CN103088352A - 一种含磷硼酸除锈防锈剂 - Google Patents
一种含磷硼酸除锈防锈剂 Download PDFInfo
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- CN103088352A CN103088352A CN2013100355381A CN201310035538A CN103088352A CN 103088352 A CN103088352 A CN 103088352A CN 2013100355381 A CN2013100355381 A CN 2013100355381A CN 201310035538 A CN201310035538 A CN 201310035538A CN 103088352 A CN103088352 A CN 103088352A
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- CN
- China
- Prior art keywords
- rust
- temperature
- acid
- boric acid
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 23
- ADTIZERIXVAGEF-UHFFFAOYSA-N B(O)(O)O.[P] Chemical compound B(O)(O)O.[P] ADTIZERIXVAGEF-UHFFFAOYSA-N 0.000 title abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- 239000004327 boric acid Substances 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 22
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 17
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 13
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 10
- 238000007599 discharging Methods 0.000 claims abstract description 7
- 230000035484 reaction time Effects 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 15
- 229940095064 tartrate Drugs 0.000 claims description 12
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- 239000002184 metal Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 3
- 238000009835 boiling Methods 0.000 abstract description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 abstract 1
- 235000019801 trisodium phosphate Nutrition 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 17
- 238000004140 cleaning Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- -1 boric acid ester Chemical class 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910000398 iron phosphate Inorganic materials 0.000 description 3
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical group [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 239000011538 cleaning material Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000006257 total synthesis reaction Methods 0.000 description 2
- 239000005069 Extreme pressure additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000001457 metallic cations Chemical group 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
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CN201310035538.1A CN103088352B (zh) | 2013-01-30 | 2013-01-30 | 一种含磷硼酸除锈防锈剂 |
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CN201310035538.1A CN103088352B (zh) | 2013-01-30 | 2013-01-30 | 一种含磷硼酸除锈防锈剂 |
Publications (2)
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CN103088352A true CN103088352A (zh) | 2013-05-08 |
CN103088352B CN103088352B (zh) | 2014-12-03 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104294297A (zh) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | 一种水基金属清洗剂及其制备方法 |
CN109680284A (zh) * | 2019-02-28 | 2019-04-26 | 苏州纳孚林科金属表面技术有限公司 | 一种还原性硼硫酸酯除锈剂 |
CN109778293A (zh) * | 2019-02-28 | 2019-05-21 | 苏州纳孚林科金属表面技术有限公司 | 一种电解除锈防锈剂 |
CN109778212A (zh) * | 2019-02-28 | 2019-05-21 | 苏州纳孚林科金属表面技术有限公司 | 一种具有抛光效果的除锈膏 |
CN114717561A (zh) * | 2022-05-20 | 2022-07-08 | 镇江纳润特高新科技发展有限公司 | 一种含磷硼酸酯的黑色金属抛光液及其制备方法 |
CN114892174A (zh) * | 2022-05-20 | 2022-08-12 | 镇江纳润特高新科技发展有限公司 | 一种具有除锈功能的黑色金属抛光液及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1733969A (zh) * | 2004-08-02 | 2006-02-15 | 牛长宽 | 一种除锈防护液及使用其进行除锈防护的方法 |
-
2013
- 2013-01-30 CN CN201310035538.1A patent/CN103088352B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1733969A (zh) * | 2004-08-02 | 2006-02-15 | 牛长宽 | 一种除锈防护液及使用其进行除锈防护的方法 |
Non-Patent Citations (2)
Title |
---|
孙小燕,等: "含磷硼酸酯润滑油添加剂的合成与性能测试", 《精细石油化工》, no. 1, 31 January 2000 (2000-01-31) * |
葛春华,等: "硼酸酯的合成与应用", 《辽宁化工》, vol. 28, no. 2, 31 March 1999 (1999-03-31) * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104294297A (zh) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | 一种水基金属清洗剂及其制备方法 |
CN109680284A (zh) * | 2019-02-28 | 2019-04-26 | 苏州纳孚林科金属表面技术有限公司 | 一种还原性硼硫酸酯除锈剂 |
CN109778293A (zh) * | 2019-02-28 | 2019-05-21 | 苏州纳孚林科金属表面技术有限公司 | 一种电解除锈防锈剂 |
CN109778212A (zh) * | 2019-02-28 | 2019-05-21 | 苏州纳孚林科金属表面技术有限公司 | 一种具有抛光效果的除锈膏 |
CN109778212B (zh) * | 2019-02-28 | 2020-09-22 | 苏州纳孚林科金属表面技术有限公司 | 一种具有抛光效果的除锈膏 |
CN114717561A (zh) * | 2022-05-20 | 2022-07-08 | 镇江纳润特高新科技发展有限公司 | 一种含磷硼酸酯的黑色金属抛光液及其制备方法 |
CN114892174A (zh) * | 2022-05-20 | 2022-08-12 | 镇江纳润特高新科技发展有限公司 | 一种具有除锈功能的黑色金属抛光液及其制备方法 |
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Publication number | Publication date |
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CN103088352B (zh) | 2014-12-03 |
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C06 | Publication | ||
PB01 | Publication | ||
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: SONG XIAOLIN Effective date: 20150727 Owner name: WUXI NANOLUBTECH SCIENCE + TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SONG XIAOLIN Effective date: 20150727 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20150727 Address after: 214000, No. 210, Xinzhou Road, Mei Cun town, Wuxi national hi tech Industrial Development Zone, Wuxi, Jiangsu Patentee after: NANOLUBTECH (WUXI) SCI&TECH CO., LTD. Patentee after: Song Xiaolin Address before: District 214000 of Jiangsu province Wuxi Xian Lu Mei Cunxi 129-1 (530 business center) Patentee before: Song Xiaolin |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Rust-removing and rust-preventing agent containing phosphorus boric acid Effective date of registration: 20160919 Granted publication date: 20141203 Pledgee: Agricultural Bank of China Limited by Share Ltd Wuxi science and Technology Branch Pledgor: Wuxi Technology Co., Ltd.|Song Xiaolin Registration number: 2016990000793 |
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PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20181219 Granted publication date: 20141203 Pledgee: Agricultural Bank of China Limited by Share Ltd Wuxi science and Technology Branch Pledgor: NANOLUBTECH (WUXI) SCI&TECH CO., LTD.|Song Xiaolin Registration number: 2016990000793 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |