CN103113823A - Functional paint and preparation method thereof - Google Patents
Functional paint and preparation method thereof Download PDFInfo
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- CN103113823A CN103113823A CN2012103886180A CN201210388618A CN103113823A CN 103113823 A CN103113823 A CN 103113823A CN 2012103886180 A CN2012103886180 A CN 2012103886180A CN 201210388618 A CN201210388618 A CN 201210388618A CN 103113823 A CN103113823 A CN 103113823A
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Abstract
The invention relates to a functional paint, particularly an anticorrosion paint for cutters, which comprises a basic paint and an organic silicon resin in a volume ratio of 1:(0.5-4), wherein the basic paint comprises the following components in percentage by volume: 5-25% of pH regulator, 0.001-0.7% of functional catalyst and the balance of siloxane composition. The functional catalyst is a catalyst containing carbon powder; and the functional catalyst comprises the following components in percentage by volume: 20-60% of zirconate, 1-15% of acetylacetone and the balance of isopropanol. The siloxane composition comprises the following components in percentage by volume: 7-25% of diphenyldimethoxysiloxane, 7-15% of methyltrimethoxysiloxane, 1-5% of gamma-glycidol ether oxypropyltrimethoxysilane, 7-10% of phenyltrimethoxysiloxane and the balance of propylene glycol monomethyl ether. The zirconate, acetylacetone and isopropanol form a space cross-linked structure, thereby being beneficial to controlling the performance of the mild reaction. Compared with the technique of using the single zirconate catalyst, the invention can better control the reaction rate.
Description
[technical field]
The present invention relates to technical field of coatings, specifically, is a kind of functional coating and preparation method thereof.
[background technology]
In coating, the granularity of pigment and the dispersiveness in base-material will affect gloss of film.The pigment fineness is thinner, and the dispersing uniformity in base-material is better, helps to form smooth smooth paint film.Resin-pigment ratio in coating exerts an influence to gloss of film.Because having weakened specular reflection, granules of pigments in paint film causes gloss reducing, and along with the increase gloss of pigment volume concentration (PVC) (P.V.C) descends gradually.Resin-pigment ratio one timing, the oil number of pigment is larger, and gloss is lower.Pigment of all kinds is different with degree of reflection to Optical Absorption, due to pitch-dark, light is absorbed fully, and white paint reflects fully to light, so black paint shows high gloss than white paint.The solvent species of selecting in paint directly affects the speed of its evaporation rate, and the too fast or excessively slow smooth degree that all can affect paint film reduces gloss of film.
The filmogen of anticorrosive coating has chemical stability in corrosive medium, its standard is relevant with composition and the chemical structure of filmogen.Be mainly see it under the dry film condition whether easily and corrosive medium reacts or resolve into small molecules in medium.No matter still consider from simple buffer action from anti-galvanic corrosion, the shielding effect of anticorrosive coating is all very important,
[summary of the invention]
The object of the invention is to overcome the deficiencies in the prior art, a kind of functional coating and preparation method thereof is provided.
The objective of the invention is to be achieved through the following technical solutions:
Technical scheme one: a kind of anticorrosive coating for cutter
A kind of anticorrosive coating for cutter, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5～4, is preferably 1: 3.
A kind of preparation method of the anticorrosive coating for cutter after basic coating and silicone resin are mixed, obtains the anticorrosive coating for cutter.
Described basic coating, its component volume percent is:
PH adjusting agent 5～25%
Function catalyzer 0.001～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of anticorrosive coating is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15, is preferably 1: 13; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 1, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 85nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 20～60%
Methyl ethyl diketone 1～15%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of anticorrosive coating for cutter can be sprayed directly into coating on cutter.
Technical scheme two: a kind of protective system for the cast iron kitchen range
A kind of protective system for the cast iron kitchen range, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5～2.5, is preferably 1: 1.5.
A kind of preparation method of the protective system for the cast iron kitchen range after basic coating and silicone resin are mixed, obtains the protective system for the cast iron kitchen range.
Described basic coating, its component volume percent is:
PH adjusting agent 1～25%
Function catalyzer 0.002～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of protective system is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 1: 2, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 75nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 15～60%
Methyl ethyl diketone 1～15%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of protective system for the cast iron kitchen range can be sprayed directly into coating on the cast iron kitchen range.
