CN103137773A - Silicon-avalanche photodetector (Si-APD) with black silicon as photosensitive layer and preparation method thereof - Google Patents
Silicon-avalanche photodetector (Si-APD) with black silicon as photosensitive layer and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a silicon-avalanche photodetector (Si-APD) with black silicon as a photosensitive layer and a preparation method of the Si-APD with the black silicon as the photosensitive layer, and belongs to the field of photoelectric detection technology. The Si-APD comprises a silicon intrinsic substrate 1, an N<+> region 2, a P type region 3, an annular N type region 4, an N<+> region black silicon layer 5, a P<+> region 6, an upper electrode 7 and a lower electrode 8, wherein the N<+> region 2 is located in the middle of the upper surface of the silicon intrinsic substrate 1, the P type region 3 is located below the N<+> region, the annular N type region 4 is located on the periphery of the upper surface of the silicon intrinsic substrate, the N<+> region black silicon layer 5 is located on the upper surface of the N<+> region, the P<+> region 6 is located on the lower surface of the silicon intrinsic substrate, the upper electrode 7 is located on the upper surfaces of the N<+> region black silicon layer and the annular N type region, and the lower electrode 8 is located on the lower surface of the P<+> region. According to the Si-PAD, the black silicon material serves as the photosensitive layer, and meanwhile the annular N type region is additionally arranged on the peripheries of the N<+> region and the P type region. Thus, the Si-APD with the black silicon as the photosensitive layer can absorb light waves of a near-infrared band and have higher light absorptivity and a wider response wave band, the preparation technique is simple, the cost is low, and the Si-PAD has the advantages of being easy to integrate, quick in response speed, high in responsivity and wide in response wave band.
Description
Technical field
The invention belongs to technical field of photoelectric detection, relate to the photoelectric detector structure, especially a kind of Si-APD photodetector take black silicon material as photosensitive layer and preparation method thereof.
Background technology
Photodetector all is widely used aspect civil and military as the important component part of Fiber Optical Communication System, infrared imaging system, laser warning system and LDMS etc.APD is a kind of photo-detector with interior gain ability, has very high sensitivity, is widely used in ultra high-speed optical communication, signal processing, measurement and sensor-based system.APD is the widely used photodetector of modern bit rate optical communication system, little with its volume, to measure wavelength band wide and a series of advantage such as higher sensitivity is arranged near infrared band, is used in a large number the association areas such as low light level field measurement, photon counting.Because the APD photodetector has higher interior gain and detectivity is higher than PIN type optical diode, be therefore the most frequently used good device in present 1.06 μ m range finder using lasers.
At present, the APD that makes with InGaAs is widely used in fields such as Fibre Optical Sensors as the photodetector of high sensitivity, high-responsivity, and has occupied leading position.But that the InGaAs single-crystal semiconductor material exists is expensive, thermomechanical property is relatively poor, crystal mass is relatively poor and the shortcoming such as difficult and existing silicon microelectronic technique compatibility.The Si material have be easy to purify, easily doping, aboundresources, cost are low, be easy to the advantages such as large-scale integrated and correlation technique maturation, are class materials that is most widely used in semicon industry.Yet, due to its energy gap large (1.12eV), even deposited anti-reflection film to improve the responsiveness of detector in Si photodetector photosurface district, still can't reach and survey greater than the lightwave signal of 1100nm and with the purpose of signal of telecommunication output.
Black silicon material is a kind of material layer of silicon face micro-structural, and this material can reach more than 90% the absorptivity of visible light and near infrared light, and the spectral absorption scope has covered near ultraviolet ~ near infrared band (0.25 μ m ~ 2.5 μ m).The method of this black silicon material of preparation has much at present, comprises femtosecond laser method, reactive ion etching method, general chemistry etching and electrochemical erosion method etc.
Along with the discovery of this black silicon material, making development have the New Si of high-responsivity and wide spectral response-APD photodetector becomes possibility.
