CN103209986A - 光敏剂及其用于由水生成氢气的用途 - Google Patents

光敏剂及其用于由水生成氢气的用途 Download PDF

Info

Publication number
CN103209986A
CN103209986A CN2011800557594A CN201180055759A CN103209986A CN 103209986 A CN103209986 A CN 103209986A CN 2011800557594 A CN2011800557594 A CN 2011800557594A CN 201180055759 A CN201180055759 A CN 201180055759A CN 103209986 A CN103209986 A CN 103209986A
Authority
CN
China
Prior art keywords
carbon atom
hydrogen
water
alkyl
branched
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011800557594A
Other languages
English (en)
Chinese (zh)
Inventor
S.诺德霍夫
U.丁格迪森
J.布泽
S.霍赫
M.布卢格
H-W.詹特霍夫
F.加特纳
D.科祖拉
S.德努拉
A.戈皮纳森
S.洛泽
H.容格
S.格拉迪亚利
M.贝勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa GmbH filed Critical Evonik Degussa GmbH
Publication of CN103209986A publication Critical patent/CN103209986A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/042—Decomposition of water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Physical Water Treatments (AREA)
CN2011800557594A 2010-11-19 2011-10-28 光敏剂及其用于由水生成氢气的用途 Pending CN103209986A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010044155.4 2010-11-19
DE102010044155A DE102010044155A1 (de) 2010-11-19 2010-11-19 Photosensibilisatoren und deren Einsatz zur Wasserstofferzeugung aus Wasser
PCT/EP2011/069031 WO2012065833A1 (de) 2010-11-19 2011-10-28 Photosensibilisatoren und deren einsatz zur wasserstofferzeugung aus wasser

Publications (1)

Publication Number Publication Date
CN103209986A true CN103209986A (zh) 2013-07-17

Family

ID=44925512

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011800557594A Pending CN103209986A (zh) 2010-11-19 2011-10-28 光敏剂及其用于由水生成氢气的用途

Country Status (8)

Country Link
US (1) US20140023582A1 (enExample)
EP (1) EP2640733A1 (enExample)
JP (1) JP2014508714A (enExample)
CN (1) CN103209986A (enExample)
DE (1) DE102010044155A1 (enExample)
IL (1) IL226366A0 (enExample)
MA (1) MA34648B1 (enExample)
WO (1) WO2012065833A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106632500A (zh) * 2016-12-14 2017-05-10 南京大学 基于2‑(4‑(二米基硼)苯基)吡啶配体的铱(iii)配合物及其制备方法和应用

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010030209A1 (de) 2010-06-17 2011-12-22 Evonik Oxeno Gmbh Energieeffiziente Synthese von aliphatischen Adelhyden aus Alkanen und Kohlendioxid
DE102012205258A1 (de) 2012-03-30 2013-10-02 Evonik Industries Ag Photoelektrochemische Zelle, System und Verfahren zur lichtgetriebenen Erzeugung von Wasserstoff und Sauerstoff mit einer photoelektrochemischen Zelle und Verfahren zur Herstellung der photoelektrochemischen Zelle
CN103396454B (zh) * 2013-07-23 2015-07-22 南京理工大学 三齿铱光敏剂、合成及其在光催化还原水出氢的应用
CN104672465B (zh) * 2015-01-12 2017-04-12 中国科学院理化技术研究所 一种树枝形聚合物和制备方法及其作为催化剂在光催化产氢中的应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050176624A1 (en) * 2003-08-07 2005-08-11 Thompson Mark E. Organometallic complexes as singlet oxygen sensitizers
WO2009067603A1 (en) * 2007-11-21 2009-05-28 Bio-Rad Laboratories, Inc. Photoluminescent metal complexes for protein staining
CN101747381A (zh) * 2008-12-19 2010-06-23 苏州纳凯科技有限公司 用作生物标记物的环金属铱配位化合物
WO2011024737A1 (ja) * 2009-08-27 2011-03-03 独立行政法人産業技術総合研究所 イリジウム錯体ならびに該化合物からなる発光材料

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI237524B (en) * 2004-05-17 2005-08-01 Au Optronics Corp Organometallic compound and organic electroluminescent device including the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050176624A1 (en) * 2003-08-07 2005-08-11 Thompson Mark E. Organometallic complexes as singlet oxygen sensitizers
WO2009067603A1 (en) * 2007-11-21 2009-05-28 Bio-Rad Laboratories, Inc. Photoluminescent metal complexes for protein staining
CN101747381A (zh) * 2008-12-19 2010-06-23 苏州纳凯科技有限公司 用作生物标记物的环金属铱配位化合物
WO2011024737A1 (ja) * 2009-08-27 2011-03-03 独立行政法人産業技術総合研究所 イリジウム錯体ならびに該化合物からなる発光材料

