CN103173917A - Hydrophilic and easy-decontamination terylene fabrics and preparation method thereof - Google Patents

Hydrophilic and easy-decontamination terylene fabrics and preparation method thereof Download PDF

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Publication number
CN103173917A
CN103173917A CN2013101036951A CN201310103695A CN103173917A CN 103173917 A CN103173917 A CN 103173917A CN 2013101036951 A CN2013101036951 A CN 2013101036951A CN 201310103695 A CN201310103695 A CN 201310103695A CN 103173917 A CN103173917 A CN 103173917A
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control
controlled
hydrophilic
temperature
fibre
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张卫东
奚炳华
李凤军
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JIANGSU NEW-KASUM ENTERPRISE DEVELOPMENT Co Ltd
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JIANGSU NEW-KASUM ENTERPRISE DEVELOPMENT Co Ltd
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Abstract

The invention provides hydrophilic and easy-decontamination terylene fabrics and a preparation method thereof and belongs to the technical field of knitted fabrics. The hydrophilic and easy-decontamination terylene fabrics comprise hygroscopic and sweat releasing modified polyester fiber and common fiber, wherein the mass percent of the hydrophilic and easy-decontamination terylene fabrics accounting for the shell fabrics is 30-100%, and the mass prevent of the common fiber accounting for the shell fabrics is less than 70%. Due to the fact that the hydrophilic and easy-decontamination terylene shell fabrics is selected to serve as raw materials, the hydrophilic and easy-decontamination terylene fabrics has an excellent and durable hydrophilic effect, or common yarn raw materials of a certain proportion are provided, so that the hydrophilic and easy-decontamination terylene fabrics is wide in source, low, and beneficial to reducing cost, and enables textiles to be adapted to mass consumption demands. A processing method which is provided is concise in processing steps, strong in reproducibility, and free of rigor processing requirements, and can ensure that the textiles have stable and durable easy-decontamination capacity.