Summary of the invention
For above-mentioned prior art, the technical problem to be solved in the present invention is: the InGaAs crystalline material exist expensive, thermomechanical property is relatively poor, crystal mass is relatively poor and the shortcoming of difficult and existing silicon microelectronic technique compatibility; The Si semi-conducting material is because energy gap is larger, and there is the deficiency that responsiveness is lower, spectrographic detection is limited in scope in traditional Si-APD photodetector.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme:
A kind of Si-APD photodetector take black silicon as photosensitive layer is characterized in that, comprises silicon intrinsic substrate 1, is positioned at the N of silicon intrinsic substrate 1 upper face center
+Distinguish 2, be positioned at N
+Distinguish 2 belows p type island region 3, be positioned at silicon intrinsic substrate 1 upper surface surrounding annular N-type district 4, be positioned at N
+Distinguish the N of 2 upper surfaces
+The district deceives silicon layer 5, is positioned at the P of silicon intrinsic substrate 1 lower surface
+Distinguish 6, be positioned at N
+The top electrode 7 of the black silicon layer 5 in district and annular N-type district 4 upper surfaces and be positioned at P
+Distinguish the bottom electrode 8 of 6 lower surfaces.
In the present invention, described N
+District 2 is the heavy diffusing, doping N-type of phosphorus district, and junction depth is 0.1 μ m ~ 0.5 μ m, doping content 〉=1 * 10
20Ion/cm
3
In the present invention, described p type island region 3 is boron diffusing, doping p type island region, and junction depth is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
In the present invention, described annular N-type district 4 is phosphorus diffusing, doping N-type district, and junction depth is 1.5 μ m ~ 3.5 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
In the present invention, described N
+The black silicon layer 5 in district is N
+Distinguish that Se is carried out in 2 surfaces after the chemical corrosion extended surface or Te ion implantation doping obtains; Wherein Se or Te ion implantation dosage scope are 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
In the present invention, described P
+ District 6 is the heavy diffusing, doping p type island region of boron, and junction depth is 0.5 μ m ~ 2.0 μ m, doping content 〉=1 * 10
20Ion/cm
3
In the present invention, described top electrode 7 and bottom electrode 8 are metal film electrode, and metal material is aluminium (Al), gold (Au) or golden evanohm (Au/Cr).
Prepare the preparation method of previously described Si-APD photodetector take black silicon material as photosensitive layer, it is characterized in that, comprise the following steps:
1. at intrinsic silicon substrate 1 upper surface oxidation growth SiO
2Rete, intrinsic silicon substrate used are the high resistant monocrystalline substrate in (111) crystal orientation, and resistivity is 1000 Ω cm ~ 2000 Ω cm; SiO
2Thicknesses of layers is 300nm ~ 400nm, and growth temperature is 1000 ℃;
2. at SiO
2The film surface surrounding makes the figure in annular N-type district 4 by lithography, then carries out the phosphorus diffusing, doping and forms annular N-type district 4; When the phosphorus diffusing, doping forms annular N-type district 4, temperature is 1000 ℃ ~ 1100 ℃, and phosphorus diffusing, doping concentration range is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3, junction depth is 1.5 μ m ~ 3.5 μ m;
3. at SiO
2Film surface makes the figure of p type island region 3 by lithography, then carries out the boron diffusing, doping and forms p type island region 3; When the boron diffusing, doping forms p type island region 3, temperature is 1000 ℃, and the junction depth of p type island region 3 is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
4. at SiO
2Film surface makes N by lithography
+Then the figure in district 2 carries out the heavy diffusing, doping of phosphorus and forms N
+District 2; The heavy diffusing, doping of phosphorus forms N
+Distinguishing 2 o'clock temperature is 1000 ℃, N
+The junction depth in district 2 is 0.1 μ m ~ 0.5 μ m, doping content 〉=1 * 10
20Ion/cm
3
5. the phosphorus heavy doping N to 4. processing through step
+District 2 carries out Se or Te ion implantation doping after the chemical corrosion extended surface, thereby forms N
+The black silicon layer 5 in district;
6. intrinsic silicon substrate 1 lower surface is carried out the heavy diffusing, doping of boron and form P
+District 6; The heavy diffusing, doping of boron forms P
+Distinguishing 6 o'clock temperature is 1000 ℃ ~ 1100 ℃, the heavy diffusing, doping concentration of boron 〉=1 * 10
20Ion/cm
3, junction depth is 0.5 μ m ~ 2.0 μ m;
7. electrode preparation.
