CN103007479B - Fire extinguishing agent - Google Patents
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- CN103007479B CN103007479B CN201210593924.8A CN201210593924A CN103007479B CN 103007479 B CN103007479 B CN 103007479B CN 201210593924 A CN201210593924 A CN 201210593924A CN 103007479 B CN103007479 B CN 103007479B
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Abstract
The invention provides a fire extinguishing agent. The fire extinguishing agent is prepared by mixing and dispersing hydrophobic solid particles, water-soluble surfactant and water solution according to mass ratio of (5-100):(0.001-2):100. The fire extinguishing agent can simultaneously play stifling, cooling and chemical inhibition roles, and the fire extinguishing efficiency is high. Compared with the existing fire extinguishing agent, according to the fire extinguishing agent, due to addition of the surfactant in the water phase, the dispersion of rotating speed in preparation process can be lowered, the dispersion time can be shortened, and the preparation efficiency can be improved; and with the fire extinguishing agent, the adhesion property of solid gas interface and liquid gas interface can be greatly improved, the usage amount for extinguishing fire can be greatly reduced, and the fire extinguishing property can be obviously improved.
Description
Technical field
The invention belongs to extinguish material technical field, be specifically related to a kind of extinguishing chemical.
Background technology
Water is as the extinguishing chemical often used, and its thermal characteristics makes it can be used for the fire extinguishing procedure of most of types of fires.But the mobility of water is very strong, and most of water of use of putting out a fire under normal conditions also has little time to work and just lost, and causes the utilization rate of above-water method lower, and is easy to cause secondary loss and environmental pollution.Chinese patent 201010605644.5 provides a kind of extinguishing chemical, this extinguishing chemical is by being strapped in water in solid housing, effectively limit flowing freely of water, there is certain accumulation, at minimizing foamite amount, improve while extinguishing effect, the secondary disaster that when significantly reducing fire extinguishing, water causes.But the dispersion rotating speed that time prepared by the extinguishing chemical in above-mentioned patent, needs are higher and longer jitter time, have impact on the preparation efficiency of extinguishing chemical.
Summary of the invention
Technical problem to be solved by this invention is, for above-mentioned the deficiencies in the prior art, to provide a kind of extinguishing chemical.This extinguishing chemical with the addition of surfactant in aqueous phase, efficiently reduces the surface energy of aqueous phase, reduces the dispersion rotating speed in extinguishing chemical preparation process, substantially reduces jitter time, thus improve preparation efficiency; And this extinguishing chemical significantly improves the adhesion property at solid gas interface and liquid gas interface, fire extinguishing consumption greatly reduces, and extinguishing property significantly improves.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of extinguishing chemical, it is characterized in that, by hydrophobic solid particle, water soluble surfactant active and the aqueous solution in mass ratio (5 ~ 100): (0.001 ~ 2): 100 mix dispersion forms; In the described aqueous solution, the mass percentage of solute is 0.1% ~ 40%;
Described hydrophobic solid particle be hydrophobically modified after solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles;
Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt,
Solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction.
Above-mentioned a kind of extinguishing chemical, is characterized in that, by hydrophobic solid particle, water soluble surfactant active and the aqueous solution in mass ratio (20 ~ 80): (0.1 ~ 1.5): 100 mix dispersion forms.
Above-mentioned a kind of extinguishing chemical, is characterized in that, in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 50: 1: 100.
Above-mentioned a kind of extinguishing chemical, is characterized in that, the contact angle of described hydrophobic solid particle is not less than 110 °.
Above-mentioned a kind of extinguishing chemical, it is characterized in that, the detailed process of described mixing dispersion is: utilize agitator to be stir 3 seconds ~ 150 seconds under the condition of 500 revs/min ~ 5000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution.
The hydrophobically modified method of solids of the present invention improves the hydrophobic conventional method of modifying of inorganic solid particle for adopting silane coupler, titanate coupling agent or LCFA.
The present invention compared with prior art has the following advantages:
1, extinguishing chemical of the present invention can play simultaneously suffocate, cools, isolates and organoselenocyanate, and fire-fighting efficiency is high.
