CN103058291B - Activated-water hydrogen production material and preparation method thereof - Google Patents
Activated-water hydrogen production material and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an activated-water hydrogen production material and a preparation method thereof. The activated-water hydrogen production material sequentially comprises the following components by weight: 45-50 parts of component A, 20-25 parts of component B, and 15-20 parts of component C, wherein the component A comprises the following components by weight: 35 parts of copper powder, 35 parts of zinc powder and 20 parts of magnesium powder; the component B comprises a plurality of magnesium particles with the diameter of 1-5mm; and the component C comprises the following components by weight: 35-40 parts of tourmaline, 5-20 parts of purified ore and 15-20 parts of pottery clay. The component A is a spheroid formed by melting at high temperature, cooling and supporting; and the component C is a spheroid formed by crushing and kneading. The invention has the advantages that fluorine and heavy metals in water can be removed, and the growth of bacteria in the water is suppressed.
Description
Technical field
The present invention relates to a kind of daily life water field of purification, be specifically related to a kind of activated water hydrogen manufacturing material and preparation method thereof.
Background technology
Along with growth in the living standard, the mankind are more and more higher to healthy expectation, food safety is also more and more paid attention to, and wherein water are the large problems that is related to health of people.For now, in all city tap-waters, all contain a large amount of chlorine, and existing water-purifying material generally only has bacteriostatic action or add rich ion in water, existing material for water treatment generally adopts and in water, adds silver ions and reach bacteriostatic action, but the wayward stripping quantity of silver ions, easily causes the slight argyria to human body.
The healthy material of existing capability generally only has nourishing function or part purification function in addition, but can not permanently effective removal heavy metal, organism, chlorine, peculiar smell and turbidity etc., use range is little, and cannot carry out using or field usage.
Summary of the invention
The object of the present invention is to provide a kind of activated water hydrogen manufacturing material that can remove chlorine, the heavy metal in anhydrating and suppress fungus grown in water.
The object of the present invention is achieved like this:
It comprises component A, B component, the component C sequentially arranging,
The ratio of weight and number of component A, B component, component C is:
Component A45～50 part
20～25 parts of B component
Component C15～20 part
Wherein component A comprises the meal of copper, zinc, magnesium, the granular magnesium that is 1～5mm for some diameters in B component; Component C is Tourmaline, purification ore, potter's clay;
In component A; The ratio of weight and number of each component is:
35 parts of copper
35 parts, zinc
20 parts, magnesium
In component C, the ratio of weight and number of each component is:
35～50 parts of Tourmalines
Purify 5～20 parts, ore
15～20 parts, potter's clay.
In order to improve effect, it also comprises component D, and the ratio of weight and number of each component is:
Component A45～50 part
20～25 parts of B component
Component C15～20 part
Component D10～15 part
Component D comprises gac, calcium sulfite, diatomite;
In component D, the ratio of weight and number of each component is:
65～70 parts of gacs
5～10 parts of calcium sulfites
20～25 parts, diatomite
The meal that also comprises " manganese, iron, Z 250, silicon " in above-mentioned component A;
In component A, the ratio of weight and number of each material is:
In above-mentioned component C, purification ore is any one in medical stone, biotite, sepiolite, stone needle;
Ratio of weight and number in component C is:
35～50 parts of Tourmalines
15～20 parts, potter's clay
15～20 parts of medical stones
Or 5～10 parts of biotite
Or 5～10 parts of sepiolites
Or 5～10 parts of stone needles.
