CN1030101A - 低反射率赤褐色涂层 - Google Patents
低反射率赤褐色涂层 Download PDFInfo
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- CN1030101A CN1030101A CN88102876A CN88102876A CN1030101A CN 1030101 A CN1030101 A CN 1030101A CN 88102876 A CN88102876 A CN 88102876A CN 88102876 A CN88102876 A CN 88102876A CN 1030101 A CN1030101 A CN 1030101A
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- 238000000576 coating method Methods 0.000 title claims description 17
- 239000011248 coating agent Substances 0.000 title claims description 14
- 229910000906 Bronze Inorganic materials 0.000 title description 3
- 239000010974 bronze Substances 0.000 title description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 title description 3
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 23
- 238000007747 plating Methods 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000002310 reflectometry Methods 0.000 claims abstract description 14
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 10
- 239000000956 alloy Substances 0.000 claims abstract description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 238000005507 spraying Methods 0.000 claims description 18
- 239000011521 glass Substances 0.000 claims description 16
- 239000010935 stainless steel Substances 0.000 claims description 14
- 229910001220 stainless steel Inorganic materials 0.000 claims description 14
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 11
- 229910052804 chromium Inorganic materials 0.000 claims description 11
- 239000011651 chromium Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 15
- 229910044991 metal oxide Inorganic materials 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- 229910001026 inconel Inorganic materials 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3607—Coatings of the type glass/inorganic compound/metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
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- Chemically Coating (AREA)
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- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
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Abstract
本发明描述了一种反射太阳能的透明制品,包括一层显示颜色的金属合金氧化物薄膜和一层低反射率的金属合金薄膜。本发明还描述了制备该制品的喷镀方法。
Description
本发明涉及透明的涂层工艺,更具体地涉及多层带色透明的,特别是用于建筑玻璃的涂层。
随着用于加热和冷却的能源的价格的增加,带有金属或金属氧化物膜的建筑玻璃产品的重要性也在日益增加。涂覆的玻璃建筑产品通常分为两种类型,即太阳能抑制透过类和高透明度低发射率涂覆产品。
太阳能抑制透过玻璃产品通常是在玻璃基片(经常是带色的)上涂有高反射率、低可见光透明度的有色薄膜,该膜可使通过窗子透进楼内的太阳能降低,从而降低了空调的费用。这种产品在温暖气候下最为有效,并且在商业建筑物中最为常见。但是在加热费用最受关注的地区,特别是住宅中,高透明度、低发射率的涂层是所希望的,这是为了得到使可见光进入室内的高透明度,同时反射红外辐射,以便将热量保持在建筑物内。高透明度、低发射率涂层常见的为多层薄膜,其中红外反射金属如银、金或铜夹在两层抗反射性金属氧化物(如铋、铟和/或锡的氧化物)之间。另一方面,太阳能抑制薄膜常见的为高反射率的一种或多种金属或金属氧化物的单层薄膜,例如钴、铁、铬、镍或铜等或它们的氧化物的薄膜。
用湿化学法来制备金属太阳能抑制膜是众所周知的,如美国专利3846152,4,091,172,3,723,158和3,457,138。用热解法来制备金属氧化物太阳能抑制膜也是已知的,如美国专利3660061,3658568,3978272和4100330。
美国专利4,462,884和4,508,789公开了供制造高透明度,低发射率的多层涂层的喷镀技术,美国专利4,512,863和4,594,137公开了供制造太阳能抑制膜的喷镀技术,
