CN103250732A - Synergistic pesticide composition for killing scale insects - Google Patents
Synergistic pesticide composition for killing scale insects Download PDFInfo
- Publication number
- CN103250732A CN103250732A CN2013101580724A CN201310158072A CN103250732A CN 103250732 A CN103250732 A CN 103250732A CN 2013101580724 A CN2013101580724 A CN 2013101580724A CN 201310158072 A CN201310158072 A CN 201310158072A CN 103250732 A CN103250732 A CN 103250732A
- Authority
- CN
- China
- Prior art keywords
- pesticide composition
- red
- spotted lizard
- synergetic pesticide
- synergistic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a synergistic pesticide composition for killing scale insects. The synergistic pesticide composition is prepared by taking abamectin and a synergist component as active components and combining the active components with aids, wherein the synergistic component is alkoxy trisiloxane or fatty alcohol-polyoxyethylene ether; and the weight ratio of the abamectin to the synergistic component is (1:1)-(1:5000). The pesticide composition has the advantages of having obvious synergistic effect, improving the effect for preventing scale insects and reducing drug dosage and has great significance to the protection of orchard ecological environment and green prevention and control of the scale insects.
Description
Technical field
The present invention relates to a kind of synergetic pesticide composition, be specially the composition pesticide that kills a red-spotted lizard class pest that contains Avermectin, and the application of this composition pesticide in agricultural, forestry.
Technical background
Cause harm in China that a red-spotted lizard class pest of fruit tree and forest mainly comprises white mulberry scale, san jose scale, tells the hard a red-spotted lizard of human relations ball, jujube ball a red-spotted lizard, olive slice armored scale, moire a red-spotted lizard, Acer negundo a red-spotted lizard, lose sharp a red-spotted lizard etc.The a red-spotted lizard class pest woody plants such as fruit tree, forest of causing harm usually cause tree vigo(u)r weak, and branch is withered, and the result reduces, and output descends, and the gently then underproduction is heavy then total crop failure also makes the product qualitative change bad simultaneously, the commodity rate reduction.Because a red-spotted lizard class pest has the periostracum protection in the middle and later periods of causing harm more, and is strong to the autoprotection sexuality.Produce at present to go up uses the middle high-toxic pesticides that contain the organic phosphates insect killing substance to be used for control more.Because the medicament permeability of using is not strong, effectively insect killing substance is difficult to contact protected a red-spotted lizard class pest polypide, and control efficiency is unsatisfactory, and bigger to the environmental destruction in orchard.
Summary of the invention
The invention provides and a kind ofly prevent and treat agricultural and forestry a red-spotted lizard class pest has the composition pesticide of synergistic effect.This composition pesticide has obvious synergistic effect, has overcome the deficiency of existing Prevention Technique, has improved the control efficiency to a red-spotted lizard class pest, has reduced the medicament usage amount, and is significant to protection orchard ecology and green prevention and control a red-spotted lizard class pest.
Employing has highly active insecticide to a red-spotted lizard class pest and carries out composite with the auxiliary agent with the strong infiltration of high synergy, the inventor is by a large amount of screening tests, after finding that Avermectin and alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether are used with, the a red-spotted lizard class pest is shown obvious synergistic effect, can effectively reduce the dosage of control a red-spotted lizard class pest, be particularly useful for the green high-efficient prevention and control of a red-spotted lizard class pest.
A kind of synergetic pesticide composition that kills a red-spotted lizard class pest is active component with Avermectin and synergistic component, combines with carrier and auxiliary agent, and the ratio of weight and number of described Avermectin and synergistic component is 1:1-1:5000.
Described synergistic component is alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether.Wherein the alkoxyl trisiloxanes can be one or more of Greenwet3710, Greenwet BP, Silwet408, Silwet806, Silwet618, organic silicon surfactants such as Silwet625, SilwetL-77.
The formulation that described synergetic pesticide composition can be made into is microemulsion, missible oil, wetting powder.