Above component has the method for being prepared as follows:
Copper, zinc, magnesium are put into medium-frequency induction furnace through high-temperature fusion in certainweight ratio, proceed to afterwards powder by atomization bucket and by high pressure water/gas, carry out atomization and prepare powder; Wherein the part by weight of copper, zinc, magnesium is:
Wherein the part by weight of copper, zinc, magnesium is:
Copper 30-35 part
Zinc 30-35 part
Magnesium 15-20 part
The preparation method of component C is: by Tourmaline, purify ore, 50～100um is pulverized, is milled to potter's clay by mobile part by weight, preparation afterwards forms 1～5mm particulate state, afterwards at 240～260 ℃, sintering 1～2 hour; Wherein the part by weight of Tourmaline, purification ore, potter's clay is:
35～50 parts of Tourmalines
Purify 5～20 parts, ore
15～20 parts, potter's clay;
It also comprises the preparation method of component D, and gac, calcium sulfite, diatomite are mixed to rear pulverizing by certainweight umber ratio, and 1～5mm particulate state is made in moulding, how many degrees Celsius of sintering 1～2 hour; Wherein gac, calcium sulfite, diatomaceous part by weight are:
65～70 parts of gacs
5～10 parts of calcium sulfites
20～25 parts, diatomite
Preparation method at component A is, has manganese, iron, Z 250, silicon adding copper, zinc, magnesium also to add, and the weight ratio of the storeroom in component A is:
In component C, purification ore is any one in medical stone, biotite, sepiolite, stone needle,
Ratio of weight and number in component C is:
35～50 parts of Tourmalines
15～20 parts, potter's clay
15～20 parts of medical stones
Or 5～10 parts of biotite
Or 5～10 parts of sepiolites
Or 5～10 parts of stone needles.
The invention has the advantages that: 1 zine ion that can discharge has obvious control action kou to microorganism, the cell walls of their energy destroy microorganisms, stops the synthetic of enzyme, thereby affects organic normal growth, reaches the object that suppresses microbial reproduction.2 can be by stoping the synthetic algal grown of controlling of chlorophyll, the existence of zine ion is produced the ability of food from having reduced in essence organism from photosynthesis, the food of bacterial population and energy derive are to rely on algal community, and the minimizing of algae is by the growth of remarkably influenced bacterium.3 water sources are when of the present invention, and its redox potential is from+change to-500mV of 200mV, in the ordinary course of things, various types of microorganisms can only grow under specific redox potential, the significantly variation of current potential, can destroy the cell of bacterium, thereby has controlled microbial growth.4 have guarantee safe drinking water, purify, remove the function of objectionable impurities in water, and can use spring or common domestic water.Wherein remove chlorine residue, its principle of heavy metal function is: Zn+HOCl+H2O+2e-→ Zn2++Cl-+H++2OH-; Zn/Cu/Zn+Pb (NO3) 2 → Zn/Cu/Pb+Zn (NO3) 2; Zn/Cu/Zn+HgCl2 → Zn/Cu/Hg+ZnCl2, has in addition absorption peculiar smell, organism and can make water cleaning remove muddiness.5 can make water small molecular group less more stable, and can produce the hydrogeneous water of lasting stability.6 uses of can regenerating, general health water materials'use for some time rear surface can have very thin zone of oxidation or the throw out of one deck, and zone of oxidation contacts with the effective of water affecting material with sedimentary existence, thereby reduces water treatment efficiency.For this reason, must adopt surface removal zone of oxidation and sedimentary method that zone of oxidation is removed.Be specially and adopt acid solution to process, such as material granule of the present invention being immersed in 1-2% citric acid solution, after stir about 3-5 minute, citric acid solution is filtered out to recovery, or pass into 1-2% citric acid solution circulation 3-5 minute, with clear water, clean material of the present invention again, until pH is neutral.
Accompanying drawing explanation
Fig. 1 is the width detection figure of the utility model part embodiment.
