CN103045030A - Waterproof coating - Google Patents
Waterproof coating Download PDFInfo
- Publication number
- CN103045030A CN103045030A CN2012105430793A CN201210543079A CN103045030A CN 103045030 A CN103045030 A CN 103045030A CN 2012105430793 A CN2012105430793 A CN 2012105430793A CN 201210543079 A CN201210543079 A CN 201210543079A CN 103045030 A CN103045030 A CN 103045030A
- Authority
- CN
- China
- Prior art keywords
- parts
- waterproof coating
- coating
- waterproof
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000576 coating method Methods 0.000 title claims abstract description 12
- 239000011248 coating agent Substances 0.000 title claims abstract description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 6
- 229920003180 amino resin Polymers 0.000 claims abstract description 6
- 235000011187 glycerol Nutrition 0.000 claims abstract description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 239000003973 paint Substances 0.000 claims description 13
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 239000010426 asphalt Substances 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000011295 pitch Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000013980 iron oxide Nutrition 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to a waterproof coating. The coating includes the components by weight: 20-30 parts of polyvinyl alcohol, 15-20 parts of a hydroxyl-containing alkyd resin, 20-25 parts of amino resin, 10-15 parts of iron oxide red, 5-10 parts of sodium silicate, 10-15 parts of asphalt, 3-5 parts of sodium hexametaphosphate, 1-5 parts of tributyl phosphate, 10-15 parts of benzoic acid, 2-5 parts of zinc oxide, and 1-3 parts of glycerin. The waterproof coating is pollution-free to environment, harmless to human body, safe and environmental-friendly.
Description
Technical field
The present invention relates to waterproof paint, especially a kind of high molecular water-proof paint that is suitable for the building trade application and preparation method thereof.
Background technology
The waterproof paint of building trade application generally is the thickness liquid state high molecular synthetic material that is at normal temperatures without solid shape, and coating is solidified rear at substrate surface formation waterproof membrane by the volatilization of solvent or evaporation or the reaction of moisture.At present the used water-proof material of building trade generally is divided into the flexible waterproof material that comprises waterproof roll, waterproof paint, sealing cement etc. and take cement matrix as rigidity water-proofing material main, that add water-resisting agent and other auxiliary agents.Although kind is abundant, it is poor generally to have a physical and mechanical property, and work-ing life is short, excessive with the gap in work-ing life of buildings, and range of application is narrow and small, the shortcomings such as dangerous environmental protection.
CN 102108234A discloses a kind of colorful environment-friendly synthetic macromolecular waterproof coating, its one-tenth by following weight part is grouped into: petroleum resin 3-7 part, SEBS 5-15 part, SBS 5-15 part, 5 10 parts of thermoplastic polyurethane elastomers, terpine resin 4-8 part, poly alpha methylstyrene 4-8 part, tung oil 2-5 part, mica powder 10-15 part, antioxidant D 0.2-0.5 part, antioxidant 264 0.2-0.5 part, defoamer 0.2-0.5 part, UV light absorber 0.3-0.5 part, 120# solvent 35-45 part, ethyl acetate 5-15 part, mill base 1-3 part.The colorful environment-friendly synthetic macromolecular waterproof coating of this invention has certain acid and alkali-resistance and uviolizing, heat insulation, anti-aging, and waterproof, anti-leakage performance, shortcoming are that the embrittlement phenomenon under the cold condition is obvious, and tensile strength and elongation at break are lower.
CN 102079918A discloses a kind of building water-proof paint, it is as follows that it forms weight percent: Vinyl Acetate Copolymer 30-50, ethene-vinyl acetate polymkeric substance 20-30, kaolin 6-10, film coalescence aid 0.5-2.5, coarse whiting 6-10, dispersion agent 0.1-3, defoamer 0.3-0.8, silicon sol 3-8, the deionized water of surplus.The building water-proof paint easy construction that this invention provides, with low cost, good leak-proof effect, shortcoming are high-low temperature resistant and chemical corrosion resistance inequality, and mechanical property is also poor.
Summary of the invention
The object of the invention is, overcomes the deficiencies in the prior art, and a kind of excellent high molecular water-proof paint that has is provided, and is suitable for being coated in multiple substrate surface.