Technical scheme three: a kind of high-performance coating for screw
A kind of high-performance coating for screw, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5～1.5, is preferably 1:1.3.
A kind of preparation method of the high-performance coating for screw after basic coating and silicone resin are mixed, obtains the high-performance coating for screw.
Described basic coating, its component volume percent is:
PH adjusting agent 1～25%
Function catalyzer 0.003～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of high-performance coating is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15, is preferably 1: 7; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 2, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 15～60%
Methyl ethyl diketone 1～15%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of high-performance coating for screw can be sprayed directly into coating on screw.
Technical scheme four: a kind of high-performance coating for electric iron
A kind of high-performance coating for electric iron, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.2～1.2, is preferably 1: 1.
A kind of preparation method of the high-performance coating for electric iron after basic coating and silicone resin are mixed, obtains the high-performance coating for electric iron.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～25%
Function catalyzer 0.004～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of high-performance coating is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 4～15, is preferably 1: 10; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 3, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 95nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～60%
Methyl ethyl diketone 1～20%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of high-performance coating for electric iron can be sprayed directly into coating on electric iron.
Technical scheme five: a kind of efficient coating for the lighting housing
A kind of efficient coating for the lighting housing, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.4～1.4, is preferably 1: 0.7.
A kind of preparation method of the efficient coating for the lighting housing after basic coating and silicone resin are mixed, obtains the efficient coating for the lighting housing.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～22%
Function catalyzer 0.005～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of efficient coating is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 7～15, is preferably 1: 9; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 4, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～55%
Methyl ethyl diketone 1～18%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of efficient coating for the lighting housing can be sprayed directly into coating on the lighting housing.
Technical scheme six: a kind of health paint for life small household appliances sandwich layer
A kind of health paint for life small household appliances sandwich layer, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.6～1.6, is preferably 1: 1.4.Life small household appliances are such as the interior coating of soybean milk maker or the undercoat of thermos cup.
A kind of preparation method of the health paint for life small household appliances sandwich layer after basic coating and silicone resin are mixed, obtains the health paint for life small household appliances sandwich layer.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～23%
Function catalyzer 0.006～0.7%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of health paint is 1～5;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 8～15, is preferably 1: 13; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 6, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 75nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～52%
Methyl ethyl diketone 1～17%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of health paint for life small household appliances sandwich layer can be sprayed directly into coating on the small household appliances sandwich layer.
Technical scheme seven: a kind of environmental protection coating material for the cosmetology fixture
A kind of environmental protection coating material for the cosmetology fixture, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.7～1.7, is preferably 1: 1.1.
A kind of preparation method of the environmental protection coating material for the cosmetology fixture after basic coating and silicone resin are mixed, obtains the environmental protection coating material for the cosmetology fixture.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～19%
Function catalyzer 0.007～0.5%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of environmental protection coating material is 1～4.1;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 8～15, is preferably 1: 10; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 3: 1, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 60nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～48%
Methyl ethyl diketone 1～14%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of environmental protection coating material for the cosmetology fixture can be sprayed directly into coating on the cosmetology fixture.
Technical scheme eight: a kind of Multifunctional composite coating for heating installation
A kind of Multifunctional composite coating for heating installation, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.8～1.8, is preferably 1: 1.4.Heating installation is radiator and other, perhaps the instrument such as heating tube.
A kind of preparation method of the Multifunctional composite coating for heating installation after basic coating and silicone resin are mixed, obtains the Multifunctional composite coating for heating installation.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～22%
Function catalyzer 0.008～0.6%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of Multifunctional composite coating is 1～4.2;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 3: 2, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 65nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～51%
Methyl ethyl diketone 1～16%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of Multifunctional composite coating for heating installation can be sprayed directly into coating on heating installation.
Technical scheme nine: a kind of anticorrosion composite coating for isolator
A kind of anticorrosion composite coating for isolator, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.9～1.9, is preferably 1: 1.7.Heating installation is radiator and other, perhaps the instrument such as heating tube.Isolator is such as being graphite flake.
A kind of preparation method of the anticorrosion composite coating for isolator after basic coating and silicone resin are mixed, obtains the anticorrosion composite coating for isolator.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～20%
Function catalyzer 0.009～0.4%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of anticorrosion composite coating is 1～4.3;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 3: 3, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 70nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～47%
Methyl ethyl diketone 1～13%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of anticorrosion composite coating for isolator can be sprayed directly into coating on the isolator head.
Technical scheme ten: a kind of high-performance coating for rolling screen door
A kind of high-performance coating for rolling screen door, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 1～5, is preferably 1: 3.Heating installation is radiator and other, perhaps the instrument such as heating tube.
A kind of preparation method of the high-performance coating for rolling screen door after basic coating and silicone resin are mixed, obtains the high-performance coating for rolling screen door.
Described basic coating, its component volume percent is:
PH adjusting agent 0.1～21%
Function catalyzer 0.0065～0.1%
The silicone composition surplus
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of high-performance coating is 1～4.6;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15, is preferably 1: 13; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 4: 1, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals, be preferably 80nm; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is:
Zirconate 1～46%
Methyl ethyl diketone 1～15%
The Virahol surplus
The preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is:
A kind of high-performance coating for rolling screen door can be sprayed directly into coating on rolling screen door.
Compared with prior art, positively effect of the present invention is:
Phenylbenzene dimethoxysiloxane of the present invention is first as one of the component of the siloxanes in coating, and its effect that has makes the coating of preparation have very high gloss for improving the gloss of coating; Main effect if it were not for playing conventional siloxanes; The orientation property of raising system increases the heat-resisting oxidation-resistance performance of system, has strengthened the repulsion performance to water, improves thermo-elasticity, improve with the consistency of organic resin, with the mutual solubility of pigment.And good to agglutinating value(of coal), the stability in storage of various materials.
The present invention is by zirconate, and methyl ethyl diketone and Virahol form a space crosslinking structure, and the gentleness that is conducive to control reaction is carried out, and more can control speed of reaction than the catalyzer that only adopts zirconate.Can with ground and coating in reactive group generation crosslinking reaction, form crane span structure, molecular weight is increased.And coating and ground finally make its sticking power improve by the crane span structure effect, can also improve water tolerance simultaneously, solvent resistance and boiling fastness, the rate of drying of raising paint film, surface luster.
The present invention contains the coffee charcoal, and product has following advantage: coffee charcoal raw materials for production are from the coffee grounds that reclaims, and the environmental protection recycling does not increase the burden of the earth, thereby reaches the purpose of carbon reduction; When health or when environment has peculiar smell at one's side, also can peculiar smell be absorbed by the Van der Waals force effect; Coffee carbon structure space is large, surface irregularity, and high to the assimilated efficiency of heat, speed is fast, has moment intensification function.
The present invention contains the fruit shell carbon of apricot shell and nut-shell formation, have that pore texture prosperity, specific surface area are large, high adsorption capacity, physical strength is high, bed resistance is little, chemical stability is good, easy regeneration, the advantage such as durable in use, and has the granularity of all size; Decompose obnoxious flavour and the various peculiar smell such as airborne formaldehyde, ammonia, benzene, cigarette, oil smoke, especially carcinogenic aromatic substance, activated carbon have extremely strong adsorptive power.
Low-temperature carbonization and middle temperature charing are taked in powdered carbon preparation of the present invention, obtain powdered carbon, and it reduces costs, and its particle diameter satisfies again the requirement of application of paints simultaneously.
The present invention plays with the carrier of powdered carbon as catalyzer the effect of controlling speed of reaction and performance powdered carbon self.
[embodiment]
The embodiment of a kind of functional coating of the present invention and preparation method thereof below is provided.
Embodiment 1
A kind of anticorrosive coating for cutter, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5.
A kind of preparation method of the anticorrosive coating for cutter after basic coating and silicone resin are mixed, obtains the anticorrosive coating for cutter.
Described basic coating, its component volume percent is: pH adjusting agent is 5%, and the function catalyzer is 0.001%, and silicone composition is 94.999%;
The preparation method of described basic coating, its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
Described pH adjusting agent is water and mixing acid, and wherein acid is hydrochloric acid and acetic acid; Be mainly used to regulate the pH value, the pH value of anticorrosive coating is 1～4;
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5; Powdered carbon is because its space is more, its adsorptive catalyst, and the slow gentleness that is conducive to react is carried out, and is conducive to control the progress with conditioned reaction.
Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 1, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals; Described method of micronization is ball milled, supercentrifugal process or nanotechnology etc.;
Described catalyzer, its component volume percent is: zirconate is 20%, methyl ethyl diketone is 1%, Virahol is 79%, the preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first add Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
The preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h;
Described silicone composition, its component volume percent is: the phenylbenzene dimethoxysiloxane is 7%, methyl trimethoxy oxygen radical siloxane is 7%, γ-glycidyl ether oxygen propyl trimethoxy silicane is 1%, the phenyl trimethoxy siloxane is 7%, and propylene glycol monomethyl ether is 78%
A kind of anticorrosive coating for cutter can be sprayed directly into coating on cutter.
Table 1-1 embodiment 1 who is used for the anticorrosive coating of cutter detects data:
Embodiment 2-5
A kind of anticorrosive coating for cutter, concrete preparation method sees technological line one for details, and the proportioning of its Raw is shown in table 2.
Table 1 is a kind of proportioning raw materials situation of the anticorrosive coating for cutter
Embodiment 6-10
A kind of protective system for the cast iron kitchen range, concrete preparation method sees technological line two for details, and the proportioning of its Raw is shown in table 2.
Table 2 is a kind of proportioning raw materials situation of the protective system for the cast iron kitchen range
Test data is: table 2-2 embodiment 6 test datas that are used for the protective system of cast iron kitchen range
Embodiment 11-15
A kind of high-performance coating for screw, concrete preparation method sees technological line three for details, and the proportioning of its Raw is shown in table 3.
Table 3 is a kind of proportioning raw materials situation of the high-performance coating for screw
Detect data: table 3-3 test data for the embodiment 11 of the high-performance coating of screw
Embodiment 16-20
A kind of high-performance coating for electric iron, concrete preparation method sees technological line four for details, and the proportioning of its Raw is shown in table 4.
Table 4 is a kind of proportioning raw materials situation of the high-performance coating for electric iron
Detect data: table 4-4 test data for the embodiment 16 of the high-performance coating of electric iron
Embodiment 21-25
A kind of efficient coating for the lighting housing, concrete preparation method sees technological line five for details, and the proportioning of its Raw is shown in table 5.
Table 5 is a kind of proportioning raw materials situation of the efficient coating for the lighting housing
Test data: table 5-5 is a kind of embodiment 21 test datas of the efficient coating for the lighting housing
Embodiment 26-30
A kind of health paint for life small household appliances sandwich layer, concrete preparation method sees technological line six for details, and the proportioning of its Raw is shown in table 6.
Table 6 is a kind of proportioning raw materials situation of the health paint for life small household appliances sandwich layer
Table 6-6 test data for the embodiment 26 of the high-performance coating of electric iron
Embodiment 31-35
A kind of environmental protection coating material for the cosmetology fixture, concrete preparation method sees technological line seven for details, and the proportioning of its Raw is shown in table 7.
Table 7 is a kind of proportioning raw materials situation of the environmental protection coating material for the cosmetology fixture
Table 7-7 is a kind of embodiment 31 test datas of the environmental protection coating material for the cosmetology fixture
Embodiment 36-40
A kind of Multifunctional composite coating for heating installation, concrete preparation method sees technological line eight for details, and the proportioning of its Raw is shown in table 8.
Table 8 is a kind of proportioning raw materials situation of the Multifunctional composite coating for heating installation
Test data is: table 8-8 embodiment 36 test datas that are used for the Multifunctional composite coating of heating installation
Embodiment 41-45
A kind of anticorrosion composite coating for isolator, concrete preparation method sees technological line nine for details, and the proportioning of its Raw is that table 9 shows.
Table 9 proportioning raw materials situation that is used for the anticorrosion composite coating of isolator
Test data: table 9-9 test data for the embodiment 41 of the anticorrosion composite coating of isolator
Embodiment 46-50
A kind of high-performance coating for rolling screen door, concrete preparation method sees technological line ten for details, and the proportioning of its Raw is table 10.
