CN103087846A - Natural cleaning agent for removing residual pesticide on fruit and vegetable surfaces and preparation method - Google Patents
Natural cleaning agent for removing residual pesticide on fruit and vegetable surfaces and preparation method Download PDFInfo
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- CN103087846A CN103087846A CN2011103493327A CN201110349332A CN103087846A CN 103087846 A CN103087846 A CN 103087846A CN 2011103493327 A CN2011103493327 A CN 2011103493327A CN 201110349332 A CN201110349332 A CN 201110349332A CN 103087846 A CN103087846 A CN 103087846A
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Abstract
The invention relates to a natural cleaning agent for removing residual pesticides on fruit and vegetable surfaces and a preparation method; the preparation method of the cleaning agent comprises the following steps: cleaning shells, removing heavy metal, sterilizing the shells, performing high temperature electrolysis and ionization of the sterilized shells to form solid powder, and refining with a mesh sieve to prepare nanometer powder; the cleaning agent comprises one or more than one natural shells according to certain weight ratios. The cleaning agent of the invention not only can remove residual toxic materials on fruit and vegetable surfaces, such as pesticides, sulfur dioxide and aflatoxin, prevent toxic materials from entering human body by eating of the fruit and vegetable, thus prevent continuous accumulation of the toxic materials in the body to damage human body health, but also has no toxicity or irritation to human skin, causes no secondary pollution of ecological environment, meets the development trend of green cleaning agents, and has good application prospects.
Description
Technical field
The present invention relates to clean-out system and the preparation method in a kind of domestic chemical products field, particularly relate to a kind of for removing residual natural cleaning agent and the preparation methods such as fruit and vegetable surfaces remains of pesticide, sulfurous gas and aflatoxin.
Background technology
Because commercially available fruit, vegetables, dry fruit etc. contain abundant nutritive ingredient, be indispensable food in the human lives.At present, the fruit and vegetable varieties that people not only eat is more, and all consumes every day such as a large amount of fruit, vegetables, dry fruit, dry vegetalbe, edible mushrooms etc.Therefore, grow fruit, vegetables etc. can be brought huge economic benefit to the peasant.But the commerial growing due to fruit, vegetables, for prevention and elimination of disease and pests occurs, the peasant uses a large amount of agricultural chemicals to be controlled usually, simultaneously because the lavishment of agricultural chemicals is abused, and do not reach and gather in the crops fruit, vegetables Safe period after medicine, cause fruit, vegetable surface residual a large amount of agricultural chemicals.These remainss of pesticide are water-soluble little, generally can't washes clean with clear water, and therefore edible such fruit, the phenomenon that vegetables cause pesticide intoxication happen occasionally, and social repercussion is very large.The Chinese government attaches great importance to problems, and since 20 century 70s, just formulates successively and promulgated the rules such as " chemistry security Application standard ", " agricultural chemicals reasonable application ", " agricultural chemicals management rules ".
Now, international and external advanced garden stuff pesticide residue standard is that the international code council (CAC) formulates, and wherein content contains the garden stuff pesticide residue standard and relates to 146 kinds, agricultural chemicals, amounts to 827 of indexs; Japan's residue criterion relates to 86 kinds, agricultural chemicals, amounts to 611 of indexs; European Union's residue criterion relates to 76 kinds, agricultural chemicals, amounts to 583 of indexs; U.S.'s residue criterion relates to 165 kinds of agricultural chemicals, amounts to 802 of indexs.At present, 35 of China's mandatory national standards relevant with fruits and vegetables relate to 58 of pesticide residue indexs, 52 kinds, agricultural chemicals.But due to the existence of many objective factors, still have the agricultural chemicals of a lot of high poison, high residue to be used in farm crop, particularly fruit, above vegetables.Because fruit, vegetables great majority are edible in fresh, add edible greatly with amount often, thereby the remains of pesticide amount on them easily consists of serious harm to human body.Find total recall rate 32% of fruit, pesticide residues in vegetables medicine according to Ministry of Agriculture monitoring, total exceeding standard rate 25%, wherein the 6 big city fruits and vegetables Pesticide Residues exceeding standard rate such as Beijing surpass 50%.1987-1992 wherein, the pesticidal contamination fruits and vegetables occur and cause more than 500 of poisoning in Guangdong Province altogether, and 10,000 people are poisoning.1994, the responsible official of the Ministry of Agriculture and the Ministry of Health points out: national pesticide intoxication number surpasses 100,000 people every year, because the nonproductive poisoning and poisoning ratio of productivity is about 1: 1, long-term edible fruit, the vegetable products that contains pesticide residue, very big to person Health hazard, can be in human body slowly accumulation, human body is produced the chronic poisonings such as carcinogenic, teratogenesis, mutagenesis; Fruit, the vegetables of edible persistent pesticide can cause acute poisoning, even cause dead.