For achieving the above object, the present invention adopts following technical scheme:
A kind of waterproof paint, component and the proportioning of this coating are as follows, in weight part, polyvinyl alcohol 20-30 part, hydroxyl Synolac 15-20 part, aminoresin 20-25 part, red iron oxide 10-15 part, water glass 5-10 part, pitch 10-15 part, Sodium hexametaphosphate 99 3-5 part, tributyl phosphate 1-5 part, phenylformic acid 10-15 part, zinc oxide 2-5 part, glycerine 1-3 part.
The preparation method of high molecular water-proof paint of the present invention may further comprise the steps:
(1) hydroxyl Synolac and aminoresin emulsification are heated to 60-170 ℃;
(2) add red iron oxide, water glass, pitch, Sodium hexametaphosphate 99, tributyl phosphate, phenylformic acid, zinc oxide, glycerine also stirred 1-5 hour;
(3) add polyvinyl alcohol, high-speed stirring 30-60min is cooled to room temperature.
Compared with prior art, the present invention has following beneficial effect:
1, anticorrosive, anti-aging, bonding force is strong, high temperature resistant, low temperature resistant, ductility is good, elongation at break is high, and multiple excellent properties rolls into one.
2, the water-borne coatings environmentally safe is harmless, safety and environmental protection.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1:
A kind of waterproof paint, component and the proportioning of this coating are as follows, in weight part, 20 parts of polyvinyl alcohol, 15 parts of hydroxyl Synolac, 20 parts in aminoresin, 10 parts of red iron oxides, 5 parts of water glass, 10 parts of pitches, 3 parts of Sodium hexametaphosphate 99s, 1 part of tributyl phosphate, 10 parts in phenylformic acid, 2 parts in zinc oxide, 1 part of glycerine.
Embodiment 2:
A kind of waterproof paint, component and the proportioning of this coating are as follows, in weight part, 30 parts of polyvinyl alcohol, 20 parts of hydroxyl Synolac, 25 parts in aminoresin, 15 parts of red iron oxides, 10 parts of water glass, 15 parts of pitches, 5 parts of Sodium hexametaphosphate 99s, 5 parts of tributyl phosphates, 15 parts in phenylformic acid, 5 parts in zinc oxide, 3 parts of glycerine.
Claims (1)
1. waterproof paint, it is characterized in that: component and the proportioning of this coating are as follows, in weight part, polyvinyl alcohol 20-30 part, hydroxyl Synolac 15-20 part, aminoresin 20-25 part, red iron oxide 10-15 part, water glass 5-10 part, pitch 10-15 part, Sodium hexametaphosphate 99 3-5 part, tributyl phosphate 1-5 part, phenylformic acid 10-15 part, zinc oxide 2-5 part, glycerine 1-3 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210543079.3A CN103045030B (en) | 2012-12-16 | 2012-12-16 | A kind of waterproof paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210543079.3A CN103045030B (en) | 2012-12-16 | 2012-12-16 | A kind of waterproof paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103045030A true CN103045030A (en) | 2013-04-17 |
| CN103045030B CN103045030B (en) | 2015-11-18 |
Family
ID=48057899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210543079.3A Active CN103045030B (en) | 2012-12-16 | 2012-12-16 | A kind of waterproof paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103045030B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602205A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Novel resin type waterproof coating material |
| CN103897543A (en) * | 2013-11-08 | 2014-07-02 | 东南大学 | Water-resistant varnish |
| CN105542615A (en) * | 2016-01-20 | 2016-05-04 | 广西丛欣实业有限公司 | Waterproof wood floor |
| CN105647332A (en) * | 2016-02-27 | 2016-06-08 | 柳州市够旺贸易有限公司 | Environment-friendly wood floor |
| CN105715017A (en) * | 2016-02-27 | 2016-06-29 | 柳州市够旺贸易有限公司 | Wood floor |
| CN106800842A (en) * | 2016-12-14 | 2017-06-06 | 池州市小康人家科技有限公司 | A kind of solar water heater water-repellent paint |
| CN110452564A (en) * | 2019-08-19 | 2019-11-15 | 周安城 | A kind of novel waterproof thermal insulation coating |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034941A (en) * | 1988-02-12 | 1989-08-23 | 成都科技大学 | Water-proof coating material of amino polyvinyl alcohol emulsified asphalt |
| CN1375534A (en) * | 2001-03-21 | 2002-10-23 | 中国科学院化学研究所 | Nano montmorillonoid modified paint and its prepn. and use |
| CN101113265A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Single-component cold-construction water-based waterproofing paint |
| CN101967352A (en) * | 2010-07-13 | 2011-02-09 | 北京立高科技股份有限公司 | Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof |
| CN102417790A (en) * | 2011-08-11 | 2012-04-18 | 湖北蓝盾之星科技股份有限公司 | Two-component castor oil polyurethane waterproof paint |
| CN102702950A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | High polymer waterproof coating |
-
2012
- 2012-12-16 CN CN201210543079.3A patent/CN103045030B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034941A (en) * | 1988-02-12 | 1989-08-23 | 成都科技大学 | Water-proof coating material of amino polyvinyl alcohol emulsified asphalt |
| CN1375534A (en) * | 2001-03-21 | 2002-10-23 | 中国科学院化学研究所 | Nano montmorillonoid modified paint and its prepn. and use |
| CN101113265A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Single-component cold-construction water-based waterproofing paint |
| CN101967352A (en) * | 2010-07-13 | 2011-02-09 | 北京立高科技股份有限公司 | Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof |
| CN102417790A (en) * | 2011-08-11 | 2012-04-18 | 湖北蓝盾之星科技股份有限公司 | Two-component castor oil polyurethane waterproof paint |
| CN102702950A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | High polymer waterproof coating |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897543A (en) * | 2013-11-08 | 2014-07-02 | 东南大学 | Water-resistant varnish |
| CN103897543B (en) * | 2013-11-08 | 2016-04-27 | 东南大学 | A kind of water-resistant varnish |
| CN103602205A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Novel resin type waterproof coating material |
| CN103602205B (en) * | 2013-11-19 | 2016-04-13 | 青岛祥嘉知识产权服务有限公司 | A kind of resin-type waterproof paint |
| CN105542615A (en) * | 2016-01-20 | 2016-05-04 | 广西丛欣实业有限公司 | Waterproof wood floor |
| CN105647332A (en) * | 2016-02-27 | 2016-06-08 | 柳州市够旺贸易有限公司 | Environment-friendly wood floor |
| CN105715017A (en) * | 2016-02-27 | 2016-06-29 | 柳州市够旺贸易有限公司 | Wood floor |
| CN106800842A (en) * | 2016-12-14 | 2017-06-06 | 池州市小康人家科技有限公司 | A kind of solar water heater water-repellent paint |
| CN110452564A (en) * | 2019-08-19 | 2019-11-15 | 周安城 | A kind of novel waterproof thermal insulation coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103045030B (en) | 2015-11-18 |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Su Jianli Inventor before: Cao Man Inventor before: Guo Bingyu Inventor before: Liu Lin |
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| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150921 Address after: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Applicant after: QINGDAO WINCHANCE TECHNOLOGY Co.,Ltd. Address before: Hi Tech Park Laoshan Keyuan weft four road 266101 Shandong Province, Qingdao City No. 30 Applicant before: QINGDAO TIANREN ENVIRONMENT Co.,Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Jianguo Inventor before: Su Jianli |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170714 Address after: Tianjin city Beichen District dual Town 300000 Jin Yong Highway North (Tianjin City, Oriental Shengjing in horticultural field) Patentee after: TIANJIN YUSHEN BUILDING WATERPROOF MATERIAL Co.,Ltd. Address before: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Patentee before: QINGDAO WINCHANCE TECHNOLOGY Co.,Ltd. |
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| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130417 Assignee: Yuncheng Yuhao Waterproof Technology Development Co.,Ltd. Assignor: TIANJIN YUSHEN BUILDING WATERPROOF MATERIAL Co.,Ltd. Contract record no.: X2023980047250 Denomination of invention: A waterproof coating Granted publication date: 20151118 License type: Common License Record date: 20231116 |