Table 10 proportioning raw materials situation that is used for the high-performance coating of rolling screen door
Test data: table 10-10 test data for the embodiment 46 of the high-performance coating of rolling screen door
Claims (8)
1. a functional coating, be specially a kind of anticorrosive coating for cutter, it is characterized in that, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5～4;
Described basic coating, its component volume percent is:
PH adjusting agent 5～25%
Function catalyzer 0.001～0.7%
The silicone composition surplus
Described function catalyzer, for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15;
Described catalyzer, its component volume percent is:
Zirconate 20～60%
Methyl ethyl diketone 1～15%
The Virahol surplus
Described silicone composition, its component volume percent is:
2. a kind of functional coating as claimed in claim 1, is characterized in that, the preparation method of described basic coating, and its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
3. a kind of functional coating as claimed in claim 1, is characterized in that, described powdered carbon preparation method, and its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 2: 1, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals.
4. a kind of functional coating as claimed in claim 1, is characterized in that, the preparation method of described catalyzer is: temperature in reactor is controlled at 40 ℃, first adds Virahol, add while stirring zirconate, low rate mixing approximately 5 minutes until mix; Slowly drip in the above-mentioned mixed solution that methyl ethyl diketone mixes to the reactor reaction 1 hour under 40 ℃ after dropwising, cooling discharging under whipped state.
5. a kind of functional coating as claimed in claim 1, is characterized in that, the preparation method of described function catalyzer is: powdered carbon is added the people in catalyzer, constantly stir, the reaction times is 1～3h.
6. a protective system that is used for the cast iron kitchen range, is characterized in that, it comprises basic coating and silicone resin, and the volume ratio of basic coating and silicone resin is 1: 0.5～2.5;
Described basic coating, its component volume percent is:
PH adjusting agent 1～25%
Function catalyzer 0.002～0.7%
The silicone composition surplus
Described catalyzer, its component volume percent is:
Zirconate 15～60%
Methyl ethyl diketone 1～15%
The Virahol surplus
Described silicone composition, its component volume percent is:
7. a kind of protective system for the cast iron kitchen range as claimed in claim 6, is characterized in that, the preparation method of described basic coating, and its concrete steps are:
One, temperature in reactor is controlled at 40 ℃, the limit is stirred and to be added according to quantity successively silicone composition, and stir speed (S.S.) is 300r/min, low rate mixing approximately 5min until mix;
Two, with the H in pH adjusting agent
2O and mixing acid mix in other clean containers, after slowly drop to while stirring in the silicone composition that mixes in reactor; Time for adding is 15～20min;
Three, after silicone composition and pH adjusting agent hybrid reaction 2h, the function catalyzer is joined mixed solution;
Four, after the function catalyzer adds reaction 1h, detect discharging after being cooled to room temperature.
8. a kind of protective system for the cast iron kitchen range as claimed in claim 6, is characterized in that, described function catalyzer, and for containing the catalyzer of powdered carbon, wherein, the solid-to-liquid ratio of powdered carbon and catalyzer is 1: 5～15; Described powdered carbon preparation method, its concrete steps are:
(1) charing: apricot shell, nut-shell and coffee grounds are raw material, three's raw materials quality ratio is 1: 1: 2, first through the drying treatment of 150～180 ℃ 1～2 hour, afterwards temperature is risen to 300～400 ℃ of calcinings 1～2 hour, and then be warming up to 600～700 ℃ of calcinings 1～2 hour, obtain multi-functional powdered carbon;
(2) micronization: multi-functional powdered carbon is carried out micronization, grind to form the powdered carbon of 30～200 nano-scale multifunctionals.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087157A (en) * | 2014-06-25 | 2014-10-08 | 沈太英 | Ceramic coating for decorative wall in public place |
| CN104403457A (en) * | 2014-12-13 | 2015-03-11 | 常熟市磊王合金工具有限公司 | Wear-resisting double-edge diamond cutter |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN101857772A (en) * | 2010-06-22 | 2010-10-13 | 北京红狮漆业有限公司 | Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof |
-
2012
- 2012-10-12 CN CN201210388618.0A patent/CN103113823B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
| CN101857772A (en) * | 2010-06-22 | 2010-10-13 | 北京红狮漆业有限公司 | Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087157A (en) * | 2014-06-25 | 2014-10-08 | 沈太英 | Ceramic coating for decorative wall in public place |
| CN104403457A (en) * | 2014-12-13 | 2015-03-11 | 常熟市磊王合金工具有限公司 | Wear-resisting double-edge diamond cutter |
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