Description

Hydrophilic easy decontamination polyester fabric and preparation method thereof
Technical field
The invention belongs to the knit fabric technical field, be specifically related to a kind of hydrophilic easy decontamination polyester fabric, and relate to its preparation method.
Background technology
Outdoor sports coat is contained in wearing process, due to the dust in absorbed air and slop and contamination etc., thereby easily forms dirt.Particularly synthetic fiber and BLENDED FABRIC thereof, easy static electrification attract dirt, and because surperficial synthetic fiber are hydrophobic fibres, therefore hydrophily is poor, water is difficult for being penetrated into fibre gap in washing process, and dirt is difficult to remove, again because fabric face has lipophile, therefore the dirt that is suspended in cleaning solution is easy to again stain fiber surface, causes to stain again.
The common practice of giving hydrophilic effect to polyester fabric is to add hydrophilic easy decontamination auxiliary agent in the fabric post-treatment process, preparation method as Chinese invention patent application publication No. CN102051824A(waterproof, grease proofing, antifouling and easy decontamination household fabric), the fabric of this patent application scheme acquisition is applicable to make the tablecloth, curtain or kitchen cleaning cloth; CN101148821A(chemical fiber plus material method of plasma processing and for example), the finishing method of the CN101942752A(easy decontamination fabric of non-ironing moisture-absorption) and the CN102051814A(hydrophilic fabric finishing method), etc.
The shortcoming that the patent application scheme ubiquity that is not limited to exemplify is above attended to one thing and lose sight of another, this is so-called Gu too to pay attention to post in to the fabric post-treatment process and wishes to give corresponding auxiliary agent, and so-called mistake that be the selection of the fiber that forms fabric and lose biased to the exploration of postfinishing process, even if so use the hydrophilic easy decontamination auxiliary agent by the exploitation of internationally recognizable 3M company, gram Lay benefactor department also only can play the effect of getting half the result with twice the effort, because the increase of passing in time and washing times, hydrophilic dirt-removing functions constantly weakens, and even exhausts.
" a kind of high water absorbent quick-drying terylene fabric and preparation method thereof " that Chinese invention patent publication number CN101469512A recommends is for solving the problems of the technologies described above enlightenment to some extent, it is to use hydrophilic polyester and polyether block copolymer to the polyster fibre modification, make the poor inadequate natural endowment of hydrophily of polyster fibre obtain certain compensation by posteriori measure, soft is the strong point of this patent, but anti-bacterial wet-absorbing sweat-repellent and permeability can not reach people's requirement; Again, " knit fabric and the weaving method thereof with warming moisture-absorbing perspire and antibiotic multi-functional " that invention patent mandate notification number CN102162165B provides, this knit fabric shows as interior, domestic and abroad three-decker, although can cash its famous technique effect in specification the 0006th hurdle, the fabric construction complexity is its shortcoming.
In view of above-mentioned prior art, be necessary rational modification in addition, for this reason, the applicant has made good try, and technical scheme described below produces under this background.
Summary of the invention
Task of the present invention is to provide that dirt-removing power in a kind of washing process is strong, easy lasting and hydrophilic easy decontamination polyester fabric good hygroscopicity when wearing of clean effect.
Another task of the present invention is to provide a kind of preparation method of hydrophilic easy decontamination polyester fabric, and the method technique is simple and easy, repeatability good and can ensure comprehensive embodiment of the described effect of described hydrophilic easy decontamination polyester fabric.
Task of the present invention is completed like this, a kind of hydrophilic easy decontamination polyester knitted fabric, consisted of by moisture absorbing and sweat releasing modified polyester fibre and general fibre, described moisture absorbing and sweat releasing modified polyester fibre shared mass percent in fabric is 30-100%, and described general fibre shared mass percent in fabric is<70%.
In a specific embodiment of the present invention, described moisture absorbing and sweat releasing modified polyester fibre is moisture absorbing and sweat releasing Cationic Dyeable Pet fiber; Described general fibre is polyster fibre or functional fibre.
In another specific embodiment of the present invention, described functional fibre is a kind of or its combination in cotton fiber, wool fibre, flax fibre and viscose.
Another task of the present invention is completed like this, and a kind of preparation method of hydrophilic easy decontamination fabric comprises the following steps:
A) weave, the moisture absorbing and sweat releasing modified polyester fibre is weaved through circular knitting machine, warp knitting machine or water jet looms, perhaps with the moisture absorbing and sweat releasing modified polyester fibre and general fibre interweaves or doubling is weaved by circular knitting machine, warp knitting machine or water jet looms, obtain grey cloth;
B) pre-treatment, will be by steps A) obtain grey cloth and introduce in the dyeing machine of being furnished with degreaser and carry out oil removal treatment under the main pump operating condition of Liang Seji, to remove the greasy dirt that attaches on fiber in weaving process, and control the pH value of consumption, oil removal treatment temperature, oil removal treatment time, main pump running speed and the control degreaser of degreaser, obtain the degreasing grey cloth;
