CN103052613B - 含烯烃的烃混合物中多重不饱和烃的选择性氢化方法 - Google Patents

含烯烃的烃混合物中多重不饱和烃的选择性氢化方法 Download PDF

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Publication number
CN103052613B
CN103052613B CN201180033117.4A CN201180033117A CN103052613B CN 103052613 B CN103052613 B CN 103052613B CN 201180033117 A CN201180033117 A CN 201180033117A CN 103052613 B CN103052613 B CN 103052613B
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China
Prior art keywords
hydrocarbon
hydrogenation
hydrocarbons
ppm
unbranched
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Expired - Fee Related
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CN201180033117.4A
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English (en)
Chinese (zh)
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CN103052613A (zh
Inventor
C·贝英
M·温特贝格
T·莱布林
G·席林
W·加施特卡
B·克赖德勒
D·马施迈耶
R·布科尔
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Evonik Operations GmbH
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Evonik Degussa GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201180033117.4A 2010-07-06 2011-06-09 含烯烃的烃混合物中多重不饱和烃的选择性氢化方法 Expired - Fee Related CN103052613B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010030990A DE102010030990A1 (de) 2010-07-06 2010-07-06 Verfahren zur selektiven Hydrierung von mehrfach ungesättigten Kohlenwasserstoffen in olefinhaltigen Kohlenwasserstoffgemischen
DE102010030990.7 2010-07-06
PCT/EP2011/059601 WO2012004081A1 (de) 2010-07-06 2011-06-09 Verfahren zur selektiven hydrierung von mehrfach ungesättigten kohlenwasserstoffen in olefinhaltigen kohlenwasserstoffgemischen

Publications (2)

Publication Number Publication Date
CN103052613A CN103052613A (zh) 2013-04-17
CN103052613B true CN103052613B (zh) 2016-01-20

Family

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Family Applications (1)

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CN201180033117.4A Expired - Fee Related CN103052613B (zh) 2010-07-06 2011-06-09 含烯烃的烃混合物中多重不饱和烃的选择性氢化方法

Country Status (10)

Country Link
US (1) US8859834B2 (enExample)
EP (1) EP2590913A1 (enExample)
JP (1) JP5774100B2 (enExample)
KR (1) KR20130087484A (enExample)
CN (1) CN103052613B (enExample)
BR (1) BR112013000225A2 (enExample)
DE (1) DE102010030990A1 (enExample)
MY (1) MY160581A (enExample)
SG (1) SG186919A1 (enExample)
WO (1) WO2012004081A1 (enExample)

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DE102011006721A1 (de) 2011-04-04 2012-10-04 Evonik Oxeno Gmbh Verfahren zur Herstellung von 1-Buten und einem 1,3-Butadienderivat
DE102012212317A1 (de) 2012-07-13 2014-01-16 Evonik Industries Ag Thioveretherung von Mercaptanen in C4-Kohlenwasserstoffgemischen
MX382912B (es) * 2013-06-25 2025-03-13 Dow Technology Investments Llc Proceso de hidrogenación selectiva.
SG10201604013RA (en) 2015-05-28 2016-12-29 Evonik Degussa Gmbh Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures
US9758446B2 (en) 2015-11-16 2017-09-12 Chevron Phillips Chemical Company Lp Selective hydrogenation using a flow index
ES2981207T3 (es) * 2017-10-25 2024-10-07 Basf Se Proceso de eliminación de dienos de un flujo de material que contiene hidrocarburos C3 a C5 mediante hidrogenación selectiva
EP3680224B1 (de) * 2019-01-08 2023-05-24 Evonik Operations GmbH Verfahren zur entfernung mehrfach ungesättigter kohlenwasserstoffe aus c4-kohlenwasserstoffströmen in anwesenheit von mercaptanen, disulfiden und c5-kohlenwasserstoffen
US11186782B2 (en) 2019-01-08 2021-11-30 Evonik Operations Gmbh Catalyst and process for removing mercaptans from hydrocarbon streams
WO2025185961A1 (de) 2024-03-04 2025-09-12 Evonik Oxeno Gmbh & Co. Kg Katalysator und verfahren zur selektivhydrierung von ungesättigten c4-kohlenwasserstoffen

Citations (3)

