to be 4-6kg/cm at 0.4-0.6MPa 2, nozzle diameter is generally 6-8mm, opens spray gun, from top to bottom even application one time, then sprays one time from left to right, and the distance of spray gun and metope is about 30-40cm, and spray gun and metope should be made in spraying to keep vertical.Theoretical glue spread is 1.2-1.8kg/m 2, concrete used in amounts is determined according to concrete paint film effect and basic unit's situation.
The durable water-based sliver multicolor finish product utilizing the inventive method to prepare, detects through the chemical building material quality Supervision Test Center of country, and every technical performance index all reaches or higher than the company standard of country or industry standard.Particularly artificial ageing-resistant performance reaches 5 times of standard, and relevant national standard is 500h, and product of the present invention after testing sample reaches more than 2500h, and concrete detected result is in table 1.Meanwhile, its imitative stone effect is very true to nature.
Product of the present invention detects all technical through the chemical building material quality Supervision Test Center of country and all reaches requirement;
Test basis: JG/T24-2000,
Assay is as following table 1.
Table 1, technical target of the product:
Illustrate: the artificial ageing-resistant performance of the product that the present invention produces reaches 5 times of standard, and relevant national standard is 500h, and product of the present invention after testing sample reaches more than 2500h.
embodiment:below in conjunction with specific embodiment, the invention will be further described.
embodimentas follows:
Illustrate: each component of the present invention is all by commercially available acquisition.

Claims (8)

1. a water-based sliver multicolor finish, comprises following quality and forms than component:
Film coalescence aid 1-3%,
PH value regulator 0.1-0.15%,
Emulsion 30-40%,
Water 30-40%,
Wetting agent 0.1-0.2%,
Propylene glycol 1-1.5%,
Fungicidal preservative 0.1-0.2%,
Defoamer 0.2-0.3%,
Thickening material 1-2%,
Compound sliver 20-25%;
Described film coalescence aid is alcohol ester 12.
2., according to a kind of water-based sliver multicolor finish according to claim 1, it is characterized in that described pH value regulator is AMP-95 or AMP-95 and/or oxysuccinic acid.
3., according to a kind of water-based sliver multicolor finish according to claim 1, it is characterized in that described emulsion is fluorine-silicon modified acrylic emulsion.
4., according to a kind of water-based sliver multicolor finish according to claim 1, it is characterized in that described wetting agent is preferably PE-100.
5. according to a kind of water-soluble colorful coating according to claim 1, it is characterized in that described compound sliver is colorful compound sliver, is the lightweight compound sliver of the high durable of shades of colour collocation.
6. prepare a method for water-based sliver multicolor finish according to claim 1, carry out as follows:
1) first compound sliver is made slurry;
2) water, emulsion, wetting agent, propylene glycol, fungicidal preservative, defoamer are dropped into and be placed in whipping appts, control under lower-speed state, stir 2-3 minute, reach uniform state, then slowly add film coalescence aid and pH value regulator neutralization, make alkaline mixed solution;
3) under lower-speed state, to stir and slow in 2 gradually) add the thickening material of formula ratio in the alkaline mixed solution of step, thickening is stirred, and forms mixed phase;
4) 3) after step adds thickening material, high-speed stirring is carried out to formation mixed phase, and to control stirring velocity be more than 800 revs/min, controls churning time 15-20 minute, make the g., jelly-like that mixed phase reaches even, unified;
5) by 1) the compound sliver slurry that makes of step, and 4) the g., jelly-like material made of step is uniformly mixed, and controls stirring velocity, mix under Ultra-Low Speed state, control mixing time 15-20 minute, make water-soluble colorful coating.
7. according to the method preparing water-based sliver multicolor finish according to claim 6, the stirring velocity that it is characterized in that controlling described whipping appts is that to control its stirring velocity be 500-600 rev/min at lower-speed state, and Ultra-Low Speed state is that to control its stirring velocity be 50-100 rev/min.
8., according to the method preparing water-based sliver multicolor finish according to claim 7, it is characterized in that 2) to control its pH be 8-10 to alkaline mixed solution described in step.
CN201410627028.8A 2014-11-10 2014-11-10 Water-based colourful slice coating and preparation method thereof Pending CN104371466A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410627028.8A CN104371466A (en) 2014-11-10 2014-11-10 Water-based colourful slice coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410627028.8A CN104371466A (en) 2014-11-10 2014-11-10 Water-based colourful slice coating and preparation method thereof

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Publication Number Publication Date
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086713A (en) * 2015-09-09 2015-11-25 山东秦恒科技有限公司 Composite waterborne multi-color architectural coating and preparation method thereof
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105482582A (en) * 2015-12-09 2016-04-13 无锡市海轮涂料有限公司 Novel high-efficiency wet-surface antibacterial paint, and preparation method thereof
CN106966681A (en) * 2017-02-21 2017-07-21 河北晨阳工贸集团有限公司 A kind of colorful sliver paint of inorganic thermal insulation and preparation method thereof
CN109162417A (en) * 2018-08-03 2019-01-08 吉安天晟新材料有限公司 A kind of imitative stone polychrome finish and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250377A (en) * 2008-03-04 2008-08-27 杭州森乐士涂料有限公司 Granite stone paint and preparation method thereof
CN104130656A (en) * 2014-07-28 2014-11-05 桐乡市屠甸天虹涂料厂 Granite-simulative multi-color paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250377A (en) * 2008-03-04 2008-08-27 杭州森乐士涂料有限公司 Granite stone paint and preparation method thereof
CN104130656A (en) * 2014-07-28 2014-11-05 桐乡市屠甸天虹涂料厂 Granite-simulative multi-color paint and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086713A (en) * 2015-09-09 2015-11-25 山东秦恒科技有限公司 Composite waterborne multi-color architectural coating and preparation method thereof
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105219195B (en) * 2015-09-30 2018-07-31 三棵树涂料股份有限公司 A kind of compound sliver paint of aqueous colorful and preparation method thereof
CN105482582A (en) * 2015-12-09 2016-04-13 无锡市海轮涂料有限公司 Novel high-efficiency wet-surface antibacterial paint, and preparation method thereof
CN106966681A (en) * 2017-02-21 2017-07-21 河北晨阳工贸集团有限公司 A kind of colorful sliver paint of inorganic thermal insulation and preparation method thereof
CN109162417A (en) * 2018-08-03 2019-01-08 吉安天晟新材料有限公司 A kind of imitative stone polychrome finish and preparation method thereof

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Application publication date: 20150225