In food-processing storage industry, the phenomenons such as the stifling dry vegetalbe of abuse sulfur-bearing SYNTHETIC OPTICAL WHITNER such as sulphur (sulfurous gas), dry fruit happen occasionally.Although sulfurous gas has bleaching and preservative activity to food such as some dry fruit, dry vegetalbe, edible mushrooms, bamboo shoots, can extend effective period of food quality, even in the food such as some dry fruit, dry vegetalbe, edible mushrooms, what sulfur dioxide residual quantity exceeded standard all accounts for more than 90%.Sulfur dioxide residual quantity is too much, can not only destroy vitamins B 1, can also make calcium form insoluble substance, affect human body to the absorption of calcium, and people for a long time the food that exceeds standard of edible sulfurous gas can cause intestinal function disorderly, infringement liver, the Digestive tract of serious harm human body.Therefore, develop a kind of nontoxic, safe, remove the residual of sulfur dioxide in food efficiently, effectively control determination of sulfur dioxide residues in foods employing, make it to reach the relevant hygienic standard of country, improving the quality of food, and can not produce secondary pollution, is also the task of top priority of cleaning agent developing.
In addition, aflatoxin (aflatoxin) is a kind of chemical substance that strong bio-toxicity is arranged, and aflatoxin and liver cancer have substantial connection, also can cause the symptoms such as tissue is lost blood, apocleisis.Flavacin is easily grown on dry fruit, and is as the highest in the content of the flavacin of peanut, cottonseed, walnut, almond, fibert, dried cured fish, dried shrimps, chillies, dried preserved radish strip etc.Flavus is heated to just begin more than 280 ℃ decompose, so general heating is survivable.Therefore, develop a kind of nontoxic, safe, efficient cleaning and remove the residual clean-out system of aflatoxin in food, effectively control the residual quantity of aflatoxin in food, make it to reach the relevant hygienic standard of country, improve the quality of food, and can not produce secondary pollution, be also the top priority of research and development clean-out system.
Generally speaking, people are before edible fruits and vegetables, adopt some means to remove the residues such as fruits and vegetables agricultural chemicals, sulfurous gas and aflatoxin, mainly contain at present clear water infusion method, alkaline soak method, boiling water infusion method, washing water of rice infusion method, washing composition infusion method, decortication method etc.Wherein, mainly still use agricultural chemicals, sulfurous gas and aflatoxin etc. that washing composition removes in fruits and vegetables residual, because its more convenient, quick, efficient, safety can tentatively satisfy people's requirement high-quality to quality of life.Many cleaning agent for dinnerware on market are the sodium alkyl benzene sulfonate synthesis materials as leading take cheapness, and its security has very large dispute.If on fruit, vegetables, residual this material, will certainly cause secondary pollution.In addition, this class washing composition does not add washing assistant and the agent of network platform, causes the effect of removing agricultural chemicals and heavy metal not good.External useful Oleum Cocois or oleic acid are produced fruit, vegetable cleaning agent, although this type of washing composition safety, the cold washing ability. itself is the unpleasant odor of remaining grease also.Therefore, exploitation environmental protection, safety and fruit, vegetables scavenger specially that can effectively eccysis pesticide residue be highly significant for protecting the healthy of the people.In order to fill up the blank of China on this series products, we have carried out professional exploitation and research work.
This shows, above-mentioned existing clean-out system and preparation method obviously still have inconvenience and defective, and demand urgently further being improved in structure and use.The problem that exists in order to solve clean-out system and preparation method, relevant manufacturer there's no one who doesn't or isn't seeks solution painstakingly, but have no for a long time applicable design is completed by development always, and common product does not have appropriate structure to address the above problem, and this is obviously the problem that the anxious wish of relevant dealer solves.Therefore how to found a kind of novel natural cleaning agent and preparation method of being used for removing the fruit and vegetable surfaces remains of pesticide who has that volume is little, cost is low concurrently and can have comprehensive adjustment function when using, real one of the current important research and development problem that belongs to, also becoming the current industry utmost point needs improved target.
Summary of the invention
The object of the invention is to, overcome the defective that existing clean-out system and preparation method exist, and a kind of novel natural cleaning agent that is used for removing the fruit and vegetable surfaces remains of pesticide is provided, technical problem to be solved is to provide a kind of natural fruit and vegetables scavenger specially, in order to remove the residuals such as agricultural chemicals harmful in fruits and vegetables, sulfurous gas and aflatoxin, avoid the residual food product such as agricultural chemicals, sulfurous gas and aflatoxin to enter human body, it constantly accumulates on human body, thereby be detrimental to health, be very suitable for practicality.
Another object of the present invention is to, overcome the existing defective of existing clean-out system making method, and provide a kind of new being used for to remove the preparation method of the natural cleaning agent of fruit and vegetable surfaces remains of pesticide, technical problem to be solved is to make it can make a clean-out system that contains natural seashell powder composition, and need not by the chemosynthesis mode, therefore do not have the residual of chemical agent, and more can form more careful, more easily be the convenient use of people, thereby more be suitable for practicality.