Described active component sum accounts for the 0.01-99% of synergetic pesticide composition gross weight.
Synergetic pesticide composition of the present invention can or manually be smeared the habitat that soup is handled woody plant a red-spotted lizard class pests such as fruit tree, forest by the apparatus spraying, is used for control white mulberry scale, san jose scale, tells a red-spotted lizard class pests such as the hard a red-spotted lizard of human relations ball, the big ball a red-spotted lizard of jujube, olive slice armored scale, moire a red-spotted lizard, Acer negundo a red-spotted lizard.
The present invention also provides the preparation method who kills the synergetic pesticide composition of a red-spotted lizard class pest.
Described synergistic composition is that the technical scheme one of microemulsion is:
Solvent and cosolvent have one or more the mixture in methyl alcohol, ethanol, butanols, ethylene glycol, propane diols, glycerine, polyethylene glycol, acetone, cyclohexanone, pyrrolidones, toluene, dimethylbenzene, ethyl acetate, dimethyl formamide (DMF), the dimethyl alum (DMSO).
Emulsifier is alkylbenzene naphthalene sulfonate, alkylphenol polyoxyethylene phosphate, diphenyl phenol polyethenoxy polyethenoxy ether, styrenated phenol APEO, alkylphenol polyoxyethylene formaldehyde condensation products, diphenyl phenol polyethenoxy polyformaldehyde condensation product, castor oil ethylene oxide adduct and derivative thereof, for example farming breast 300, farming breast 500, farming breast 600, Nongru-700, agricultural newborn Sorp1KS, OX2511, NNO, NP series etc., emulsifier can be one or more mixture.
Antifreezing agent has one or more the mixture in ethylene glycol, propane diols, glycerine, polyethylene glycol, the sorbierite.
Stabilizing agent can be one or more the mixture in urea, methyl alcohol, soluble starch, sodium sorbate, pyrogallic acid, aminobenzoic acid, cresyl glycidyl ether, the phenyl glycidyl ether.
The concrete production stage of microemulsion adds the oily liquids that becomes transparent and homogeneous after emulsifier, antifreezing agent, stabilizing agent stir after the dissolving fully again for earlier active ingredient Avermectin and alkoxyl trisiloxanes being added in the cosolvent, can namely makes the microemulsion formulation of synergistic composition of the present invention.
Described synergistic composition is that the technical scheme two of microemulsion is:
The concrete production stage of microemulsion adds the oily liquids that becomes transparent and homogeneous after emulsifier, antifreezing agent, stabilizing agent stir after the dissolving fully again for earlier active ingredient Avermectin and fatty alcohol-polyoxyethylene ether being added in the cosolvent, can namely makes the microemulsion formulation of synergistic composition of the present invention.
Described synergistic composition is that the technical scheme one of missible oil is:
Conventional emulsifier has one or more among Nongru-700, farming breast 401, farming breast 300, farming breast 600, farming breast 1602, agricultural newborn 0203B, agricultural newborn 0201B, the agricultural newborn OX2568,6201,2201.
The concrete production stage of this missible oil is for will adding the oily liquids that the even back of emulsifier for mixing becomes transparent and homogeneous again after the dissolving fully in active ingredient Avermectin and the fatty alcohol-polyoxyethylene ether adding cosolvent earlier, can namely makes the cream preparation of synergistic composition of the present invention.
Described synergistic composition is that the technical scheme two of missible oil is:
The concrete production stage of this missible oil is for will adding the oily liquids that the even back of emulsifier for mixing becomes transparent and homogeneous again after the dissolving fully in active ingredient Avermectin and the fatty alcohol-polyoxyethylene ether adding solvent earlier, can namely makes the cream preparation of synergistic composition of the present invention.
Described synergistic composition is that the technical scheme of wetting powder is:
Dispersant is sodium lignin sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products, nekal, polyoxyethylene polyoxypropylene base ether charcoal down section copolymer, the alkylphenol-polyethenoxy phosphoric acid fat of lignosulfonates and collapses among the outstanding DK8 one or more.