C) dye or brighten, described dyeing is first the waste water in dyeing machine to be discharged, diversion and control bath raio again in the dyeing machine again, then add dyestuff and easy detergent in dyeing machine, control the addition of dyestuff and the easy detergent of control, obtain dye bath, will be by step B) the degreasing grey cloth that obtains drops in dye bath and dyes, and control the temperature of dye bath, heating rate and temperature retention time, insulation is lowered the temperature after finishing, and drop to normal temperature at the state of controlling rate of temperature fall, go out dye bath, obtain stained clot-h, described brightening is to use described dyestuff instead brightening agent, and control the consumption of brightening agent, obtain brightening cloth,
D) arrange after, will be by step C) stained clot-h that obtains or brighten cloth and introduce the padding liquor tank of being furnished with the moisture absorbing and sweat releasing auxiliary agent and pad, go out the padding liquor tank post-drying, and control the consumption of cloth speed, moisture absorbing and sweat releasing auxiliary agent and control bake out temperature, the hydrophilic easy decontamination polyester fabric that obtains dyeing or brighten.
In another specific embodiment of the present invention, the consumption of the control degreaser step B) is that the consumption with degreaser is controlled to be 0.2-2.5g/L, described control oil removal treatment temperature is that the oil removal treatment temperature is controlled to be 60-100 ℃, the described control oil removal treatment time is that the oil removal treatment time is controlled to be 20-25min, described control main pump running speed is that the main pump running speed is controlled to be 800-1300n/min, and the pH value of described control degreaser is that the pH value is controlled to be 4-5.
Also have a specific embodiment of the present invention, step C) described in the control bath raio refer to the weight ratio of degreasing grey cloth and water is controlled to be 1: 8-20.
More of the present invention and in specific embodiment, step C) the control dyestuff described in and the addition of controlling easy detergent be with dyestuff and easily the addition of detergent be controlled to be respectively 0.1-12% and 1-7% less than degreasing grey cloth weight; The temperature of described control dye bath is that the temperature with dye bath is controlled to be 120-140 ℃, described control heating rate is that heating rate is controlled to be 1-1.5 ℃/min, described control temperature retention time is that temperature retention time is controlled to be 25-35min, and described control rate of temperature fall is that rate of temperature fall is controlled to be 1-1.5 ℃/min; The consumption of described control brightening agent is that the amount with brightening agent is controlled to be 0.001-3g/L.
In of the present invention and then specific embodiment, step D) the control cloth speed described in is that cloth speed is controlled to be 20-40m/min, described control moisture absorbing and sweat releasing auxiliary dosage is that consumption is controlled to be 1-3g/L, and described control bake out temperature is that bake out temperature is controlled to be 120-160 ℃.
Of the present invention again more and in specific embodiment, described easy detergent is the SRCN of gram Lay benefactor department.
In again of the present invention and then specific embodiment, described moisture absorbing and sweat releasing auxiliary agent is the FC-226 of 3M company.
Technical scheme provided by the invention is owing to choosing the perspire modified polyester fibre as raw material, thereby have excellent and a lasting hydrophilic effect, perhaps be equipped with the wide and cheapness of a certain proportion of common yarn raw material sources and help to reduce costs, make fabric can adapt to popular consumption demand; The processing method that provides, processing step is terse, and reproducibility is strong, and technique is without harsh requirement, can ensure that fabric has to stablize lasting easy dirt-removing power (after tested, after 75 washings, the easy decontamination rank of four kinds of spots is reached 4.5 grades<totally 5 grades 〉).
The specific embodiment
For the auditor that the makes Patent Office especially public can be expressly understood technical spirit of the present invention and beneficial effect more, the applicant general elaborates in the mode of embodiment below, but be not all restriction to the present invention program to the description of embodiment, any according to the present invention's design done only for pro forma but not substantial equivalent transformation all should be considered as technical scheme category of the present invention.
Embodiment 1:
A) weave, moisture absorbing and sweat releasing Cationic Dyeable Pet fiber is put to circular knitting machine weaves, obtain grey cloth;
B) pre-treatment, will be by steps A) obtain grey cloth that the moisture absorbing and sweat releasing Cationic Dyeable Pet fiber of 100% one-tenth consists of and introduce in the dyeing machine of being furnished with degreaser and carry out oil removal treatment, attach in weaving process on fiber or claim to attach greasy dirt on grey cloth to remove, wherein: the consumption of degreaser is that 2g/L(adds 2g in every premium on currency), the oil removal treatment temperature is 80 ℃, the time of oil removal treatment is 22min, the main pump running speed of dyeing machine is controlled to be 1300n/min in the oil removing process, the pH value of degreaser is 4, described degreaser preferably uses that produce by Guangzhou, Guangdong Province, China city new beneficial textile auxiliary Co., Ltd and the trade mark that widely sold in market before the application proposes is GL-A weaving degreaser, obtain the degreasing grey cloth,
