CN103087355A - Tea polyphenol-containing chitosan-minced fillet protein composite film and preparation method thereof - Google Patents
Tea polyphenol-containing chitosan-minced fillet protein composite film and preparation method thereof Download PDFInfo
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- CN103087355A CN103087355A CN2012105918472A CN201210591847A CN103087355A CN 103087355 A CN103087355 A CN 103087355A CN 2012105918472 A CN2012105918472 A CN 2012105918472A CN 201210591847 A CN201210591847 A CN 201210591847A CN 103087355 A CN103087355 A CN 103087355A
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Abstract
The invention provides a tea polyphenol-containing chitosan-minced fillet protein composite film used for food package and a preparation method thereof. The composite film is prepared by the following method: dissolving chitosan and minced fillet protein in an acidic aqueous solution, adding glycerol and tea polyphenol, stirring to obtain a chitosan-minced fillet protein film-forming solution, keeping the temperature of the film-forming solution at 30-80 DEG C for 10-60 minutes, and centrifuging for 20 minutes at the speed of 3000rpm; uniformly pouring the solution into an organic glass plate frame, drying to form the film at the film-forming temperature of 20-60 DEG C, wherein the film-forming time is 6-24 hours; and stripping the film to obtain the tea polyphenol-containing chitosan-minced fillet protein composite film. The tea polyphenol-containing chitosan-minced fillet protein composite film has the beneficial effects that the composite film is edible, biodegradable and pollution-free and has a good mechanical performance, barrier property and oxidation resistance.
Description
(1) technical field
The present invention relates to a kind of chitosan that contains tea-polyphenol that can be used for food product pack-rotten albumen composite membrane of fish and preparation method thereof.
(2) background technology
Along with the raising of human consumer to Food Quality and preservation term requirement, and the enhancing of environmental consciousness, edible packing membrane has become one of study hotspot of present Food Packaging technology.Edible packing membrane is take edible natural materials such as polysaccharide, protein and lipids as raw material, adds softening agent and linking agent etc., the film that forms by the interaction between differing molecular.Compare with the synthesising packing material, edible packing membrane can be biodegradable, without any pollution, and can also be as the carrier of flavour of food products material, nutrition-fortifying agent, antioxidant and antiseptic-germicide.Can be divided into polyose, protein, lipid and composite edible packing film according to raw material, wherein compound packing film receives much concern.
Chitosan is the macromolecular cpd that the extensive chitin that exists of nature obtains through deacetylation, have good film-forming properties, biocompatibility and biodegradability, be commonly used for the functional membranes such as ultrafiltration, reverse osmosis, ion-exchange, in fields such as medicine, environment, printing and dyeing and food, more application arranged.The rotten albumen of fish is take fribrillin as main component, and the protein film performance of its formation is better than soybean protein film and maize alcohol-soluble protein film, but its research in the edible packing membrane field is also fewer.Tea-polyphenol is the natural phenolic compound that extracts from tealeaves, has bridging property, oxidation-resistance and germ resistance, is applied in edible packing membrane, is expected to improve edible packing membrane film properties and oxidation-resistance.At present there are no the rotten albumen of tea-polyphenol, chitosan and fish is prepared edible packing membrane jointly.
(3) summary of the invention
The purpose of this invention is to provide a kind of edible chitosan that contains tea-polyphenol-rotten albumen composite membrane of fish and preparation method thereof.
The technical solution used in the present invention is:
the rotten albumen composite membrane of a kind of chitosan that contains tea-polyphenol-fish, make by the following method: chitosan and the rotten albumen of fish are dissolved in pH 1.0 ~ 4.0 acidic aqueous solutions, chitosan dosage is 5 ~ 20g/L acidic aqueous solution, the rotten albumen consumption of fish is 10 ~ 100 g/L acidic aqueous solutions, after adding again the tea-polyphenol of the glycerine of 2.5 ~ 50 g/L acidic aqueous solutions and 0.1 ~ 3 g/L acidic aqueous solution, stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish, film-forming soln is incubated 10 ~ 60min under 30 ~ 80 ℃, centrifugal 20min under 3000rpm, then pour evenly in the synthetic glass sheet frame that (the large I of glass holder is adjusted according to film thickness into, general film thickness is between 0.100 ~ 0.15mm), drying and forming-film, film-forming temperature is 20 ~ 60 ℃, film formation time is 6 ~ 24h, take off film and namely get the rotten albumen composite membrane of the described chitosan that contains tea-polyphenol-fish.
