CN103007478A - Fire extinguishing agent and preparation method thereof - Google Patents

Fire extinguishing agent and preparation method thereof Download PDF

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CN103007478A
CN103007478A CN2012105926318A CN201210592631A CN103007478A CN 103007478 A CN103007478 A CN 103007478A CN 2012105926318 A CN2012105926318 A CN 2012105926318A CN 201210592631 A CN201210592631 A CN 201210592631A CN 103007478 A CN103007478 A CN 103007478A
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sodium
potassium
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ammonium
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CN103007478B (en
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贺拥军
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Guangzhou Shenzhou Security Technology Co Ltd
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Xian University of Science and Technology
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Abstract

The invention provides a fire extinguishing agent. The fire extinguishing agent is prepared by evenly mixing 1-25 parts of hydrophilic solid powder and 100 parts of water or water solution, and then adding 0.001-2 parts of surfactant for evenly mixing; and then adding 2-100 parts of hydrophobic solid particles. The invention provides a preparation method of the fire extinguishing agent. Compared with the existing fire extinguishing agent, the fire extinguishing agent can simultaneously play stifling, cooling and chemical inhibition roles, and the fire extinguishing efficiency is high; according to the fire extinguishing agent, due to addition of the surfactant in the water phase, the dispersion of rotating speed in preparation process can be lowered, the dispersion time can be shortened, and the preparation efficiency can be improved; and with the fire extinguishing agent, the adhesion property of solid gas interface and liquid gas interface can be greatly improved, the usage amount for extinguishing fire can be greatly reduced, and the fire extinguishing property can be obviously improved.