As further description of the present invention, described step is 5. to N
+District 2 carries out the chemical corrosion extended surface when processing, and corrosive liquid used is to be that 30% hydrogen peroxide mixes by volume by deionized water, absolute ethyl alcohol, hydrofluoric acid, gold chloride and concentration; Wherein, to account for corrosive liquid total volume percent scope be 9% ~ 15% to absolute ethyl alcohol consumption volume; It is 9% ~ 15% that the hydrofluoric acid volume accounts for corrosive liquid total volume percent scope; It is 4% ~ 7% that the gold chloride volume accounts for corrosive liquid total volume percent scope; Concentration is that to account for corrosive liquid total volume percent scope be 50% ~ 60% for 30% hydrogen peroxide volume; All the other are deionized water.
As further description of the present invention, described step is the phosphorus heavy doping N to 4. processing through step 5.
+Distinguish the N on 2 surfaces
+When the district carried out ion implantation doping, doped chemical was selenium (Se) or tellurium (Te), and the ion implantation dosage scope is 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
Compared with prior art, the present invention has following beneficial effect:
One, in device when work,, being detected light radiation or the various reflector laser that material inspires is N by the photosurface of Si-APD photodetector
+The black silicon layer in district absorbs, the photo-generated carrier (hole-electron pair) that produces is high-speed motion under the inner high electric field action of APD optical diode, pass through impact ionization in motion process, produce quantity and be secondary, three new hole-electron pairs of tens times of hole-electron pairs first, thus the very large optical signal current of formation.
Two, adopted black silicon material as photosensitive layer in existing Si-APD photodetector, because black silicon material is processed through the chemical corrosion extended surface, had high specific area, so absorptivity is significantly improved, absorptivity can reach more than 90%; Simultaneously, black silicon material forms N through the heavy diffusing, doping of phosphorus
+District's conduction type is as the absorption light anti-reflection function district of APD photodetector; At last, Se or Te ion implantation doping help photosensitive layer to absorb the near infrared band light wave, thereby effectively widen the response wave band of photodetector.
Three, the present invention compares with traditional Si-APD photodetector, at the N of device
+District and p type island region surrounding have increased annular N-type district, due to the existence in annular N-type district, can reduce the generation of horizontal dark current, the light induced electron that produces when helping to absorb illumination rapidly, thus greatly improve the response speed of device.
Four, the present invention is with Novel black silicon materials and a kind of New Si that traditional Si-the APD photodetector combines-APD photodetector structure; Have the characteristics such as wide spectral absorption and antiradar reflectivity due to black silicon material, make this New Si-APD photodetector have the feature of spectrum extension and higher responsiveness, can improve responsiveness and the quantum efficiency of device especially in 700nm ~ 1200nm wave-length coverage.
Five, the Si-APD photodetector material therefor take black silicon material as photosensitive layer provided by the invention all take silicon as stock, therefore is easy to and existing semiconductor standard processes compatibility, and preparation process is simple, and cost is low; And, due to the micro-structural of black silicon material and have the oxygen group elements doping, make this new device have higher responsiveness and wide spectral response range.