The rotten albumen of described fish is frozen minced fillets, comprise the gruel of seawater freezing fish and fresh water frozen minced fillets, such as freezing bighead surimi, freezing chub surimi, the gruel of freezing hairtail fish, the gruel of freezing scad fish etc. (frozen minced fillets can directly be buied from the market, by freezing making after the rubbing of raw material fish flesh of fish part, rinsing and dehydration); Described acidic aqueous solution is one of following: acetum, lactic acid solution, malic acid solution, citric acid solution, hydrochloric acid soln.
The present invention is dissolved in chitosan and the rotten albumen of fish in acidic aqueous solution, adds glycerine and tea-polyphenol, and after insulation and the degassed processing of low-speed centrifugal, film-forming soln is in synthetic glass sheet frame inner drying film forming.
The invention still further relates to a kind of method for preparing the described chitosan that contains tea-polyphenol-rotten albumen composite membrane of fish, described method comprises: (1) is dissolved in chitosan and the rotten albumen of fish in pH 1.0 ~ 4.0 acidic aqueous solutions, chitosan dosage is that the rotten albumen consumption of 5 ~ 20g/L, fish is 10 ~ 100 g/L, after adding again the tea-polyphenol of the glycerine of 2.5 ~ 50 g/L and 0.1 ~ 3 g/L, stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; (2) step (1) gained film-forming soln is incubated 10 ~ 60min under 30 ~ 80 ℃, centrifugal 20min under 3000rpm, then evenly pour in the synthetic glass sheet frame, drying and forming-film, film-forming temperature is 20 ~ 60 ℃, film formation time is 6 ~ 24h, takes off film and namely gets the rotten albumen composite membrane of the described chitosan that contains tea-polyphenol-fish.
Described acidic aqueous solution is one of following: acetum, lactic acid solution, malic acid solution, citric acid solution, hydrochloric acid soln.
Preferably, chitosan dosage is 5 ~ 20g/L, and the rotten albumen consumption of fish is 20 ~ 80 g/L, and the glycerine addition is 10 ~ 20 g/L, and the tea-polyphenol addition is 1 ~ 2 g/L.
The characteristics of the chitosan that contains tea-polyphenol of the present invention's preparation-rotten albumen composite membrane of fish: film thickness 0.100 ~ 0.150mm, tensile strength is 10 ~ 40MPa, elongation at break 50 ~ 90% has good mechanical property; Under 600nm, transmittance is 70 ~ 80%, water vapor transmission rate (WVTR) 0.8 ~ 1.2 * 10
-10G/m * s * Pa, the DPPH free radical is eliminated ability 30 ~ 60%.
The analytical procedure that the present invention adopts:
1, the thickness of composite membrane: adopt vernier callipers to measure.
2, the mechanical property of composite membrane: adopt instrumental test.
3, the transmittance of composite membrane: adopt UV3000 UV, visible light spectrophotometer.
4, the water vapor transmission rate (WVTR) of composite membrane: adopt and intend cup method mensuration.
5, composite membrane DPPH radical scavenging activity is measured: adopt UV3000 UV, visible light spectrophotometer.
