CN103044072A - Oriented reflective ultra-thin vitrified clay-porcelain exterior wall tile/floor tile and manufacturing method thereof - Google Patents

Oriented reflective ultra-thin vitrified clay-porcelain exterior wall tile/floor tile and manufacturing method thereof Download PDF

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CN103044072A
CN103044072A CN2013100324345A CN201310032434A CN103044072A CN 103044072 A CN103044072 A CN 103044072A CN 2013100324345 A CN2013100324345 A CN 2013100324345A CN 201310032434 A CN201310032434 A CN 201310032434A CN 103044072 A CN103044072 A CN 103044072A
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exterior wall
tile
ultra
floor tile
main body
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CN103044072B (en
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钱宏诚
钱月亮
钱宏元
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Abstract

The invention discloses an oriented reflective ultra-thin vitrified clay-porcelain exterior wall tile/floor tile and a manufacturing method thereof. The exterior wall tile/floor tile comprises a clay-porcelain main body, and multiple transparent glass beads are densely distributed on the top surface of the main body so as to form a vitrified surface. The main body is formed by rolling clay powder, an adhesive, a surfactant and short fibers, and the exterior wall tile/floor tile is implemented without calcining technologically. The problem that the manufacturing of porcelain exterior wall tiles/floor tiles relies on coal and oil, so that the energy consumption is high, the discharge is high, and the pollution is serious is solved. The oriented reflective ultra-thin vitrified clay-porcelain exterior wall tile/floor tile is mainly applied to exterior walls and floors of high-rise buildings, and wall bodies, cement divided blocks and road edge stones of expressway tunnels, and the like.