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
ERIC D. CLINE等,: "Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes", 《INORG. CHEM.》, 22 October 2008 (2008-10-22), pages 10378 - 10388 *
JONAS I. GOLDSMITH等,: "Discovery and High-Throughput Screening of Heteroleptic Iridium Complexes for Photoinduced Hydrogen Production", 《J. AM. CHEM. SOC.》, 28 April 2005 (2005-04-28), pages 7502 - 7510 *
KENNETH KAM-WING LO等,: "Luminescent Cyclometalated Iridium(III) Arylbenzothiazole Biotin Complexes", 《ORGANOMETALLICS》, 6 August 2005 (2005-08-06), pages 4594 - 4601 *
KENNETH KAM-WING LO等,: "Synthesis, Photophysical and Electrochemical Properties, and Protein-Binding Studies of Luminescent Cyclometalated Iridium(III) Bipyridine Estradiol Conjugates", 《CHEM. EUR. J.》, 13 June 2007 (2007-06-13), pages 7110 - 7120 *
VALENTIN S. SOUKHAREV等,: "Synthesis, properties, and biosensor applications of cycloruthenated 2-phenylimidazoles", 《JOURNAL OF ORGANOMETALLIC CHEMISTRY》, 17 February 2003 (2003-02-17), pages 75 - 81, XP004411615, DOI: doi:10.1016/S0022-328X(02)02143-5 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106632500A (zh) * 2016-12-14 2017-05-10 南京大学 基于2‑(4‑(二米基硼)苯基)吡啶配体的铱(iii)配合物及其制备方法和应用
CN106632500B (zh) * 2016-12-14 2019-09-20 南京大学 基于2-(4-(二米基硼)苯基)吡啶配体的铱(iii)配合物及其制备方法和应用

Also Published As

Publication number Publication date
EP2640733A1 (de) 2013-09-25
US20140023582A1 (en) 2014-01-23
JP2014508714A (ja) 2014-04-10
WO2012065833A1 (de) 2012-05-24
DE102010044155A1 (de) 2012-05-24
IL226366A0 (en) 2013-07-31
MA34648B1 (fr) 2013-11-02

Similar Documents

Publication Publication Date Title
JP4572393B2 (ja) ギ酸分解用触媒、ギ酸の分解方法、水素製造方法、ギ酸製造および分解用装置、水素貯蔵および発生方法
Lee et al. Visible-light photocatalytic conversion of carbon dioxide by Ni (II) complexes with N4S2 coordination: Highly efficient and selective production of formate
JP2009078200A (ja) ギ酸分解用触媒、ギ酸の分解方法、水素製造方法、ギ酸製造および分解用装置、水素貯蔵および発生方法
Krishnan et al. Preparation and reactivity of a square-planar PNP cobalt (II)–hydrido complex: isolation of the first {Co–NO} 8–hydride
CN103209986A (zh) 光敏剂及其用于由水生成氢气的用途
CN111848688B (zh) 一种阳离子型金属铱配合物、其制备方法及光催化水解的方法
Wang et al. pH, solvent and metal ion induced octamolybdate-based metal–organic complexes decorated with a pyridyl-carboxylate ligand containing an amide group
Ehsan et al. Fabrication of CuO–1.5 ZrO 2 composite thin film, from heteronuclear molecular complex and its electrocatalytic activity towards methanol oxidation
JP5397806B2 (ja) 重水素（ｄ２）および重水素化水素（ｈｄ）の少なくとも一方を製造する方法、並びにこれに使用するギ酸分解用触媒
Wang et al. Diverse polyoxometalate-based metal–organic complexes constructed by a tetrazole-and pyridyl-containing asymmetric amide ligand or its in situ transformed ligand
Nakanishi et al. Synthesis and reactions of a zirconium naphthalene complex bearing a tetraanionic C-capped triaryloxide ligand
CN103360429B (zh) 环金属铱光敏剂、合成及其在光催化还原水出氢的应用
Wu et al. CO 2 fixation and transformation on a thiolate-bridged dicobalt scaffold under oxidising conditions
Man et al. Synthesis, characterization and reactivity of heterobimetallic complexes (η 5-C 5 R 5) Ru (CO)(μ-dppm) M (CO) 2 (η 5-C 5 H 5)(R= H, CH 3; M= Mo, W). Interconversion of hydrogen/carbon dioxide and formic acid by these complexes
Feng et al. N-ligands mediated Co (Ⅱ) coordination polymer incorporating 5-hydroxyisophthalic acid: syntheses, structures, and theoretical calculations
Jung et al. Synthesis and Crystal Structure of Blue Phosphorescent mer-Tris (2', 6'-difluoro-2, 3'-bipyridinato-N, C 4') Iridium (III)
Gu et al. Synthesis, structures, and properties of ruthenium (II) complexes of N-(1, 10-phenanthrolin-2-yl) imidazolylidenes
CN115028849A (zh) 具有室温荧光的金属三角形超分子的制备方法及其应用
CN101693727A (zh) 一种含有半夹心结构铱、铑、钌的四核/六核大环配合物及其制备方法
Paparo et al. Formate complexes of titanium (IV) supported by a triamido-amine ligand
JP5443025B2 (ja) 二核金属錯体及びそれを含む光触媒
JP2014062038A (ja) 一酸化炭素および／または水素の製造方法
Wang et al. Temperature-driven growth of uranyl-organic frameworks for efficient photocatalytic CO 2 reduction
JP5524908B2 (ja) 光触媒およびその製造方法
CN100439381C (zh) 二(乙酰丙酮)合钯(ⅱ)的合成方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20130717