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CN103113823B - Functional paint and preparation method thereof - Google Patents

Functional paint and preparation method thereof Download PDF

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CN103113823B
CN103113823B CN 201210388618 CN201210388618A CN103113823B CN 103113823 B CN103113823 B CN 103113823B CN 201210388618 CN201210388618 CN 201210388618 CN 201210388618 A CN201210388618 A CN 201210388618A CN 103113823 B CN103113823 B CN 103113823B
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functional
paint
preparation
method
functional paint
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CN 201210388618
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CN103113823A (en )
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李力锋
张德刚
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上海宜瓷龙新材料股份有限公司
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Abstract

本发明涉及一种功能性涂料,具体为一种用于刀具的防腐蚀涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1∶0.5~4;所述的基本涂料,其组份体积百分比为:pH调节剂为5~25%,功能催化剂为0.001~0.7%,硅氧烷组合物为余量,所述的功能催化剂,为含有炭粉的催化剂;异丙醇为余量,所述的硅氧烷组合物,其组份体积百分比为:二苯基二甲氧基硅氧烷为7~25%,甲基三甲氧基硅氧烷为7~15%,γ-缩水甘油醚氧丙基三甲氧基硅烷为1~5%,苯基三甲氧基硅氧烷为7~10%,丙二醇甲醚为余量。 The present invention relates to a functional coating, in particular to an anti-corrosion coatings for cutting tools, comprising a base paint and a silicone resin, the volume ratio of base paint and the silicone resin is 0.5 to 4; said substantially coating volume percentage of the group were as follows: pH adjusting agent is from 5 to 25%, the function of the catalyst is from 0.001 to 0.7%, the balance of the silicone composition, the function of the catalyst, a catalyst containing carbon powder; isopropyl alcohol balance, the silicone composition, volume percentage of the group were: diphenyldimethoxysilane 7 to 25%, silicones, methyl trimethoxy siloxane is 7 to 15% , [gamma] glycidoxypropyl trimethoxysilane of 1 to 5%, of silicone phenyltrimethoxysilane 7 to 10%, the balance of propylene glycol methyl ether. 本发明通过锆酸酯,乙酰丙酮以及异丙醇形成一个空间交联结构,有利于控制反应的温和进行,比单单采用锆酸酯的催化剂更加能够控制反应速率。 The catalyst of the present invention, a space is formed crosslinked structure, mild facilitate control of the reaction, than by simply using zirconate zirconate, acetylacetone and isopropanol better able to control the reaction rate.

Description

一种功能性涂料及其制备方法【技术领域】 A functional coating and preparation method thereof FIELD

[0001] 本发明涉及涂料技术领域,具体地说,是一种功能性涂料及其制备方法。 [0001] The present invention relates to the field of coating technology, specifically, a functional coating and its method of preparation. 【背景技术】 【Background technique】

[0002] 涂料中颜料的粒度及在基料中的分散性将影响漆膜光泽。 [0002] The particle size of the paint pigment and the dispersibility in binder will affect the film gloss. 颜料细度越细,在基料中的分散均匀性越好,有助于形成平整光滑的漆膜。 The finer the pigment fineness, uniformity of dispersion in the binder the better, contribute to the formation of smooth film. 涂料中的颜基比对漆膜光泽产生影响。 Paint pigment to binder ratio affect the film gloss. 由于漆膜中颜料颗粒弱化了镜面反射致使光泽降低,而且随着颜料体积浓度(PVC)的增加光泽逐渐下降。 Since the pigment particles weaken the film specular reflection causes reduced gloss, but also with a pigment volume concentration (PVC) is decreased to increase the gloss. 颜基比一定时,颜料的吸油量越大,光泽越低。 It is constant, the larger the oil absorption of the pigment of pigment to binder ratio, the lower the gloss. 各色颜料对光的吸收和反射程度不同,由于黑漆对光完全吸收,而白漆对光完全反射,所以黑色漆比白色漆显示高光泽。 Different absorption and degree of reflection of light colored pigments, black due to the light is completely absorbed, and the light totally reflecting white paint, black paint so that a white display than the high-gloss paints. 油漆中选用的溶剂种类直接影响其挥发速度的快慢,而过快或过慢都会影响漆膜的平整程度,降低漆膜光泽。 Type of solvent chosen directly affects the paint in which the speed of volatilization rate, and fast or too slow will affect the degree of formation of the film, reduce film gloss.

[0003] 防腐蚀涂料的成膜物质在腐蚀介质中具有化学稳定性,其标准与成膜物质的组成和化学结构有关。 [0003] The anticorrosive coating film-forming material having a chemical stability in corrosive media, the standard composition and chemical structure of the film material concerned. 主要是看它在干膜条件下是否易与腐蚀介质发生反应或在介质中分解成小分子。 Mainly to see if it is easy to react with the corrosive medium or broken down into small molecules in the medium at a dry film conditions. 无论从防电化学腐蚀还是从单纯的隔离作用考虑,防腐蚀涂料的屏蔽作用都很重要, 【发明内容】 Whether or consideration from the anti-electrochemical corrosion from the simple isolation, anti-corrosion coating shielding effect is very important, SUMMARY OF THE INVENTION

[0004] 本发明的目的在于克服现有技术的不足,提供一种功能性涂料及其制备方法。 [0004] The object of the present invention is to overcome the disadvantages of the prior art, to provide a functional coating and its method of preparation.

[0005] 本发明的目的是通过以下技术方案来实现的: [0005] The object of the present invention is achieved by the following technical solution:

[0006] 技术方案一:一种用于刀具的防腐蚀涂料 [0006] Technical Solution a: an anti-corrosion coatings for tools

[0007] -种用于刀具的防腐蚀涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.5〜4,优选为1 : 3。 [0007] - anti-corrosion coatings for kinds of tools, comprising a base paint and the volume ratio of the silicone resin, and a silicone resin base paint is 1: 0.5~4, preferably 1: 3.

[0008] -种用于刀具的防腐蚀涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于刀具的防腐蚀涂料。 [0008] - anti-corrosion coatings for kinds of tool preparation method, after mixing base paint and a silicone resin, to obtain the anti-corrosion coatings for tools.

[0009] 所述的基本涂料,其组份体积百分比为: [0009] The basic coating, the volume percentage of components:

[0010] pH调节剂5〜25% [0010] pH adjusting agents 5~25%

[0011] 功能催化剂0.001〜0.7% [0011] The function of the catalyst 0.001~0.7%

[0012] 硅氧烷组合物余量 [0012] The silicone composition balance

[0013] 所述的基本涂料的制备方法,其具体步骤为: [0013] The method of preparing the basic coating, including the following steps:

[0014] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0014] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0015] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0015] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0016] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0016] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0017] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0017] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0018] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,防腐蚀涂料的pH值为1〜4 ; pH adjusters [0018] The mixing of water and acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of 1 ~ 4 anticorrosive coating;

[0019] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15,优选为1 : 13;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0019], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15, preferably 1: 13; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0020] 所述的炭粉制备方法,其具体步骤为: [0020] The method for preparing carbon powder, including the following steps:

[0021] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 1,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0021] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 1, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0022] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为85nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0022] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably of 85 nm; the micronization process of ball milling, or high-speed centrifugation nanotechnology;

[0023] 所述的催化剂,其组份体积百分比为: [0023] The catalyst component volume percentage of which:

[0024] 锆酸酯20〜60% [0024] zirconate 20~60%

[0025] 乙酰丙酮1〜15% [0025] acetylacetonate 1~15%

[0026] 异丙醇余量 [0026] The remaining isopropanol

[0027] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0027] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0028] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0028] The catalyst was: addition of the carbon powder into the catalyst, for continuous stirring, the reaction time is 1~3h;

[0029] 所述的硅氧烷组合物,其组份体积百分比为: [0029] The silicone composition, its composition by volume percent:

[0030] 本咕:1丨1U _氧烷7〜25% 1 丨ΠΙ'.ΨΗ._Ί::Η 烷7++++--15% γ-缩水llliMtKWC 111¾.½¾ 烷卜〜5% 苯坫--:屮氣坫砧氣烷7〜10% W :醉余M [0030] The present cushions: Shu 1U 1 _ 1% alumoxane 7~25 alkyl Shu ΠΙ'.ΨΗ._Ί :: Η 7 ++++ - 15% γ- glycidyl llliMtKWC 111¾.½¾ ~ 5% alkyl benzene Bu goblets -: Che gas goblets anvil gas alkoxy 7~10% W: M drunk

[0031] 一种用于刀具的防腐蚀涂料,可以将涂料直接喷涂到刀具上。 [0031] A tool for anti-corrosion coatings, paints can be sprayed directly onto the tool.

[0032] 技术方案二:一种用于铸铁灶头的防腐涂料 [0032] Technical Solution II: cast iron stove for anticorrosive coating

[0033] -种用于铸铁灶头的防腐涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.5〜2. 5,优选为1 : 1.5。 [0033] - preservatives and coatings for cast iron stove, comprising a base paint and a silicone resin, a silicone resin base paint and a volume ratio of 1: 0.5~2 5, preferably 1: 1.5.

[0034] 一种用于铸铁灶头的防腐涂料的制备方法,将基本涂料以及有机硅树脂混合后, 得到用于铸铁灶头的防腐涂料。 Preparation of anti-corrosion coatings [0034] A cast iron stove, and after mixing base paint and a silicone resin, to obtain the anti-corrosion coatings for cast iron stove.

[0035] 所述的基本涂料,其组份体积百分比为: [0035] The basic coating, the volume percentage of components:

[0036] pH调节剂1〜25% [0036] pH adjusting agents 1~25%

[0037] 功能催化剂0.002〜0.7% [0037] The function of the catalyst 0.002~0.7%

[0038] 硅氧烷组合物余量 [0038] The silicone composition balance

[0039] 所述的基本涂料的制备方法,其具体步骤为: [0039] The method of preparing the basic coating, including the following steps:

[0040] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0040] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0041] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0041] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0042] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0042] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0043] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0043] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0044] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,防腐涂料的pH值为1〜4 ; [0044] The pH adjusting agents are water and a mixed acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH, anti-corrosion coating is pH ~ 4;

[0045] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15 ;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0045], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15; Toner As more voids which adsorption catalyst to facilitate the reaction slowly be moderate, it is conducive to control and regulate the progress of the reaction.

[0046] 所述的炭粉制备方法,其具体步骤为: [0046] The method for preparing carbon powder, including the following steps:

[0047] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为I : 1 : 2,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0047] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three I: 1: 2, after the first drying process 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0048] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为75nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0048] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 75nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0049] 所述的催化剂,其组份体积百分比为: [0049] The catalyst component volume percentage of which:

[0050] 锆酸酯15〜60% [0050] zirconate 15~60%

[0051] 乙酰丙酮1〜15% [0051] acetylacetonate 1~15%

[0052] 异丙醇余量 [0052] The remaining isopropanol

[0053] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0053] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0054] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0054] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0055] 所述的硅氧烷组合物,其组份体积百分比为: [0055] The silicone composition, its composition by volume percent:

[0056] 二苯沾屮ϋ坫ii氧烷7〜25% 屮咕〔屮+H^rtH烷7〜15% ¥-缩水内-坫〜15% 苯M…:111鉍M砧%[烷7〜10% [0056] James Che ϋ diphenyl siloxane 7~25% goblets ii cushions [Cao Cao + H ^ rtH alkoxy 7~15% ¥ - the glycidyl - benzene goblets ~ 15% M ...: 111% bismuth anvil M [7 alkoxy ~ 10%

[Al-余M: [Al- Yu M:

[0057] -种用于铸铁灶头的防腐涂料,可以将涂料直接喷涂到铸铁灶头上。 [0057] - kind of anti-corrosion coatings for cast iron stove, the coating can be sprayed directly onto the cast iron stove.

[0058] 技术方案三:一种用于螺钉的高性能涂料 A method for high performance coatings screw: [0058] Technical Solution three

[0059] -种用于螺钉的商性能涂料,其包含基本涂料以及有机娃树脂,基本涂料以及有机硅树脂的体积比为1 : 0. 5〜1. 5,优选为I :1. 3。 [0059] - List performance coatings for kinds of screws, comprising a base paint and the volume ratio of the organic resin baby, base paint and the silicone resin is 1: 5~1 0. 5, preferably from I: 1 3...

[0060] 一种用于螺钉的高性能涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于螺钉的高性能涂料。 Preparation Method [0060] A high-performance coatings for screws, after mixing base paint and a silicone resin, to give high performance coatings for screws.

[0061] 所述的基本涂料,其组份体积百分比为: [0061] The basic coating, the volume percentage of components:

[0062] pH调节剂1〜25% [0062] pH adjusting agents 1~25%

[0063] 功能催化剂0.003〜0.7% [0063] The function of the catalyst 0.003~0.7%

[0064] 硅氧烷组合物余量 [0064] The silicone composition balance

[0065] 所述的基本涂料的制备方法,其具体步骤为: [0065] The method of preparing the basic coating, including the following steps:

[0066] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0066] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0067] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0067] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0068] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0068] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0069] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0069] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0070] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,高性能涂料的pH值为1〜4 ; [0070] The pH adjusting agents are water and a mixed acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of 1 ~ 4 Performance Coatings;

[0071] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15,优选为1 : 7;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0071], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15, preferably from 1: 7; more voids Since the toner which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0072] 所述的炭粉制备方法,其具体步骤为: [0072] The method for preparing carbon powder, including the following steps:

[0073] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 2,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0073] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 2, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0074] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为80nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0074] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 80nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0075] 所述的催化剂,其组份体积百分比为: [0075] The catalyst component volume percentage of which:

[0076] 锆酸酯15〜60% [0076] zirconate 15~60%

[0077] 乙酰丙酮1〜15% [0077] acetylacetonate 1~15%

[0078] 异丙醇余量 [0078] The remaining isopropanol

[0079] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0079] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0080] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0080] The catalyst was: addition of the carbon powder into the catalyst, for continuous stirring, the reaction time is 1~3h;

[0081] 所述的硅氧烷组合物,其组份体积百分比为: [0081] The silicone composition, its composition by volume percent:

[0082] 二笨坫:I μ H坫睡氣烷7〜25% [0082] bis stupid goblets: I μ H goblets sleep gas alkoxy 7~25%

[0083] 1|1坫烷7〜]5% Y -缩水H+ _S+Vi内坫:.111 试+tt+fij.:烷:! [0083] 1 | 1 goblets alkoxy 7~] 5% Y - H + _S + glycidyl within goblets Vi: .111 + tt + fij .: test alkoxy:! 〜丨5% 苯.½ •:屮-Vi.MHiim烷7〜11% w :mnm + 余>v-: Shu ~ 5% benzene .½ •: Che -Vi.MHiim alkoxy 7~11% w: mnm + I> v-:

[0084] 一种用于螺钉的高性能涂料,可以将涂料直接喷涂到螺钉上。 [0084] A screw for high performance coatings, the coating may be sprayed directly to the screw.