Wetting agent is sodium alkyl benzene sulfonate, fatty acid sulphate, bay alcohol radical sulphate, alkylphenol polyoxyethylene, moistening penetrating agent JFC, the withered powder of tea, spaonin powder, draw back a kind of in the powder.
Filler is one or more mixture of atlapulgite, clay, talcum powder, bentonite, precipitated calcium carbonate, kaolin, montmorillonite, diatomite, attapulgite, white carbon etc.
Stabilizing agent is one or more in alkyl phosphate and alkoxide, fatty acid polyoxy alkane alkene ester, phosphate and radical derivative, polyethylene glycol, glycerine, Isopropanediol, the tricresyl phosphate butyrite.
The concrete production stage of this wetting powder is that above-mentioned each composition mixes, and evenly stirs in stirred tank, after airslide disintegrating mill mixes, namely can be made into the wetting powder of this bright described synergistic composition.
Embodiment
The inventor finds Avermectin and is mixed as the alkoxyl trisiloxanes of synergist or fatty alcohol-polyoxyethylene ether that the control white mulberry scale is had synergistic effect, and the present invention is further illustrated in conjunction with the embodiments in the present invention, but the present invention is not limited thereto.
The synergy test of Avermectin and alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether.
Medicament preparation: the former medicinal acetone of Avermectin or dimethyl sulfoxide (DMSO) dilution are the high concentration mother liquor, and then with 0.05% Qu Latong x-100 solution as solvent, method according to geometric ratio or equal difference is the soup of Different Weight concentration with the reagent agent dilution again, and with 0.05% Qu Latong x-100 solution-treated in contrast, determine that Avermectin is to the lethal concentration of 50 LC50 of white mulberry scale.
Laboratory test method: fetch the branch that has the white mulberry scale larva in the field, behind the cleaning foreign material, in different soups, soak 5-10s, every concentration repeats 4 times, and at indoor feeding, each processing lethality of statistics behind the 2-4d, lethality and correcting controling effect calculate by following formula.Synergetic pesticide composition in indoor toxic action data to a red-spotted lizard class pest referring to table 1.
Field trial method: serve as that pharmacy test is carried out in contrast with clear water and 1.8% abamectin emulsifiable concentrate.The white mulberry scale nymph based on 2 ages at the beginning of nymph.Utilize knapsack hand sprayer that each is handled even spraying, till processed limb is all squirted.Behind the medicine 4 days, 3 fruit trees of every residential quarter investigation were gathered the branch that has the white mulberry scale nymph, take back indoor statistics lethality and correcting controling effect.Synergetic pesticide composition in the field to the toxic action data of a red-spotted lizard class pest referring to table 2.
Embodiment 1:
0.9g Avermectin, 0.9g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 4g dimethyl sulfoxide (DMSO), 7g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.The medicament that makes is diluted 4500 times, is contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 2:
0.01g Avermectin, 25g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 6g dimethyl sulfoxide (DMSO), 15g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.The medicament that makes is diluted 50 times, is contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 3:
0.01g Avermectin, 50g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.The medicament that makes is diluted 50 times, is contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 4:
0.1g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.The medicament that makes is diluted 500 times, is contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 5:
0.01g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.The medicament that makes is diluted 50 times, is contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 6:
0.01g Avermectin, 50g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 50 times of medicament dilutions, be contrast with clear water and 1.8% abamectin emulsifiable concentrate.According to above-mentioned laboratory test method white mulberry scale is done synergism experiment, the toxic action data are referring to table 1.