C) dyeing, first the waste water in dyeing machine (be the degreasing in step B after waste water) is discharged, again introduce clean water such as running water again in dyeing machine, bath raio is controlled to be 1: 20, the weight ratio that is degreasing grey cloth and water is controlled to be 1: 20, then add dyestuff and easy detergent in dyeing machine, dyestuff such as G/L are yellow, any one in the red and G/L basket of G/L, addition is 8% of degreasing grey cloth weight, easily to adopt by gram Lay benefactor department be the easy detergent of SRCN at the trade mark of Chinese market sale before the application proposes to detergent, consumption is 7% of degreasing grey cloth weight, obtain dye bath, then will be by step B) the degreasing grey cloth that obtains drops in dye bath and dyes, and the heating rate with 1.5 ℃/min is warming up to 140 ℃ with the dye bath temperature from normal temperature, be incubated 25min after reaching 140 ℃, insulation is down to normal temperature with the rate of temperature fall of 1 ℃/min with dye bath after finishing, go out dye bath, obtain stained clot-h,
D) arrange after, will be by step C) stained clot-h that obtains introduces the padding liquor tank of being furnished with the moisture absorbing and sweat releasing auxiliary agent and pads, padding number of times is to soak one to roll, it was FC-226 moisture absorbing and sweat releasing auxiliary agent at the trade mark of Chinese market sale the application proposes before that aforesaid moisture absorbing and sweat releasing auxiliary agent adopts by 3M company, and consumption is 2g/L, namely adds 2g in every premium on currency, dry after going out padding liquor tank, bake out temperature is 160 ℃, and cloth speed is 40m/min, the hydrophilic easy decontamination polyester fabric that obtains dyeing.
Embodiment 2:
A) weave, to weave for warp knitting machine after moisture absorbing and sweat releasing Cationic Dyeable Pet fiber and general fibre doubling, obtain grey cloth, wherein, moisture absorbing and sweat releasing CATION terylene fiber shared mass percent in grey cloth is 30%, and general fibre shared mass percent in grey cloth is 70%, and general fibre adopts polyster fibre;
B) pre-treatment, will be by steps A) obtain grey cloth and introduce in the dyeing machine of being furnished with degreaser and carry out oil removal treatment, attach in weaving process on fiber or claim to attach greasy dirt on grey cloth to remove, wherein: the consumption of degreaser is 0.2g/L, the oil removal treatment temperature is 100 ℃, and the time of oil removal treatment is 20min, and the main pump running speed is 800n/min, the pH value of degreaser is 5, obtains the degreasing grey cloth;
C) dyeing, the weight ratio of degreasing grey cloth and water changes 1: 8 into, the consumption of dyestuff changes 12% of degreasing grey cloth weight into, easily the consumption of detergent changes 5% of degreasing grey cloth weight into, heating rate changes 1 ℃/min into, and holding temperature changes 120 ℃ into, and temperature retention time changes 35min into, rate of temperature fall changes 1.5 ℃/min into, obtains stained clot-h;
D) arrange after, the consumption of moisture absorbing and sweat releasing auxiliary agent changes 1g/L into, and bake out temperature changes 120 ℃ into, and cloth speed changes 20m/min into, the hydrophilic easy decontamination polyester fabric that obtains dyeing.
The content that does not relate in the present embodiment is all with the description to embodiment 1.
Embodiment 3:
Only with steps A) in the mass percent of moisture absorbing and sweat releasing Cationic Dyeable Pet fiber change 50% into, the mass percent of general fibre changes 50% into, and use functional fibre instead, it is the combination of cotton fiber, wool fibre and the flax fibre of 1: 1: 1 that functional fibre adopts weight ratio; With step B) in the consumption of degreaser change 1g/L into, except oil temperature changes 60 ℃ into, the oil removal treatment time changes 25min into, the main pump running speed changes 1000n/min into, the pH value of degreaser changes 4.5 into; With step C) in bath raio change 1: 15 into, be also, change the weight ratio of degreasing grey cloth and water into 1: 15, change the consumption of dyestuff 0.2% of degreasing grey cloth weight into, change the consumption of detergent 1% of degreasing grey cloth weight into, heating rate changes 1.2 ℃/min into, and holding temperature changes 130 ℃ into, temperature retention time changes 30min into, changes rate of temperature fall into 1.2 ℃/min; With step D) in the consumption of moisture absorbing and sweat releasing auxiliary agent change 2g/L into, bake out temperature changes 140 ℃ into, cloth speed changes 30m/min into, all the other are all with the description to embodiment 1.
Embodiment 4:
Only with steps A) in the mass percent of suction temperature perspire Cationic Dyeable Pet fiber change 40% into, general fibre is used functional fibre instead, functional fibre is viscose, and mass percent is 60%, and is put to water jet looms after moisture absorbing and sweat releasing Cationic Dyeable Pet fiber one viscose is interweaved and weaves; With step B) in the consumption of degreaser change 2.5g/L into, except oil temperature changes 70 ℃ into, the oil removal treatment time changes 24min into, the main pump running speed changes 1200n/min into, the pH value of degreaser changes 4.3 into; With step C) change into and brightening, namely dyestuff is used brightening agent instead, and the consumption of brightening agent is 0.009g/L; With step D) in the consumption of moisture absorbing and sweat releasing auxiliary agent change 1.5g/L into, bake out temperature changes 150 ℃ into, cloth speed changes 25m/min into, the hydrophilic easy decontamination polyester fabric that obtains bleaching, all the other are all with the description to embodiment 1.
Embodiment 5:
Only with step C) in the consumption of brightening agent change 3g/L into, all the other are all with the description to embodiment 4.
Embodiment 6:
Only with step C) in the consumption of brightening agent change 1.5g/L into, all the other are all with the description to embodiment 4.