Embodiment
Below in conjunction with specific embodiment, the proportion relation of each component of the present invention is described;
Component A, the B sequentially arranging, the ratio of weight and number of C:
| ? | Proportioning 1 (part) | Proportioning 2 (part) | Proportioning 3 (part) | Proportioning 4 (part) |
| Component A | 45 | 46 | 47 | 50 |
| B component | 25 | 21 | 23 | 20 |
| Component C | 19 | 20 | 15 | 16 |
Wherein proportioning 1 for embodiment 1, proportioning 2 for embodiment 2, proportioning 3 for embodiment 3, proportioning 4 for embodiment 4
Embodiment 1
B component is that diameter range is at the granular magnesium of 2～3mm;
The ratio of weight and number of copper, zinc, magnesium in component A: (referring to table 1)
The ratio of weight and number of Tourmaline, purification ore (employing medical stone), potter's clay in component C: (referring to table 1)
Table 1
Embodiment 2
B component is that diameter range is at the granular magnesium of 4～5mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 2)
The ratio of weight and number of Tourmaline, purification ore (employing biotite), potter's clay in component C: (referring to table 2)
Table 2
Embodiment 3
B component is that diameter range is at the granular magnesium of 1～2mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 3)
The ratio of weight and number of Tourmaline, purification ore (employing sepiolite), potter's clay in component C: (referring to table 3)
Table 3
Embodiment 4
B component is that diameter range is at the granular magnesium of 3～4mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 4)
The ratio of weight and number of Tourmaline, purification ore (employing stone needle), potter's clay in component C: (referring to table 4)
Table 4
Component A, the B sequentially arranging, the ratio of weight and number of C, D:
| ? | Proportioning 5 (part) | Proportioning 6 (part) | Proportioning 7 (part) | Proportioning 8 (part) |
| Component A | 45 | 46 | 47 | 50 |
| B component | 25 | 21 | 23 | 20 |
| Component C | 19 | 20 | 15 | 16 |
| Component D | 13 | 11 | 10 | 15 |
The corresponding embodiment 5 of proportioning 5 wherein, the corresponding embodiment 6 of proportioning 6, the corresponding embodiment 7 of proportioning 7, the corresponding embodiment 8 of proportioning 8,
Embodiment 5
B component is that diameter range is at the granular magnesium of 1～2mm;
The ratio of weight and number of copper, zinc, magnesium in component A: (referring to table 5)
The ratio of weight and number of Tourmaline, purification ore (employing medical stone), potter's clay in component C: (referring to table 5)
Gac in component D, calcium sulfite, diatomaceous ratio of weight and number: (referring to table 5)
Table 5
Embodiment 6
B component is that diameter range is at the granular magnesium of 4～5mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 6)
The ratio of weight and number of Tourmaline, purification ore (employing biotite), potter's clay in component C: (referring to table 6)
Table 6
Embodiment 7
B component is that diameter range is at the granular magnesium of 1～2mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 7)
The ratio of weight and number of Tourmaline, purification ore (employing sepiolite), potter's clay in component C: (referring to table 7)
Table 7
Embodiment 8
B component is that diameter range is at the granular magnesium of 3～4mm;
The ratio of weight and number of the element such as copper, zinc, magnesium and manganese, iron in component A: (referring to table 8)
The ratio of weight and number of Tourmaline, purification ore (employing stone needle), potter's clay in component C: (referring to table 8)
Table 8
In the present invention, each component can realize function:
In component A, the alloy that copper, zinc, magnesium form has potential difference, can removal heavy metal, and chlorine residue etc., and leachable zine ion; Magnesium can also generate hydrogeneous water with water reaction; The magnesium ion of stripping, zine ion can be stablized the subset state of water, in B component, magnesium and water reaction generate hydrogeneous water, and in component C, Tourmaline has micro-electrolytic action, reduce the negative potential of water, medical stone, biotite, sepiolite, stone needle can purify water, stripping mineral substance, and potter's clay is mainly to play cohesive action; The effect that component D gac, calcium sulfite, diatomite all have absorption impurity, purify water;
Component A integral body can realize removing heavy metals, remove the objectionable impuritiess such as chlorine residue, antibacterial, stripping zine ion, produce hydrogeneous water, B component integral body can realize the effect that produces hydrogeneous water, and component C integral body can realize healthy activated water function, generates healthy water, negative potential water, the effect that supplements mineral trace element; Component D integral body can realize absorption, purifies water, and deodorizing reduces the effect of turbidity.