Grubb等的美国专利4022947公开了一种透明镶板,该镶板可以透过所要求的部分可见光,同时反射大部分射入的太阳辐射,同时还公开了一种该镶板的制备方法,该方法是通过喷镀铁、镍和铬的合金来得到一种透明金属膜,以及在氧气存在下,喷镀铁、镍和铬的合金或类似的合金并使其反应,得到一种氧化物膜。在一种最佳实施方案中,金属膜处于基板和金属氧化物膜之间。在另一种最佳实施方案中,金属氧化物膜处于基板和金属膜之间。
R.C.Criss的题目为“具有干涉色的建筑涂层”的美国专利申请第682136号公开了深色的涂层,这些涂层包括组合在一起的一层高反射率的金属及一层其颜色是由于吸收和干涉作用而产生的金属化合物。
本发明涉及一项通过阴极喷镀,最好是磁控管喷镀而沉积在一种基板如玻璃上的低反射率、低透明度的赤褐色太阳能抑制薄膜,该薄膜包括一层低反射率带色的金属合金氧化物以及一层中性金属合金。该金属合金氧化物层提供颜色和低反射率,而金属合金层则提供中性低透明度。
将一种透明基板,最好是玻璃用阴极喷镀法,最好是磁控管喷镀法得到一种太阳能抑制产品。该涂层至少包括一层带色的金属合金氧化物如不锈钢氧化物,以及至少一层提供中性低透明度的金属合金,如镍合金。推荐的金属合金是铬镍铁合金(Inconel)。
在一个本发明的推荐的实施方案中,是首先在玻璃基板上通过在氧化反应性气氛中喷镀不锈钢阴极靶来涂覆一层不锈钢氧化物。然后在不锈钢氧化物涂覆面上通过在非反应性气氛如氩气氛下喷镀镍合金靶来涂覆一层中性金属合金。涂层的厚度可有很多种以达到不同的视觉效果。特别是中性金属层厚度可以改变以便在不改变颜色及玻璃侧光线的反射率的情况下增加或减少光的透明度。
在本发明最好的实施方案中,是将不锈钢氧化物层和铬镍铁合金(Inconel)层组合在一起形成赤褐色涂层。本发明将通过下列实施例来进行进一步解释。
实施例Ⅰ
在喷镀室中在多个顺序排列的阴极下面,在下列条件下,将不锈钢氧化物和镍金属合金的多重涂层沉积在一个玻璃基板上。将一个干净的玻璃基板放在真空室中,室中有压力为3毫乇的由50%氧气和50%氩气组成的气体。使一个具有靶表面积为106×15英寸(约2.75×0.4米)的不锈钢阴极加上98千瓦的电源。在线速为93英寸/分(2.36米/分)下使不锈钢氧化物涂层沉积在玻璃上,其沉积厚度应使1/4英寸(约6毫米)厚的浮法玻璃的90%的透明度降至59%。在本实施例中应用的不锈钢组合物是316号合金,该合金包括68%的铁、17%的铬、12%的镍和2.25%的钼。然后,在3毫乇压力的惰性氩气气氛下使镍合金阴极喷镀,采用和上述相同的线速度和7千瓦的电源,将镍合金涂层沉积在不锈钢氧化物涂层上面,将透明度进一步减小至16.8%。在本实施例中使用的镍合金是625号铬镍铁合金,该合金包括62.6%的镍、20%的铬、6.85%的铁和3.95%的钴,另外还有痕量的钽、碳、锰、铁、硫、硅、铜、铝和钛(含量小于1%)。当涂覆的制品暴露在外界环境中时,镍合金涂层表面会发生氧化,可稍微增加透明度。该涂覆制品有低反射率,在玻璃侧呈现赤褐色外观。该涂覆产品光线透明度约为20%,玻璃侧的光反射率约为14%。反射的颜色为赤褐色,色坐标x=0.3401,y=0.3518。
上述实施例只是为了说明本发明。很多其它带色金属合金氧化物以及其它中性、低反射率金属(如铬合金)都可以使用。任何合适的透明有保护性的基板都可以使用。
Claims (19)
1、一种用来反射太阳能的制品,该制品包括:
a)透明基板;
b)沉积在所述基板表面的有颜色的金属合金氧化物透明薄膜;以及
c)沉积在所述金属合金氧化物薄膜上的低反射率透明金属合金薄膜。
2、权利要求1所述的制品,其中的基材是玻璃。
3、权利要求2所述的制品,其中的低反射率金属合金薄膜包括一种选自镍和铬的金属的合金。
4、权利要求3所述的制品,其中所述的金属合金包括镍。
5、权利要求4所述的制品,其中所述的镍合金包括镍、铬和铁。
6、权利要求2所述的制品,其中的金属合金氧化物膜包括不锈钢。
7、权利要求6所述的制品,其中的金属合金氧化物膜包括不锈钢氧化物。
8、权利要求7所述的制品,其中的不锈钢包括铁、铬、镍和钼。
9、权利要求7所述的制品,该制品在玻璃表面反射的为赤褐色。
10、权利要求1所述的制品,其中所述的金属合金氧化物和低反射率金属的透明薄膜是喷镀薄膜。
11、一种制造反射太阳能的涂覆制品的方法,该方法包括下列步骤:
a.在一种基板的表面上首先喷镀上一层可显出颜色的金属合金氧化物的透明涂层;
b.在所述的金属合金氧化物膜上再喷镀上一层低反射率透明金属合金薄膜。
12、权利要求11所述的方法,其中所述的基板是玻璃且所述的喷镀是用磁场来加强的。
13、权利要求12所述的方法,其中所述的金属合金氧化物薄膜是通过喷镀一种包括不锈钢的金属合金来沉积的。
14、权利要求13所述的方法,其中不锈钢是在氧化气氛中喷镀的。
15、权利要求14所述的方法,其中所述的金属合金薄膜是通过喷镀选自镍和铬的一种金属的合金来沉积的。
16、权利要求15所述的方法,其中所述的金属合金膜是通过在惰性气氛下喷镀镍合金来沉积的。
17、权利要求16所述的方法,其中的镍合金是在包括氩的气氛下喷镀的。
18、权利要求17所述的方法,其中的镍合金包括镍、铬和铁。
19、权利要求18所述的方法,其中的镍合金包括镍、铬、铁和铌。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/050,825 US4847158A (en) | 1987-05-15 | 1987-05-15 | Low reflectance bronze coating |
US50825 | 2001-12-28 |
Publications (1)
Publication Number | Publication Date |
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CN1030101A true CN1030101A (zh) | 1989-01-04 |
Family
ID=21967677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN88102876A Pending CN1030101A (zh) | 1987-05-15 | 1988-05-16 | 低反射率赤褐色涂层 |
Country Status (18)
Country | Link |
---|---|
US (1) | US4847158A (zh) |
EP (1) | EP0291010B1 (zh) |
JP (1) | JP2528937B2 (zh) |
KR (1) | KR930006324B1 (zh) |
CN (1) | CN1030101A (zh) |