Claims (10)

1. hydrophilic easy decontamination polyester knitted fabric, it is characterized in that being consisted of by moisture absorbing and sweat releasing modified polyester fibre and general fibre, described moisture absorbing and sweat releasing modified polyester fibre shared mass percent in fabric is 30-100%, and described general fibre shared mass percent in fabric is<70%.
2. hydrophilic easy decontamination polyester knitted fabric according to claim 1, is characterized in that described moisture absorbing and sweat releasing modified polyester fibre is moisture absorbing and sweat releasing Cationic Dyeable Pet fiber; Described general fibre is polyster fibre or functional fibre.
3. hydrophilic easy decontamination polyester knitted fabric according to claim 2, is characterized in that described functional fibre is a kind of or its combination in cotton fiber, wool fibre, flax fibre and viscose.
4. the preparation method of a hydrophilic easy decontamination fabric as claimed in claim 1 is characterized in that comprising the following steps:
A) weave, the moisture absorbing and sweat releasing modified polyester fibre is weaved through circular knitting machine, warp knitting machine or water jet looms, perhaps with the moisture absorbing and sweat releasing modified polyester fibre and general fibre interweaves or doubling is weaved by circular knitting machine, warp knitting machine or water jet looms, obtain grey cloth;
B) pre-treatment, will be by steps A) obtain grey cloth and introduce in the dyeing machine of being furnished with degreaser and carry out oil removal treatment under the main pump operating condition of Liang Seji, to remove the greasy dirt that attaches on fiber in weaving process, and control the pH value of consumption, oil removal treatment temperature, oil removal treatment time, main pump running speed and the control degreaser of degreaser, obtain the degreasing grey cloth;
C) dye or brighten, described dyeing is first the waste water in dyeing machine to be discharged, diversion and control bath raio again in the dyeing machine again, then add dyestuff and easy detergent in dyeing machine, control the addition of dyestuff and the easy detergent of control, obtain dye bath, will be by step B) the degreasing grey cloth that obtains drops in dye bath and dyes, and control the temperature of dye bath, heating rate and temperature retention time, insulation is lowered the temperature after finishing, and drop to normal temperature at the state of controlling rate of temperature fall, go out dye bath, obtain stained clot-h, described brightening is to use described dyestuff instead brightening agent, and control the consumption of brightening agent, obtain brightening cloth,
D) arrange after, will be by step C) stained clot-h that obtains or brighten cloth and introduce the padding liquor tank of being furnished with the moisture absorbing and sweat releasing auxiliary agent and pad, go out the padding liquor tank post-drying, and control the consumption of cloth speed, moisture absorbing and sweat releasing auxiliary agent and control bake out temperature, the hydrophilic easy decontamination polyester fabric that obtains dyeing or brighten.
5. the preparation method of hydrophilic easy decontamination fabric according to claim 4, it is characterized in that step B) described in the consumption of control degreaser be that consumption with degreaser is controlled to be 0.2-2.5g/L, described control oil removal treatment temperature is that the oil removal treatment temperature is controlled to be 60-100 ℃, the described control oil removal treatment time is that the oil removal treatment time is controlled to be 20-25min, described control main pump running speed is that the main pump running speed is controlled to be 800-1300n/min, and the pH value of described control degreaser is that the pH value is controlled to be 4-5.
6. the preparation method of hydrophilic easy decontamination fabric according to claim 4, is characterized in that step C) described in the control bath raio refer to the weight ratio of degreasing grey cloth and water is controlled to be 1: 8-20.
7. the preparation method of hydrophilic easy decontamination fabric according to claim 4, is characterized in that step C) described in the control dyestuff and the addition of controlling easy detergent be with dyestuff and easily the addition of detergent be controlled to be respectively 0.1-12% and 1-7% less than degreasing grey cloth weight; The temperature of described control dye bath is that the temperature with dye bath is controlled to be 120-140 ℃, described control heating rate is that heating rate is controlled to be 1-1.5 ℃/min, described control temperature retention time is that temperature retention time is controlled to be 25-35min, and described control rate of temperature fall is that rate of temperature fall is controlled to be 1-1.5 ℃/min; The consumption of described control brightening agent is that the amount with brightening agent is controlled to be 0.001-3g/L.
8. the preparation method of hydrophilic easy decontamination fabric according to claim 4, it is characterized in that step D) described in control cloth speed be that cloth speed is controlled to be 20-40m/min, described control moisture absorbing and sweat releasing auxiliary dosage is that consumption is controlled to be 1-3g/L, and described control bake out temperature is that bake out temperature is controlled to be 120-160 ℃.
9. the preparation method of according to claim 1 or 7 described hydrophilic easy decontamination fabrics, is characterized in that described easy detergent is the SRCN of gram Lay benefactor department.
10. the preparation method of according to claim 1 or 8 described hydrophilic easy decontamination fabrics, is characterized in that described moisture absorbing and sweat releasing auxiliary agent is the FC-226 of 3M company.
CN2013101036951A 2013-03-28 2013-03-28 Hydrophilic and easy-decontamination terylene fabrics and preparation method thereof Pending CN103173917A (en)