Description of drawings
Fig. 1 is the cross-sectional view take black silicon as the Si-APD photodetector of photosensitive layer provided by the invention;
Fig. 2 is the top plan view structural representation take black silicon as the Si-APD photodetector of photosensitive layer provided by the invention;
Fig. 3 is the preparation method's schematic flow sheet take black silicon as the Si-APD photodetector of photosensitive layer provided by the invention;
Reference numeral wherein: the 1st, silicon intrinsic substrate, the 2nd, N
+District, the 3rd, p type island region, the 4th, annular N-type district, the 5th, N
+The black silicon layer, the 6th in district, P
+District, the 7th, top electrode, the 8th, bottom electrode.
Embodiment
Below in conjunction with drawings and Examples, specific implementation method of the present invention is further described.
A kind of Si-APD photodetector take black silicon as photosensitive layer as shown in Figure 1, 2, comprises silicon intrinsic substrate 1, is positioned at the N of silicon intrinsic substrate 1 upper face center
+Distinguish 2, be positioned at N
+Distinguish 2 belows p type island region 3, be positioned at silicon intrinsic substrate 1 upper surface surrounding annular N-type district 4, be positioned at N
+Distinguish the N of 2 upper surfaces
+The district deceives silicon layer 5, is positioned at the P of silicon intrinsic substrate 1 lower surface
+Distinguish 6, be positioned at N
+The top electrode 7 of the black silicon layer 5 in district and annular N-type district 4 upper surfaces and be positioned at P
+Distinguish the bottom electrode 8 of 6 lower surfaces.
In technique scheme:
Described N
+District 2 is the heavy diffusing, doping N-type of phosphorus district, and junction depth is 0.1 μ m ~ 0.5 μ m, doping content 〉=1 * 10
20Ion/cm
3
Described p type island region 3 is boron diffusing, doping p type island region, and junction depth is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
Described annular N-type district 4 is phosphorus diffusing, doping N-type district, and junction depth is 1.5 μ m ~ 3.5 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
Described N
+The black silicon layer 5 in district is N
+Distinguish that Se is carried out in 2 surfaces after the chemical corrosion extended surface or Te ion implantation doping obtains; Wherein Se or Te ion implantation dosage scope are 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
Described P
+ District 6 is the heavy diffusing, doping p type island region of boron, and junction depth is 0.5 μ m ~ 2.0 μ m, doping content 〉=1 * 10
20Ion/cm
3
Described top electrode 7 and bottom electrode 8 are metal film electrode, and metal material can be aluminium (Al), gold (Au) or golden evanohm (Au/Cr).
A kind of preparation method take black silicon as the Si-APD photodetector of photosensitive layer as shown in Figure 3, comprises the following steps:
Step 1: at intrinsic silicon substrate 1 upper surface oxidation growth SiO
2Rete.Intrinsic silicon substrate used is the high resistant monocrystalline substrate in (111) crystal orientation, and resistivity is 1000 Ω cm ~ 2000 Ω cm; SiO
2Thicknesses of layers is 300nm ~ 400nm, and growth temperature is 1000 ℃.
Step 2: at SiO
2The film surface surrounding makes the figure in annular N-type district 4 by lithography, then carries out the phosphorus diffusing, doping and forms annular N-type district 4; When the phosphorus diffusing, doping forms annular N-type district 4, temperature is 1000 ℃ ~ 1100 ℃, and phosphorus diffusing, doping concentration range is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3, junction depth is 1.5 μ m ~ 3.5 μ m.
Step 3: at SiO
2Film surface makes the figure of p type island region 3 by lithography, then carries out the boron diffusing, doping and forms p type island region 3; When the boron diffusing, doping forms p type island region 3, temperature is 1000 ℃, and the junction depth of p type island region 3 is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
Step 4: at SiO
2Film surface makes N by lithography
+Then the figure in district 2 carries out the heavy diffusing, doping of phosphorus and forms N
+District 2; The heavy diffusing, doping of phosphorus forms N
+Distinguishing 2 o'clock temperature is 1000 ℃, N
+The junction depth in district 2 is 0.1 μ m ~ 0.5 μ m, doping content 〉=1 * 10
20Ion/cm
3
Step 5: to the phosphorus heavy doping N that processes through step 4
+District 2 carries out Se or Te ion implantation doping after the chemical corrosion extended surface, thereby forms N
+The black silicon layer 5 in district.
