CN102992899A - Insecticide-fertilizer composition containing bisultap and humic acid - Google Patents
Insecticide-fertilizer composition containing bisultap and humic acid Download PDFInfo
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- CN102992899A CN102992899A CN2012104997439A CN201210499743A CN102992899A CN 102992899 A CN102992899 A CN 102992899A CN 2012104997439 A CN2012104997439 A CN 2012104997439A CN 201210499743 A CN201210499743 A CN 201210499743A CN 102992899 A CN102992899 A CN 102992899A
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Abstract
The invention relates to an insecticide-fertilizer composition containing bisultap and humic acid. The composition comprises an active ingredient, synergistic ingredients and fertilizing ingredients, wherein the active ingredient is the bisultap; the synergistic ingredients consist of humic acid and chloromethylsilatrane; the fertilizing ingredients contain any one or more of ammonium sulfate, potassium sulfate, urea, ammonium nitrate, ammonium bicarbonate, potassium chloride, potassium dihydrogen phosphate, superphosphate and calcium magnesia phosphate fertilizer. The insecticide-fertilizer composition has beneficial effects that with humic acid and chloromethylsilatrane as the synergistic auxiliary agents of an insecticide, and at the same time in cooperation with the use of a compound fertilizer, the insecticide-fertilizer composition can increase the crop yield, and at the same time can also improve the pest preventing effect.
Description
Technical field
The invention belongs to agrochemical field, relate to the medicine fertilizer composition that is formed by sterilant, synergistic component and plant nutrient substance, relate to particularly a kind of medicine fertilizer composition that comprises disosultap and humic acids and uses thereof.
Background technology
Disosultap is the sandworm toxin insecticide of China's 20 century 70 exploitations in mid-term, and rice grub, particularly rice borer are had good prevention effect.To insect have stomach toxicity, tag, systemic action.
Do not have effective medicine fertilizer composition for disosultap at present, that is to say that the disosultap medicine fertilizer that can reach desinsection and the effective cooperation of volume increase does not also have.The present invention has proposed the technical scheme for the medicine fertilizer composition of disosultap for the blank of the medicine fertilizer composition of solution disosultap.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of medicine fertilizer composition that comprises disosultap and humic acids, said composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is disosultap, synergistic component is comprised of humic acids and silicon Feng Huan, fertilizer component comprises ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, any one in Repone K, potassium primary phosphate, calcium superphosphate and the fused(calcium magnesium)phosphate or multiple.
In the above-mentioned medicine fertilizer composition, the weight ratio of humic acids and silicon Feng Huan is 1: 0.01-5, preferred, weight ratio is 1: 0.1-1.
In the above-mentioned medicine fertilizer composition, the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.1-1: 1-20: 80-99, and preferred, weight ratio is 0.1-0.5: 5-15: 85-95.
In the above-mentioned medicine fertilizer composition, humic acids is preferably xanthohumic acid, the xanthohumic acid of xanthohumic acid for extracting from the alcohol slops of sugarcane deep processing alcohol.The preparation method of the xanthohumic acid that preferably, extracts from the alcohol slops of sugarcane deep processing alcohol is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of measuring dry-matter in the concentrated solution reaches 60% obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Acetone soln is partly inputted in the still kettle, concentrated acetone solns under the decompression heating maintains the temperature at 45 ℃ ± 2 ℃, with recover acetone, remaining material maintains the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtains the solid phase prod xanthohumic acid after the drying.
Above-mentioned medicine fertilizer composition can be prepared into the liquid medicine fertilizer composition, also can be prepared into the solid medicine fertilizer composition.
The fertilizing method of above-mentioned medicine fertilizer composition sprays for spraying or irrigate, being preferably.
The present invention also provides a kind of method of preventing and treating crop pest and improving crop yield, the method comprises and will spray crop after the above-mentioned medicine fertilizer composition dilution, wherein said crop is eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, in peach and the cotton any is preferably paddy rice.
In the aforesaid method, described insect is Cnaphalocrocis medinali(rice leaf roller), rice plant skipper, rice thrips, and planthopper etc. are preferably Cnaphalocrocis medinali(rice leaf roller).
The present invention also provides above-mentioned composition to be used for pest control and has improved the purposes of crop yield, and described insect is Cnaphalocrocis medinali(rice leaf roller), and described crop is paddy rice.
Medicine fertilizer composition of the present invention through with humic acids and silicon Feng Huan as the builder of sterilant, cooperate simultaneously the use of composite fertilizer so that medicine fertilizer composition of the present invention can improve the output of crop, can also improve the preventive effect to insect simultaneously.
Embodiment
In order to understand the present invention, the below further specifies the present invention with embodiment, but does not limit the present invention.