Description

The ultra-thin glass face of a kind of directional reflective mud porcelain exterior wall tile floor tile and manufacture method thereof
Technical field
Patent of the present invention relates to the exterior wall ceramic tile, floor tile, the porcelain tendre exterior wall tile the technological improvement of floor tile, specifically the ultra-thin glass face of a kind of directional reflective mud porcelain exterior wall tile floor tile and manufacturing process thereof.Be mainly used in high-rise building exterior wall, floor, and freeway tunnel body of wall, cement separation mound, city curb etc. are located.
Background technology
Present various countries exterior wall ceramic tile, floor tile all burns till in high temperature, needs to consume mass energy, and row's carbon is high, not environmental protection.
Patent of invention 200710027926(CN101045831) and 200610122135(CN1944509), be repeatedly to be coated on the 52-182 ℃ of constant temperature template until reach desired thickness with modification mud; The moisture rear skinning that volatilizees fully forms elastic face material; Compound layer of non-woven fabric or chemical fibre grid cloth below the elastic face material that forms form skin material (being commonly called as porcelain tendre) again.Although unburned environmental protection, the surface does not have vitreous, and smooth finish is poor, and the surface is not suitable for and makes floor tile without wear-resistant surface, can not be difficult for being stained with dirt as pottery replaces paint.
The pottery porcelain tendre all do not have directional reflective function and anti-heat drop temperature function.
Freeway tunnel body of wall, highway isolated mound, curb, isolation flower platform etc. still use the eighties concrete prefabricated, easily are stained with pollutent dirty, and self-cleaning power is too low.For the various places, beautifying city indicate with yellow or black paint, although strengthened alert looking and aesthetic feeling, easily pollute too.
Present useful bulk tunnel brick is decorated the tunnel body of wall, but without the global orientation reflective wall, visual effect is very dark, just as the white oil lacquer of no-reflection material can only be seen about 50 meters.The white oil lacquer that has added light reflecting material can be seen 200 meters.
The purpose of this invention is to provide the ultra-thin glass face of a kind of directional reflective mud porcelain exterior wall tile floor tile and manufacture method thereof, its body is light, is used for the high-rise building outer wall safety; Be used for the floor withstand voltage, wear-resisting, like the ceramic tile performance; Be used for the freeway tunnel body of wall, cement separation mound, city curb etc. are located its can directional reflective, make the officer lamp according under see night object such as daytime effect, induce the stimulation eyestrain of travelling and causing thereby avoid the reflective bright spot of Fa Guang to be linked to be line.Reforming traffic luminous environment raising safety factor is target of the present invention, the more important thing is to solve the exterior wall ceramic tile, and the floor tile manufacturing relies on coal, oil high energy consumption, maximum discharge, seriously polluted problem.
Technical scheme of the present invention is: the ultra-thin glass face of a kind of directional reflective mud porcelain exterior wall tile or floor tile, comprise mud porcelain main body, and be densely covered with some transparent glass microballons at this main body end face, form the vitreous reflective surface.
Bottom surface in described mud porcelain main body is bonded with nonwoven layer.
Described glass microballon adopts the high refractive index glass micro pearl of aluminizing.
Composition and the weight percent of described mud porcelain main body are: binding agent 2-25%, tensio-active agent 0.05-0.2%, staple fibre 0.5-2%, all the other compositions are the earth powder.
Described binding agent is hot-melt adhesive powder or glass cement glue; Described earth adopts natural earth, building stones to carry out crushing screening, and its granularity is the 100-800 order; Tensio-active agent is EDTA; Staple fibre adopts chemical fibre, fiber crops or cotton, and length is 1-3mm.
Described mud porcelain main body also comprises stearic acid or/and coupling agent, and weight percent is: stearic acid 1-3% and/or coupling agent 0.1-0.3%.
The manufacture method of the ultra-thin glass face of a kind of described directional reflective mud porcelain exterior wall tile or floor tile is characterized in that: add hot-melt adhesive powder, tensio-active agent and staple fibre in described ratio; In the tank pot, heat 180-240 ℃ and be mixed into the dough shape; Then be plates with the roller press roll extrusion; While hot at this spreading glass microballon above plates; Roll extrusion partly or entirely embeds the main body upper surface with glass microballon again; Be cut at last the finished product of desired size.
The manufacture method of the ultra-thin glass face of a kind of described directional reflective mud porcelain exterior wall tile or floor tile, it is characterized in that: in described ratio earth powder, glass cement glue, tensio-active agent, staple fibre and an amount of water are added in the tank pot, in the tank pot, be stirred to the pasty state material; Then with pasty state material blade coating on non-woven fabrics, enter drying tunnel oven dry; Repeat blade coating pasty state material and oven dry in the above, until meet the requirements of thickness; Behind the last blade coating pasty state material, spreading glass common vetch pearl is sent into the drying tunnel oven dry after the roll extrusion in the above; After the water oven dry, be cut into the finished product of desired size.
The manufacture method of the ultra-thin glass face of a kind of described directional reflective mud porcelain exterior wall tile or floor tile is characterized in that: be the dough shape in described ratio with mixing in earth powder, glass cement glue, tensio-active agent, the filling of staple fibre adding pot; Fill up below one deck grid non-woven fabrics, send into the thin forming machine of many roll extrusion, dough shape pug is pressed into plates; Take advantage of the soft glass common vetch pearl that perfuses on the surface; Enter the drying tunnel oven dry after the roll extrusion; After the water oven dry, be cut into the finished product of desired size.