Step 6: intrinsic silicon substrate 1 lower surface is carried out the heavy diffusing, doping of boron form P
+District 6; The heavy diffusing, doping of boron forms P
+Distinguishing 6 o'clock temperature is 1000 ℃ ~ 1100 ℃, the heavy diffusing, doping concentration of boron 〉=1 * 10
20Ion/cm
3, junction depth is 0.5 μ m ~ 2.0 μ m.
Step 7: electrode preparation.
And, step 5 described above couple N
+District 2 carries out the chemical corrosion extended surface when processing, and corrosive liquid used is to be that 30% hydrogen peroxide mixes by volume by deionized water, absolute ethyl alcohol, hydrofluoric acid, gold chloride and concentration.Wherein, to account for corrosive liquid total volume percent scope be 9% ~ 15% to absolute ethyl alcohol consumption volume; It is 9% ~ 15% that the hydrofluoric acid volume accounts for corrosive liquid total volume percent scope; It is 4% ~ 7% that the gold chloride volume accounts for corrosive liquid total volume percent scope; Concentration is that to account for corrosive liquid total volume percent scope be 50% ~ 60% for 30% hydrogen peroxide volume; All the other are deionized water.The step 5 couple phosphorus heavy doping N through step 4 processing
+Distinguish the N on 2 surfaces
+When the district carried out ion implantation doping, doped chemical was selenium (Se) or tellurium (Te), and the ion implantation dosage scope is 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
Through the Si-APD photodetector take black silicon material as photosensitive layer that above-mentioned steps is prepared, after tested, its response wave length scope is 400nm ~ 1200nm, and the responsiveness scope is 0.5A/W ~ 30A/W.
Be only below the exemplary embodiment in the numerous concrete ranges of application of the present invention, protection scope of the present invention is not constituted any limitation.All employing conversion or equivalence are replaced and the technical scheme of formation, within all dropping on rights protection scope of the present invention.
Claims (10)
1. the Si-APD photodetector take black silicon as photosensitive layer, is characterized in that, comprises silicon intrinsic substrate (1), is positioned at the N of silicon intrinsic substrate (1) upper face center
+Distinguish (2), be positioned at N
+The district (2) below p type island region (3), be positioned at silicon intrinsic substrate (1) upper surface surrounding annular N-type district (4), be positioned at N
+The N of district's (2) upper surface
+The district deceives silicon layer (5), is positioned at the P of silicon intrinsic substrate (1) lower surface
+Distinguish (6), be positioned at N
+The district deceives the top electrode (7) of silicon layer (5) and annular N-type district (4) upper surface and is positioned at P
+The bottom electrode (8) of district's (6) lower surface.
2. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that described N
+District (2) is the heavy diffusing, doping N-type of phosphorus district, and junction depth is 0.1 μ m ~ 0.5 μ m, doping content 〉=1 * 10
20Ion/cm
3
3. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that, described p type island region (3) is boron diffusing, doping p type island region, and junction depth is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
4. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that, described annular N-type district (4) is phosphorus diffusing, doping N-type district, and junction depth is 1.5 μ m ~ 3.5 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
5. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that described N
+The black silicon layer (5) in district is N
+District (2) carries out Se in the surface after the chemical corrosion extended surface or Te ion implantation doping obtains; Wherein Se or Te ion implantation dosage scope are 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
6. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that described P
+District (6) is the heavy diffusing, doping p type island region of boron, and junction depth is 0.5 μ m ~ 2.0 μ m, doping content 〉=1 * 10
20Ion/cm
3
7. the Si-APD photodetector take black silicon as photosensitive layer according to claim 1, is characterized in that, described top electrode (7) and bottom electrode (8) are metal film electrode, and metal material is aluminium Al, golden Au or golden evanohm Au/Cr.