Description

A kind of extinguishing chemical and preparation method thereof
Technical field
The invention belongs to the extinguish material technical field, be specifically related to a kind of extinguishing chemical and preparation method thereof.
Background technology
Water is as the extinguishing chemical that often uses, and its thermal characteristics makes it can be used for the fire extinguishing procedure of most of type fire.Yet the flowability of water is very strong, and most of water of fire extinguishing use also has little time to work just to have run off under normal conditions, causes the utilization rate of water fire extinguishing lower, and is easy to cause secondary loss and environmental pollution.Chinese patent 201110316520.X provides a kind of extinguishing chemical, this extinguishing chemical is by being strapped in water in the solid housing, effectively limited flowing freely of water, has certain accumulation, when reducing foamite amount, improving the fire extinguishing effect, the secondary disaster that water causes when significantly having reduced fire extinguishing.But the dispersion rotating speed that needs were higher when the extinguishing chemical in the above-mentioned patent prepared and long jitter time have affected the preparation efficiency of extinguishing chemical.
Summary of the invention
Technical problem to be solved by this invention is for above-mentioned the deficiencies in the prior art, and the extinguishing chemical that a kind of preparation efficiency is high, the fire extinguishing consumption is few and fire-fighting efficiency is high is provided.This extinguishing chemical has added surfactant at aqueous phase, has effectively reduced the surface energy of water, has reduced the dispersion rotating speed in the extinguishing chemical preparation process, has greatly shortened jitter time, thereby has improved preparation efficiency; And this extinguishing chemical has significantly improved the adhesion property at solid gas interface and liquid gas interface, and the fire extinguishing consumption greatly reduces, and extinguishing property significantly improves.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of extinguishing chemical is characterized in that, raw material by following weight portion is made: 1～25 part in solid hydrophilic powder, 0.001～2 part of water soluble surfactant active, 2～100 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution; The quality percentage composition of solute is 0.1%～10% in the described aqueous solution;
Described hydrophobic solid particle is the solids after hydrophobically modified; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles;
Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more;
Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, aluminium-hydroxide powder, the magnesium carbonate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more;
Solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more; Between described solute and the solid hydrophilic powder chemical reaction not occuring, when solute is two or more, chemical reaction does not occur all between each solute.
Above-mentioned a kind of extinguishing chemical is characterized in that, is made by the raw material of following weight portion: 6～18 parts in solid hydrophilic powder, 0.1～1.5 part of water soluble surfactant active, 20～80 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution.
Above-mentioned a kind of extinguishing chemical is characterized in that, is made by the raw material of following weight portion: 12 parts in solid hydrophilic powder, 1 part of water soluble surfactant active, 50 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution.
Above-mentioned a kind of extinguishing chemical is characterized in that, the contact angle of described hydrophobic solid particle is not less than 110 °.
In addition, the present invention also provides a kind of method for preparing above-mentioned extinguishing chemical, it is characterized in that, the method is: first the solid hydrophilic powder is dispersed in water or the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 3 seconds～150 seconds under 500 rev/mins～5000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The hydrophobically modified method of solids of the present invention is for adopting silane coupler, titanate coupling agent or LCFA to improve the hydrophobic method of modifying commonly used of inorganic solid particle.
The present invention compared with prior art has the following advantages:
1, extinguishing chemical of the present invention can bring into play simultaneously suffocate, cooling, isolation and organoselenocyanate, fire-fighting efficiency is high.
2, extinguishing chemical of the present invention and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, owing to having added surfactant at aqueous phase, effectively reduced the surface energy of water, reduce dispersion rotating speed when extinguishing chemical prepares, reduced jitter time, thereby improved the preparation efficiency of extinguishing chemical.
3, extinguishing chemical of the present invention and same prescription do not add the extinguishing chemical that surfactant makes and compare, and have improved the adhesion property at solid gas interface and liquid gas interface, and consumption greatly reduces during fire extinguishing, and extinguishing property significantly improves.
Below in conjunction with embodiment the present invention is described in further detail.
The specific embodiment
Embodiment 1
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 1 part in solid hydrophilic powder, 0.08 part of water soluble surfactant active, 2 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 10% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably silicon dioxide granule, the water soluble surfactant active is preferably neopelex, solute in the aqueous solution is to mix at 20: 14: 1 by sodium acid carbonate, potash and NaOH in mass ratio preferably, and the solid hydrophilic powder is preferably the magnesium silicate powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 3 seconds under 5000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 20%, and mixing time has shortened 30%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 12%.
Embodiment 2
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 25 parts in solid hydrophilic powder, 0.5 part of water soluble surfactant active, 10 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 5% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably the imvite particle, and the water soluble surfactant active is preferably neopelex, and the solute in the aqueous solution is preferably sodium chloride, and the solid hydrophilic powder is preferably magnesium carbonate.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 150 seconds under 500 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 32%, and mixing time has shortened 21%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 25%.
Embodiment 3
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 12 parts in solid hydrophilic powder, 1 part of water soluble surfactant active, 50 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 1% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 120 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably the talcum particle, the water soluble surfactant active is preferably mixed in mass ratio by AESA and sldium lauryl sulfate at 1: 1, solute in the aqueous solution is preferably mixed in mass ratio by urea and saleratus at 5: 1, and the solid hydrophilic powder is preferably mixed in mass ratio by SiO 2 powder and magnesium silicate powder at 100: 3.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 100 seconds under 1000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 14%, and mixing time has shortened 23%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 24%.
Embodiment 4
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 18 parts in solid hydrophilic powder, 0.1 part of water soluble surfactant active, 80 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 0.5% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 130 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably mica particle, the water soluble surfactant active is preferably mixed in mass ratio by sodium sulfate of polyethenoxy ether of fatty alcohol and hexadecyltrimethylammonium chloride at 4: 3, solute in the aqueous solution is preferably mixed in mass ratio by magnesium sulfate, sodium sulphate and sodium chloride at 10: 3: 20, and the solid hydrophilic powder is preferably mixed in mass ratio by alumina powder, croci and magnesium hydroxide magnesium dust at 10: 3: 8.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 10 seconds under 2000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 50%, and mixing time has shortened 13%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire has reduced 31%.
Embodiment 5