Embodiment 7:
0.9g Avermectin, 0.9g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 4g dimethyl sulfoxide (DMSO), 7g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition.With 4500 times of synergistic combination dilutions, adopt spraying to handle.According to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Embodiment 8:
0.01g Avermectin, 25g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 6g dimethyl sulfoxide (DMSO), 15g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 50 times of medicament dilutions, according to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Embodiment 9:
0.01g Avermectin, 50g alkoxyl trisiloxanes (Silwet408), 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 50 times of medicament dilutions, according to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Embodiment 10:
0.1g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 500 times of medicament dilutions, according to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Embodiment 11:
0.01g Avermectin, 25g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 50 times of medicament dilutions, according to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Embodiment 12:
0.01g Avermectin, 50g fatty alcohol-polyoxyethylene ether, 15g cyclohexanone, 8g dimethyl sulfoxide (DMSO), 20g farm chemical emulgent 0203B number, 4g ethylene glycol, 2g methyl alcohol, water are supplied 100g, mix strongly and homogenize, obtain the microemulsion formulation of synergistic composition, with 50 times of medicament dilutions, according to above-mentioned field trial method white mulberry scale is done synergism experiment, the toxic action data are referring to table 2.
Table 1 is that the indoor measurement synergetic pesticide composition is to the toxic action data of a red-spotted lizard class pest.
Table 2 is the toxic action data of field test synergetic pesticide composition to a red-spotted lizard class pest.
Claims (7)
1. synergetic pesticide composition that kills a red-spotted lizard class pest, it is characterized in that, described synergetic pesticide composition is active component with Avermectin and synergistic component, combines with carrier and auxiliary agent, and the ratio of weight and number of described Avermectin and synergistic component is 1:1-1:5000.
2. synergetic pesticide composition according to claim 1 is characterized in that, described synergistic component is alkoxyl trisiloxanes or fatty alcohol-polyoxyethylene ether.
3. synergetic pesticide composition according to claim 1 is characterized in that, described synergetic pesticide composition is microemulsion, missible oil, wetting powder.
4. according to any described synergetic pesticide composition of claim 1 to 3, it is characterized in that described active component sum accounts for the 0.01-99% of synergetic pesticide composition gross weight.
5. synergetic pesticide composition according to claim 1 is characterized in that, described synergetic pesticide composition is by the apparatus spraying or manually smear a red-spotted lizard class pest of soup control woody plant.
6. synergetic pesticide composition according to claim 1 is characterized in that, described woody plant is fruit tree or forest.
7. synergetic pesticide composition according to claim 1 is characterized in that, described a red-spotted lizard class pest is white mulberry scale, san jose scale, tell the hard a red-spotted lizard of human relations ball, the big ball a red-spotted lizard of jujube, olive slice armored scale, moire a red-spotted lizard or Acer negundo a red-spotted lizard.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310158072.4A CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310158072.4A CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103250732A true CN103250732A (en) | 2013-08-21 |
| CN103250732B CN103250732B (en) | 2015-05-20 |
Family
ID=48955246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310158072.4A Active CN103250732B (en) | 2013-05-02 | 2013-05-02 | Synergistic pesticide composition for killing scale insects |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103250732B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719622A (en) * | 2016-11-25 | 2017-05-31 | 广东省农业科学院植物保护研究所 | A kind of pesticide synergistic decrement agent |
| CN107821428A (en) * | 2017-11-15 | 2018-03-23 | 惠州市永耐宝新材料有限公司 | A kind of composite synergistic agricultural chemicals |