[0085] 技术方案四:一种用于电熨斗的高性能涂料 [0085] Technical Solution four: the high-performance coatings for iron

[0086] 一种用于电熨斗的高性能涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0. 2〜1. 2,优选为1 : 1。 [0086] A high-performance coatings for iron, comprising a base paint and a silicone resin, the volume ratio of base paint and the silicone resin is 1: 2~1 0. 2, preferably 1: 1.

[0087] 一种用于电熨斗的高性能涂料的制备方法,将基本涂料以及有机硅树脂混合后, 得到用于电熨斗的高性能涂料。 [0087] A method for preparing a high-performance coatings for iron, the mixing base paint and the silicone resin to obtain high-performance coatings for the electric iron.

[0088] 所述的基本涂料,其组份体积百分比为: [0088] The basic coating, the volume percentage of components:

[0089] pH 调节剂0· 1 〜25% [0089] pH adjusting agent 0 ~ 25% * 1

[0090] 功能催化剂0.004〜0.7% [0090] The function of the catalyst 0.004~0.7%

[0091] 硅氧烷组合物余量 [0091] The silicone composition balance

[0092] 所述的基本涂料的制备方法,其具体步骤为: [0092] The method of preparing the basic coating, including the following steps:

[0093] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0093] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0094] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0094] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0095] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0095] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0096] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0096] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0097] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,高性能涂料的pH值为1〜4 ; [0097] The pH adjusting agents are water and a mixed acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of 1 ~ 4 Performance Coatings;

[0098] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 4〜15,优选为1 : 10;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0098], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 4~15, preferably 1: 10; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0099] 所述的炭粉制备方法,其具体步骤为: [0099] The production method of carbon powder, including the following steps:

[0100] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 3,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0100] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 3, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0101] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为95nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0101] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 95nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0102] 所述的催化剂,其组份体积百分比为: [0102] The catalyst component volume percentage of which:

[0103] 锆酸酯1〜60% [0103] zirconate 1~60%

[0104] 乙酰丙酮1〜20% [0104] acetylacetonate 1~20%

[0105] 异丙醇余量 [0105] Isopropanol balance

[0106] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0106] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0107] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0107] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0108] 所述的硅氧烷组合物,其组份体积百分比为: [0108] The silicone composition, its composition by volume percent:

[0109] 准坫:屮从坫儀氧烷7〜25% i(U»t 7〜15% Y -缩水Π -油Sl氧爾11三¥氧基illl 1〜15% 苯-JlIr -:屮氣J1HI:氣烷卜〜10% W- wvm 余M [0109] quasi-goblets: Che from goblets instrument alumoxane 7~25% i (U »t 7~15% Y - 1~15% benzene oil -JlIr Sl 11 Seoul three oxygen ¥ yloxy illl - - [pi glycidyl: Che gas J1HI: gas alkoxy Bu ~10% W- wvm I M

[0110] 一种用于电熨斗的高性能涂料,可以将涂料直接喷涂到电熨斗上。 [0110] A high-performance coatings for iron, the coating may be sprayed directly onto the iron.

[0111] 技术方案五:一种用于照明灯具壳体的高效涂料 [0111] Technical Solution V: Efficient paint for a lighting fixture housing

[0112] 一种用于照明灯具壳体的高效涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 〇. 4〜1. 4,优选为1 : 0. 7。 [0112] Efficient light fixture housing for paint, coatings and substantially comprising a silicone resin, the volume ratio of base paint and the silicone resin is 1: 4~1 4 billion, preferably 1: 0. 7.

[0113] 一种用于照明灯具壳体的高效涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于照明灯具壳体的高效涂料。 Preparation Method [0113] An efficient coating of the light fixture housing for, after mixing base paint and a silicone resin, to obtain effective coatings for the light fixture housing.

[0114] 所述的基本涂料,其组份体积百分比为: [0114] The basic coating, the volume percentage of components:

[0115] pH 调节剂0.1 〜22% [0115] pH adjusting agent 0.1 ~ 22%

[0116] 功能催化剂0.005〜0.7% [0116] functional catalyst 0.005~0.7%

[0117] 硅氧烷组合物余量 [0117] The silicone composition balance

[0118] 所述的基本涂料的制备方法,其具体步骤为: [0118] The method of preparing the basic coating, including the following steps:

[0119] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0119] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0120] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0120] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0121] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0121] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0122] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0122] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0123] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,高效涂料的pH值为1〜4 ; [0123] The pH adjusting agent is mixed acid and water, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH, high pH value of the coating ~ 4;

[0124] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 7〜15,优选为1 : 9;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0124], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 7~15, preferably from 1: 9; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0125] 所述的炭粉制备方法,其具体步骤为: [0125] The production method of carbon powder, including the following steps:

[0126] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 4,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0126] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 4, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0127] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为80nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0127] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 80nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0128] 所述的催化剂,其组份体积百分比为: [0128] The catalyst component volume percentage of which:

[0129] 锆酸酯1〜55% [0129] zirconate 1~55%

[0130] 乙酰丙酮1〜18% [0130] acetylacetonate 1~18%

[0131] 异丙醇余量 [0131] Isopropanol balance

[0132] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0132] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0133] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0133] The catalyst was: addition of the carbon powder into the catalyst, for continuous stirring, the reaction time is 1~3h;

[0134] 所述的硅氧烷组合物,其组份体积百分比为: [0134] The silicone composition, its composition by volume percent:

[0135] ::苯.¾ :屮^坫確氧烷1+++++-25% 屮站―-烷1 〜15% ¥ -鑛水猶1丨_氣内'取·:111 fUfli說卜15% [0135] :: benzene .¾: Che ^ goblets determined alumoxane 1 +++++ - 25% Che station - alkyl 1 ~15% ¥ - 1 still mineral water within the gas Shu _ 'taken ·: 111 fUfli said BU 15%

[0136] 苯坫烷卜〜10% |A| :©'[)«! 余W [0136] goblets alkyl benzene Bu ~10% | A |: © '[) «W is I!

[0137] 一种用于照明灯具壳体的高效涂料,可以将涂料直接喷涂到照明灯具壳体上。 [0137] A light fixture housing for efficient coating, the coating may be sprayed directly onto the light fixture housing.

[0138] 技术方案六:一种用于生活小家电芯层的健康涂料 [0138] Technical Solution six: living small appliances coatings for core health

[0139] 一种用于生活小家电芯层的健康涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.6〜1.6,优选为1 : 1.4。 [0139] A small home appliances life healthy core coating, comprising a coating base and a silicone resin, the volume ratio of base paint and the silicone resin is 1: 0.6~1.6, preferably 1: 1.4. 生活小家电比如豆浆机的内层涂料或者保温杯的内涂层。 Small appliances such as living within the inner coating of paint or mug Soymilk.

[0140] 一种用于生活小家电芯层的健康涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于生活小家电芯层的健康涂料。 [0140] A method of preparing a coating healthy life for small appliances core, after mixing base paint and a silicone resin, coatings for healthy small home appliances core.