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 6 parts in solid hydrophilic powder, 1.5 parts of water soluble surfactant actives, 50 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 6% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably mixed in mass ratio by silicon dioxide granule and talcum particle at 20: 1, the water soluble surfactant active is preferably sodium octyl sulfate, solute in the aqueous solution is 50: 2: 1 by sodium chloride, sodium formate, potassium acetate and potassium sulfate in mass ratio preferably: 25 mix, and the solid hydrophilic powder is preferably mixed in mass ratio by concave convex rod powder and zinc phosphate powder at 25: 6.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 80 seconds under 800 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 62%, and mixing time has shortened 11%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 21%.
Embodiment 6
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 15 parts in solid hydrophilic powder, 1.2 parts of water soluble surfactant actives, 40 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 8% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably mixed in mass ratio by TiO 2 particles and silicon dioxide granule at 1: 3, the water soluble surfactant active is preferably mixed in mass ratio by imidazoline quaternary ammonium salt and softex kw at 1: 4, solute in the aqueous solution is preferably mixed in mass ratio by zinc sulfate, ammonium acetate and copper chloride at 50: 50: 1, and the solid hydrophilic powder is preferably zinc phosphate powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 150 seconds under 500 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 45%, and mixing time has shortened 22%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire has reduced 32%.
Embodiment 7
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 6 parts in solid hydrophilic powder, 0.8 part of water soluble surfactant active, 80 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 6% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 130 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably zeolite particles, and the water soluble surfactant active is preferably the N-alkyl betaine, and the solute in the aqueous solution is preferably ammonium chloride, and the solid hydrophilic powder is preferably the atlapulgite powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 50 seconds under 2000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 18%, and mixing time has shortened 42%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 12%.
Embodiment 8
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 25 parts in solid hydrophilic powder, 2 parts of water soluble surfactant actives, 100 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 10% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably hydrotalcite particle, and the water soluble surfactant active is preferably peregal, and the solute in the aqueous solution is preferably calcium acetate, and the solid hydrophilic powder is preferably calcium sulphate powders.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 30 seconds under 3000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 8%, and mixing time has shortened 16%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 19%.
Embodiment 9
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 1 part in solid hydrophilic powder, 0.001 part of water soluble surfactant active, 4 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 0.1% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 115 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably the zinc oxide particle, and the water soluble surfactant active is preferably sodium sulfate of polyethenoxy ether of fatty alcohol, and the solute in the aqueous solution is preferably ammonium sulfate, and the solid hydrophilic powder is preferably the kaolin powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 30 seconds under 700 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 60%, and mixing time has shortened 11%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 15%.
Embodiment 10
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 3 parts in solid hydrophilic powder, 0.005 part of water soluble surfactant active, 20 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 0.6% in the described aqueous solution; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably aluminum hydroxide particles, and the water soluble surfactant active is preferably hexadecyltrimethylammonium chloride, and the solute in the aqueous solution is preferably sodium sulphate, and the solid hydrophilic powder is preferably the vermiculite powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 60 seconds under 1000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 15%, and mixing time has shortened 43%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 19%.
Embodiment 11
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 8 parts in solid hydrophilic powder, 0.03 part of water soluble surfactant active, 8 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 3% in the described aqueous solution;
Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 140 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably diatomaceous earth particle, and the water soluble surfactant active is preferably lauryl sodium sulfate, and the solute in the aqueous solution is preferably sodium chloride, and the solid hydrophilic powder is preferably magnesium hydroxide powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 50 seconds under 5000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 21%, and mixing time has shortened 26%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 36%.
Embodiment 12
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 25 parts in solid hydrophilic powder, 2 parts of water soluble surfactant actives, 4 parts on hydrophobic solid particle, 100 parts of the aqueous solution; The quality percentage composition of solute is 10% in the described aqueous solution;
Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 150 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; Described solute is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, N, dinethylformamide, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more, chemical reaction does not occur between described solute and the solid hydrophilic powder, when solute was two or more, chemical reaction did not all occur between each solute; In the present embodiment, solids are preferably the houghite particle, and the water soluble surfactant active is preferably NPE, and the solute in the aqueous solution is preferably sodium acetate, and the solid hydrophilic powder is preferably the magnesium silicate powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the aqueous solution, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 100 seconds under 1000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 38%, and mixing time has shortened 17%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 23%.
Embodiment 13
The present embodiment extinguishing chemical is made by the raw material of following weight portion: 12 parts in solid hydrophilic powder, 1 part of water soluble surfactant active, 50 parts on hydrophobic solid particle, 100 parts in water; Described hydrophobic solid particle is that the contact angle after hydrophobically modified is 110 ° solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles; Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more; Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, aluminium-hydroxide powder, the magnesium carbonate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more; In the present embodiment, solids are preferably the flyash particle, and the water soluble surfactant active is preferably diglycollic amide, and the solid hydrophilic powder is preferably the Firebrake ZB powder.
The preparation method of the present embodiment is: first the solid hydrophilic powder is dispersed in the water, then add the water soluble surfactant active, the rear adding hydrophobic solid particle that stirs is to stir 5 seconds under 4000 rev/mins the condition in stir speed (S.S.), mixes to obtain extinguishing chemical after disperseing.
The present embodiment extinguishing chemical and application number are that the Chinese patent extinguishing chemical of 201110316520.X is compared, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduced by 35%, and mixing time has shortened 12%; And the consumption that the present embodiment extinguishing chemical puts out 1A grillage fire has reduced 25%.
The above only is preferred embodiment of the present invention, is not that the present invention is imposed any restrictions.Every any simple modification, change and equivalence of above embodiment being done according to the invention technical spirit changes, and all still belongs in the protection domain of technical solution of the present invention.