The object of the invention to solve the technical problems realizes by the following technical solutions.Its that proposes according to the present invention comprises: a simple powder clean-out system made from shell, wherein said shell powder comprises arbitrary component of a Margarita, a bold and unconstrained shellfish, an abalone shellfish, one or nine hole shellfishes, an oyster shellfish, or their arbitrary combination.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said this natural cleaning agent is respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made and form, refine by Margarita the 15-50 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish the 10-40 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells the 10-25 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes the 5-25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 10-25 % by weight that the natural component that is made accounts for the natural cleaning agent composition.
aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, in wherein said this natural cleaning agent one preferred embodiment, refine by Margarita 30 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 15 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 15 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 20 % by weight that the natural component that is made accounts for the natural cleaning agent composition, form and refine by the oyster shellfish 20 % by weight that the natural component be made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
The object of the invention to solve the technical problems also realizes by the following technical solutions.Its that proposes according to the present invention comprises the following steps: clean a shell with removal heavy metal; To toast this shell and to carry out sterilization more than or equal to the temperature of 50 ℃; This shell of electrolysis with 1000～2500 ℃ of these shells of high-temperature calcination; Standing this shell and this shell of ionization and form shell powder; And this shell powder of mesh screen.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
The preparation method of aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said its described cleaning one shell comprises with the removal heavy metal step: with this shell of vibrations ultrasonic cleaning; Soaked this shell 100～200 hours with tap water, and change at least water once every day; And this shell of Exposure to Sunlight 5～8 days.
The preparation method of aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said its used more than or equal to the temperature of 50 ℃ and toasted this shell and carry out sterilisation step, need to be to this shell baking 10～12 hours.
The preparation method of aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said its described this shell step of electrolysis is to this shell calcination 8～12 hours with 1000～2500 ℃ of these shells of high-temperature calcination.
The preparation method of aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said its described standing this shell and this shell of ionization and form the shell powder step are that standing this shell is in the enclosed space of constant temperature drying and make this shell gasification form shell powder.
The preparation method of aforesaid natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide, wherein said this shell powder step of its described mesh screen is to screen with the mesh screen more than micron 600 orders.
The present invention compared with prior art has obvious advantage and beneficial effect.by technique scheme, the present invention is used for removing the residual agricultural chemicals of fruit and vegetable surfaces, the natural cleaning agent of sulfurous gas and aflatoxin etc. and preparation method can reach suitable technical progress and practicality, and has an extensive utility value on industry, it has following advantages at least: the pure natural shell powder is refining to be formed because raw material adopts in the present invention, to fruit, vegetables remains of pesticide, the clearance of sulfurous gas and aflatoxin etc. is high, can also remove the dust of fruit and vegetable surfaces, greasy dirt, worm dirt etc., human body is had no side effect, to the environment non-secondary pollution, the characteristics such as safe and reliable simple and easy to use.
In sum, the present invention is used for removing natural cleaning agent and the preparation method of fruit and vegetable surfaces remains of pesticide, the making step of this clean-out system is: clean shell and removal heavy metal, to shell carry out sterilization, to the shell of completing sterilization carry out high-temperature electrolysis, the ionization shell forms pressed powder, refined with mesh screen the nanometer powder that is made, this clean-out system is combined according to a certain weight ratio by one or more natural seashells thereafter.Product of the present invention can not only effectively be removed the residual toxicity materials such as agricultural chemicals, sulfurous gas and aflatoxin of fruit and vegetable surfaces, avoid toxicant to enter human body via edible fruits and vegetables, constantly accumulate in human body and be detrimental to health, and to the nontoxic nonirritant of human body skin, simultaneously can not cause secondary pollution to ecotope, meet the trend of green cleaning agent development, have a good application prospect.The present invention is a significant progress in technology, and has obvious positively effect, is really a new and innovative, progressive, practical new design.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, for can clearer understanding technique means of the present invention, and can be implemented according to the content of specification sheets, and for above and other objects of the present invention, feature and advantage can be become apparent, below especially exemplified by preferred embodiment, and the cooperation accompanying drawing, be described in detail as follows.
Description of drawings
Fig. 1 is the schema of making method of the natural cleaning agent of one embodiment of the invention.
Fig. 2 be one embodiment of the invention make the schema of the making method of natural cleaning agent with the oyster shellfish.
Fig. 3 be one embodiment of the invention make the schema of the making method of natural cleaning agent with Margarita.
Fig. 4 be one embodiment of the invention make the schema of the making method of natural cleaning agent with bold and unconstrained shellfish.
Fig. 5 be one embodiment of the invention make the schema of the making method of natural cleaning agent with the abalone shellfish.
Fig. 6 be one embodiment of the invention make the schema of the making method of natural cleaning agents with nine hole shellfishes.