[0141] 所述的基本涂料,其组份体积百分比为: [0141] The basic coating, the volume percentage of components:

[0142] pH 调节剂0.1 〜23% [0142] pH adjusting agent 0.1% ~23

[0143] 功能催化剂0.006〜0.7% [0143] functional catalyst 0.006~0.7%

[0144] 硅氧烷组合物余量 [0144] The silicone composition balance

[0145] 所述的基本涂料的制备方法,其具体步骤为: [0145] The method of preparing the basic coating, including the following steps:

[0146] -、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0146] - the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0147] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0147] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0148] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0148] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0149] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0149] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0150] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,健康涂料的pH值为1〜5 ; [0150] The pH adjusting agent is mixed acid and water, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH, a pH of ~ 5 healthy coating;

[0151] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为I : 8〜15,优选为I : 13;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0151], carbon powder containing a catalyst, wherein the solid-liquid ratio of the carbon powder catalyst I: 8~15, preferably from I: 13; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0152] 所述的炭粉制备方法,其具体步骤为: [0152] The production method of carbon powder, including the following steps:

[0153] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 6,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0153] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 6, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0154] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为75nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0154] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 75nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0155] 所述的催化剂,其组份体积百分比为: [0155] The catalyst component volume percentage of which:

[0156] 锆酸酯1〜52% [0156] zirconate 1~52%

[0157] 乙酰丙酮1〜17% [0157] acetylacetonate 1~17%

[0158] 异丙醇余量 [0158] Isopropanol balance

[0159] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0159] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0160] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0160] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0161] 所述的硅氧烷组合物,其组份体积百分比为: [0161] The silicone composition, its composition by volume percent:

[0162] 二苯坫:φ W坫ii氧鏡1 -20% 'I1-½ ·.'IlUiiMirftiI 〗〜丨◎% γ -it水曹油《Τγί内' 坫·'. f 11 坫碰鏡卜+〜丨0% 本.VrJI AUWIi-K 烷卜5% ιλ] wm 余μ: [0162] diphenyl goblets:. Φ W goblets ii oxygen mirror 1 -20% 'I1-½ · .'IlUiiMirftiI within ~ Shu〗 ◎% γ -it water Cao oil "Τγί' goblets · 'f 11 touch the mirror goblets Bu 0% ~ + Shu present .VrJI AUWIi-K alkoxy Bu 5% ιλ] wm μ:

[0163] 一种用于生活小家电芯层的健康涂料,可以将涂料直接喷涂到小家电芯层上。 [0163] a life of small appliances for the core of a healthy coating, the coating can be sprayed directly onto the core layer of small home appliances.

[0164] 技术方案七:一种用于美容美发夹具的环保涂料 [0164] Technical Solution VII: hairdressing jig for a green paint

[0165] 一种用于美容美发夹具的环保涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 〇. 7〜1. 7,优选为I : 1. 1。 [0165] A jig for hairdressing green paint, comprising a base paint and a silicone resin, the volume ratio of base paint and the silicone resin is 1: 7~1 7 billion, preferably I: 1. 1 .

[0166] 一种用于美容美发夹具的环保涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于美容美发夹具的环保涂料。 [0166] A method for producing the clamp hairdressing green paint for mixing the base paint and the silicone resin to obtain a green paint hairdressing clamp.

[0167] 所述的基本涂料,其组份体积百分比为: [0167] The basic coating, the volume percentage of components:

[0168] pH 调节剂0.1 〜19% [0168] pH adjusting agent 0.1% ~19

[0169] 功能催化剂0.007〜0.5% [0169] functional catalyst 0.007~0.5%

[0170] 硅氧烷组合物余量 [0170] The silicone composition balance

[0171] 所述的基本涂料的制备方法,其具体步骤为: [0171] The method of preparing the basic coating, including the following steps:

[0172] -、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0172] - the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0173] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0173] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0174] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0174] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0175] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0175] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0176] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,环保涂料的pH值为1〜4. 1 ; [0176] The pH adjusting agent is mixed acid and water, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of green paint 1 ~ 4;

[0177] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 8〜15,优选为1 : 10;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0177], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 8~15, preferably 1: 10; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0178] 所述的炭粉制备方法,其具体步骤为: [0178] The production method of carbon powder, including the following steps:

[0179] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 3 : 1,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0179] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 3: 1, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0180] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为60nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0180] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 60 nm; the micronization process of ball milling, or high-speed centrifugation nanotechnology;

[0181] 所述的催化剂,其组份体积百分比为: [0181] The catalyst component volume percentage of which:

[0182] 锆酸酯1〜48% [0182] zirconate 1~48%

[0183] 乙酰丙酮1〜14% [0183] acetylacetonate 1~14%

[0184] 异丙醇余量 [0184] Isopropanol balance

[0185] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0185] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0186] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0186] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0187] 所述的硅氧烷组合物,其组份体积百分比为: [0187] The silicone composition, its composition by volume percent:

[0188] : '.笨坫:屮氣坫鐘氧烷1 - !9% »!<« 卜12% P缩水懷11_%〔内―坫.111M 11烷卜丨2% -:111¼¾.¾¼烷】〜10% . [0188]: 'stupid goblets:!! Che gas bell goblets alumoxane 1--9% »<« Bu glycidyl pregnant within 12% P% [11_ - goblets .111M 11 alkoxy Bu Shu 2% -: 111¼¾.¾¼ alkoxy ] ~ 10%

[0189] |AjHim+:醇〒隨余+¾ [0189] | AjHim +: 〒 alcohol with more than + ¾

[0190] 一种用于美容美发夹具的环保涂料,可以将涂料直接喷涂到美容美发夹具上。 [0190] A jig for hairdressing green paint, paint can be sprayed directly onto the jig beauty salons.

[0191] 技术方案八:一种用于加热设备的多功能复合涂料 Multifunctional composite coating apparatus for heating: [0191] Technical Solution eight

[0192] 一种用于加热设备的多功能复合涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.8〜1.8,优选为1 : 1.4。 [0192] multifunctional composite coating for a heating apparatus, comprising a base paint and a volume of a silicone resin, a silicone resin base paint, and the ratio of 1: 0.8~1.8, preferably 1: 1.4. 加热设备为暖气片以及其它,或者加热管等工具。 A heating radiator, and other equipment, tools or heating pipe.

[0193] 一种用于加热设备的多功能复合涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于加热设备的多功能复合涂料。 After [0193] Preparation of the multifunctional composite coating apparatus for heating, mixing the base paint and a silicone resin, the multifunctional composite coatings for heating apparatus.

[0194] 所述的基本涂料,其组份体积百分比为: [0194] The basic coating, the volume percentage of components:

[0195] pH 调节剂0.1 〜22% [0195] pH adjusting agent 0.1 ~ 22%

[0196] 功能催化剂0.008〜0.6% [0196] functional catalyst 0.008~0.6%

[0197] 硅氧烷组合物余量 [0197] The silicone composition balance

[0198] 所述的基本涂料的制备方法,其具体步骤为: [0198] The method of preparing the basic coating, including the following steps:

[0199] -、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0199] - the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0200] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0200] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0201] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0201] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0202] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0202] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0203] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,多功能复合涂料的pH值为1〜4. 2 ; pH adjusters [0203] The mixing of water and acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH, pH multifunctional composite coating is 2 ~ 4.;

[0204] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15 ;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0204], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15; Toner As more voids which adsorption catalyst to facilitate the reaction slowly be moderate, it is conducive to control and regulate the progress of the reaction.