Claims (5)

1. extinguishing chemical, it is characterized in that, mixed by solid hydrophilic powder and water or the aqueous solution rear adding surfactant that stirs, and then adding hydrophobic solid mix particles disperses to form: 1～25 part in solid hydrophilic powder, 0.001～2 part of water soluble surfactant active, 2～100 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution; The quality percentage composition of solute is 0.1%～10% in the described aqueous solution;
Described hydrophobic solid particle is the solids after hydrophobically modified; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talcum particle, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particle, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and the zeolite particles;
Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, the dioctyl sodium sulfosuccinate, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, the N-alkyl betaine, in sodium octyl sulfate and the imidazoline quaternary ammonium salt one or more;
Described solid hydrophilic powder is magnesium hydroxide powder, alumina powder, Zinc oxide powder, croci, SiO 2 powder, the magnesium silicate powder, the calcirm-fluoride powder, strontium carbonate powder, calcium phosphate powder, the zinc carbonate powder, zinc phosphate powder, aluminium-hydroxide powder, the magnesium carbonate powder, calcium carbonate powder, the calcium silicates powder, the kaolin powder, the vermiculite powder, the pyrophillite powder, the glauconite powder, the atlapulgite powder, calcium sulphate powders, the calcium hydroxide powder, the Firebrake ZB powder, the imvite powder, the hydrotalcite powder, the houghite powder, flyash powder, diatomite powder, mica powder, the concave convex rod powder, in starch powder and the cellulose powder one or more;
Solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, in ammonium sulfate and the APP one or more; Between described solute and the solid hydrophilic powder chemical reaction not occuring, when solute is two or more, chemical reaction does not occur all between each solute.
2. a kind of extinguishing chemical according to claim 1 is characterized in that, 6～18 parts in solid hydrophilic powder, 0.1～1.5 part of water soluble surfactant active, 20～80 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution.
3. a kind of extinguishing chemical according to claim 2 is characterized in that, 12 parts in solid hydrophilic powder, 1 part of water soluble surfactant active, 50 parts on hydrophobic solid particle, 100 parts of water or the aqueous solution.
4. according to claim 1,2 or 3 described a kind of extinguishing chemicals, it is characterized in that, the contact angle of described hydrophobic solid particle is not less than 110 °.
5. method for preparing such as extinguishing chemical as described in the claim 1,2 or 3, it is characterized in that, the method is: first the solid hydrophilic powder is dispersed in water or the aqueous solution, then add the water soluble surfactant active, rear adding hydrophobic solid particle stirs, be to stir 3 seconds～150 seconds under 500 rev/mins～5000 rev/mins the condition in stir speed (S.S.), mix obtaining extinguishing chemical after disperseing.
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