CN102994243A - Washing powder containing mineral ions and method for preparing same - Google Patents
Washing powder containing mineral ions and method for preparing same Download PDFInfo
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- CN102994243A CN102994243A CN2012104881292A CN201210488129A CN102994243A CN 102994243 A CN102994243 A CN 102994243A CN 2012104881292 A CN2012104881292 A CN 2012104881292A CN 201210488129 A CN201210488129 A CN 201210488129A CN 102994243 A CN102994243 A CN 102994243A
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- mineral ion
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- 238000005406 washing Methods 0.000 title claims abstract description 63
- 239000000843 powder Substances 0.000 title claims abstract description 32
- 150000002500 ions Chemical class 0.000 title claims abstract description 27
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 23
- 239000011707 mineral Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title abstract description 6
- 229920001661 Chitosan Polymers 0.000 claims abstract description 18
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 8
- 239000003240 coconut oil Substances 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 6
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 32
- 238000002360 preparation method Methods 0.000 claims description 25
- 235000010755 mineral Nutrition 0.000 claims description 18
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- 235000019387 fatty acid methyl ester Nutrition 0.000 abstract description 9
- 231100000252 nontoxic Toxicity 0.000 abstract description 7
- 230000003000 nontoxic effect Effects 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 5
- 239000001509 sodium citrate Substances 0.000 abstract description 3
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 238000003287 bathing Methods 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 abstract 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 abstract 1
- 239000002563 ionic surfactant Substances 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 239000003599 detergent Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 230000002401 inhibitory effect Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004519 grease Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 241000237502 Ostreidae Species 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- 230000009965 odorless effect Effects 0.000 description 4
- 235000020636 oyster Nutrition 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- -1 sanitas Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 241000222122 Candida albicans Species 0.000 description 2
- 235000014653 Carica parviflora Nutrition 0.000 description 2
- 244000132059 Carica parviflora Species 0.000 description 2
- 235000005956 Cosmos caudatus Nutrition 0.000 description 2
- 244000293323 Cosmos caudatus Species 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 235000021588 free fatty acids Nutrition 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- 235000019605 sweet taste sensations Nutrition 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a washing article and particularly relates to a green, safe, non-toxic and harmless washing powder containing mineral ions and a method for preparing the same. According to the technical scheme for solving the technical problems, the washing powder containing mineral ions comprises the following components in parts by weight: 10-35 parts of ionic surfactant, 5-20 parts of salt lake water concentrate, 5-10 parts of sodium carbonate peroxide, 3-12 parts of chitosan quaternary ammonium salt, 5-15 parts of coconut oil fatty acid methyl ester sodium sulfonate, 5-15 parts of sodium metasilicate, 1-3 parts of hydroxymethyl cellulose and 1-3 parts of sodium citrate. The invention also relates to a method for preparing the washing powder containing mineral ions. The washing powder containing mineral ions has the advantages of cleaning efficiently, being safe and environment-friendly and saving energy and can be widely used for washing and cleaning various clothes, bathing equipment, floors and walls.
Description
Technical field
The present invention relates to a kind of articles for washing, particularly a kind of safe green, the nontoxic washing powder of mineral ion and preparation method thereof that contains.
Background technology
The articles for washing of tradition usefulness such as washing powder, detergent etc., is mainly the petrochemical industry washing composition.It utilizes various petrochemical industry interfacial agents, lipid acid tensio-active agent, by grease and alkali generation saponification, is made by the method for entirely boiling, method of cooling, carbonation etc. again.
Yet there are a lot of shortcomings in petrochemical industry type washing composition, as not allowing with the hard water mutual exclusion, causes washing effect poor, and dirt is residual obviously, and the part material color jaundice can occur after using, fabric hardens; Alkalescence, corrodibility is excessively strong, and the article that cause being not suitable for various material use, and versatility is poor, and bringing also for simultaneously the human epidermal that belongs to weakly acidic condition stimulates and injury.Petrochemical industry type washing composition can produce a large amount of foams when cleaning, and needs with large water gaging flushing; Discharging of waste liquid after the flushing also can cause water quality, soil to pollute and destroy to nature simultaneously; Both cause the wasting of resources, caused again environmental pollution.
