CN103094072B - Improve the method for gate lithography critical dimension uniformity on wafer - Google Patents

Improve the method for gate lithography critical dimension uniformity on wafer Download PDF

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CN103094072B
CN103094072B CN201110341214.1A CN201110341214A CN103094072B CN 103094072 B CN103094072 B CN 103094072B CN 201110341214 A CN201110341214 A CN 201110341214A CN 103094072 B CN103094072 B CN 103094072B
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reflective coating
wafer
critical dimension
dielectric anti
flow
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CN103094072A (en
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廖映雪
杨兆宇
许宗能
赵志勇
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CSMC Technologies Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/02126Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
    • H01L21/0214Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC the material being a silicon oxynitride, e.g. SiON or SiON:H
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/09Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/091Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers characterised by antireflection means or light filtering or absorbing means, e.g. anti-halation, contrast enhancement
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • H01L21/02271Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
    • H01L21/02274Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0273Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
    • H01L21/0274Photolithographic processes
    • H01L21/0276Photolithographic processes using an anti-reflective coating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/3213Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
    • H01L21/32139Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28026Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
    • H01L21/28035Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities

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Abstract

The present invention relates to a kind of method improving gate lithography critical dimension uniformity on wafer, comprise the following steps: wafer is provided, form grid layer at described crystal column surface; At described grid layer surface deposition silicon oxynitride, form dielectric anti-reflective coating, any thickness at a place of described dielectric anti-reflective coating and the deviation of target thickness are all less than 2%; Described dielectric anti-reflective coating applies photoresist, and exposure forms the photoengraving pattern of grid.The invention still further relates to the dielectric anti-reflective coating after a kind of improvement.The above-mentioned method improving gate lithography critical dimension uniformity on wafer, use the dielectric anti-reflective coating (DARC) after a kind of improvement, by improving the uniformity of the thickness of SiON in DARC, the uniformity of controlling and adjustment critical size of polycrystalline silicon grid electrode effectively, reaches the object solving crystal round fringes electric leakage.Compared by the method for adjustment photoetching formula with traditional, do not need again to make a plate and verify, shorten time and the cost of yield improvement.