AT (1) | ATE131939T1 (zh) |
AU (1) | AU584541B2 (zh) |
CA (2) | CA1328090C (zh) |
DE (1) | DE3854798T2 (zh) |
DK (1) | DK264488A (zh) |
ES (1) | ES2083358T3 (zh) |
FI (1) | FI882234A (zh) |
GR (1) | GR3019206T3 (zh) |
HK (1) | HK1000474A1 (zh) |
MY (1) | MY103372A (zh) |
NO (1) | NO882106L (zh) |
NZ (1) | NZ224378A (zh) |
ZA (1) | ZA883009B (zh) |
Cited By (2)
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CN103963387A (zh) * | 2014-01-15 | 2014-08-06 | 洛阳新晶润工程玻璃有限公司 | 一种高吸热低反射蓝膜镀膜玻璃及其制造方法 |
TWI456452B (zh) * | 2011-11-25 | 2014-10-11 | 低金屬光澤可視性的觸控面板的製作方法及其產品 |
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US5112693A (en) * | 1988-10-03 | 1992-05-12 | Ppg Industries, Inc. | Low reflectance, highly saturated colored coating for monolithic glazing |
US5055358A (en) * | 1989-09-29 | 1991-10-08 | Libbey-Owens-Ford Co. | Low reflectance films for transparent substrates |
US5229194A (en) * | 1991-12-09 | 1993-07-20 | Guardian Industries Corp. | Heat treatable sputter-coated glass systems |
US5376455A (en) * | 1993-10-05 | 1994-12-27 | Guardian Industries Corp. | Heat-treatment convertible coated glass and method of converting same |
ATE358108T1 (de) * | 1998-12-22 | 2007-04-15 | Glaverbel | Schutzschicht für beschichtetes substrat |
US6365284B1 (en) | 1999-06-04 | 2002-04-02 | Crown Operations International, Ltd. | Flexible solar-control laminates |
US7067195B2 (en) | 2002-04-29 | 2006-06-27 | Cardinal Cg Company | Coatings having low emissivity and low solar reflectance |
US7122252B2 (en) * | 2002-05-16 | 2006-10-17 | Cardinal Cg Company | High shading performance coatings |
CA2493803C (en) * | 2002-07-31 | 2011-09-27 | Cardinal Cg Compagny | Temperable high shading performance coatings |
US7807248B2 (en) * | 2007-08-14 | 2010-10-05 | Cardinal Cg Company | Solar control low-emissivity coatings |
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US2676117A (en) * | 1949-04-18 | 1954-04-20 | Libbey Owens Ford Glass Co | Light transmissive electrically conducting optical article |
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DE2256441C3 (de) * | 1972-11-17 | 1978-06-22 | Flachglas Ag Delog-Detag, 8510 Fuerth | In Durchsicht und Draufsicht farbneutrale wärmereflektierende Scheibe und ihre Verwendung in Verbundsicherheits- und Doppelscheiben |
FR2218301A1 (en) * | 1973-02-16 | 1974-09-13 | Saint Gobain | Semi-reflecting glaze with semi-conductor layer - of pref tin oxide, indium oxide or titanium nitride applied on film of gold, silver or copper |
JPS5128091A (ja) * | 1974-08-29 | 1976-03-09 | Mizukawa Sangyo Kk | Hosobakonojidoshiirusochi |
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DE2924833C3 (de) * | 1979-06-20 | 1982-05-19 | Bfg Glassgroup, Paris | Wärmereflexionsscheibe mit farbneutraler Außenansicht und deren Verwendung als Außenscheibe einer Mehrscheibenanordnung |