| CN108781932A (en) * | 2018-05-22 | 2018-11-13 | 广西昭平县古书茶业有限公司 | A kind of control method of the tea tree a red-spotted lizard class pest of tea tree |
| CN110754484A (en) * | 2019-09-27 | 2020-02-07 | 贵州省果树科学研究所 | Mulberry scale control method for reducing pesticide residues in dragon orchard |
| CN113349226A (en) * | 2021-05-26 | 2021-09-07 | 仲恺农业工程学院 | Application of rose oil in pest control |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101502266A (en) * | 2009-03-27 | 2009-08-12 | 郭正 | Liquid pesticide formulation containing avermectin pesticide and organosilicon surfactant and preparation method thereof |
| CN101564036A (en) * | 2009-04-08 | 2009-10-28 | 陶钧炳 | Abamectin-containing aqueous emulsion |
| CN102599175A (en) * | 2008-12-31 | 2012-07-25 | 浙江世佳科技有限公司 | Emulsifiable concentrate of propylene glycol alginate and avermectin |
-
2013
- 2013-05-02 CN CN201310158072.4A patent/CN103250732B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102599175A (en) * | 2008-12-31 | 2012-07-25 | 浙江世佳科技有限公司 | Emulsifiable concentrate of propylene glycol alginate and avermectin |
| CN101502266A (en) * | 2009-03-27 | 2009-08-12 | 郭正 | Liquid pesticide formulation containing avermectin pesticide and organosilicon surfactant and preparation method thereof |
| CN101564036A (en) * | 2009-04-08 | 2009-10-28 | 陶钧炳 | Abamectin-containing aqueous emulsion |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719622A (en) * | 2016-11-25 | 2017-05-31 | 广东省农业科学院植物保护研究所 | A kind of pesticide synergistic decrement agent |
| CN106719622B (en) * | 2016-11-25 | 2020-10-27 | 广东省农业科学院植物保护研究所 | Pesticide synergistic decrement agent |
| CN107821428A (en) * | 2017-11-15 | 2018-03-23 | 惠州市永耐宝新材料有限公司 | A kind of composite synergistic agricultural chemicals |
| CN108781932A (en) * | 2018-05-22 | 2018-11-13 | 广西昭平县古书茶业有限公司 | A kind of control method of the tea tree a red-spotted lizard class pest of tea tree |
| CN110754484A (en) * | 2019-09-27 | 2020-02-07 | 贵州省果树科学研究所 | Mulberry scale control method for reducing pesticide residues in dragon orchard |
| CN110754484B (en) * | 2019-09-27 | 2021-05-25 | 贵州省果树科学研究所 | Mulberry scale control method for reducing pesticide residues in dragon orchard |
| CN113349226A (en) * | 2021-05-26 | 2021-09-07 | 仲恺农业工程学院 | Application of rose oil in pest control |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103250732B (en) | 2015-05-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104663679B (en) | A kind of insecticide acaricide composition containing macrolide insecticide | |
| CN103518764B (en) | Acaricidal composition and application thereof | |
| CN103250732B (en) | Synergistic pesticide composition for killing scale insects | |
| CN101352167B (en) | Pesticide composition based on nitenpyram | |
| CN101380008A (en) | Disinsection composition with synergistic action | |
| CN101743970A (en) | Cyhalofop-butyl-containing pesticide composition and application thereof | |
| CN101700039A (en) | Rynaxypyr and dursban insecticidal composition | |
| CN103155929B (en) | Binary pesticide composition and application thereof | |
| CN103053554B (en) | Wheat paddock weeding composition | |
| CN103518729A (en) | Insecticidal acaricidal composition and application thereof | |
| CN102265836A (en) | Acaricide composition containing spirodiclofen and etoxazole and application thereof | |
| CN102302038A (en) | Weedicide for orchards and forest lands | |
| CN101617676B (en) | Pesticide compound | |
| CN102265889B (en) | Acaricide composition containing spirodiclofen and hexythiazox and application thereof | |
| CN104996458B (en) | Composition pesticide and its application | |
| CN103250713B (en) | Synergistic pesticide composition for killing gall midge insects | |
| CN103651506B (en) | A kind of Pesticidal combination containing penta pyrrole worm guanidine and nimbin | |
| CN104397011B (en) | Insect-killing mite-killing agent composition with synergic effect | |
| CN101263824A (en) | Insecticidal composition | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN101180964A (en) | Insecticidal composition | |
| CN102771494A (en) | Insecticidal composition containing Guadipyr and macrolide pesticide | |
| CN103070190B (en) | Combination used for preventing and removing weed in paddy field | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN103503896A (en) | Insecticide composition having synergistic effect |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |