CN103214905A - Thermochromic heat insulation coating and preparation method thereof - Google Patents
Thermochromic heat insulation coating and preparation method thereof Download PDFInfo
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- CN103214905A CN103214905A CN2013101354329A CN201310135432A CN103214905A CN 103214905 A CN103214905 A CN 103214905A CN 2013101354329 A CN2013101354329 A CN 2013101354329A CN 201310135432 A CN201310135432 A CN 201310135432A CN 103214905 A CN103214905 A CN 103214905A
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- insulating coating
- thermal insulating
- temperature sensing
- paint
- color changing
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- 238000000576 coating method Methods 0.000 title claims abstract description 62
- 239000011248 coating agent Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000009413 insulation Methods 0.000 title abstract description 13
- 239000003973 paint Substances 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 37
- 239000000839 emulsion Substances 0.000 claims abstract description 23
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 230000002441 reversible effect Effects 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000012752 auxiliary agent Substances 0.000 claims description 18
- 239000013530 defoamer Substances 0.000 claims description 15
- 230000008719 thickening Effects 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 238000004581 coalescence Methods 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- -1 frostproofer Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 238000002845 discoloration Methods 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 239000011796 hollow space material Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000004005 microsphere Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 235000010215 titanium dioxide Nutrition 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 239000000049 pigment Substances 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 238000000227 grinding Methods 0.000 abstract description 2
- 238000004537 pulping Methods 0.000 abstract 6
- 239000000945 filler Substances 0.000 abstract 2
- 238000005034 decoration Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012782 phase change material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y02P20/121—
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a thermochromic heat insulation coating prepared from the following components in percentage by weight: 32-52% of pigment and filler, 2-10% of pulping solvent, 1-12% of pulping auxiliaries, 30-50% of film forming emulsion, 1-8% of reversible thermochromic material, 1-11.5% of paint mixing auxiliaries and 0-10% of paint mixing solvent. The thermochromic heat insulation coating can be used for achieving the aims of thermochromism, high temperature reflective heat insulation and low temperature heat absorption, and has favorable energy saving and decoration effects. The invention also discloses a preparation method of the thermochromic heat insulation coating. The preparation method comprises the following steps of: grinding the pigment and filler, the pulping solvent and the pulping auxiliaries to obtain a pulping part; stirring the film forming emulsion, the reversible thermochromic material, the paint mixing auxiliaries and the paint mixing solvent to obtain a paint mixing part; and mixing the pulping part and the paint mixing part to prepare the thermochromic heat insulation coating. The method is simple in preparation, easy for realizing large-scale industrial production and better in economic benefit.
Description
Technical field
The invention belongs to the building coating technical field, particularly a kind of temperature sensing color changing thermal insulating coating and preparation method thereof.
Background technology
Reflective heat-insulation paint has good effect of heat insulation, can reflect the solar radiant heat about 80%, and the thermal insulating coating easy construction, only needs simple spraying; Cost is lower, 1/2 of only inorganic heat-insulation and heat-preservation material.Therefore, utilizing thermal insulating coating to reduce building energy consumption is very practicable energy-saving and emission-reduction means, is particularly useful for areas to the south, China the Changjiang river.
The tempo of thermal insulating coating is exceedingly fast, and using more at present is environment-friendly water-based thermal insulating coating, as water-base reflecting heat-islating paint (CN 1986664 A); And progressively develop the product of aqueous contamination resistant thermal insulating coating (CN 101481583A), water-proof heat-insulating paint (CN 101818013A), vibration damping thermal insulating coating difference in functionalitys such as (CN 101709188A) and characteristics, satisfy the different market requirements.Although above-mentioned functional type thermal insulating coating has excellent heat insulation property and other advantages, yet its reflected solar radiation energy still during low temperature in the winter time is unfavorable for the energy-conservation of winter on the contrary.
Chinese patent ZL 200410051965.X discloses a kind of solar heat intelligent temperature control coating, this coating as functional additive, comprises the macromolecule filming material of 10～35 weight parts, the dispersion agent of 0.1～0.4 weight part, the composite pigment of 16～52 weight parts, the solvent of 19～65 weight parts and the softening agent of 0.5～1.7 weight part with the doped vanadium dioxide phase change material.When the coating temperature was higher than transformation temperature, this coating had higher full infrared band reflection potential, and effect of heat insulation is remarkable; When the coating temperature was lower than transformation temperature, this coating can see through infrared rays, and insulating efficiency is good, thereby realized intelligent temperature control.Regrettably, this patent does not contrast and is higher than/sunlight reflectivity when being lower than transformation temperature, and the color of this coating does not change with envrionment temperature.