The water that the present invention is purified detects, and detects index as follows:
Detect index (in Table 9)
Table 9
Water sample width detects (reference table 10)
Table 10
| ? | Place 1H | Place 15H |
| Tap water water sample | 140.912HZ(at0.50) | 142.331HZ(at0.50) |
| Embodiment 1 | 49.312HZ(at0.50) | 50.563HZ(at0.50) |
| Embodiment 2 | 49.132HZ(at0.50) | 50.163HZ(at0.50) |
| Embodiment 3 | 48.996HZ(at0.50) | 50.031HZ(at0.50) |
| Embodiment 4 | 48.532HZ(at0.50) | 49.938HZ(at0.50) |
| Embodiment 5 | 48.565HZ(at0.50) | 49.998HZ(at0.50) |
| Embodiment 6 | 48.356HZ(at0.50) | 49.893HZ(at0.50) |
| Embodiment 7 | 48.432HZ(at0.50) | 49.902HZ(at0.50) |
| Embodiment 8 | 48.123HZ(at0.50) | 49.711HZ(at0.50) |
Claims (10)
1. an activated water hydrogen manufacturing material, is characterized in that: it comprises component A, B component, the component C sequentially arranging,
The ratio of weight and number of component A, B component, component C is:
Component A45～50 part
20～25 parts of B component
Component C15～20 part
Wherein component A comprises copper, zinc, magnesium, the granular magnesium that is 1～5mm for diameter in B component; Component C is Tourmaline, purification ore, potter's clay;
In component A; The ratio of weight and number of each component is:
Copper 30-35 part
Zinc 30-35 part
Magnesium 15-20 part
In component C, the ratio of weight and number of each component is:
35～50 parts of Tourmalines
Purify 5～20 parts, ore
15～20 parts, potter's clay.
2. activated water hydrogen manufacturing material according to claim 1, is characterized in that: it also comprises component D, and the ratio of weight and number of each component is:
Component A45～50 part
20～25 parts of B component
Component C15～20 part
Component D10～15 part
Component D comprises gac, calcium sulfite, diatomite;
In component D, the ratio of weight and number of each component is:
65～70 parts of gacs
5～10 parts of calcium sulfites
20～25 parts, diatomite.
3. activated water hydrogen manufacturing material according to claim 1 and 2, is characterized in that: the meal that also comprises " manganese, iron, Z 250, silicon " in the component A of component A, B, C;
In component A, the ratio of weight and number of each material is:
4. activated water hydrogen manufacturing material according to claim 1 and 2, is characterized in that: in described component C, purification ore is any one in medical stone, biotite, sepiolite, stone needle;
Ratio of weight and number in component C is:
35～50 parts of Tourmalines
15～20 parts, potter's clay
15～20 parts of medical stones
Or 5～10 parts of biotite
Or 5～10 parts of sepiolites
Or 5～10 parts of stone needles.
5. activated water hydrogen manufacturing material according to claim 3, is characterized in that: in described component C, purification ore is wheat
Any one in meal stone, biotite, sepiolite, stone needle;
Ratio of weight and number in component C is:
35～50 parts of Tourmalines
15～20 parts, potter's clay
15～20 parts of medical stones
Or 5～10 parts of biotite
Or 5～10 parts of sepiolites
Or 5～10 parts of stone needles.
6. activated water hydrogen manufacturing material according to claim 1, is characterized in that: component A is sheet or granular metallic particles granular big or small 20～30 orders.
7. a preparation method for activated water hydrogen manufacturing material, is characterized in that:
The preparation method of component A is: copper, zinc, magnesium are put into medium-frequency induction furnace through high-temperature fusion in certainweight ratio, proceed to afterwards powder by atomization bucket and by high pressure water/gas, carry out atomization and prepare powder; Wherein the part by weight of copper, zinc, magnesium is:
Copper 30-35 part
Zinc 30-35 part
Magnesium 15-20 part
The preparation method of component C is: by Tourmaline, purify ore, 50～100um is pulverized, is milled to potter's clay by mobile part by weight, preparation afterwards forms 1～5mm particulate state, afterwards at 240～260 ℃, sintering 1～2 hour; Wherein the part by weight of Tourmaline, purification ore, potter's clay is:
35～50 parts of Tourmalines
Purify 5～20 parts, ore
15～20 parts, potter's clay.