Beneficial effect of the present invention is mainly reflected in: composite membrane edible of the present invention, and biodegradable, pollution-free, and have good mechanical property, barrier property and antioxidant property.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
Taking the freezing bighead surimi of 1g chitosan and 1g is dissolved in 50ml pH2.0 acetum, add 0.5g glycerine and 0.05g tea-polyphenol (product purity 85%, available from Hangzhou Qinyuan Natural Plant High-tech Limited Company) after, at the uniform velocity stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; Film-forming soln is incubated 20min under 70 ℃, under 3000rpm, low-speed centrifugal 20min is to remove bubble; The rotten albumen film-forming soln of chitosan after processing-fish is evenly poured in 100 * 100 * 10mm synthetic glass sheet frame into 60 ℃ of film-forming temperatures, film formation time 6h.The rotten albumen composite membrane of the chitosan that contains tea-polyphenol that makes-fish thickness 0.128mm, tensile strength is 12MPa, elongation at break 64%, under 600nm, transmittance is 78%, water vapor transmission rate (WVTR) 1.05 * 10
-10G/m * s * Pa, the DPPH free radical is eliminated ability 35%.
Embodiment 2:
Taking the freezing chub surimi of 0.5g chitosan and 3g is dissolved in 50ml pH2.5 lactic acid solution, add 1g glycerine and 0.1g tea-polyphenol (product purity 70%, available from Hangzhou Qinyuan Natural Plant High-tech Limited Company) after, at the uniform velocity stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; Film-forming soln is incubated 30min under 50 ℃, under 3000rpm, low-speed centrifugal 20min is to remove bubble; The rotten albumen film-forming soln of chitosan after processing-fish is evenly poured in 100 * 100 * 10mm synthetic glass sheet frame into 40 ℃ of film-forming temperatures, film formation time 12h.The rotten albumen composite membrane of the chitosan that contains tea-polyphenol that makes-fish thickness 0.124mm, tensile strength 25MPa, elongation at break 80%, under 600nm, transmittance is 74%, water vapor transmission rate (WVTR) 1.18 * 10
-10G/m * s * Pa, the DPPH free radical is eliminated ability 60%.
Embodiment 3:
Taking the gruel of the freezing hairtail fish of 0.3g chitosan and 4g is dissolved in 50ml pH3.0 hydrochloric acid soln, add 0.5g glycerine and 0.05g tea-polyphenol (product purity 80%, available from Hangzhou Qinyuan Natural Plant High-tech Limited Company) after, at the uniform velocity stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; Film-forming soln is incubated 50min under 40 ℃, under 3000rpm, low-speed centrifugal 20min is to remove bubble; The rotten albumen film-forming soln of chitosan after processing-fish is evenly poured in 100 * 100 * 10mm synthetic glass sheet frame into 50 ℃ of film-forming temperatures, film formation time 8h.The rotten albumen composite membrane of the chitosan that contains tea-polyphenol that makes-fish thickness 0.138mm, tensile strength is 31MPa, elongation at break 89%, under 600nm, transmittance is 78%, water vapor transmission rate (WVTR) 1.17 * 10
-10G/m * s * Pa, the DPPH free radical is eliminated ability 52%.
Embodiment 4:
Taking the gruel of the freezing scad fish of 0.8g chitosan and 1.5g is dissolved in 50ml pH3.5 acetum, add 0.8g glycerine and 0.05g tea-polyphenol (product purity 90%, available from Hangzhou Qinyuan Natural Plant High-tech Limited Company) after, at the uniform velocity stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; Film-forming soln is incubated 60min under 30 ℃, under 3000rpm, low-speed centrifugal 20min is to remove bubble; The rotten albumen film-forming soln of chitosan after processing-fish is evenly poured in 100 * 100 * 10mm synthetic glass sheet frame into 25 ℃ of film-forming temperatures, film formation time 24h.The rotten albumen composite membrane of the chitosan that contains tea-polyphenol that makes-fish thickness 0.115mm, tensile strength is 28MPa, elongation at break 82%, under 600nm, transmittance is 74%, water vapor transmission rate (WVTR) 0.95 * 10
-10G/m * s * Pa, the DPPH free radical is eliminated ability 47%.