Progressively raising along with people's environmental consciousness, so-called green wash articles for use have appearred on the market, and the improvement of these products is to fill a prescription not contain phosphorus, reduced phosphorus to the infringement of human body skin with to the eutrophication of water quality, its essence still is that the petrochemical industry synthetics of the tensio-active agent, sequestrant, sanitas, antioxidant or the anti-heavy agent that contain the petrochemical industry class is composite.
Summary of the invention
The technical problem to be solved in the present invention is the defects that how to overcome prior art, and a kind of safe green, the nontoxic washing powder of mineral ion and preparation method thereof that contains are provided.
For solving the problems of the technologies described above, originally the washing powder component that contains mineral ion comprises ionic surface active agent alive, salt lake saline enriched material, sodium carbonate peroxide, chitosan quaternary ammonium salt, fatty acid distribution of coconut oil formicester sodium sulfonate, the preparation of weight ratio scope shown in being pressed by following component:
As optimization, the washing powder that originally contains mineral ion by following component by shown in the preparation of weight ratio scope:
As optimization, the washing powder that originally contains mineral ion by following component by shown in the preparation of weight ratio scope:
As optimization, the washing powder that originally contains mineral ion by following component by shown in the weight ratio preparation:
Above-mentioned ionic surface active agent is active ionized calcium; Above-mentioned salt lake saline enriched material is anhydrous sodium sulphate.
The preparation method of described active ionized calcium is to adopt natural Margarita, coral, agate, oyster shells are raw material, and the exchange of application ion and calcining are made and be rich in calcium, the preparation of magnesium, potassium, sodium, manganese, germanium ion, wherein the calcium ion calcining temperature is the 1400-1800 degree, has active alkalescence.The calcium ion activity can be decomposed the removal oily dirt, soak not smelly, but alkalescence bacteria growing inhibiting, anti-oxidant, the alkaline medium effect can improve tensio-active agent to the dirt washability of oily dirt particularly, contain on the other hand the free fatty acids about 30% in the natural fats and oils dirt, in washing composition, add a certain amount of active alkaline element, can generate soap with fatty acid response, be conducive to grease emulsifying, disperse to reach the decontamination purpose.
Described anhydrous sodium sulphate proterties is evenly fine particle or powder of white, and is odorless, distinguishes the flavor of salty and the band hardship; Be dissolved in glycerine, be insoluble to ethanol; It is neutral that the aqueous solution is.The drying that is mainly used in organic solvent dewaters, and fast, the residual characteristics such as few of water removal effect are arranged.
Described sodium carbonate peroxide, solid hydrogen peroxide is the addition mixture of yellow soda ash and hydrogen peroxide, SPC-D has nontoxic, odorless, the advantage such as pollution-free, SPC-D also has bleaching in addition, sterilization, washing, the characteristics such as good water solubility.The stability that the advantage of SPC-D is to store and good with the compatibility of other washing powder composition, this point are the washing auxiliary detergents that SPC-D is incomparable and do not replace.
Described chitosan quaternary ammonium salt is the chitosan higher derivative that chitosan makes through chemical modification, and full name is HACC, is called for short HACC, is white or pale yellow powder shape solid, and water absorbability is strong, and tasty and refreshing sweet taste is arranged.Chitosan quaternary ammonium salt has good water-soluble, and good stability; Also have the performances such as good film-forming properties, conditioning property, moisture absorbability and moisture retentivity, static resistance and germ resistance, its anti-microbial property is better than chitosan and other chitosan derivatives, be 0.01% to streptococcus aureus minimal inhibitory concentration (MIC), the minimal inhibitory concentration of intestinal bacteria and Candida albicans is 0.02%.What especially be worth emphasizing is to the experiment proved that the antibacterial effect of chitosan quaternary ammonium salt pair subtilis is best in all natural antibacterial agents.