8. the preparation method of a kind of activated water hydrogen manufacturing material according to claim 7, it is characterized in that: it also comprises the preparation method of component D, gac, calcium sulfite, diatomite are mixed to rear pulverizing by certainweight umber ratio, 1～5mm particulate state is made in moulding, 240～260 ℃ of sintering 1～2 hour; Wherein gac, calcium sulfite, diatomaceous part by weight are:
65～70 parts of gacs
5～10 parts of calcium sulfites
20～25 parts, diatomite.
9. the preparation method of a kind of activated water hydrogen manufacturing material according to claim 7, is characterized in that: the preparation method of component A is, has manganese, iron, Z 250, silicon adding copper, zinc, magnesium also to add, and the weight ratio of the storeroom in component A is:
10. the preparation method of a kind of activated water hydrogen manufacturing material according to claim 7: it is characterized in that, described purification ore is any one in medical stone, biotite, sepiolite, stone needle,
Ratio of weight and number in component C is:
35～50 parts of Tourmalines
15～20 parts, potter's clay
15～20 parts of medical stones
Or 5～10 parts of biotite
Or 5～10 parts of sepiolites
Or 5～10 parts of stone needles.
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| CN105585097B (en) * | 2015-12-01 | 2019-03-19 | 刘应军 | A kind of hydrogen-rich water generating device and its manufacturing method for producing hydrogen source |
| CN105747954A (en) * | 2016-03-16 | 2016-07-13 | 福州品行科技发展有限公司 | Magnet therapy bathtub and working method thereof |
| CN106473094A (en) * | 2016-09-26 | 2017-03-08 | 广州市纳能环保技术开发有限公司 | A kind of sintering hydrogen manufacturing activated material |
| CN108658039B (en) * | 2018-05-24 | 2019-12-24 | 河北云悦生物科技有限公司 | Water hydrogen production material and preparation method and application thereof |
| CN114620681B (en) * | 2021-12-24 | 2023-05-23 | 杭州江涌节能技术有限公司 | Recyclable hydrogen production material and preparation method and application thereof |
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| CN1868900A (en) * | 2006-05-31 | 2006-11-29 | 杨启彪 | Micro electrolytic energy water treatment element and its preparation method |
| CN101643255A (en) * | 2009-09-07 | 2010-02-10 | 胡建忠 | Micro-electrolysis water-activating material and preparation method thereof |
| CN101863575A (en) * | 2009-09-24 | 2010-10-20 | 上海珍奥生物科技有限公司 | Functional material and special device for preparing multifunctional healthy running water |
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| JP2001047058A (en) * | 1999-08-12 | 2001-02-20 | Hoshino Kibutsu:Kk | Sterilizing/cleaning apparatus for hot water of bathtub |
| JP2002068987A (en) * | 2000-08-31 | 2002-03-08 | Fuairudo Kk | Method and unit for producing water dispersed with activated carbon ultrafine particle |
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|---|---|---|---|---|
| CN1868900A (en) * | 2006-05-31 | 2006-11-29 | 杨启彪 | Micro electrolytic energy water treatment element and its preparation method |
| CN101643255A (en) * | 2009-09-07 | 2010-02-10 | 胡建忠 | Micro-electrolysis water-activating material and preparation method thereof |
| CN101863575A (en) * | 2009-09-24 | 2010-10-20 | 上海珍奥生物科技有限公司 | Functional material and special device for preparing multifunctional healthy running water |
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| JP特开2002-68987A 2002.03.08 |
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Effective date of registration: 20150120 Address after: 350000, No. 22, Rong Rong North Road, Jianxin Town, Cangshan District, Fujian, Fuzhou Patentee after: Fuzhou Ospring Technology & Development Co., Ltd. Patentee after: FUZHOU PINXING TECHNOLOGY DEVELOPMENT CO., LTD. Address before: 350000, No. 22, Rong Rong North Road, Jianxin Town, Cangshan District, Fujian, Fuzhou Patentee before: Fuzhou Ospring Technology & Development Co., Ltd. |