Claims (6)
1. rotten albumen composite membrane of the chitosan that contains tea-polyphenol-fish, make by the following method: chitosan and the rotten albumen of fish are dissolved in pH 1.0 ~ 4.0 acidic aqueous solutions, chitosan dosage is 5 ~ 20g/L, the rotten albumen consumption of fish is 10 ~ 100 g/L, after adding again the tea-polyphenol of the glycerine of 2.5 ~ 50 g/L and 0.1 ~ 3 g/L, stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish, film-forming soln is incubated 10 ~ 60min under 30 ~ 80 ℃, centrifugal 20min under 3000rpm, then evenly pour in the synthetic glass sheet frame, drying and forming-film, film-forming temperature is 20 ~ 60 ℃, film formation time is 6 ~ 24h, take off film and namely get the rotten albumen composite membrane of the described chitosan that contains tea-polyphenol-fish.
2. composite membrane as claimed in claim 1 is characterized in that described acidic aqueous solution is one of following: acetum, lactic acid solution, malic acid solution, citric acid solution, hydrochloric acid soln.
3. composite membrane as claimed in claim 1, it is characterized in that: chitosan dosage is 5 ~ 20g/L, and the rotten albumen consumption of fish is 20 ~ 80 g/L, and the glycerine addition is 10 ~ 20 g/L, and the tea-polyphenol addition is 1 ~ 2 g/L.
4. method for preparing the described chitosan that contains tea-polyphenol of claim 1-rotten albumen composite membrane of fish, described method comprises: (1) is dissolved in chitosan and the rotten albumen of fish in pH 1.0 ~ 4.0 acidic aqueous solutions, chitosan dosage is that the rotten albumen consumption of 5 ~ 20g/L, fish is 10 ~ 100 g/L, after adding again the tea-polyphenol of the glycerine of 2.5 ~ 50 g/L and 0.1 ~ 3 g/L, stir 10min, obtain the rotten albumen film-forming soln of chitosan-fish; (2) step (1) gained film-forming soln is incubated 10 ~ 60min under 30 ~ 80 ℃, centrifugal 20min under 3000rpm, then evenly pour in the synthetic glass sheet frame, drying and forming-film, film-forming temperature is 20 ~ 60 ℃, film formation time is 6 ~ 24h, takes off film and namely gets the rotten albumen composite membrane of the described chitosan that contains tea-polyphenol-fish.
5. method as claimed in claim 4 is characterized in that described acidic aqueous solution is one of following: acetum, lactic acid solution, malic acid solution, citric acid solution, hydrochloric acid soln.
6. method as claimed in claim 4, it is characterized in that: chitosan dosage is 5 ~ 20g/L, and the rotten albumen consumption of fish is 20 ~ 80 g/L, and the glycerine addition is 10 ~ 20 g/L, and the tea-polyphenol addition is 1 ~ 2 g/L.
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| CN104877180A (en) * | 2015-05-25 | 2015-09-02 | 苏州市贝克生物科技有限公司 | Water-soluble food packaging film and preparation method thereof |
| CN104893314A (en) * | 2015-05-22 | 2015-09-09 | 浙江海洋学院 | Application of composite active edible film prepared from peeled shrimp processing leftovers |
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| CN112137094A (en) * | 2020-08-26 | 2020-12-29 | 江苏大学 | Preparation method of synergistic antioxidant tea polyphenol-meat protein compound |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020779A (en) * | 2010-11-17 | 2011-04-20 | 河南工业大学 | Preparation method of edible anti-bacterial packaging film |
-
2012
- 2012-12-29 CN CN201210591847.2A patent/CN103087355B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020779A (en) * | 2010-11-17 | 2011-04-20 | 河南工业大学 | Preparation method of edible anti-bacterial packaging film |
Non-Patent Citations (1)
| Title |
|---|
| 王京: "鱼糜可食用蛋白膜的制备、性质与应用研究", 《中国优秀硕士学位论文全文数据库（电子期刊）工程科技Ⅰ辑》 * |
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