[0205] 所述的炭粉制备方法,其具体步骤为: [0205] The production method of carbon powder, including the following steps:

[0206] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 3 : 2,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0206] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 3: 2, to the processing of the dried 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0207] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为65nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0207] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 65nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0208] 所述的催化剂,其组份体积百分比为: [0208] The catalyst component volume percentage of which:

[0209] 锆酸酯1〜51% [0209] zirconate 1~51%

[0210] 乙酰丙酮1〜16% [0210] acetylacetonate 1~16%

[0211] 异丙醇余量 [0211] Isopropanol balance

[0212] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0212] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0213] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0213] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0214] 所述的硅氧烷组合物,其组份体积百分比为: [0214] The silicone composition, its composition by volume percent:

[0215] 一V·圍f- * Hi^ i If- rl-^ f 1 -ϊ I n/ ...4^hk -1Ij Λ 11 〜2 〗% 丨烷ι~9% Y-缩水曹油ftTrtiAitf. -:|||从坫砘烷1〜9% 苯基ΞΞψ 氧SIiIiiJI 1 〜5% IAj :醇屮_ 余M: [0215] V · a circumference f- * Hi ^ i If- rl- ^ f 1 -ϊ I n / ... 4 ^ hk -1Ij Λ 11 ~2% Shu〗 alkoxy ι ~ 9% Y- glycidyl oil Cao ftTrtiAitf -:. ||| 1~9% from goblets Dun alkyl phenyl ΞΞψ oxygen SIiIiiJI 1 ~5% IAj: alcohol Che _ I M:

[0216] 一种用于加热设备的多功能复合涂料,可以将涂料直接喷涂到加热设备上。 [0216] A multifunctional device for heating the composite coating, the coating may be sprayed directly onto the heating device.

[0217] 技术方案九:一种用于绝缘体的防腐复合涂料 [0217] Technical Solution IX: an insulator composite anti-corrosion coatings for

[0218] 一种用于绝缘体的防腐复合涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.9〜1.9,优选为1 : 1.7。 [0218] A composite insulator anticorrosive coating, comprising a coating base and a silicone resin, the volume ratio of base paint and the silicone resin is 1: 0.9~1.9, preferably 1: 1.7. 加热设备为暖气片以及其它, 或者加热管等工具。 A heating radiator, and other equipment, tools or heating pipe. 绝缘体比如为石墨片。 Insulator such as graphite sheet.

[0219] 一种用于绝缘体的防腐复合涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于绝缘体的防腐复合涂料。 [0219] A method for preparing a composite anti-corrosion coating for insulators, after mixing base paint and a silicone resin, to obtain anticorrosive coatings for composite insulators.

[0220] 所述的基本涂料,其组份体积百分比为: [0220] The basic coating, the volume percentage of components:

[0221] pH 调节剂0.1 〜20% [0221] pH adjusting agent 0.1 ~ 20%

[0222] 功能催化剂0.009〜0.4% [0222] functional catalyst 0.009~0.4%

[0223] 硅氧烷组合物余量 [0223] The silicone composition balance

[0224] 所述的基本涂料的制备方法,其具体步骤为: [0224] The method of preparing the basic coating, including the following steps:

[0225] -、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0225] - the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0226] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0226] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0227] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0227] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0228] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0228] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0229] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,防腐复合涂料的pH值为1〜4.3 ; [0229] The pH adjusting agent is mixed acid and water, wherein the acid is hydrochloric acid and acetic acid; pH is mainly used to adjust the pH value, the composite coating is 1~4.3 corrosion;

[0230] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15 ;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0230], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15; Toner As more voids which adsorption catalyst to facilitate the reaction slowly be moderate, it is conducive to control and regulate the progress of the reaction.

[0231] 所述的炭粉制备方法,其具体步骤为: [0231] The production method of carbon powder, including the following steps:

[0232] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 3 : 3,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0232] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 3: 3, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0233] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为70nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0233] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 70nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0234] 所述的催化剂,其组份体积百分比为: [0234] The catalyst component volume percentage of which:

[0235] 锆酸酯1〜47% [0235] zirconate 1~47%

[0236] 乙酰丙酮1〜13% [0236] acetylacetonate 1~13%

[0237] 异丙醇余量 [0237] Isopropanol balance

[0238] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0238] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0239] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0239] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0240] 所述的硅氧烷组合物,其组份体积百分比为: [0240] The silicone composition, its composition by volume percent:

[0241] :+.^½ :屮氣码破氧烷卜23% ψ丨烷卜丨〇% γ4f水WiliNTri内-丨,t 111¾¾!!!¾ I 〜10% -1((¾½!,!;¼¾ 1-8% . [0241]: + ^ ½: Che air break code alumoxane Bu Bu 23% ψ Shu Shu square inner alkoxy% γ4f water WiliNTri - Shu, t 111¾¾ !!! ¾ I ~10% -1 ((¾½,!! ; ¼¾ 1-8%

[0242] 内-:®「πϋ 余朵 [0242] within -: ® "πϋ more than flowers

[0243] -种用于绝缘体的防腐复合涂料,可以将涂料直接喷涂到绝缘体头上。 [0243] - preservatives and coatings for composite insulators, the coating may be sprayed directly to the insulator head.

[0244] 技术方案十:一种用于卷帘门的高性能涂料 Performance Coatings for the shutter doors: [0244] Technical Solution ten

[0245] -种用于卷帘门的高性能涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为I : 1〜5,优选为1 : 3。 [0245] - high-performance coatings for kinds of shutter doors, comprising a base paint and a volume of a silicone resin, a silicone resin base paint and the ratio of I: 1~5, preferably 1: 3. 加热设备为暖气片以及其它,或者加热管等工具。 A heating radiator, and other equipment, tools or heating pipe.

[0246] -种用于卷帘门的高性能涂料的制备方法,将基本涂料以及有机硅树脂混合后, 得到用于卷帘门的高性能涂料。 [0246] - high-performance coatings for kinds of roll-up doors of the preparation method, after mixing base paint and a silicone resin, to obtain high-performance coatings for roll-up doors.

[0247] 所述的基本涂料,其组份体积百分比为: [0247] The basic coating, the volume percentage of components:

[0248] pH 调节剂0.1 〜21% [0248] pH adjusting agent 0.1% ~21

[0249] 功能催化剂0· 0065〜0· 1 % [0249] function of the catalyst 1% · 0 · 0065~0

[0250] 硅氧烷组合物余量 [0250] The silicone composition balance

[0251] 所述的基本涂料的制备方法,其具体步骤为: [0251] The method of preparing the basic coating, including the following steps:

[0252] -、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0252] - the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0253] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0253] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0254] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0254] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0255] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0255] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0256] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,高性能涂料的pH值为1〜4. 6 ; [0256] The pH adjusting agent is mixed acid and water, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of 1 ~ 4 6 high performance coatings.;

[0257] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5〜15,优选为1 : 13;炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0257], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5~15, preferably 1:13; Toner As more voids which adsorption catalyst conducive to moderate reactions were slow, it is conducive to control and regulate the progress of the reaction.

[0258] 所述的炭粉制备方法,其具体步骤为: [0258] The production method of carbon powder, including the following steps:

[0259] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 4 : 1,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0259] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 4: 1, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0260] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉, 优选为80nm ;所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0260] (2) micronized: a multifunctional toner micronized, ground into the multifunction 30~200 nanoscale carbon powder, preferably 80nm; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0261] 所述的催化剂,其组份体积百分比为: [0261] The catalyst component volume percentage of which:

[0262] 锆酸酯1〜46% [0262] zirconate 1~46%

[0263] 乙酰丙酮1〜15% [0263] acetylacetonate 1~15%

[0264] 异丙醇余量 [0264] Isopropanol balance

[0265] 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0265] The catalyst preparation method is as follows: The reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; the stirring acetylacetone added dropwise slowly to the reactor the mixed in the mixed solution, after the addition was complete the reaction 1 hour at 40 ° C, cooling the material.