Summary of the invention
The invention provides a kind of temperature sensing color changing thermal insulating coating,, reach the purpose of temperature sensing color changing, high temperature reflective insulation, low temperature heat absorption by in coating, introducing the temperature-sensitive reversible color material.
A kind of temperature sensing color changing thermal insulating coating is made by the raw material of following weight percentage;
Color stuffing 32%～52%;
Slurrying solvent 2%～10%;
Slurrying auxiliary agent 1%～12%;
Filming emulsion 30%～50%;
Temperature-sensitive reversible color material 1%～8%;
Paint auxiliary agent 1%～11.5%;
Paint solvent 0%～10%.
The temperature sensing color changing thermal insulating coating partly is made up of slurrying part and paint, and wherein, color stuffing, slurrying solvent and slurrying auxiliary agent form the slurrying part, and the paint solvent that filming emulsion, temperature sensing color changing material, paint auxiliary agent and selectivity are added forms the paint part.Slurrying part and paint part can separately prepare, and during use, both mixing are got final product.
Described temperature-sensitive reversible color material is optional to be used in the certain temperature interval range, rising with temperature, the temperature-sensitive reversible color material gradually becomes white or transparent, reduction with temperature, the temperature-sensitive reversible color material gradually becomes sunlight is absorbed colour preferably, thereby make temperature sensing color changing thermal insulating coating of the present invention reversible color between colour and white, described colour comprises redness, yellow, orange, blue, green, purple, brown, grey.Described temperature-sensitive reversible color material can adopt the commercially available prod; as preferably; described temperature-sensitive reversible color material is that a class can vary with temperature and the microcapsule of variable color repeatedly; microcapsule are the color development system with the electron transfer type organic compound, are protective layer with the transparent outer cover, are also referred to as the heat discoloration powder; as adopt yellow variable color powder, red variable color powder, green variable color powder or blue variable colour powder; particle diameter is smaller or equal to 40 μ m, and general particle diameter is more little, and color is even more.
As preferably, described color stuffing is two or more in titanium dioxide, lime carbonate, kaolin, diatomite, mica, talcum powder, barium sulfate, pure aluminium silicate, zinc oxide, hollow glass micropearl, hollow ceramic microspheres, polymkeric substance hollow material, the ceramic, and the particle diameter of described color stuffing is smaller or equal to 80 μ m.Color stuffing can play the effect of regulating color and filling.Select above-mentioned color stuffing for use, make that white background color is brighter, make when summer temperature is higher, can reflect more sunlight.Further preferred, the particle diameter of described color stuffing is smaller or equal to 40 μ m, and particle diameter is more little, and outward appearance is even more.
As preferably, described slurrying solvent is a water, makes things convenient for slurrying, thus the preparation water-borne coatings.
As preferably, described slurrying auxiliary agent is made up of wetting agent, frostproofer, dispersion agent, first defoamer, first thickening material, antiseptic-germicide and the first pH regulator agent, and the weight percentage in total raw material is:
Wetting agent 0.05%～0.5%;
Frostproofer 0.5%～2%;
Dispersion agent 0.1%～0.5%;
First defoamer 0.1%～0.5%;
First thickening material 0.5%～4%;
Antiseptic-germicide 0.05%～0.3%;
The second pH regulator agent 0.05%～0.4%.
Select for use the slurrying auxiliary agent of above-mentioned content and component can make the temperature sensing color changing thermal insulating coating of the present invention of final preparation have good performance.
As preferably, described filming emulsion is one or more in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, fluorine carbon emulsion, the polyaminoester emulsion, the glass transition temperature of above-mentioned several filming emulsions is lower, snappiness under the room temperature is better, has film-forming properties preferably simultaneously, can make temperature sensing color changing thermal insulating coating of the present invention have cohesiveness preferably in use, thereby improve the performance of coating.
As preferably, described paint auxiliary agent is made up of second defoamer, second thickening material, the second pH regulator agent and film coalescence aid, and the weight percentage in total raw material is:
Second defoamer 0.1%～0.4%;
Second thickening material 0.5%～5%;
The second pH regulator agent 0.2%～1%;
Film coalescence aid 0.5%～5%.
Select for use the paint auxiliary agent of above-mentioned content and component can make the temperature sensing color changing thermal insulating coating of the present invention of final preparation have good performance, help film forming, improve the cohesiveness of coating.
As preferably, described paint solvent is a water, can add as required or not add.Further preferred, the weight percentage of described paint solvent in total raw material is 1%～10%.
As preferably, described temperature sensing color changing thermal insulating coating is made by the raw material of following weight percentage;
Color stuffing 37%～47%;
Slurrying solvent 5%～7%;
Wetting agent 0.1%～0.3%;
Frostproofer 0.5%～1.5%;
Dispersion agent 0.2%～0.4%;
First defoamer 0.1%～0.3%;
First thickening material 1%～3%;
Antiseptic-germicide 0.05%～0.15%;
The first pH regulator agent 0.1%～0.3%;
Filming emulsion 33%～43%;
Temperature-sensitive reversible color material 2%～5%;
Second defoamer 0.1%～0.3%;
Second thickening material 1.5%～4%;
The second pH regulator agent 0.3%～0.7%;
Film coalescence aid 0.5%～3%;
Paint solvent 1%～4%.
First defoamer and second defoamer can be the same or different.
The first pH regulator agent and the second pH regulator agent can be the same or different, and be preferably identical.
First thickening material and second thickening material can be the same or different, and be preferably identical.
Wetting agent, frostproofer, dispersion agent, first defoamer, thickening material, antiseptic-germicide, the first pH regulator agent, second defoamer, thickening material, the second pH regulator agent and film coalescence aid can be selected paint field wetting agent, frostproofer, dispersion agent, defoamer, thickening material, antiseptic-germicide, pH regulator agent and film coalescence aid commonly used.
The invention also discloses a kind of preparation method of temperature sensing color changing thermal insulating coating, its preparation is simple, easy to implement.
A kind of preparation method of temperature sensing color changing thermal insulating coating may further comprise the steps:
1) with color stuffing, slurrying solvent and slurrying auxiliary agent by high speed dispersor at 400rmp～2000rmp(rev/min) speed grind 15min～60min, obtain the slurrying part;
With filming emulsion, temperature-sensitive reversible color material and paint auxiliary agent three, perhaps with filming emulsion, temperature-sensitive reversible color material, paint auxiliary agent and paint solvent, stir 10min～30min at 200rmp～600rmp, obtain the paint part;
2) slurrying part and paint is partially mixed, obtain the temperature sensing color changing thermal insulating coating.
Compared with prior art, the present invention has following advantage:
Conventional thermal insulating coating keeps the nice and cool of architectural exterior-protecting construction by reflected sunlight, thereby saves air conditioning energy consumption; But then can further reduce the temperature of architectural exterior-protecting construction in the winter time, increase the heating energy consumption on the contrary.Temperature sensing color changing thermal insulating coating of the present invention can provide the thermal insulating coating of reversible color between colour and the white.Temperature sensing color changing thermal insulating coating of the present invention can make thermal insulating coating keep white when summer high temperature, reflects most solar radiant energy; And become colour during low temperature in the winter time, absorb more solar radiant energy, thereby realize higher energy-saving effect.Simultaneously, reversible color of the present invention changes gives thermal insulating coating good ornamental, has vast market prospect.
Temperature sensing color changing thermal insulating coating of the present invention has good energy-saving effect and decorative effect, can be used for fields such as outer surface of building, metal roof, chemical storage tank, has broad application prospects.
The preparation method of temperature sensing color changing thermal insulating coating of the present invention, its preparation is simple, is easy to operate and control, and is easy to large-scale industrialization production, possesses favorable economic benefit.
Embodiment
Below in conjunction with specific examples the present invention is further specified.Percentage ratio is weight percentage among following Comparative Examples and the embodiment.
The preparation of temperature sensing color changing thermal insulating coating
Slurrying: obtain the slurrying part after grinding 30min by high speed dispersor with the speed of 800rmp by the listed raw material of table 1 " slurrying part ", the sealing of cooling back is preserved.
Paint: the listed raw material of table 1 " paint part " is finished with 500rmp stirring at low speed 20min by stirring rake, obtained the paint part, the room temperature sealed storage.
Slurrying part and paint is partially mixed, can obtain the temperature sensing color changing thermal insulating coating and use.
The composition of table 1 temperature sensing color changing thermal insulating coating
Color stuffing in the his-and-hers watches 1 and temperature sensing color changing material composition carry out further concrete the selection, and be as shown in table 2, obtains the thermal insulating coating of Comparative Examples 1 and the temperature sensing color changing material of the present invention of embodiment 1～4 respectively, carries out performance test then, and the result is as shown in table 2.
The color stuffing of table 2 Comparative Examples and embodiment and temperature sensing color changing material are formed and performance
By table 2 as seen, the temperature sensing color changing thermal insulating coating product of the present invention's preparation has the reversible color between colour and the white, have that temperature sensing color changing, summer are heat insulation, the function of heat absorption in winter, possess good ornamental and energy-saving effect, temperature sensing color changing thermal insulating coating of the present invention is had broad application prospects.
At last, it is also to be noted that what more than enumerate only is several specific embodiments of the present invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (10)
1. a temperature sensing color changing thermal insulating coating is characterized in that, is made by the raw material of following weight percentage;
Color stuffing 32%～52%;
Slurrying solvent 2%～10%;
Slurrying auxiliary agent 1%～12%;
Filming emulsion 30%～50%;
Temperature-sensitive reversible color material 1%～8%;
Paint auxiliary agent 1%～11.5%;
Paint solvent 0%～10%.
2. temperature sensing color changing thermal insulating coating according to claim 1, it is characterized in that described color stuffing is two or more in titanium dioxide, lime carbonate, kaolin, diatomite, mica, talcum powder, barium sulfate, pure aluminium silicate, zinc oxide, hollow glass micropearl, hollow ceramic microspheres, polymkeric substance hollow material, the ceramic.
3. temperature sensing color changing thermal insulating coating according to claim 1 is characterized in that, the particle diameter of described color stuffing is smaller or equal to 80 μ m.
4. temperature sensing color changing thermal insulating coating according to claim 3 is characterized in that, the particle diameter of described color stuffing is smaller or equal to 40 μ m.
5. temperature sensing color changing thermal insulating coating according to claim 1 is characterized in that, described slurrying solvent and paint solvent are water.
6. temperature sensing color changing thermal insulating coating according to claim 1, it is characterized in that, described slurrying auxiliary agent is made up of wetting agent, frostproofer, dispersion agent, first defoamer, first thickening material, antiseptic-germicide and the first pH regulator agent, and the weight percentage in total raw material is:
Wetting agent 0.05%～0.5%;
Frostproofer 0.5%～2%;
Dispersion agent 0.1%～0.5%;
First defoamer 0.1%～0.5%;
First thickening material 0.5%～4%;
Antiseptic-germicide 0.05%～0.3%;
The first pH regulator agent 0.05%～0.4%.
7. temperature sensing color changing thermal insulating coating according to claim 1 is characterized in that, described filming emulsion is one or more in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, fluorine carbon emulsion, the polyaminoester emulsion.
8. temperature sensing color changing thermal insulating coating according to claim 1 is characterized in that, described temperature-sensitive reversible color material is the heat discoloration powder, and particle diameter is smaller or equal to 40 μ m.
9. temperature sensing color changing thermal insulating coating according to claim 1 is characterized in that, described paint auxiliary agent is made up of second defoamer, second thickening material, the second pH regulator agent and film coalescence aid, and the weight percentage in total raw material is:
Second defoamer 0.1%～0.4%;
Second thickening material 0.5%～5%;
The second pH regulator agent 0.2%～1%;
Film coalescence aid 0.5%～5%.
10. according to the preparation method of each described temperature sensing color changing thermal insulating coating of claim 1～9, it is characterized in that, may further comprise the steps:
1) color stuffing, slurrying solvent and slurrying auxiliary agent are ground 15min～60min by high speed dispersor in the speed of 400rmp～2000rmp, obtain the slurrying part;
With filming emulsion, temperature-sensitive reversible color material and paint auxiliary agent three, perhaps with filming emulsion, temperature-sensitive reversible color material, paint auxiliary agent and paint solvent, stir 10min～30min at 200rmp～600rmp, obtain the paint part;
2) slurrying part and paint is partially mixed, obtain the temperature sensing color changing thermal insulating coating.
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| CN201310135432.9A CN103214905B (en) | 2013-04-17 | 2013-04-17 | A kind of temperature sensing color changing thermal insulating coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310135432.9A CN103214905B (en) | 2013-04-17 | 2013-04-17 | A kind of temperature sensing color changing thermal insulating coating and preparation method thereof |
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| CN103214905A true CN103214905A (en) | 2013-07-24 |
| CN103214905B CN103214905B (en) | 2016-02-10 |
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| CN104088130A (en) * | 2014-06-30 | 2014-10-08 | 沛县海情纺织有限责任公司 | Preparation process of chromotropic heat-insulating textiles |
| CN104130688A (en) * | 2014-08-13 | 2014-11-05 | 宁波多尔贝家居制品实业有限公司 | Continuous color-changing interior decoration coating and preparation method thereof |
| CN104449101A (en) * | 2014-12-31 | 2015-03-25 | 江阴市天邦涂料股份有限公司 | Preparing method for water-based thermal insulation coating |
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