102: clean shell and removal heavy metal
104: shell is carried out sterilization;
106: the high-temperature electrolysis shell;
108: ionization shell and form shell powder
110: this shell powder of mesh screen
202: with vibrations ultrasonic cleaning oyster shellfish
204: soak the oyster shellfish with tap water
206: Exposure to Sunlight oyster shellfish
208: the oyster shellfish is toasted
210: with the temperature calcination of at least 1380 ℃ nine hole shellfishes
212: standing nine hole shellfishes are in the enclosed space of constant temperature drying and make nine hole shellfishes gasifications form shell powder
214: screen with micron 600 orders and above mesh screen shell powder
302: with vibrations ultrasonic cleaning Margarita
304: soak Margarita with tap water
306: the Exposure to Sunlight Margarita
308: Margarita is toasted
310: with the temperature calcination Margarita of at least 1720 ℃
312: standing Margarita is in the enclosed space of constant temperature drying and make Margarita gasification form calcium ion powder
314: screen with the mesh screen calcium ion powder more than micron 600 orders
402: with vibrations ultrasonic cleaning person of outstanding talent shellfish
404: soak bold and unconstrained shellfish with tap water
406: Exposure to Sunlight person of outstanding talent shellfish
408: bold and unconstrained shellfish is toasted
410: with the temperature calcination person of outstanding talent shellfish of at least 2300 ℃
412: standing bold and unconstrained shellfish is in the enclosed space of constant temperature drying and make the gasification of bold and unconstrained shellfish form bold and unconstrained shellfish powder
414: screen with the mesh screen calcium ion powder more than micron 600 orders
502: with vibrations ultrasonic cleaning abalone shellfish
504: soak the abalone shellfish with tap water
506: Exposure to Sunlight abalone shellfish
508: the abalone shellfish is toasted
510: with the temperature calcination abalone shellfish of at least 1560 ℃
512: standing abalone shellfish is in the enclosed space of constant temperature drying and make abalone shellfish gasification form calcium ion powder
514: screen with the mesh screen calcium ion powder more than micron 600 orders
602: with vibrations ultrasonic cleaning nine hole shellfishes
604: soak nine hole shellfishes with tap water
606: Exposure to Sunlight nine hole shellfishes
608: nine hole shellfishes are toasted
610: with the temperature calcination of at least 1560 ℃ nine hole shellfishes
612: standing nine hole shellfishes are in the enclosed space of constant temperature drying and make nine hole shellfishes gasifications form calcium ion powder
614: screen with the mesh screen calcium ion powder more than micron 600 orders
Embodiment
Reach for further setting forth the present invention technique means and the effect that predetermined goal of the invention is taked, below in conjunction with accompanying drawing and preferred embodiment, the natural cleaning agent and its embodiment of preparation method, structure, feature and the effect thereof that are used for removing the fruit and vegetable surfaces remains of pesticide to foundation the present invention proposes are described in detail as follows.
See also shown in Figure 1ly, Fig. 1 is the schema of making method of the natural cleaning agent of one embodiment of the invention.The making method of the making method of clean-out system of the present invention, particularly a kind of natural cleaning agent comprises the following steps: at first, clean shell and removal heavy metal (step 102); Then shell is carried out sterilization (step 104); Then, the shell of completing sterilization is carried out high-temperature electrolysis (step 106); Ionization shell and form pressed powder (step 108) again; At last, refined the calcium ion powder (step 110) that is made with mesh screen, to obtain even nano level powder more than micron order.
Wherein, in one embodiment of this invention, cleaning shell and removal heavy metal (step 102), is that shell is soaked in mung bean soya bean gypsum, and continues to boil more than at least 16 hours or 16 hours and removal heavy metal.In another embodiment of the present invention, cleaning shell and removal heavy metal (step 102), is to comprise the following step: at first, and with vibrations ultrasonic cleaning shell; Soak shell more than at least 80 hours or 80 hours with tap water again, the better soak time of one is probably about 80～220 hours, and daily requirement changes water once; At last, shell is picked up and Exposure to Sunlight more than 4 days or 4 days at least, better Exposure to Sunlight time of one is probably about 4～9 days and removal heavy metal.
Shell is carried out sterilization (step 104), be even to toast shell higher than the temperature of 50 ℃ with at least 50 ℃ to carry out sterilization, and continue baking more than at least 8 hours.In another preferred embodiment of the present invention, it continues baking 10～15 hours to shell.
The shell of completing sterilization is carried out high-temperature electrolysis (step 106), is with the high-temperature calcination shell more than 900 ℃, shell to be carried out electrolysis, and continues constant temperature calcination shell more than at least 7 hours or 7 hours.In a preferred embodiment of the present invention, be with the high-temperature calcination shell more than 900～2700 ℃, shell to be carried out electrolysis, and continue constant temperature calcination shell 7～18 hours.
Ionization shell and form calcium ion powder (step 108) is with in the standing enclosed space of the shell after high-temperature electrolysis, and makes shell be gasificated into calcium ion powder (being ionized calcium).Temperature in this enclosed space for fixing, can be controlled with a constant temperature system or device the temperature of this enclosed space with humidity, and with a humidity conditioner, such as dehumidifier etc., controls the interior humidity of enclosed space; In addition, this enclosed space can be a room, a factory building or an airtight container.