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Publication number Priority date Publication date Assignee Title
US4517395A (en) * 1981-11-04 1985-05-14 Chemische Werke Huls Aktiengesellschaft Process for the selective hydrogenation of polyunsaturated hydrocarbons in hydrocarbon mixtures
CN1377331A (zh) * 1999-09-17 2002-10-30 菲利浦石油公司 催化剂组合物和制备该组合物的方法
CN101072637A (zh) * 2004-10-13 2007-11-14 巴斯福股份公司 选择性加氢催化剂

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FR2482953A1 (fr) 1980-05-22 1981-11-27 Inst Francais Du Petrole Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
DE4123246A1 (de) 1991-07-13 1993-01-14 Basf Ag Verfahren zur selektiven hydrierung von butadienreichen roh-c(pfeil abwaerts)4(pfeil abwaerts)-schnitten
AU654757B2 (en) 1992-02-10 1994-11-17 Chemical Research & Licensing Company Selective hydrogenation of C5 streams
FR2742679B1 (fr) 1995-12-22 1998-01-16 Inst Francais Du Petrole Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur
DE19636064A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Hydrierung
US6127310A (en) * 1997-02-27 2000-10-03 Phillips Petroleum Company Palladium containing hydrogenation catalysts
DE19839459A1 (de) 1998-08-29 2000-03-02 Basf Ag Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen
US6469223B2 (en) * 2000-01-04 2002-10-22 Fina Technology, Inc. Selective hydrogenation of dienes
DE10149347A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen durch reduktive Telomerisation
DE10149348A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
DE10232868A1 (de) 2002-07-19 2004-02-05 Oxeno Olefinchemie Gmbh Feinporiger Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
US7045670B2 (en) * 2003-09-03 2006-05-16 Synfuels International, Inc. Process for liquid phase hydrogenation
DE10359628A1 (de) 2003-12-18 2005-07-21 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen
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DE102005035816A1 (de) 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
DE102006031964A1 (de) 2006-07-11 2008-01-17 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 3-Methylbut-1-en
DE102006040431A1 (de) 2006-08-29 2008-03-20 Oxeno Olefinchemie Gmbh Verfahren zur Spaltung von MTBE
DE102006040434A1 (de) 2006-08-29 2008-03-06 Oxeno Olefinchemie Gmbh Verfahren zur Spaltung von MTBE
DE102006040430B4 (de) 2006-08-29 2022-06-15 Evonik Operations Gmbh Verfahren zur Spaltung von MTBE
US7959793B2 (en) 2006-09-27 2011-06-14 Amarjit Singh Bakshi Optimum process for selective hydrogenation/hydro-isomerization, aromatic saturation, gasoline, kerosene and diesel/distillate desulfurization (HDS). RHT-hydrogenationSM, RHT-HDSSM
DE102008040511A1 (de) 2008-07-17 2010-01-21 Evonik Oxeno Gmbh Verfahren zur Herstellung von Isobuten durch Spaltung von MTBE-haltigen Gemischen
DE102009027406A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Verfahren zur Herstellung von geruchsarmen n-Butan
DE102009027404A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Herstellung von Isobuten durch Spaltung von MTBE
DE102009029284A1 (de) 2009-09-08 2011-03-10 Evonik Oxeno Gmbh Verfahren zur Oligomerisierung von Olefinen

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517395A (en) * 1981-11-04 1985-05-14 Chemische Werke Huls Aktiengesellschaft Process for the selective hydrogenation of polyunsaturated hydrocarbons in hydrocarbon mixtures
CN1377331A (zh) * 1999-09-17 2002-10-30 菲利浦石油公司 催化剂组合物和制备该组合物的方法
CN101072637A (zh) * 2004-10-13 2007-11-14 巴斯福股份公司 选择性加氢催化剂

Also Published As

Publication number Publication date
KR20130087484A (ko) 2013-08-06
DE102010030990A1 (de) 2012-01-12
JP2013535409A (ja) 2013-09-12
BR112013000225A2 (pt) 2019-09-24
CN103052613A (zh) 2013-04-17
SG186919A1 (en) 2013-02-28
MY160581A (en) 2017-03-15
US8859834B2 (en) 2014-10-14
WO2012004081A1 (de) 2012-01-12
EP2590913A1 (de) 2013-05-15
US20130172641A1 (en) 2013-07-04
JP5774100B2 (ja) 2015-09-02

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: EVONIK DEGUSSA GMBH

Free format text: FORMER OWNER: OXENO OLEFINCHEMIE GMBH

Effective date: 20140704

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20140704

Address after: essen

Applicant after: Evonik Degussa GmbH

Address before: mAhR

Applicant before: Oxeno Olefinchemie GmbH

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160120

Termination date: 20170609