2, extinguishing chemical of the present invention and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, extinguishing chemical of the present invention owing to the addition of surfactant in aqueous phase, efficiently reduce the surface energy of aqueous phase, reduce the dispersion rotating speed in extinguishing chemical preparation process, substantially reduce jitter time, thus improve the preparation efficiency of extinguishing chemical.
3, extinguishing chemical of the present invention and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and extinguishing chemical of the present invention significantly improves the adhesion property at solid gas interface and liquid gas interface, and fire extinguishing consumption greatly reduces, and extinguishing property significantly improves.
Below in conjunction with embodiment, the present invention is described in further detail.
Detailed description of the invention
Embodiment 1
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 100: 2: 100, in the described aqueous solution, the mass percentage of solute is 0.5%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably magnesium silicate particle, and water soluble surfactant active is preferably neopelex, and the solute in the aqueous solution is preferably sodium carbonate.
The preparation method of the present embodiment is: utilize agitator to be stir 3 seconds under the condition of 5000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 22%, and mixing time shortens 62%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 30%.
Embodiment 2
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 40: 0.001: 100, in the described aqueous solution, the mass percentage of solute is 31%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably mixed in mass ratio by imvite particle and aluminium oxide particles at 10: 3, water soluble surfactant active is preferably mixed in mass ratio by hexadecyltrimethylammonium chloride and lauryl sodium sulfate at 5: 2, and the solute in the aqueous solution is preferably mixed in mass ratio by urea, sodium chloride and potassium chloride at 10: 10: 3.
The preparation method of the present embodiment is: utilize agitator to be stir 150 seconds under the condition of 500 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 63%, and mixing time shortens 12%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 9%.
Embodiment 3
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 50: 1: 100, in the described aqueous solution, the mass percentage of solute is 10%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 120 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably mixed in mass ratio by hydrotalcite particle, silicon dioxide granule and TiO 2 particles at 20: 4: 1, water soluble surfactant active is preferably AESA, and the solute in the aqueous solution is preferably mixed in mass ratio by magnesium chloride, sodium chloride and zinc chloride at 20: 40: 3.
The preparation method of the present embodiment is: utilize agitator to be stir 100 seconds under the condition of 1000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 65%, and mixing time shortens 55%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 23%.
Embodiment 4
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 80: 1.5: 100, in the described aqueous solution, the mass percentage of solute is 25%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 130 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably mixed in mass ratio by Firebrake ZB particle and silicon dioxide granule at 3: 20, water soluble surfactant active is preferably mixed in mass ratio by sodium sulfate of polyethenoxy ether of fatty alcohol and lauryl sodium sulfate at 1: 10, and the solute in the aqueous solution is preferably mixed in mass ratio by magnesium sulfate, potassium chloride, sodium sulphate and zinc sulfate at 20: 2: 10: 1.
The preparation method of the present embodiment is: utilize agitator to be stir 10 seconds under the condition of 2000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 58%, and mixing time shortens 46%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire decreases 25%.
Embodiment 5
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 20: 0.1: 100, in the described aqueous solution, the mass percentage of solute is 30%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably Firebrake ZB particle, water soluble surfactant active is preferably mixed in mass ratio by sodium octyl sulfate, hexadecyltrimethylammonium chloride and NPE at 10: 3: 5, and the solute in the aqueous solution is preferably mixed in mass ratio by copper chloride, calcium acetate and zinc nitrate at 1: 10: 2.
The preparation method of the present embodiment is: utilize agitator to be stir 80 seconds under the condition of 800 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 70%, and mixing time shortens 14%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 8%.
Embodiment 6
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 5: 0.001: 100, in the described aqueous solution, the mass percentage of solute is 0.1%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably aluminium oxide particles, and water soluble surfactant active is preferably imidazoline quaternary ammonium salt, and the solute in the aqueous solution is preferably potassium sulfate.
The preparation method of the present embodiment is: utilize agitator to be stir 150 seconds under the condition of 500 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 69%, and mixing time shortens 16%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 19%.