Mesh screen refines the calcium ion powder (step 110) that is made, and is with micron 600 orders and above mesh screen, calcium ion powder to be screened, and obtains even nano level calcium ion powder more than micron order.
Make natural cleaning agent of the present invention when adopting the oyster shellfish, or natural cleaning agent contains when containing the alkaline components of natural calcium ion component with oyster shellfish refinement making, its making method sees also shown in Figure 2, be one embodiment of the invention make the schema of the making method of natural cleaning agent with the oyster shellfish.Making method of making natural cleaning agent with the oyster shellfish of the present invention comprises the following steps: with vibrations ultrasonic cleaning oyster shellfish (step 202); Soak oyster shellfish at least 192 hours (step 204) with tap water again; Again with the oyster shellfish by taking out in tap water and Exposure to Sunlight at least 7 days (step 206); Then, carry out sterilization with the temperature baking oyster shellfishes of at least 50 ℃, and continue at least 12 hours (step 208) of baking; Then, continued at least 12 hours and made the oyster shellfish carry out electrolysis (step 210) with the high-temperature calcination oyster shellfish of at least 1380 ℃; In the enclosed space that just the standing constant temperature drying of oyster shellfish after calcination or temperature and humidity are all fixed again, and make the oyster shellfish be gasificated into calcium ion powder (being ionized calcium) (step 212); At last, with micron 600 orders and above mesh screen, calcium ion powder is screened, and obtain even nano level calcium ion powder (step 214) more than micron order.
Make natural cleaning agent of the present invention when adopting Margarita, or natural cleaning agent contains when containing the alkaline components of natural calcium ion component with Margarita refinement making, its making method sees also shown in Figure 3, be one embodiment of the invention make the schema of the making method of natural cleaning agent with Margarita.Making method of making natural cleaning agent with Margarita of the present invention comprises the following steps: with vibrations ultrasonic cleaning Margarita (step 302); Soak Margarita at least 120 hours (step 304) with tap water again; Again with Margarita by taking out in tap water and Exposure to Sunlight at least 6 days (step 306); Then, carry out sterilization with the temperature baking Margaritas of at least 50 ℃, and continue at least 12 hours (step 308) of baking; Then, continued at least 12 hours and made Margarita carry out electrolysis (step 310) with the high-temperature calcination Margarita of at least 1720 ℃; In the enclosed space that just the standing constant temperature drying of Margarita after calcination or temperature and humidity are all fixed again, and make Margarita be gasificated into calcium ion powder (being ionized calcium) (step 312); At last, with micron 600 orders and above mesh screen, calcium ion powder is screened, and obtain even nano level calcium ion powder (step 314) more than micron order.
Make natural cleaning agent of the present invention when adopting bold and unconstrained shellfish, or natural cleaning agent contains when containing the alkaline components of natural calcium ion component with bold and unconstrained shellfish refinement making, its making method sees also shown in Figure 4, be one embodiment of the invention make the schema of the making method of natural cleaning agent with bold and unconstrained shellfish.Making method of making natural cleaning agent with bold and unconstrained shellfish of the present invention comprises the following steps: with vibrations ultrasonic cleaning person of outstanding talent shellfish (step 402); Soak bold and unconstrained shellfish at least 192 hours (step 404) with tap water again; Again with bold and unconstrained shellfish by taking out in tap water and Exposure to Sunlight at least 8 days (step 406); Then, carry out sterilization with the bold and unconstrained shellfishes of temperature baking of at least 50 ℃, and continue at least 12 hours (step 408) of baking; Then, continued at least 10 hours and made bold and unconstrained shellfish carry out electrolysis (step 410) with the bold and unconstrained shellfish of the high-temperature calcination of at least 2300 ℃; In the enclosed space that just the standing constant temperature drying of bold and unconstrained shellfish after calcination or temperature and humidity are all fixed again, and make bold and unconstrained shellfish be gasificated into calcium ion powder (being ionized calcium) (step 412); At last, with micron 600 orders and above mesh screen, calcium ion powder is screened, and obtain even nano level calcium ion powder (step 414) more than micron order.
Make natural cleaning agent of the present invention when adopting the abalone shellfish, or natural cleaning agent contains when containing the alkaline components of natural calcium ion component with abalone shellfish refinement making, its making method sees also shown in Figure 5, be one embodiment of the invention make the schema of the making method of natural cleaning agent with the abalone shellfish.Making method of making natural cleaning agent with the abalone shellfish of the present invention comprises the following steps: with vibrations ultrasonic cleaning abalone shellfish (step 502); Soak abalone shellfish at least 120 hours (step 504) with tap water again; Again with the abalone shellfish by taking out in tap water and Exposure to Sunlight at least 5 days (step 506); Then, carry out sterilization with the temperature baking abalone shellfishes of at least 50 ℃, and continue at least 12 hours (step 508) of baking; Then, high-temperature calcination abalone shellfish with at least 1560 ℃ continued 18 hours and made the abalone shellfish carry out electrolysis (step 510) at least, in the enclosed space that just the standing constant temperature drying of abalone shellfish after calcination or temperature and humidity are all fixed again, and make the abalone shellfish be gasificated into calcium ion powder (being ionized calcium) (step 512); At last, with micron 600 orders and above mesh screen, calcium ion powder is screened, and obtain even nano level calcium ion powder (step 514) more than micron order.