Advantage of the present invention is: can directional reflective, make the officer lamp according under see night object such as daytime effect, thereby avoid the reflective bright spot of Fa Guang to be linked to be line and to induce the stimulation eyestrain of travelling and causing.The more important thing is to have solved the exterior wall ceramic tile that the floor tile production relies on coal, oil high energy consumption, maximum discharge, pollution problem.Energy-conserving and environment-protective of the present invention, reform traffic luminous environment has improved the traffic safety rate.
Description of drawings
Fig. 1 be the ultra-thin glass face of the directional reflective mud porcelain exterior wall tile for preparing of the present invention the cross section structure schematic diagram of the first embodiment of floor tile;
Fig. 2 be the ultra-thin glass face of the directional reflective mud porcelain exterior wall tile for preparing of the present invention the cross section structure schematic diagram of the second embodiment of floor tile;
Fig. 3 be the ultra-thin glass face of the directional reflective mud porcelain exterior wall tile for preparing of the present invention the cross section structure schematic diagram of the 3rd embodiment of floor tile.
Embodiment
Referring to Fig. 1, the ultra-thin glass face of a kind of directional reflective of the present invention mud porcelain exterior wall tile floor tile the first embodiment, comprise mud porcelain main body 1, be densely covered with some transparent glass microballons 2 at this main body 1 end face, form reflective vitreous face.Described glass microballon 2 adopts the high refractive index glass micro pearl of aluminizing.
Referring to Fig. 2, the ultra-thin glass face of a kind of directional reflective of the present invention mud porcelain exterior wall tile floor tile the second embodiment, comprise mud porcelain main body 1, be densely covered with some transparent glass microballons 2 at this main body 1 end face, form reflective vitreous face.Be bonded with nonwoven layer 3(such as grid non-woven fabrics in the bottom surface of described mud porcelain main body 1).Described glass microballon 2 adopts the high refractive index glass micro pearl of aluminizing.
Referring to Fig. 3; the ultra-thin glass face of a kind of directional reflective of the present invention mud porcelain exterior wall tile floor tile the 3rd embodiment; this embodiment is divided into multilayer with the mud porcelain main body 1 among the second embodiment and (is illustrated as three layers; be followed successively by from top to bottom the first layer 11, the second layer 12, the 3rd layer 13) make respectively (explanation that concrete technology sees below) by repeatedly applying, drying; be densely covered with some transparent glass microballons 2 at this main body 1 end face, form reflective vitreous face.Be bonded with nonwoven layer 3(such as grid non-woven fabrics in the bottom surface of described mud porcelain main body 1).Described glass microballon 2 adopts the high refractive index glass micro pearl of aluminizing.
The ultra-thin glass face of directional reflective of the present invention mud porcelain exterior wall tile floor tile make by following technique:
1, first method: composition and the weight percent of described mud porcelain main body 1 are: hot-melt adhesive powder 10-20%, tensio-active agent 0.05-0.2%, staple fibre 0.5-2%, all the other compositions are the earth powder.
According to the above ratio hot-melt adhesive powder, tensio-active agent and staple fibre are added in the tank pot; In the tank pot, heat 180-240 ℃ and be mixed into the dough shape; Then be flake main body with the roller press roll extrusion; On main body, broadcast sowing while hot glass microballon; Roll extrusion embeds the main body upper surface with glass microballon again; Be cut at last the finished product of desired size.
2, second method: composition and the weight percent of described mud porcelain main body 1 are: glass cement glue 2-10%, tensio-active agent 0.05-0.2%, staple fibre 0.5-2%, all the other compositions are the earth powder.
According to the above ratio earth powder, glass cement glue, tensio-active agent, staple fibre and an amount of water are added in the tank pot, in the tank pot, be stirred to pasty state material (not heating); Then with pasty state material blade coating on non-woven fabrics, enter drying tunnel oven dry; Repeat blade coating pasty state material and oven dry in the above, until meet the requirements of thickness; Behind the last blade coating pasty state material, spreading glass common vetch pearl is sent into the drying tunnel oven dry after the roll extrusion in the above; After the water oven dry, be cut into the finished product of desired size.
3, the third method: composition and the weight percent of described mud porcelain main body 1 are: glass cement glue 10-25%, tensio-active agent 0.05-0.2%, staple fibre 0.5-2%, all the other compositions are the earth powder.
According to the above ratio earth powder, glass cement glue, tensio-active agent, staple fibre are added in the pot filling and mix as under the dough shape normal temperature; Fill up below one deck grid non-woven fabrics, send into the thin forming machine of many roll extrusion, dough shape pug is pressed into the 2-3 mm thick; Take advantage of the soft glass common vetch pearl that perfuses on the surface; Enter again the drying tunnel oven dry after the roll extrusion; After the water oven dry, be cut into the finished product of desired size.
Earth of the present invention adopts natural earth, stone pulverizing to sieve, and its granularity is the 100-800 order; Tensio-active agent is EDAT; Staple fibre adopts chemical fibre, fiber crops or cotton, and length is 1-3mm.
Mud porcelain main body 1 of the present invention can add stearic acid, coupling agent individually or simultaneously in three kinds of above-mentioned prescriptions, the weight percent of the two is: stearic acid 1-3% and/or coupling agent 0.1-0.3%.Adopt silane, titante coupling agent to get final product.Manufacturing process is constant.
The most important thing is to be improved in the processing method of the present invention and need not fire, its product of making can replace floor tile and exterior wall tile, and outstanding is the present situation that has changed the high energy consumption that has history to come Di Zhuan exterior wall tile technique, high Prevent Carbon Contamination, not environmental protection.Emphasis of the present invention applies to freeway tunnel body of wall, highway cement hard shoulder, city curb, isolates and spend platform to beautify and the directional reflective traffic safety.