8. prepare the method take black silicon as the Si-APD photodetector of photosensitive layer as claimed in claim 1, it is characterized in that, comprise the following steps:
1. at intrinsic silicon substrate (1) upper surface oxidation growth SiO
2Rete, intrinsic silicon substrate used are the high resistant monocrystalline substrate in (111) crystal orientation, and resistivity is 1000 Ω cm ~ 2000 Ω cm; SiO
2Thicknesses of layers is 300nm ~ 400nm, and growth temperature is 1000 ℃;
2. at SiO
2The film surface surrounding makes the figure in annular N-type district (4) by lithography, then carries out the phosphorus diffusing, doping and forms annular N-type district (4); When the phosphorus diffusing, doping forms annular N-type district (4), temperature is 1000 ℃ ~ 1100 ℃, and phosphorus diffusing, doping concentration range is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3, junction depth is 1.5 μ m ~ 3.5 μ m;
3. at SiO
2Film surface makes the figure of p type island region (3) by lithography, then carries out the boron diffusing, doping and forms p type island region (3); When the boron diffusing, doping forms p type island region (3), temperature is 1000 ℃, and the junction depth of p type island region (3) is 0.5 μ m ~ 3.0 μ m, and the doping content scope is 4 * 10
15Ion/cm
3~ 2 * 10
17Ion/cm
3
4. at SiO
2Film surface makes N by lithography
+The figure in district (2) then carries out the heavy diffusing, doping of phosphorus and forms N
+District (2); The heavy diffusing, doping of phosphorus forms N
+During district (2), temperature is 1000 ℃, N
+The junction depth in district (2) is 0.1 μ m ~ 0.5 μ m, and the doping content scope is 〉=1 * 10
20Ion/cm
3
5. to the phosphorus heavy doping N through 4. processing
+District (2) carries out Se or Te ion implantation doping after the chemical corrosion extended surface, thereby forms N
+The black silicon layer (5) in district;
6. intrinsic silicon substrate (1) lower surface is carried out the heavy diffusing, doping of boron and form P
+District (6); The heavy diffusing, doping of boron forms P
+During district (6), temperature is 1000 ℃ ~ 1100 ℃, the heavy diffusing, doping concentration of boron 〉=1 * 10
20Ion/cm
3, junction depth is 0.5 μ m ~ 2.0 μ m;
7. electrode preparation.
9. the preparation method take black silicon as the Si-APD photodetector of photosensitive layer according to claim 8, is characterized in that, described step is 5. to N
+District (2) carries out the chemical corrosion extended surface when processing, and corrosive liquid used is to be that 30% hydrogen peroxide mixes by volume by deionized water, absolute ethyl alcohol, hydrofluoric acid, gold chloride and concentration; Wherein, to account for corrosive liquid total volume percent scope be 9% ~ 15% to absolute ethyl alcohol consumption volume; It is 9% ~ 15% that the hydrofluoric acid volume accounts for corrosive liquid total volume percent scope; It is 4% ~ 7% that the gold chloride volume accounts for corrosive liquid total volume percent scope; Concentration is that to account for corrosive liquid total volume percent scope be 50% ~ 60% for 30% hydrogen peroxide volume; All the other are deionized water.
10. the preparation method take black silicon as the Si-APD photodetector of photosensitive layer according to claim 8, is characterized in that, described step is the phosphorus heavy doping N to 4. processing through step 5.
+The N on surface, district (2)
+When the district carried out ion implantation doping, doped chemical was selenium Se or tellurium Te, and the ion implantation dosage scope is 1 * 10
14Ion/cm
2~ 1 * 10
16Ion/cm
2
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