Make natural cleaning agent of the present invention when adopting nine hole shellfishes, or natural cleaning agent contains when containing the alkaline components of natural calcium ion component with nine hole shellfishes refinement making, its making method sees also shown in Figure 6, be one embodiment of the invention make the schema of the making method of natural cleaning agents with nine hole shellfishes.Making method of making natural cleaning agent with nine hole shellfishes of the present invention comprises the following steps: with vibrations ultrasonic cleaning nine hole shellfishes (step 602); Soak nine hole shellfishes at least 100 hours (step 604) with tap water again; Again with nine hole shellfishes by taking out in tap water and Exposure to Sunlight at least 6 days (step 606); Then, carry out sterilization with the temperature baking nine hole shellfishes of at least 50 ℃, and continue at least 12 hours (step 608) of baking; Then, continued at least 12 hours and made nine hole shellfishes carry out electrolysis (step 610) with the high-temperature calcination nine hole shellfishes of at least 1260 ℃; In the enclosed space that just the standing constant temperature drying of nine hole shellfishes after calcination or temperature and humidity are all fixed again, and make nine hole shellfishes be gasificated into calcium ion powder (being ionized calcium) (step 612); At last, with micron 600 orders and above mesh screen, calcium ion powder is screened, and obtain even nano level calcium ion powder (step 614) more than micron order.
The invention provides a kind of clean-out system, particularly contain the natural alkaline components of a class.The alkaline components that this is natural includes natural calcium ion components, or its main component is natural calcium ion.In this natural cleaning agent, contained natural calcium ion components, formed by refining refinement in shell.Should in order to refine the shell of making, can be Margarita, abalone shellfish, nine hole shellfishes, oyster shellfish or bold and unconstrained shellfish; Or should can comprise wherein one or several shells of Margarita, bold and unconstrained shellfish, abalone shellfish, nine hole shellfishes or oyster shellfish in order to refine the shell of making, even can all comprise.Yet the present invention is not limited with these five kinds of shells, but can adopt the shell of other kind to make calcium ion according to its demand.
Natural cleaning agent of the present invention, have one or more in it and refined the simple powder of making by different types of shell, by these calcium ion compositions with positive electricity and alkalize, when being added to the water, even water-soluble and in order to soak fruits and vegetables, natural calcium ion composition can be by in this and water or the acidic substance in fruits and vegetables carry out acid-base neutralisation, and absorption pesticide residue toxicity material, and with these acidic substance and toxicant removal; Simultaneously, because the granularity of this simple powder has reached micron or near nanometer range, and those atomic special space frameworks have formed larger adsorption specific surface area, therefore its residual toxicity material such as agricultural chemicals, sulfurous gas and aflatoxin to fruits and vegetables upper stratas outer surface, have stronger adsorption.So the fruits and vegetables after cleaning are comparatively clean, can avoid acidic substance and toxicant, enter human body and accumulate in human body via edible fruits and vegetables, and causing human body constitution acidifying or increase to cause allergy or disease.
In an embodiment of the present invention, the natural seashell clean-out system comprises a kind of by single kind of shell, for example Margarita, bold and unconstrained shellfish, abalone shellfish, nine hole shellfishes or oyster shellfish, refine outside the simple powder that is made, more can several be refined the mixed clean-out system that forms of the natural component that is made by different types of shell respectively according to certain ratio, but not as limit, refine ratio in the natural cleaning agent that is made but various different types of shell can be changed according to its demand.Natural cleaning agent can be refined in the natural component be made by institutes such as Margarita, bold and unconstrained shellfish, abalone shellfish, nine hole shellfishes and oyster shellfishes, takes two kinds, three kinds even multiple, or whole natural components is mixed and forms.But not as limit, but can change its mixed ratio according to its demand.
in embodiments of the invention 1, respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made, refine by Margarita 20 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 40 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 15 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 10 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 15 % by weight that the natural component that is made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
in embodiments of the invention 2, respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made, refine by Margarita 50 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 10 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 10 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 5 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
in embodiments of the invention 3, respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made, refine by Margarita 35 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 10 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 20 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 10 % by weight that the natural component that is made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
in embodiments of the invention 4, respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made, refine by Margarita 15 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 25 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 10 % by weight that the natural component that is made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
in a preferred embodiment 5 of the present invention, respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made, refine by Margarita 30 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 15 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 15 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 20 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 20 % by weight that the natural component that is made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
Table one is removed the analytical test table for pesticide residue.
Illustrate:
1. this report is totally 1 page, and it is invalid that separation use and/or summary copy.
2. " ⊙ ": the check system of the U.S. suggestion of platform, after agreeing, the client tests.
Table two is removed the analytical test result for pesticide residue.
Annotate: the measured value lower than the method detecting limit does not represent with " detecting ".