Claims (9)

1. the ultra-thin glass face of a directional reflective mud porcelain exterior wall tile or floor tile comprise mud porcelain main body, are densely covered with some transparent glass microballons at this main body end face, form the vitreous reflective surface.
2. the ultra-thin glass face of directional reflective according to claim 1 mud porcelain exterior wall tile or floor tile, it is characterized in that: the bottom surface in described mud porcelain main body is bonded with nonwoven layer.
3. the ultra-thin glass face of directional reflective according to claim 1 mud porcelain exterior wall tile or floor tile is characterized in that: described glass microballon adopts the high refractive index glass micro pearl of aluminizing.
4. the ultra-thin glass face of directional reflective according to claim 1 mud porcelain exterior wall tile or floor tile, it is characterized in that: composition and the weight percent of described mud porcelain main body are: binding agent 2-25%, tensio-active agent 0.05-0.2%, staple fibre 0.5-2%, all the other compositions are the earth powder.
5. the ultra-thin glass face of directional reflective according to claim 4 mud porcelain exterior wall tile or floor tile, it is characterized in that: described binding agent is hot-melt adhesive powder or glass cement glue; Described earth adopts natural earth, building stones to carry out crushing screening, and its granularity is the 100-800 order; Tensio-active agent is EDTA; Staple fibre adopts chemical fibre, fiber crops or cotton, and length is 1-3mm.
6. the ultra-thin glass face of directional reflective according to claim 4 mud porcelain exterior wall tile or floor tile is characterized in that: described mud porcelain main body also comprises stearic acid or/and coupling agent, and weight percent is: stearic acid 1-3% and/or coupling agent 0.1-0.3%.
7. the manufacture method of the ultra-thin glass face of a directional reflective claimed in claim 5 mud porcelain exterior wall tile or floor tile is characterized in that: add hot-melt adhesive powder, tensio-active agent and staple fibre in described ratio; In the tank pot, heat 180-240 ℃ and be mixed into the dough shape; Then be plates with the roller press roll extrusion; While hot at this spreading glass microballon above plates; Roll extrusion partly or entirely embeds the main body upper surface with glass microballon again; Be cut at last the finished product of desired size.
8. the manufacture method of the ultra-thin glass face of a directional reflective claimed in claim 5 mud porcelain exterior wall tile or floor tile, it is characterized in that: in described ratio earth powder, glass cement glue, tensio-active agent, staple fibre and an amount of water are added in the tank pot, in the tank pot, be stirred to the pasty state material; Then with pasty state material blade coating on non-woven fabrics, enter drying tunnel oven dry; Repeat blade coating pasty state material and oven dry in the above, until meet the requirements of thickness; Behind the last blade coating pasty state material, spreading glass common vetch pearl is sent into the drying tunnel oven dry after the roll extrusion in the above; After the water oven dry, be cut into the finished product of desired size.
9. the manufacture method of the ultra-thin glass face of a directional reflective claimed in claim 5 mud porcelain exterior wall tile or floor tile is characterized in that: in described ratio earth powder, glass cement glue, tensio-active agent, staple fibre are added pot and mix in filling with and be the dough shape; Fill up below one deck grid non-woven fabrics, send into the thin forming machine of many roll extrusion, dough shape pug is pressed into plates; Take advantage of the soft glass common vetch pearl that perfuses on the surface; Enter the drying tunnel oven dry after the roll extrusion; After the water oven dry, be cut into the finished product of desired size.
CN201310032434.5A 2013-01-29 2013-01-29 Oriented reflective ultra-thin vitrified clay-porcelain exterior wall tile/floor tile and manufacturing method thereof Active CN103044072B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105350427A (en) * 2015-09-30 2016-02-24 南通路桥工程有限公司 Side pavement colorful road brick and preparation method
CN106988181A (en) * 2016-12-19 2017-07-28 梁洲辅 A kind of luminous building block brick and preparation method thereof
CN107098646A (en) * 2017-05-12 2017-08-29 罗碧贤 A kind of wall light stalk fibre fire prevention wall brick