Described fatty acid distribution of coconut oil methyl esters sodium sulfonate outward appearance is light yellow to white powdery solid, and gross activity thing content is slight alkalinity more than or equal to 85%.Fatty acid methyl ester sulfonate is the Sulfonates anion surfactant of excellent property, and safety non-toxic is to the skin nonirritant.The preparation of fatty acid methyl ester sulfonate is take natural coconut oil, palm wet goods grease as raw material, the product that obtains after sulfonation, neutralization.Fatty acid methyl ester sulfonate is applied in the washing composition, washing composition is obviously increased tolerance, the soil removability of hard water, the rate of deoiling and viscosity, and produce foam hardly; Fatty acid methyl ester sulfonate has extremely strong calcium soap dispersiveness, emulsifying property and lyotropy in addition, and three days is fully biodegradable, has overcome the defective of petrochemical industry washing composition waste resource and welding.
Described Starso is metasilicate pentahydrate sodium, has another name called the inclined to one side silicon of five water.Its molecular formula is Na2Si03a5H20, relative molecular weight 212.14, and proterties is white particle, and Relative bulk density 0.8-1.0 in 72.2 ℃ of the fusing points, soluble in water and sig water, is insoluble to pure and mild acid, and the aqueous solution is alkalescence.Reveal and put easy moisture absorption deliquescence in the air.Have de-sludging emulsification, dispersion, moistening, perviousness and pH value surge capability, be widely used in disposing all kinds of washing composition.
Described Xylo-Mucine CMC is white or oyster white fibrous powder or particle, and the pH value is between 6.5-8.5, and density is 0.5-0.7 g/cc.CMC is the best coagent of synthetic detergent.Being used for washing composition mainly is emulsification and the protective rubber volume property that utilizes it, its generation negatively charged ion can make the substrate surface all electronegative with the dirt particle simultaneously in washing process, the dirt particle has a minute phasic property at aqueous phase like this, with solid phase substrate surface repellency is arranged, therefore can prevent soil redeposition on substrate, can make white fabrics keep whiteness, colored fabric is bright in colour, wash white fabrics add 05 type CMC in washing composition after, its whiteness can remain on more than 90%.Xylo-Mucine has the reparation improving effect to acid soil in addition, thus the waste water that uses this washing composition to discharge, not only can polluted source, also have the effect of purifying ecological.
Described Trisodium Citrate is the washing auxiliary detergent in the free phosphate detergent, and it has sequestering action, the element such as nonnitrogenous phosphorus in the structure, and also biological degradability is good.
Originally the preparation method who contains the washing powder of mineral ion may further comprise the steps:
1) screen analysis:
Component raw material is crossed respectively 30 mesh sieves;
2) weighing:
After checking Dishwasher equipment, above-mentioned weight ratio takes by weighing step 1) in each component after sieving;
3) mix:
With step 2) in each component fully mix;
4) secondary screen analysis:
With step 3) mixture that obtains Guo 30 mesh sieves and get final product.
The present invention contains that the washing powder preparation of mineral ion is convenient, with low cost, accumulating makes things convenient for, cost performance is high, have simultaneously the advantages such as high-efficiency cleaning, safety and environmental protection, the saving energy, overcome the harm of traditional petrochemical industry articles for washing, not containing the raw materials such as interfacial agent necessary in the conventional washing agent technique, sequestrant, washing auxiliary detergent, is the desirable upgraded product of conventional washing agent.Be widely used in washing and the cleaning of various clothings, sanitary bath equipment, ground metope.
Embodiment
Embodiment one: its component of washing powder that originally contains mineral ion comprises active ionized calcium, anhydrous sodium sulphate, sodium carbonate peroxide, chitosan quaternary ammonium salt, fatty acid distribution of coconut oil formicester sodium sulfonate, the preparation of quality shown in being pressed by following component:
The preparation method of described active ionized calcium is to adopt natural Margarita, coral, agate, oyster shells are raw material, and the exchange of application ion and calcining are made and be rich in calcium, the preparation of magnesium, potassium, sodium, manganese, germanium ion, wherein the calcium ion calcining temperature is the 1400-1800 degree, has active alkalescence.The calcium ion activity can be decomposed the removal oily dirt, soak not smelly, but alkalescence bacteria growing inhibiting, anti-oxidant, the alkaline medium effect can improve tensio-active agent to the dirt washability of oily dirt particularly, contain on the other hand the free fatty acids about 30% in the natural fats and oils dirt, in washing composition, add a certain amount of active alkaline element, can generate soap with fatty acid response, be conducive to grease emulsifying, disperse to reach the decontamination purpose.