[0266] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0266] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0267] 所述的硅氧烷组合物,其组份体积百分比为: [0267] The silicone composition, its composition by volume percent:

[0268] '.¾½ 卜29% 丨〜丨丨% γ -缝水懷烷卜η% 苯ft (「puftiiim烷:ι 〜8% iai -Mnm 氽ί+{: [0268] '.¾½ Bu ~ 29% Shu Shushu% γ - water pregnant seam alkoxy Bu η% benzene. Ft ( "alkoxy puftiiim: ι ~8% iai -Mnm Tun ί + {:

[0269] 一种用于卷帘门的高性能涂料,可以将涂料直接喷涂到卷帘门上。 [0269] A roll-up doors for high performance coatings, the coating can be sprayed directly onto the shutter doors.

[0270] 与现有技术相比,本发明的积极效果是: [0270] Compared with the prior art, the positive effect of the invention is:

[0271] 本发明的二苯基二甲氧基硅氧烷是首次作为涂料中的硅氧烷的组份之一,其具有的效果为提高涂料的光泽,使制备的涂料具有很高的光泽;主要不是起到常规的硅氧烷的功效;提高体系的定向能力,增加体系的耐热抗氧化性能,增强了对水的排斥性能,改进热弹性,改进与有机树脂的相容性、与颜料的互溶性。 [0271] diphenyldimethoxysilane siloxanes of the invention is the first one of the ingredients as a coating of silicone, which has a high gloss effect to improve the gloss coating, the coating prepared ; efficacy not primarily functions as a conventional silicone; improved compatibility orientation capabilities of the system, the system increases heat oxidation resistance, and enhance the water repellency properties and improved thermoelastic, and the organic resin is improved, and miscible pigment. 以及对各种物质的黏结性、储存稳定性好。 And, for good storage stability of the bonding of various materials.

[0272] 本发明通过锆酸酯,乙酰丙酮以及异丙醇形成一个空间交联结构,有利于控制反应的温和进行,比单单采用锆酸酯的催化剂更加能够控制反应速率。 [0272] The catalyst of the present invention, a space is formed crosslinked structure, mild facilitate control of the reaction, than by simply using zirconate zirconate, acetylacetone and isopropanol better able to control the reaction rate. 可与底材及涂料中的的活泼基团发生交联反应,形成桥架,使分子量增大。 A crosslinking reaction with the substrate and coating the reactive groups to form a bridge, so increase in molecular weight. 而涂料与底材通过桥架作用最终使其附着力提高,同时还可以提高耐水性,耐溶剂性以及耐煮性,提高漆膜的干燥速度,表面光泽。 The coating and the substrate by action of the bridge so that ultimately improve adhesion, but also can improve the water resistance, solvent resistance and Naizhu, improve the film drying rate, surface gloss.

[0273] 本发明含有咖啡炭,产品具有如下优点:咖啡炭生产原料来自回收的咖啡渣,环保回收再利用,不增加地球的负担,从而达到节能减碳的目的;当身体或身边环境有异味时, 也会通过范德华引力作用将异味吸收;咖啡炭结构空隙大,表面粗糙,对热量的吸收效率高,速度快,具有瞬间升温功能。 [0273] The present invention comprises coffee carbon, the product has the following advantages: coffee carbon raw material from the recovery of coffee grounds, environmental recycling, without increasing the burden on the earth, so as to achieve energy saving and carbon reduction; When the body or the immediate environment odor when will the smell absorbed by the action of van der Waals attraction; coffee carbon structure large voids, rough surface, high absorption efficiency of heat, speed, with an instant heating function.

[0274] 本发明含有杏壳及核桃壳形成的果壳炭,具有孔隙结构发达、比表面积大、吸附能力强、机械强度高、床层阻力小、化学稳定性能好、易再生、经久耐用等优点,并具有各种规格的颗粒度;分解空气中的甲醛、氨、苯、香烟、油烟等有害气体及各种异味,尤其是致癌的芳香类物质,活性碳具有极强的吸附能力。 [0274] The present invention comprises almond shell charcoal and walnut husk shell formed having a developed pore structure, surface area, adsorption capacity, high mechanical strength, bed resistance, good chemical stability, easy regeneration, durability and other advantages and having a variety of particle size; decomposition air formaldehyde, ammonia, benzene, cigarette, smoke and other harmful gases and a variety of odors, especially carcinogenic aromatic substances, activated carbon has a strong adsorption capacity.

[0275] 本发明的炭粉制备采取低温炭化以及中温炭化,得到炭粉,其降低成本,同时其粒径又满足涂料应用的要求。 [0275] Preparation of toner of the present invention taken in the low-temperature carbonization and the carbonization temperature, to obtain toner, which reduces costs, while the particle size and meet the requirements for coating applications.

[0276] 本发明将炭粉作为催化剂的载体,起到控制反应速率以及发挥炭粉自身的功效。 [0276] The toner of the present invention as a catalyst carrier, and functions to control the rate of reaction effect itself play charcoal. 【具体实施方式】 【detailed description】

[0277] 以下提供本发明一种功能性涂料及其制备方法的具体实施方式。 [0277] The following provides a method of preparing functional coatings of the present invention and specific embodiments.

[0278] 实施例1 [0278] Example 1

[0279] -种用于刀具的防腐蚀涂料,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1 : 0.5。 [0279] - anti-corrosion coatings for kinds of tools, comprising a base paint and the volume ratio of the silicone resin, and silicone resin paint base was 1: 0.5.

[0280] 一种用于刀具的防腐蚀涂料的制备方法,将基本涂料以及有机硅树脂混合后,得到用于刀具的防腐蚀涂料。 After the [0280] method for producing a tool for anti-corrosion coatings, and mixing the base paint and a silicone resin, to obtain the anti-corrosion coatings for tools.

[0281] 所述的基本涂料,其组份体积百分比为:pH调节剂为5%,功能催化剂为0. 001%, 硅氧烷组合物为94. 999% ; Base paint according to [0281], which component volume percentage as follows: pH adjusting agent is 5%, the function the catalyst is 0.001%, the silicone composition was 94.999%;

[0282] 所述的基本涂料的制备方法,其具体步骤为: [0282] The method of preparing the basic coating, including the following steps:

[0283] 一、将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌约5min直至混合均勻; [0283] First, the reactor temperature was controlled at 40 ° C, with stirring in amounts successively added to the silicone composition, stirring rate 300r / min, slowly stirred for about 5min until uniformly mixed;

[0284] 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀,后边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; [0284] Second, the pH adjusting agent in the mixed acid H2O and other containers mixed clean, stirring slowly dropped back to the reactor the mixed silicone composition; dropwise over 15~ 20min;

[0285] 三、在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; [0285] III, mixed in the silicone composition and pH adjusting agents after 2h the reaction mixture was added to the function of the catalyst;

[0286] 四、在功能催化剂加入反应Ih后,冷却至室温后检测出料。 [0286] Fourth, the function of the catalyst added to the reaction Ih, cooled to room temperature, the material is detected.

[0287] 所述的pH调节剂为水和混合酸,其中酸为盐酸和醋酸;主要用来调节pH值,防腐蚀涂料的pH值为1〜4 ; pH adjusters [0287] The mixing of water and acid, wherein the acid is hydrochloric acid and acetic acid; mainly used to adjust the pH value, pH value of 1 ~ 4 anticorrosive coating;

[0288] 所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1 : 5; 炭粉由于其空隙较多,其吸附催化剂,有利于反应的缓慢温和进行,有利于控制和调节反应的进度。 Function of the catalyst according to [0288], carbon powder containing a catalyst, wherein the solid-liquid ratio of carbon powder with the catalyst is 1: 5; Toner As more voids, adsorption catalyst which is conducive to slow mild reaction proceeds help control and regulate the progress of the reaction.