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CN2734891Y (en) * 2004-09-29 2005-10-19 潘英豪 Luminous and reflecting concrete floor tile
CN101078200A (en) * 2007-06-05 2007-11-28 廖志强 Light reflecting ceramic chip and preparation method thereof
CN102191752A (en) * 2011-06-03 2011-09-21 钱宏诚 Directional reflective ceramic wafer
CN102786268A (en) * 2012-08-14 2012-11-21 北京市建筑工程研究院有限责任公司 Preparation method of polymer cement base sheet
CN203189030U (en) * 2013-01-29 2013-09-11 钱宏诚 Directional reflection ultrathin glass surface mud ceramic external wall tile or floor tile

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1032869A (en) * 1987-03-15 1989-05-10 钱宏诚 A kind of directional reflective coating process
CN2084074U (en) * 1990-06-25 1991-09-04 陈志强 Flash energy saving tile-hanging for wall
CN1088281A (en) * 1992-12-15 1994-06-22 钱宏诚 Stuck long-service marking line belt
CN1203988A (en) * 1997-06-27 1999-01-06 钱宏诚 Reflecting ceramic marking insert and its making method
CN1225344A (en) * 1998-11-20 1999-08-11 中国科学院上海硅酸盐研究所 Inorganic and flame-retardant type composite slab and method for mfg. same
CN1128262C (en) * 1999-05-11 2003-11-19 深圳市夜明珠高新技术有限责任公司 Directional reflector material and the producing method of the same
CN1357502A (en) * 2000-06-01 2002-07-10 任文林 Soil-base multicomponent composite material and its product and use
CN2734891Y (en) * 2004-09-29 2005-10-19 潘英豪 Luminous and reflecting concrete floor tile
CN101078200A (en) * 2007-06-05 2007-11-28 廖志强 Light reflecting ceramic chip and preparation method thereof
CN102191752A (en) * 2011-06-03 2011-09-21 钱宏诚 Directional reflective ceramic wafer
CN102786268A (en) * 2012-08-14 2012-11-21 北京市建筑工程研究院有限责任公司 Preparation method of polymer cement base sheet
CN203189030U (en) * 2013-01-29 2013-09-11 钱宏诚 Directional reflection ultrathin glass surface mud ceramic external wall tile or floor tile

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105350427A (en) * 2015-09-30 2016-02-24 南通路桥工程有限公司 Side pavement colorful road brick and preparation method
CN106988181A (en) * 2016-12-19 2017-07-28 梁洲辅 A kind of luminous building block brick and preparation method thereof
CN107098646A (en) * 2017-05-12 2017-08-29 罗碧贤 A kind of wall light stalk fibre fire prevention wall brick

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