Described anhydrous sodium sulphate proterties is evenly fine particle or powder of white, and is odorless, distinguishes the flavor of salty and the band hardship; Be dissolved in glycerine, be insoluble to ethanol; It is neutral that the aqueous solution is.The drying that is mainly used in organic solvent dewaters, and fast, the residual characteristics such as few of water removal effect are arranged.
Described sodium carbonate peroxide, solid hydrogen peroxide is the addition mixture of yellow soda ash and hydrogen peroxide, SPC-D has nontoxic, odorless, the advantage such as pollution-free, SPC-D also has bleaching in addition, sterilization, washing, the characteristics such as good water solubility.The stability that the advantage of SPC-D is to store and good with the compatibility of other washing powder composition, this point are the washing auxiliary detergents that SPC-D is incomparable and do not replace.
Described chitosan quaternary ammonium salt is the chitosan higher derivative that chitosan makes through chemical modification, and full name is HACC, is called for short HACC, is white or pale yellow powder shape solid, and water absorbability is strong, and tasty and refreshing sweet taste is arranged.Chitosan quaternary ammonium salt has good water-soluble, and good stability; Also have the performances such as good film-forming properties, conditioning property, moisture absorbability and moisture retentivity, static resistance and germ resistance, its anti-microbial property is better than chitosan and other chitosan derivatives, be 0.01% to streptococcus aureus minimal inhibitory concentration (MIC), the minimal inhibitory concentration of intestinal bacteria and Candida albicans is 0.02%.What especially be worth emphasizing is to the experiment proved that the antibacterial effect of chitosan quaternary ammonium salt pair subtilis is best in all natural antibacterial agents.
Described fatty acid distribution of coconut oil methyl esters sodium sulfonate outward appearance is light yellow to white powdery solid, and gross activity thing content is slight alkalinity more than or equal to 85%.Fatty acid methyl ester sulfonate is the Sulfonates anion surfactant of excellent property, and safety non-toxic is to the skin nonirritant.The preparation of fatty acid methyl ester sulfonate is take natural coconut oil, palm wet goods grease as raw material, the product that obtains after sulfonation, neutralization.Fatty acid methyl ester sulfonate is applied in the washing composition, washing composition is obviously increased tolerance, the soil removability of hard water, the rate of deoiling and viscosity, and produce foam hardly; Fatty acid methyl ester sulfonate has extremely strong calcium soap dispersiveness, emulsifying property and lyotropy in addition, and three days is fully biodegradable, has overcome the defective of petrochemical industry washing composition waste resource and welding.
Described Starso is metasilicate pentahydrate sodium, has another name called the inclined to one side silicon of five water.Its molecular formula is Na2Si03a5H20, relative molecular weight 212.14, and proterties is white particle, and Relative bulk density 0.8-1.0 in 72.2 ℃ of the fusing points, soluble in water and sig water, is insoluble to pure and mild acid, and the aqueous solution is alkalescence.Reveal and put easy moisture absorption deliquescence in the air.Have de-sludging emulsification, dispersion, moistening, perviousness and pH value surge capability, be widely used in disposing all kinds of washing composition.
Described Xylo-Mucine CMC is white or oyster white fibrous powder or particle, and the pH value is between 6.5-8.5, and density is 0.5-0.7 g/cc.CMC is the best coagent of synthetic detergent.Being used for washing composition mainly is emulsification and the protective rubber volume property that utilizes it, its generation negatively charged ion can make the substrate surface all electronegative with the dirt particle simultaneously in washing process, the dirt particle has a minute phasic property at aqueous phase like this, with solid phase substrate surface repellency is arranged, therefore can prevent soil redeposition on substrate, can make white fabrics keep whiteness, colored fabric is bright in colour, wash white fabrics add 05 type CMC in washing composition after, its whiteness can remain on more than 90%.Xylo-Mucine has the reparation improving effect to acid soil in addition, thus the waste water that uses this washing composition to discharge, not only can polluted source, also have the effect of purifying ecological.
Described Trisodium Citrate is the washing auxiliary detergent in the free phosphate detergent, and it has sequestering action, the element such as nonnitrogenous phosphorus in the structure, and also biological degradability is good.