Embodiment 7
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 90: 1.8: 100, in the described aqueous solution, the mass percentage of solute is 15%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 130 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably zeolite particles, and water soluble surfactant active is preferably N-alkyl betaine, and the solute in the aqueous solution is preferably ammonium chloride.
The preparation method of the present embodiment is: utilize agitator to be stir 50 seconds under the condition of 2000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 45%, and mixing time shortens 20%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire decreases 21%.
Embodiment 8
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 60: 0.1: 100, in the described aqueous solution, the mass percentage of solute is 40%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably hydrotalcite particle, and water soluble surfactant active is preferably peregal, and the solute in the aqueous solution is preferably sodium acetate.
The preparation method of the present embodiment is: utilize agitator to be stir 30 seconds under the condition of 3000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 30%, and mixing time shortens 35%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 18%.
Embodiment 9
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 80: 1.5: 100, in the described aqueous solution, the mass percentage of solute is 5%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 115 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably zinc oxide particles, and water soluble surfactant active is preferably sodium sulfate of polyethenoxy ether of fatty alcohol, and the solute in the aqueous solution is preferably ammonium dihydrogen phosphate (ADP).
The preparation method of the present embodiment is: utilize agitator to be stir 30 seconds under the condition of 700 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 65%, and mixing time shortens 10%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire decreases 27%.
Embodiment 10
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 5: 2: 100, in the described aqueous solution, the mass percentage of solute is 0.1%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably aluminum hydroxide particles, and water soluble surfactant active is preferably hexadecyltrimethylammonium chloride, and the solute in the aqueous solution is preferably potash.
The preparation method of the present embodiment is: utilize agitator to be stir 60 seconds under the condition of 1000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 55%, and mixing time shortens 31%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 22%.
Embodiment 11
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 100: 1.2: 100, in the described aqueous solution, the mass percentage of solute is 40%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably diatomaceous earth particle, and water soluble surfactant active is preferably neopelex, and the solute in the aqueous solution is preferably potassium citrate.
The preparation method of the present embodiment is: utilize agitator to be stir 50 seconds under the condition of 5000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 16%, and mixing time shortens 42%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 11%.
Embodiment 12
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 80: 1: 100, in the described aqueous solution, the mass percentage of solute is 0.2%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 150 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably houghite particle, and water soluble surfactant active is preferably NPE, and the solute in the aqueous solution is preferably potassium chloride.
The preparation method of the present embodiment is: utilize agitator to be stir 100 seconds under the condition of 1000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 45%, and mixing time shortens 28%; And the consumption that the present embodiment extinguishing chemical puts out 1A Wood crib Fire decreases 30%.
Embodiment 13
The present embodiment extinguishing chemical in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 10: 0.6: 100, in the described aqueous solution, the mass percentage of solute is 18%, described hydrophobic solid particle be hydrophobically modified after contact angle be the solids of 110 °, described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles, described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt, solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, one or more in ammonium sulfate and APP, when solute is two or more, between each solute, all there is not chemical reaction, in the present embodiment, solids are preferably flyash particle, and water soluble surfactant active is preferably diglycollic amide, and the solute in the aqueous solution is preferably sodium sulphate.
The preparation method of the present embodiment is: utilize agitator to be stir 5 seconds under the condition of 4000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution, obtain extinguishing chemical.
The present embodiment extinguishing chemical and application number are compared with the Chinese patent extinguishing chemical of 201010605644.5, and the speed of agitator of the present embodiment extinguishing chemical in preparation process reduces 36%, and mixing time shortens 27%; And the consumption that the present embodiment extinguishing chemical puts out 9B food tray fire decreases 17%.
The above is only preferred embodiment of the present invention, not imposes any restrictions the present invention.Every above embodiment is done according to invention technical spirit any simple modification, change and equivalence change, all still belong in the protection domain of technical solution of the present invention.