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Cited By (6)

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CN104328696A (en) * 2014-10-30 2015-02-04 上海嘉麟杰纺织品股份有限公司 Processing method of white hair/cation modified polyester fiber fabric
CN105088761A (en) * 2015-09-17 2015-11-25 福建师范大学泉港石化研究院 Method for hydrophilic modification of polyester fibers by amphiphilic triazine monomer
CN108457098A (en) * 2017-12-20 2018-08-28 浙江雅雪染整有限公司 The gold stamping pre-treating technology of staple fibre
CN110205812A (en) * 2019-06-19 2019-09-06 东莞世丽纺织有限公司 A kind of warming quick dried environment protection cloth setting process
CN110754888A (en) * 2018-07-26 2020-02-07 潍坊迅纺新材料科技有限公司 Preparation method of napkin tablecloth fabric easy to remove dirt
CN113463263A (en) * 2021-05-28 2021-10-01 衡阳市人赢网络科技有限公司 Non-ironing knitted bamboo fiber fabric and manufacturing method thereof

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Cited By (8)

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Publication number Priority date Publication date Assignee Title
CN104328696A (en) * 2014-10-30 2015-02-04 上海嘉麟杰纺织品股份有限公司 Processing method of white hair/cation modified polyester fiber fabric
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CN105088761A (en) * 2015-09-17 2015-11-25 福建师范大学泉港石化研究院 Method for hydrophilic modification of polyester fibers by amphiphilic triazine monomer
CN105088761B (en) * 2015-09-17 2017-03-22 福建师范大学泉港石化研究院 Method for hydrophilic modification of polyester fibers by amphiphilic triazine monomer
CN108457098A (en) * 2017-12-20 2018-08-28 浙江雅雪染整有限公司 The gold stamping pre-treating technology of staple fibre
CN110754888A (en) * 2018-07-26 2020-02-07 潍坊迅纺新材料科技有限公司 Preparation method of napkin tablecloth fabric easy to remove dirt
CN110205812A (en) * 2019-06-19 2019-09-06 东莞世丽纺织有限公司 A kind of warming quick dried environment protection cloth setting process
CN113463263A (en) * 2021-05-28 2021-10-01 衡阳市人赢网络科技有限公司 Non-ironing knitted bamboo fiber fabric and manufacturing method thereof

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Application publication date: 20130626