Originally the preparation method who contains the washing powder of mineral ion may further comprise the steps:
1) screen analysis:
Component raw material is crossed respectively 30 mesh sieves;
2) weighing:
After checking Dishwasher equipment, above-mentioned quality takes by weighing step 1) in each component after sieving;
3) mix:
With step 2) in each component fully mix;
4) secondary screen analysis:
With step 3) mixture that obtains Guo 30 mesh sieves and get final product.
Embodiment two: the washing powder that originally contains mineral ion by following component by shown in the quality preparation:
All the other component characteristics and preparation method omit as described in embodiment 1.
The present invention includes but be not limited to above-mentioned embodiment, anyly meet the product that these claims are described, all fall within protection scope of the present invention.
Claims (6)
1. washing powder that contains mineral ion, it is characterized in that: its component comprises ionic surface active agent alive, salt lake saline enriched material, sodium carbonate peroxide, chitosan quaternary ammonium salt, fatty acid distribution of coconut oil formicester sodium sulfonate, the preparation of weight ratio scope shown in being pressed by following component:
2. the washing powder that contains mineral ion according to claim 1 is characterized in that: the preparation of weight ratio scope shown in it is pressed by following component:
3. the washing powder that contains mineral ion according to claim 2 is characterized in that: the preparation of weight ratio scope shown in it is pressed by following component:
4. the washing powder that contains mineral ion according to claim 3 is characterized in that: the preparation of weight ratio shown in it is pressed by following component:
5. according to claim 1 to 4 arbitrary described washing powders that contain mineral ion, it is characterized in that: described ionic surface active agent is active ionized calcium; Described salt lake saline enriched material is anhydrous sodium sulphate.
6. preparation method who contains the washing powder of mineral ion, it is characterized in that: its preparation method may further comprise the steps:
1) screen analysis:
Component raw material is crossed respectively 30 mesh sieves;
2) weighing:
After checking Dishwasher equipment, take by weighing step 1 by the arbitrary described weight ratio of claim 1 to 4) in each component after sieving;
3) mix:
With step 2) in each component fully mix;
4) secondary screen analysis:
With step 3) mixture that obtains Guo 30 mesh sieves and get final product.
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| CN201210488129.2A CN102994243B (en) | 2012-11-15 | 2012-11-15 | Washing powder containing mineral ions and method for preparing same |
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| CN201210488129.2A CN102994243B (en) | 2012-11-15 | 2012-11-15 | Washing powder containing mineral ions and method for preparing same |
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| CN102994243A true CN102994243A (en) | 2013-03-27 |
| CN102994243B CN102994243B (en) | 2014-03-26 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112553010A (en) * | 2020-12-17 | 2021-03-26 | 聂绪明 | EM (effective microorganisms) bacterium laundry detergent and preparation method thereof |
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|---|---|---|---|---|
| CN1220306A (en) * | 1997-12-19 | 1999-06-23 | 巫松虎 | Concentrated detergent powder |
| WO2009004294A1 (en) * | 2007-07-05 | 2009-01-08 | Reckitt Benckiser N.V. | Laundry cleaning product |
| WO2009004295A1 (en) * | 2007-07-05 | 2009-01-08 | Reckitt Benckiser N.V. | Laundry cleaning product |
| CN102660407A (en) * | 2012-02-22 | 2012-09-12 | 陈冠群 | A novel detergent for pesticide residue on vegetables and fruits |
-
2012
- 2012-11-15 CN CN201210488129.2A patent/CN102994243B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220306A (en) * | 1997-12-19 | 1999-06-23 | 巫松虎 | Concentrated detergent powder |
| WO2009004294A1 (en) * | 2007-07-05 | 2009-01-08 | Reckitt Benckiser N.V. | Laundry cleaning product |
| WO2009004295A1 (en) * | 2007-07-05 | 2009-01-08 | Reckitt Benckiser N.V. | Laundry cleaning product |
| CN102660407A (en) * | 2012-02-22 | 2012-09-12 | 陈冠群 | A novel detergent for pesticide residue on vegetables and fruits |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112553010A (en) * | 2020-12-17 | 2021-03-26 | 聂绪明 | EM (effective microorganisms) bacterium laundry detergent and preparation method thereof |
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| CN102994243B (en) | 2014-03-26 |
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