[0289] 所述的炭粉制备方法,其具体步骤为: [0289] The production method of carbon powder, including the following steps:

[0290] (1)炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1 : 2 : 1,先经过150〜180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; [0290] (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material mass ratio of the three is 1: 2: 1, after the first drying process of 150~180 ° C ~ 2 hours, after which the temperature calcination was raised to 300~400 ° C ~ 2 hours and then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder;

[0291] (2)微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉; 所述的微粉化方法为球磨法、高速离心法或纳米技术等; [0291] (2) micronized: a multifunctional toner micronized, ground into toner multifunctional nanoscale 30~200; micronization process is the ball mill, high speed centrifugation or nanotechnology;

[0292] 所述的催化剂,其组份体积百分比为:锆酸酯为20%,乙酰丙酮为1%,异丙醇为79%,所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌约5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料。 [0292] The catalyst, which component volume percentage: 20% zirconate, 1% acetylacetone, 79% isopropyl alcohol, the catalyst preparation method is as follows: the temperature in the reactor control at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for about 5 minutes until uniformly mixed; acetylacetone was slowly added dropwise under stirring to the mixed reactor in the liquid mixture, after completion of the dropwise addition for 1 hour at 40 ° C, cooling the material.

[0293] 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1〜3h ; The function of the production method [0293] catalyst: the addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1~3h;

[0294] 所述的硅氧烷组合物,其组份体积百分比为:二苯基二甲氧基硅氧烷为7%,甲基三甲氧基硅氧烷为7%,Y-缩水甘油醚氧丙基三甲氧基硅烷为1%,苯基三甲氧基硅氧烷为7%,丙二醇甲醚为78%, [0294] The silicone composition of component volume percentage: diphenyldimethoxysilane 7% silicone, silicone methyltrimethoxysilane 7%, Y-ether trimethoxy silane 1%, phenyltrimethoxysilane 7% silicone, 78% propylene glycol methyl ether,

[0295] -种用于刀具的防腐蚀涂料,可以将涂料直接喷涂到刀具上。 [0295] - anti-corrosion coatings for kinds of tools, a coating may be sprayed directly to the tool.

[0296] 表1-1 一种用于刀具的防腐蚀涂料的实施例1检测数据: [0296] Table 1-1 Example anticorrosive coating a tool for detecting data:

[0297] [0297]

Figure CN103113823BD00171

[0298] 实施例2-5 [0298] Example 2-5

[0299] -种用于刀具的防腐蚀涂料,具体的制备方法详见技术路线一,其中原料的配比为表2所示。 [0299] - anti-corrosion coatings for kinds of tools, a specific method for preparing a detailed technical route, wherein the ratio of the raw material is shown in Table 2.

[0300] 表1为一种用于刀具的防腐蚀涂料的原料配比情况 [0300] Table 1 shows the anti-corrosion coating for a cutting tool where the ratio of raw materials

Figure CN103113823BD00172

[0302] 实施例6-10 [0302] Example 6-10

[0303] 一种用于铸铁灶头的防腐涂料,具体的制备方法详见技术路线二,其中原料的配比为表2所示。 [0303] A cast iron stove for anti-corrosion coatings, particularly the production method shown in the technical second route, wherein the ratio of the raw materials shown in Table 2.

[0304] 表2为一种用于铸铁灶头的防腐涂料的原料配比情况 [0304] Table 2 shows the anti-corrosion coatings for cast iron stove where the ratio of raw materials

Figure CN103113823BD00181

[0307] 测试数据为:表2-2 -种用于铸铁灶头的防腐涂料的实施例6测试数据 [0307] Test data: Table 2-2 - Example preservatives and coatings for cast iron burner test data 6

[0308] [0308]

Figure CN103113823BD00191

[0309] 实施例11-15 [0309] Example 11-15

[0310] 一种用于螺钉的高性能涂料,具体的制备方法详见技术路线三,其中原料的配比为表3所示。 [0310] A high-performance coatings for screws, concrete preparation methods shown in the technical Route 3, wherein the ratio of the raw materials shown in Table 3.

[0311] 表3为一种用于螺钉的高性能涂料的原料配比情况 [0311] Table 3 is a high-performance coatings for a case where a screw ratio of raw materials

[0312] [0312]

Figure CN103113823BD00201

[0313] 检测数据:表3-3 -种用于螺钉的高性能涂料的实施例11的测试数据 [0313] Detection data: Table 3-3 - Testing Example data types of high performance coatings for the screw 11

Figure CN103113823BD00202

[0315] 实施例16-20 [0315] Examples 16-20

[0316] 一种用于电熨斗的高性能涂料,具体的制备方法详见技术路线四,其中原料的配比为表4所示。 [0316] A high-performance coatings for iron, particular route preparation method shown in the technical IV wherein the ratio of raw materials shown in Table 4.

[0317] 表4为一种用于电熨斗的高性能涂料的原料配比情况 [0317] Table 4 is a high-performance coatings for a case where electric iron ratio of raw materials

[0318] [0318]

Figure CN103113823BD00211

[0319] 检测数据:表4-4 一种用于电熨斗的高性能涂料的实施例16的测试数据 [0319] Detection data: Example 4-4 for a high performance coating iron test data in Table 16

Figure CN103113823BD00212
Figure CN103113823BD00221

[0322] 实施例21-25 [0322] Example 21-25

[0323] 一种用于照明灯具壳体的高效涂料,具体的制备方法详见技术路线五,其中原料的配比为表5所示。 [0323] Efficient light fixture housing for the coating material, the specific preparation method detailed five technical route, wherein the ratio of the raw materials shown in Table 5.

[0324] 表5为一种用于照明灯具壳体的高效涂料的原料配比情况 Where the ratio of starting material [0324] Table 5 is a highly effective coating for the light fixture housing

Figure CN103113823BD00222

[0326] 测试数据:表5-5为一种用于照明灯具壳体的高效涂料的实施例21测试数据 [0326] Test data: Table 5-5 as a coating efficiency of the light fixture housing for the test data of Example 21

[0327] [0327]

Figure CN103113823BD00231

[0328] 实施例26-30 [0328] Example 26-30

[0329] 一种用于生活小家电芯层的健康涂料,具体的制备方法详见技术路线六,其中原料的配比为表6所示。 [0329] A small home appliances life coatings for core health, the specific preparation method detailed technical route six, which is the ratio of the raw materials shown in Table 6. 「03301 表6为一种用干牛活小家电芯层的健康涂料的原料配比情况 "03301 Table 6 as a dry cow healthy living small appliances core coating ratio of raw materials situation

Figure CN103113823BD00232
Figure CN103113823BD00241

[0333] 表6-6 -种用于电熨斗的高性能涂料的实施例26的测试数据 [0333] Table 6-6 - kind of embodiment of a high-performance coatings iron test data 26

Figure CN103113823BD00242

[0335] 实施例31-35 [0335] Example 31-35

[0336] 一种用于美容美发夹具的环保涂料,具体的制备方法详见技术路线七,其中原料的配比为表7所示。 [0336] A jig for hairdressing green paint, concrete preparation methods detailed technical route seven, wherein the ratio of the raw materials shown in Table 7.