Table three is removed the analytical test result for sulfur dioxide residue.
Illustrate:
1. this report is totally 1 page, and it is invalid that separation use and/or summary copy.
2. " ⊙ ": the check system of the U.S. suggestion of platform, after agreeing, the client tests.
Table four is aflatoxin clearance analysis of experiments result
Illustrate:
1. this report is totally 1 page, and it is invalid that separation use and/or summary copy.
2. " ⊙ ": the check system of the U.S. suggestion of platform, after agreeing, the client tests.
3.「*」：Ann?Rept.BFDA?Taiwan?R.O.C.24：421-4302006.
The natural cleaning agent that this is better, can deposit in Powdered being stored in packing box, during use, the 1-2g natural cleaning agent is mixed the mixing in 2 premium on currency, contained by refining the calcium that the natural composition that is made is into ionic condition in shell in it, because expecting the positive electricity alkalize, therefore can remove the pesticide residue material in fruits and vegetables, and this one is for more than micron order or even nano level powder by refining the natural composition be made in shell, and is easier to absorb the pesticide residue toxicity material.
Above-mentioned better natural cleaning agent, Science and Technology Ltd. carries out the physico-chemical analysis detection through the U.S. check of TaiWan, China platform, this natural cleaning agent is by after carrying out soaking and washing to commercially available multiple fruits and vegetables, show with regard to fruits and vegetables after cleaning the removal analytical test of having carried out the residual aspect of three of pesticide residue, sulfurous gas, aflatoxin toxicant respectively, detected result is listed in table one to table four.Detect analytical results from table one, table two, clean-out system of the present invention can effectively be removed and remain in the multiple remains of pesticide that commercially available fruits and vegetables show, clearance reaches more than 95%.Detect analytical results from table three, clean-out system of the present invention can effectively be removed and remain in sulfurous gas that commercially available fruits and vegetables show etc., and clearance reaches more than 95%.Detect analytical results from table four, clean-out system of the present invention can effectively be removed and remain in aflatoxin that commercially available fruits and vegetables show etc., and clearance reaches more than 93%, removes aflatoxin B2, G1, G2 nearly 100%.Therefore, detected result shows the product of making according to the present invention, and the residual toxin such as agricultural chemicals, sulfurous gas and aflatoxin are had efficient cleaning removal effect.
the above, it is only preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, although the present invention discloses as above with preferred embodiment, yet be not to limit the present invention, any those skilled in the art, within not breaking away from the technical solution of the present invention scope, when the technology contents that can utilize above-mentioned announcement is made a little change or is modified to the equivalent embodiment of equivalent variations, every content that does not break away from technical solution of the present invention, any simple modification that foundation technical spirit of the present invention is done above embodiment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (9)
1. natural cleaning agent of be used for removing the fruit and vegetable surfaces remains of pesticide is characterized in that it comprises:
The clean-out system that one simple powder made from shell is made, wherein said shell powder comprises arbitrary component of a Margarita, a bold and unconstrained shellfish, an abalone shellfish, one or nine hole shellfishes, an oyster shellfish, or their arbitrary combination.
2. the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 1, it is characterized in that this natural cleaning agent is respectively by Margarita, the person of outstanding talent shellfish, the abalone shellfish, nine hole shellfishes and oyster shellfish are refined the natural component that is made and form, refine by Margarita the 15-50 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish the 10-40 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells the 10-25 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes the 5-25 % by weight that the natural component that is made accounts for the natural cleaning agent composition, and refine by the oyster shellfish 10-25 % by weight that the natural component that is made accounts for the natural cleaning agent composition.
3. the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 2, it is characterized in that this natural cleaning agent one preferred embodiment, refine by Margarita 30 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by bold and unconstrained shellfish 15 % by weight that the natural component that is made accounts for the natural cleaning agent composition, refine by abalone shells 15 % by weight that the natural component that is made accounts for natural product clean-out system composition, refine by nine hole shellfishes 20 % by weight that the natural component that is made accounts for the natural cleaning agent composition, form and refine by the oyster shellfish 20 % by weight that the natural component be made accounts for the natural cleaning agent composition, said components has formed a kind of natural cleaning agent of better cleaning performance.
4. preparation method who be used for to remove the natural cleaning agent of fruit and vegetable surfaces remains of pesticide is characterized in that it comprises the following steps:
Clean a shell with removal heavy metal;
To toast this shell and to carry out sterilization more than or equal to the temperature of 50 ℃;
This shell of electrolysis with 900～2700 ℃ of these shells of high-temperature calcination;
Standing this shell and this shell of ionization and form shell powder; And
This shell powder of mesh screen.
5. the preparation method of the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 4 is characterized in that its described cleaning one shell comprises with the removal heavy metal step:
With this shell of vibrations ultrasonic cleaning;
Soaked this shell 80～220 hours with tap water, and change at least water once every day; And
This shell of Exposure to Sunlight 4～9 days.