JPS5918134A (ja) * | 1982-07-16 | 1984-01-30 | Asahi Glass Co Ltd | 酸化物膜を有する熱線反射積層体の形成方法 |
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US4594137A (en) * | 1983-09-09 | 1986-06-10 | Ppg Industries, Inc. | Stainless steel overcoat for sputtered films |
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-
1987
- 1987-05-15 US US07/050,825 patent/US4847158A/en not_active Expired - Lifetime
-
1988
- 1988-04-26 NZ NZ224378A patent/NZ224378A/xx unknown
- 1988-04-27 ZA ZA883009A patent/ZA883009B/xx unknown
- 1988-05-10 CA CA000566433A patent/CA1328090C/en not_active Expired - Fee Related
- 1988-05-10 CA CA000566432A patent/CA1315461C/en not_active Expired - Fee Related
- 1988-05-10 ES ES88107482T patent/ES2083358T3/es not_active Expired - Lifetime
- 1988-05-10 EP EP88107482A patent/EP0291010B1/en not_active Expired - Lifetime
- 1988-05-10 AT AT88107482T patent/ATE131939T1/de not_active IP Right Cessation
- 1988-05-10 DE DE3854798T patent/DE3854798T2/de not_active Expired - Fee Related
- 1988-05-12 FI FI882234A patent/FI882234A/fi not_active IP Right Cessation
- 1988-05-13 AU AU16127/88A patent/AU584541B2/en not_active Ceased
- 1988-05-13 DK DK264488A patent/DK264488A/da not_active Application Discontinuation
- 1988-05-13 MY MYPI88000508A patent/MY103372A/en unknown
- 1988-05-13 JP JP63116789A patent/JP2528937B2/ja not_active Expired - Lifetime
- 1988-05-13 NO NO882106A patent/NO882106L/no unknown
- 1988-05-14 KR KR1019880005636A patent/KR930006324B1/ko not_active IP Right Cessation
- 1988-05-16 CN CN88102876A patent/CN1030101A/zh active Pending
-
1996
- 1996-03-05 GR GR960400610T patent/GR3019206T3/el unknown
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1997
- 1997-10-23 HK HK97102008A patent/HK1000474A1/xx not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI456452B (zh) * | 2011-11-25 | 2014-10-11 | 低金屬光澤可視性的觸控面板的製作方法及其產品 | |
CN103963387A (zh) * | 2014-01-15 | 2014-08-06 | 洛阳新晶润工程玻璃有限公司 | 一种高吸热低反射蓝膜镀膜玻璃及其制造方法 |
Also Published As
Publication number | Publication date |
---|---|
ES2083358T3 (es) | 1996-04-16 |
NO882106L (no) | 1988-11-16 |
MY103372A (en) | 1993-06-30 |
DK264488A (da) | 1988-11-16 |
HK1000474A1 (en) | 1998-03-27 |
EP0291010B1 (en) | 1995-12-20 |
AU584541B2 (en) | 1989-05-25 |
AU1612788A (en) | 1988-11-17 |
NO882106D0 (no) | 1988-05-13 |
US4847158A (en) | 1989-07-11 |
EP0291010A2 (en) | 1988-11-17 |
CA1328090C (en) | 1994-03-29 |
NZ224378A (en) | 1990-07-26 |
JPS643036A (en) | 1989-01-06 |
DE3854798D1 (de) | 1996-02-01 |
JP2528937B2 (ja) | 1996-08-28 |
EP0291010A3 (en) | 1989-03-22 |
KR930006324B1 (ko) | 1993-07-14 |
GR3019206T3 (en) | 1996-06-30 |
DK264488D0 (da) | 1988-05-13 |
ATE131939T1 (de) | 1996-01-15 |
CA1315461C (en) | 1993-03-30 |
FI882234A (fi) | 1988-11-16 |
DE3854798T2 (de) | 1997-02-06 |
KR880013834A (ko) | 1988-12-22 |
ZA883009B (en) | 1989-12-27 |
FI882234A0 (fi) | 1988-05-12 |
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