[0337] 表7为一种用于美容美发夹具的环保涂料的原料配比情况 [0337] Table 7 as a green paint hairdressing clamp ratio of raw materials for the case

[0338] [0338]

Figure CN103113823BD00251

[0339] 表7-7为一种用于美容美发夹具的环保涂料的实施例31测试数据 [0339] Table 7-7 is an embodiment of a jig for hairdressing green paint test data 31

Figure CN103113823BD00252
Figure CN103113823BD00261

[0342] 实施例36-40 [0342] Example 36-40

[0343] 一种用于加热设备的多功能复合涂料,具体的制备方法详见技术路线八,其中原料的配比为表8所示。 [0343] A multifunctional composite coatings for the heating device, the specific preparation method detailed technical route eight, wherein the ratio of the raw materials shown in Table 8.

[0344] 表8为一种用于加热设备的多功能复合涂料的原料配比情况 [0344] Table 8 multifunctional composite coating for a heating apparatus where the ratio of raw materials

Figure CN103113823BD00262

[0346] 测试数据为:表8-8 -种用于加热设备的多功能复合涂料的实施例36测试数据 [0346] Test data: Table 8-8--36 test data of Example multifunctional composite coatings for kinds of heating equipment

[0347] [0347]

Figure CN103113823BD00271

[0348] 实施例41-45 [0348] Example 41-45

[0349] 一种用于绝缘体的防腐复合涂料,具体的制备方法详见技术路线九,其中原料的配比为表9示。 [0349] A composite insulator anticorrosive coating for concrete preparation method detailed technical route nine, wherein the ratio of the raw materials shown in Table 9.

[0350] 表9 一种用于绝缘体的防腐复合涂料的原料配比情况 [0350] Table 9 where an insulator material ratio of composite coatings for anticorrosive

Figure CN103113823BD00272

[0353] 测试数据:表9-9 一种用于绝缘体的防腐复合涂料的实施例41的测试数据 Table 9-9 Test Data Example insulator composite coatings for anticorrosive 41: [0353] Test Data

Figure CN103113823BD00281

[0355] 实施例46-50 [0355] Example 46-50

[0356] 一种用于卷帘门的高性能涂料,具体的制备方法详见技术路线十,其中原料的配比为表10。 [0356] A roll-up doors for high performance coatings, concrete preparation methods detailed technical route ten, wherein the ratio of raw materials in Table 10.

[0357] 表10 -种用于卷帘门的高性能涂料的原料配比情况 [0357] Table 10 - high-performance coatings for kinds of rolling doors where ratio of raw materials

Figure CN103113823BD00282
Figure CN103113823BD00291

Claims (2)

1. 一种功能性涂料,其特征在于,其包含基本涂料以及有机硅树脂,基本涂料以及有机硅树脂的体积比为1:0. 5〜4; 所述的基本涂料,其组份体积百分比为: pH调节剂5〜25% 功能催化剂0.001〜0.7% 硅氧烷组合物余量所述的功能催化剂,为含有炭粉的催化剂,其中,炭粉与催化剂的固液比为1:5〜15 ; 所述的催化剂,其组份体积百分比为: 锆酸酯20〜60% 乙酰丙酮1〜15% 异丙醇余量所述的硅氧烷组合物,其组份体积百分比为: 1. A functional coating, characterized in that it comprises a base paint and a silicone resin, the volume ratio of base paint and the silicone resin is 1: 5~4 0; the basic coating, the percentage by volume of the as follows: pH adjusting agents 5~25% functional catalyst 0.001~0.7% of the silicone composition balance function catalyst, comprising carbon powder as catalyst, wherein the catalyst and the carbon powder liquid ratio of 1: -5 to 15; said catalyst component volume percentage:% zirconium acetylacetonate 1~15 20~60% isopropanol balance of the silicone composition, volume percentage of its components:
Figure CN103113823BC00021
所述的炭粉制备方法,其具体步骤为: (1) 炭化:杏壳,核桃壳以及咖啡渣为原料,三者的原料质量比为1:2:1,先经过150〜 180°C的干燥处理1〜2小时,之后将温度升至300〜400°C煅烧1〜2小时,然后再升温至600〜700°C煅烧1〜2小时,得到多功能的炭粉; (2) 微粉化:将多功能的炭粉进行微粉化,研磨成30〜200纳米级多功能的炭粉; 所述的催化剂的制备方法为:将反应器中温度控制在40°C,先加入异丙醇,边搅拌边加入锆酸酯,慢速搅拌5分钟直至混合均匀;在搅拌状态下缓慢滴加乙酰丙酮至反应器中混合好的上述混合液中,滴加完毕后在40°C下反应1小时,冷却出料; 所述的功能催化剂的制备方法为:将炭粉加人到催化剂中,进行不断搅拌,反应时间为1 〜3h〇 The method of preparing the toner, including the following steps: (1) carbonized: almond shell, walnut shells and coffee grounds as a raw material, the raw material of the three mass ratio of 1: 2: 1, after first of 150~ 180 ° C dried ~ 2 hours, after which the temperature was raised to 300~400 ° C calcined 1~2 hours, then heated to 600~700 ° C ~ 2 hours calcination, the multifunctional carbon powder; (2) micronized : the toner micronized versatile, multi-functional nano-milled to 30~200 carbon powder; preparation method of the catalyst was: the reactor temperature was controlled at 40 ° C, before the addition of isopropanol, zirconate added with stirring, slowly stirred for 5 minutes until uniformly mixed; acetylacetone was slowly added dropwise under stirring to the reactor and mixed well in the above mixture, after the addition was complete the reaction at 40 ° C 1 hours cooling the material; preparation method of the catalyst functions to: addition of charcoal to the catalyst, for continuous stirring, the reaction time is 1 ~3h〇
2. 如权利要求1所述的一种功能性涂料,其特征在于,所述的基本涂料的制备方法,其具体步骤为: 一、 将反应器中温度控制在40°C,边搅拌依次按量加入硅氧烷组合物,搅拌速率为300r/min,慢速搅拌5min直至混合均勻; 二、将pH调节剂中的H2O和混合酸在其他洁净的容器中混合均匀后,边搅拌边缓慢滴加至反应器中混合好的硅氧烷组合物中;滴加时间为15〜20min ; 三、 在硅氧烷组合物和pH调节剂混合反应2h后将功能催化剂加入到混合液中; 四、 在功能催化剂加入反应Ih后,冷却至室温后检测出料。 2. A functional coating according to claim 1, characterized in that the basic method of preparation of the coating, including the following steps: First, the reactor temperature was controlled at 40 ° C, with stirring by sequentially the amount of silicone added to the composition, stirring rate 300r / min, slowly stirring until mixed 5min; Second, the pH adjusting agent after the mixed acid H2O and mixed in another clean container, while stirring slowly added dropwise was added to the reactor the mixed silicone composition; dropwise over 15~20min; three-functional catalyst 2h the reaction was mixed in the silicone composition and pH adjusting agent is added to the mixture; IV. after the catalyst addition the reaction function Ih, cooled to room temperature, the material is detected.
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US5413628A (en) * 1993-09-22 1995-05-09 Savin; Ronald R. Stable inorganic zinc-powder rich coating composition
CN101857772A (en) * 2010-06-22 2010-10-13 北京红狮漆业有限公司 Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5413628A (en) * 1993-09-22 1995-05-09 Savin; Ronald R. Stable inorganic zinc-powder rich coating composition
CN101857772A (en) * 2010-06-22 2010-10-13 北京红狮漆业有限公司 Scratch resistance nanometre water-based inorganic-organic polymer paint and application thereof

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