6. the preparation method of the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 4 is characterized in that it is used more than or equal to the temperature of 50 ℃ to toast this shell and carry out sterilisation step, need to be to this shell baking 10～15 hours.
7. the preparation method of the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 4 is characterized in that described this shell step of electrolysis is to this shell calcination 7～15 hours with 900～2700 ℃ of these shells of high-temperature calcination for it.
8. the preparation method of the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 4, it is characterized in that its described standing this shell and this shell of ionization and form the shell powder step, is that standing this shell is in the enclosed space of constant temperature drying and make this shell gasification form shell powder.
9. the preparation method of the natural cleaning agent for removing the fruit and vegetable surfaces remains of pesticide according to claim 4, is characterized in that this shell powder step of its described mesh screen, is to screen with micron 600 orders and above mesh screen.
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| CN2011103493327A CN103087846A (en) | 2011-10-31 | 2011-10-31 | Natural cleaning agent for removing residual pesticide on fruit and vegetable surfaces and preparation method |
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| CN2011103493327A CN103087846A (en) | 2011-10-31 | 2011-10-31 | Natural cleaning agent for removing residual pesticide on fruit and vegetable surfaces and preparation method |
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| CN103666855A (en) * | 2013-12-27 | 2014-03-26 | 中国科学院海洋研究所 | Fruit-vegetable preparation for removing fruit-vegetable pesticide residue and preparation method thereof |
| CN104073377A (en) * | 2014-06-12 | 2014-10-01 | 浙江海洋学院 | Method for preparing pure natural fruit and vegetable cleaning agent |
| CN104388208A (en) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | Method for preparing pesticide-removing fruit and vegetable cleaning agent based on shell powder |
| CN105779171A (en) * | 2016-04-07 | 2016-07-20 | 中海得金科技有限公司 | Micro-nano shell powder fruit-vegetable cleaning agent and preparation method thereof |
| CN106085614A (en) * | 2016-06-20 | 2016-11-09 | 安徽强旺生物工程有限公司 | Fruit-vegetable clear desalinization of soil by flooding or leaching and preparation method thereof |
| CN106434041A (en) * | 2016-09-14 | 2017-02-22 | 江苏省淡水水产研究所 | Preparation method of Corbicula fluminea shell natural cleaner |
| CN106753902A (en) * | 2016-12-08 | 2017-05-31 | 焦翔 | A kind of agricultural product cleaning agent and preparation method thereof |
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| CN111004687A (en) * | 2019-12-05 | 2020-04-14 | 广东贝尤安新材料科技有限公司 | Vegetable and fruit cleaning agent based on shells and preparation and use methods thereof |
| CN112374519A (en) * | 2020-11-20 | 2021-02-19 | 厦门中美康泰生物技术有限公司 | Preparation method and application of micro-nano natural shell calcitonin powder |
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| CN103666855A (en) * | 2013-12-27 | 2014-03-26 | 中国科学院海洋研究所 | Fruit-vegetable preparation for removing fruit-vegetable pesticide residue and preparation method thereof |
| CN103666855B (en) * | 2013-12-27 | 2016-03-16 | 中国科学院海洋研究所 | A kind of fruits and vegetables preparation removing fruit and vegetable residual pesticide and preparation method thereof |
| CN104073377A (en) * | 2014-06-12 | 2014-10-01 | 浙江海洋学院 | Method for preparing pure natural fruit and vegetable cleaning agent |
| CN104388208A (en) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | Method for preparing pesticide-removing fruit and vegetable cleaning agent based on shell powder |
| CN105779171A (en) * | 2016-04-07 | 2016-07-20 | 中海得金科技有限公司 | Micro-nano shell powder fruit-vegetable cleaning agent and preparation method thereof |
| CN106085614A (en) * | 2016-06-20 | 2016-11-09 | 安徽强旺生物工程有限公司 | Fruit-vegetable clear desalinization of soil by flooding or leaching and preparation method thereof |
| CN106434041A (en) * | 2016-09-14 | 2017-02-22 | 江苏省淡水水产研究所 | Preparation method of Corbicula fluminea shell natural cleaner |
| CN106753902A (en) * | 2016-12-08 | 2017-05-31 | 焦翔 | A kind of agricultural product cleaning agent and preparation method thereof |
| CN109943420A (en) * | 2019-03-07 | 2019-06-28 | 杭州航民雪贝儿生物科技有限公司 | A kind of reactive violet Mussel shell powder and preparation method thereof that aflatoxin is effectively reduced |
| CN111004687A (en) * | 2019-12-05 | 2020-04-14 | 广东贝尤安新材料科技有限公司 | Vegetable and fruit cleaning agent based on shells and preparation and use methods thereof |
| CN112374519A (en) * | 2020-11-20 | 2021-02-19 | 厦门中美康泰生物技术有限公司 | Preparation method and application of micro-nano natural shell calcitonin powder |
| CN112374519B (en) * | 2020-11-20 | 2022-11-15 | 厦门中美康泰生物技术有限公司 | Preparation method and application of micro-nano natural shell calcitonin powder |
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Application publication date: 20130508 |