Claims (3)
1. an extinguishing chemical, is characterized in that, in mass ratio by hydrophobic solid particle, water soluble surfactant active and the aqueous solution is mixed dispersion forms at 50: 1: 100; In the described aqueous solution, the mass percentage of solute is 0.1% ~ 40%;
Described hydrophobic solid particle be hydrophobically modified after solids; Described solids are one or more in magnesium hydroxide particles, silicon dioxide granule, calcium carbonate particle, talc particles, aluminium oxide particles, aluminum hydroxide particles, Firebrake ZB particle, zinc oxide particles, zinc carbonate particle, calcium carbonate particle, iron oxide particles, TiO 2 particles, imvite particle, hydrotalcite particle, houghite particle, flyash particle, diatomaceous earth particle, mica particle, concave convex rod particle and zeolite particles;
Described water soluble surfactant active is neopelex, lauryl sodium sulfate, softex kw, hexadecyltrimethylammonium chloride, dioctyl succinate disulfonate acid, perfluorinated nonene oxygen base benzene sulfonic acid sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, AESA, sldium lauryl sulfate, NPE, OPEO, peregal, diglycollic amide, N-alkyl betaine, one or more in sodium octyl sulfate and imidazoline quaternary ammonium salt,
Solute in the described aqueous solution is sodium acid carbonate, saleratus, sodium carbonate, ammonium carbonate, potassium chloride, sodium chloride, potash, carbonic hydroammonium, urea, ammonium dihydrogen phosphate (ADP), diammonium hydrogen phosphate, ammonium phosphate, sodium phosphate, potassium phosphate, dipotassium hydrogen phosphate, sodium hydrogen phosphate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Boratex, ammonium borate, strontium nitrate, ammonium chloride, sodium sulphate, potassium sulfate, potassium acid sulfate, niter cake, copper sulphate, magnesium sulfate, zinc sulfate, ammonium molybdate, sodium molybdate, molybdic acid, sodium metasilicate, chromium sulfate, amion acetic acid, dimethyl oxalate, tartaric acid, potassium tartrate, sodium tartrate, potassium hydrogen tartrate, sodium hydrogen tartrate, sodium potassium tartrate tetrahydrate, salicylic acid, potassium salicylate, sodium salicylate, DMF, potassium fluoride, sodium fluoride, melamine, NaOH, potassium hydroxide, KBr, sodium bromide, ammonium bromide, potassium oxalate, sodium oxalate, copper chloride, manganese chloride, oxalic acid, acetic acid, lactic acid, sulfuric acid, hydrochloric acid, nitric acid, sodium lactate, potassium lactate, sodium acetate, potassium acetate, ammonium acetate, calcium acetate, magnesium acetate, nickel chloride, zinc chloride, cobalt chloride, chromium chloride, iron chloride, sodium iodide, KI, magnesium chloride, calcium chloride, sodium formate, potassium formate, ammonium formate, calcium formate, sodium nitrate, potassium nitrate, ammonium nitrate, magnesium nitrate, zinc nitrate, copper nitrate, calcium nitrate, calcium lactate, sodium lactate, potassium lactate, ammonium lactate, formic acid, phosphoric acid, citric acid, ammonium citrate, potassium citrate, natrium citricum, , when solute is two or more, between each solute, all there is not chemical reaction in one or more in ammonium sulfate and APP.
2. a kind of extinguishing chemical according to claim 1, is characterized in that, the contact angle of described hydrophobic solid particle is not less than 110 °.
3. a kind of extinguishing chemical according to claim 1, it is characterized in that, the detailed process of described mixing dispersion is: utilize agitator to be stir 3 seconds ~ 150 seconds under the condition of 500 revs/min ~ 5000 revs/min at rotating speed by hydrophobic solid particle, water soluble surfactant active and the aqueous solution.
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| RU2658055C1 (en) * | 2017-04-20 | 2018-06-19 | Общество с ограниченной ответственностью "ЦеоТрейдРесурс" | Multipurpose fire extinguishing powder |
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| CN105013124B (en) * | 2014-04-25 | 2020-09-15 | 上海纽特消防设备有限公司 | K-class fire extinguishing agent and preparation method thereof |
| CN103949032B (en) * | 2014-05-13 | 2015-06-17 | 国家电网公司 | Electric transmission line caused forest fire extinguishing agent capable of reducing temperature and preventing after-combustion |
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