Description

Improve the method for gate lithography critical dimension uniformity on wafer
[technical field]
The present invention relates to field of semiconductor manufacture, particularly relate to a kind of method improving gate lithography critical dimension uniformity on wafer, also relate to a kind of dielectric anti-reflective coating.
[background technology]
In CMOSFET pipe (CMOS) chip manufacturing, the processing procedure of polysilicon (poly) grid is one very important operation, and the size of polysilicon gate critical size (polyCD) directly can affect the various electrical parameters of device.Therefore the control of the uniformity of polysilicon gate critical size become extremely important.
In a kind of traditional 0.16 micron gate length (LG) processing procedure, after polysilicon gate photoetching, the uniformity of critical size is bad, especially in the edge of wafer, polysilicon gate critical size 10nm more than less of place of crystal circle center, cause at wafer probing (ChipProbing, CP) time, crystal round fringes occurs that the electric leakage of special pattern was lost efficacy, and has a strong impact on the confidence of product yield and client, therefore solves very important that crystal round fringes electric leakage Problem of Failure becomes.
At present in order to solve crystal round fringes polysilicon gate critical size problem less than normal, main way is controlled by the debugging of parameter in the formula (recipe) to polysilicon gate photoetching process, the parameter such as the focal length in photoetching process, NA (numerical aperture), sigma, energy, photoresist thickness generally can be regulated to do and improve.
But the adjustment of these parameters can have influence on the size of PR profile (PRprofile) and critical size, corresponding impact is also had on optical approach effect correction (OPC), therefore high to the method cost of parameter adjustment in photoetching process formula, efficiency is low.
[summary of the invention]
Based on this, be necessary to provide a kind of cost lower, the method for gate lithography critical dimension uniformity on the improvement wafer that efficiency is high.
Improve a method for gate lithography critical dimension uniformity on wafer, comprise the following steps: wafer is provided, form grid layer at described crystal column surface; At described grid layer surface deposition silicon oxynitride, form dielectric anti-reflective coating, any thickness at a place of described dielectric anti-reflective coating and the deviation of target thickness are all less than 2%; Described dielectric anti-reflective coating applies photoresist, and exposure forms the photoengraving pattern of grid.
Preferably, the THICKNESS CONTROL of described dielectric anti-reflective coating exists in, N value controls in 2.09 ~ 2.11, and K value controls in 0.62 ~ 0.66.
Preferably, described deposit is chemical vapor deposition, and reacting gas comprises SiH 4, N 2o and He, SiH 4flow be 69 ~ 89sccm, N 2the flow of O is the flow of 130 ~ 230sccm, He is 1800 ~ 2200sccm, and the reaction pressure of described deposit is 4 ~ 7Torr, and the reaction power of described deposit is 80 ~ 120W.
Preferably, described SiH 4flow be 75sccm.
Preferably, described N 2the flow of O is 210sccm.
Preferably, the flow of described He is 1900sccm.
Preferably, the reaction pressure of described deposit is 5.5Torr.
Preferably, the reaction power of described deposit is 95W.
Preferably, the board model that described deposit uses is Producer.
There is a need to the dielectric anti-reflective coating after a kind of improvement is provided.
A kind of dielectric anti-reflective coating, be located at the surface of grid layer, material is silicon oxynitride, and any thickness at a place of described dielectric anti-reflective coating and the deviation of target thickness are all less than 2%.
The above-mentioned method improving gate lithography critical dimension uniformity on wafer, use the dielectric anti-reflective coating (DARC) after a kind of improvement, by improving the uniformity of the thickness of SiON in DARC, the uniformity of controlling and adjustment critical size of polycrystalline silicon grid electrode effectively, reaches the object solving crystal round fringes electric leakage.Compared by the method for adjustment photoetching formula with traditional, do not need again to make a plate and verify, shorten time and the cost of yield improvement.
[accompanying drawing explanation]
Fig. 1 is the flow chart of the method improving gate lithography critical dimension uniformity on wafer in an embodiment;
Fig. 2 be a kind of use AMAT5000 board traditional handicraft deposit SiON dielectric anti-reflective coating after form by follow-up technique the curve chart that the wafer critical size of polycrystalline silicon grid electrode of polysilicon gate changes with wafer back gauge;
Fig. 3 is the comparison diagram of the response curve that the parameter of curve shown in Fig. 2 and employing Producer board and the first preferred embodiment obtains;
Fig. 4 is the curve chart of the thickness evenness before and after SiON depositing technics improves;
Fig. 5 is the curve chart of the N value uniformity before and after SiON depositing technics improves;
Fig. 6 is the curve chart of the K value uniformity before and after SiON depositing technics improves;
Fig. 7 is the electric leakage fail data figure of wafer before and after SiON depositing technics improves.
[embodiment]
For enabling object of the present invention, feature and advantage more become apparent, and are described in detail the specific embodiment of the present invention below in conjunction with accompanying drawing.
In traditional photoetching process, generally use antireflecting coating (ARC) technique to reduce standing wave effect.The material one that to be the dielectric anti-reflective coating (DielectricAnti-reflectiveCoating, DARC) of SiON (silicon oxynitride) be in ARC, is usually used in the photoetching process of polysilicon gate.Find through inventor's research and experiment, by improving the uniformity of the dielectric anti-reflective coating on polysilicon gate, effectively can solve the problem that the critical size of the polysilicon gate of crystal round fringes is less than normal than design load, thus solve edge current leakage Problem of Failure, the yields of improving product.
Good uniformity can be obtained to make dielectric anti-reflective coating, found by a large amount of experiments, in the technique of deposit SiON, the thickness of the change of each technological parameter and dielectric anti-reflective coating, N value, K value, the scope of N value, the scope of K value have close relationship.Such as within the specific limits, thickness and reaction pressure, reaction power, N 2the flow of O, SiH 4flow be directly proportional, be inversely proportional to the flow of He; N value, K value and SiH 4flow, He flow be directly proportional, with reaction pressure, reaction power, N 2the flow of O is inversely proportional to; N value, K value are directly proportional to the flow of reaction power, He, with reaction pressure, SiH 4flow, N 2the flow of O is inversely proportional to.
Be aided with great many of experiments according to above-mentioned relation, as shown in Figure 1, the invention provides a kind of method improving gate lithography critical dimension uniformity on wafer, comprise the following steps:
S110, provides wafer, forms grid layer at crystal column surface.The material of this grid layer is polysilicon.
S120, at grid layer surface deposition silicon oxynitride, form dielectric anti-reflective coating, control any thickness at a place of dielectric anti-reflective coating and the deviation of target thickness are all less than 2%.Namely thickness is very even.
S130, dielectric anti-reflective coating applies photoresist, and exposure forms the photoengraving pattern of grid.
The mode of deposit is chemical vapor deposition (ChemicalVaporDeposition, CVD), and the reacting gas of deposit comprises SiH 4, N 2o and He, SiH 4flow be 69 ~ 89sccm, N 2the flow of O is the flow of 130 ~ 230sccm, He is 1800 ~ 2200sccm, and the reaction pressure of deposit is 4 ~ 7Torr, and the reaction power of deposit is 80 ~ 120W.
Experimental data shows in above-mentioned parameter area, the uniformity of the thickness of dielectric anti-reflective coating, N value, K value, and the problem that the critical size of polysilicon gate reduces at crystal round fringes just can significantly improve.Understandable, inventor determines separately preferred value a: SiH of each parameter on this basis by experiment 4flow be 75sccm, N 2the flow of O is the flow of 210sccm, He is 1900sccm, and the reaction pressure of deposit is 5.5Torr, and the reaction power of deposit is 95W, and the thickness of dielectric anti-reflective coating is
Following table is the value of each parameter in the first preferred embodiment.
The reaction pressure of deposit 5.5Torr
SiH 4Flow 75sccm
N 2The flow of O 210sccm
The reaction power of deposit 95W
The flow of He 1900sccm
The deposit board deposit dielectric anti-reflection coating that inventor's deposit board that also uses model to be AMAT5000 respectively and model are Producer, find the dielectric anti-reflective coating using Producer board relative to the deposit of AMAT5000 board, the uniformity of N value, K value, thickness is obtained for improvement, thus makes the uniformity of the critical size of polysilicon gate have also been obtained improvement.
Fig. 2 be a kind of use AMAT5000 board traditional handicraft deposit SiON dielectric anti-reflective coating after form by follow-up technique the curve chart that the wafer critical size of polycrystalline silicon grid electrode of polysilicon gate changes with wafer back gauge.Abscissa represents the distance with crystal round fringes, and ordinate represents the critical size of polysilicon gate, can see that the critical size of polysilicon gate is larger with edge gap in the middle part of wafer.
Fig. 3 is the comparison diagram of the response curve that the parameter of curve shown in Fig. 1 and employing Producer board and the first preferred embodiment obtains.Can see that the uniformity of the critical size of polysilicon gate obtains very big improvement.Fig. 4,5,6 is the curve chart using the thickness of AMAT5000 board traditional handicraft and Producer board first preferred embodiment deposit SiON dielectric anti-reflective coating (namely SiON depositing technics improves front and back), N value, K value uniformity respectively.Can see that the uniformity of thickness, N value, K value is obtained for very big improvement.Referring to Fig. 3, although expect to obtain siON, but reality still has close error.Fig. 7 is the electric leakage fail data figure of wafer before and after SiON depositing technics improves.After adopting Producer board first preferred embodiment deposit SiON dielectric anti-reflective coating, the average leakage rate of DIE has dropped to less than 1%.
The above-mentioned method improving gate lithography critical dimension uniformity on wafer, use the dielectric anti-reflective coating (DARC) after a kind of improvement, by improving the uniformity of the K value of SiON in DARC, N value and thickness, the uniformity of controlling and adjustment critical size of polycrystalline silicon grid electrode effectively, reaches the object solving crystal round fringes electric leakage.Compared by the method for adjustment photoetching formula with traditional, do not need again to make a plate and verify, shorten time and the cost of yield improvement, promote client to product confidence.
The above embodiment only have expressed several execution mode of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection range of patent of the present invention should be as the criterion with claims.

Claims (7)

1. improve a method for gate lithography critical dimension uniformity on wafer, comprise the following steps:
Wafer is provided, forms grid layer at described crystal column surface;
At described grid layer surface deposition silicon oxynitride, form dielectric anti-reflective coating, any thickness at a place of described dielectric anti-reflective coating and the deviation of target thickness are all less than 2%; The THICKNESS CONTROL of described dielectric anti-reflective coating exists in, N value controls in 2.09 ~ 2.11, and K value controls in 0.62 ~ 0.66; Described deposit is chemical vapor deposition, and reacting gas comprises SiH 4, N 2o and He, SiH 4flow be 69 ~ 89sccm, N 2the flow of O is the flow of 130 ~ 230sccm, He is 1800 ~ 2200sccm, and the reaction pressure of described deposit is 4 ~ 7Torr, and the reaction power of described deposit is 80 ~ 120W;
Described dielectric anti-reflective coating applies photoresist, and exposure forms the photoengraving pattern of grid.
2. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, described SiH 4flow be 75sccm.
3. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, described N 2the flow of O is 210sccm.
4. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, the flow of described He is 1900sccm.
5. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, the reaction pressure of described deposit is 5.5Torr.
6. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, the reaction power of described deposit is 95W.
7. the method improving gate lithography critical dimension uniformity on wafer according to claim 1, is characterized in that, the board model that described deposit uses is Producer.
CN201110341214.1A 2011-11-01 2011-11-01 Improve the method for gate lithography critical dimension uniformity on wafer Active CN103094072B (en)

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PCT/CN2012/083354 WO2013064025A1 (en) 2011-11-01 2012-10-23 Method for improving gate photo-etching key size uniformity on wafer

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CN111696849A (en) * 2019-03-13 2020-09-22 上海新微技术研发中心有限公司 Composite film, composite silicon wafer, and preparation method and application thereof
CN112802797B (en) * 2020-12-29 2023-08-15 上海华力集成电路制造有限公司 Method for improving uniformity of critical dimension in wafer surface
CN113140505B (en) * 2021-03-18 2023-08-11 上海华力集成电路制造有限公司 Method for manufacturing through hole
CN113391520A (en) * 2021-05-14 2021-09-14 上海华力集成电路制造有限公司 Coating method of photoresist and photoetching method thereof

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CN1445818A (en) * 2002-03-15 2003-10-01 台湾积体电路制造股份有限公司 Multiple-layer type dielectric antireflection layer and its forming method
CN1385884A (en) * 2002-06-20 2002-12-18 上海华虹(集团)有限公司 Novel button anti-reflection film structure
CN1471132A (en) * 2002-07-22 2004-01-28 ����ʿ�뵼�����޹�˾ Method for forming pattern of semiconductor device and semiconductor device
CN1567529A (en) * 2003-06-13 2005-01-19 南亚科技股份有限公司 Multi-layer type anti-reflection layer and semiconductor process adopting the same
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