The material of using among the following embodiment is market and buys, and all can buy from market to obtain.The preparation method of liquid medicine fertilizer mixes activeconstituents, synergistic component and fertilizer component.
The xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting, the preparation method is as follows:
1kg alcohol slops decompression heating evaporation is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of dry-matter reaches 60% in the measurement concentrated solution obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Partly input acetone soln in the still kettle, the decompression heating maintains the temperature at 45 ℃ ± 2 ℃ lower concentrated acetone solns, with recover acetone, and remaining material, maintain the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtain solid phase prod xanthohumic acid 21.78g after the drying.
Embodiment 1:
Get the agricultural chemicals minute disosultap 0.25kg that generates alive, xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.75kg fully mixes each component according to weight.
The comparative example 1:
Get xanthohumic acid 8kg, the former medicine 2kg of silicon Feng Huan, urea 31kg, fused(calcium magnesium)phosphate 30kg, vitriolate of tartar 28.75kg fully mixes each component according to weight.。
Effect embodiment:
Application Example 1 and comparative example 1 spray paddy rice, the control Cnaphalocrocis medinali(rice leaf roller).For the experiment that the essentially identical rice terrace of upgrowth situation carries out, the experiment number of each processing is 3 times, the calculating output of averaging, the preventive effect of Cnaphalocrocis medinali(rice leaf roller).Various samples are watered dilution to be sprayed.
It is identical with 25% dimehypo water solution processing paddy rice effective level that embodiment 1 processes paddy rice, in medicine fertilizer, owing to contain synergistic agent and the fertilizer such as humic acids, institute is so that increasing production of rice, not only can reach the purpose of increasing production of rice, also realized the raising of paddy rice Cnaphalocrocis medinali(rice leaf roller) preventive effect, this raising is to realize that by the synergistic blend of pesticide activity component and synergistic agent, fertilizer this synergy has exceeded inventor's expectation.Because the composition of using separately comparative example 1 also can reach the purpose of volume increase, but after adding pesticide activity component, output further improves.The medicine fertilizer composition has demonstrated the dual purpose of good volume increase and insect protected, and is the effect that increases insect protected.
Claims (10)
1. medicine fertilizer composition that comprises disosultap and humic acids, said composition comprise live to generate minute, synergistic component and fertilizer component, live in generating and be divided into disosultap, synergistic component is comprised of humic acids and silicon Feng Huan, fertilizer component comprises ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, in Repone K, potassium primary phosphate, calcium superphosphate and the fused(calcium magnesium)phosphate any one or multiple, the weight ratio of humic acids and silicon Feng Huan is 1: 0.01-5.
2. medicine fertilizer composition according to claim 1, wherein the weight ratio of humic acids and silicon Feng Huan is 1: 0.1-1.
3. medicine fertilizer composition according to claim 1, wherein the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.1-1: 1-20: 80-99, preferred, weight ratio is 0.1-0.5: 5-15: 85-95.
4. medicine fertilizer composition according to claim 1, wherein humic acids is xanthohumic acid.
5. medicine fertilizer composition according to claim 4, the xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting wherein, its preparation method is as follows:
The alcohol slops heating evaporation that reduces pressure is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of measuring dry-matter in the concentrated solution reaches 60% obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Acetone soln is partly inputted in the still kettle, concentrated acetone solns under the decompression heating maintains the temperature at 45 ℃ ± 2 ℃, with recover acetone, remaining material maintains the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtains the solid phase prod xanthohumic acid after the drying.
6. each described medicine fertilizer composition according to claim 1-5, its Chinese medicine fertilizer composition is prepared into liquid medicine fertilizer composition or solid medicine fertilizer composition.
7. each described medicine fertilizer composition according to claim 1-6, wherein the application process of composition sprays for spraying or irrigate, being preferably.
8. method of preventing and treating crop pest and improving crop yield, the method comprises and will spray crop after each described medicine fertilizer composition dilution of claim 1-7, wherein said crop is eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, in peach and the cotton any is preferably paddy rice.
9. method according to claim 8, wherein insect is Cnaphalocrocis medinali(rice leaf roller), rice plant skipper, rice thrips, planthoppers etc. are preferably Cnaphalocrocis medinali(rice leaf roller).
10. each described composition of claim 1-7 is used for pest control and improves the purposes of crop yield, and described insect is Cnaphalocrocis medinali(rice leaf roller), and described crop is paddy rice.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833472A (en) * | 2014-03-21 | 2014-06-04 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide fertilizer for increasing yield and killing pests of corn and preparation method thereof |
| CN104987259A (en) * | 2015-07-20 | 2015-10-21 | 南宁汉和生物科技有限公司 | Special fertilizer for banana and preparation method thereof |
| CN103772068B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising neires toxin and nicotinic insecticide utilizing sugar refinery, grain distillery's waste |
| CN105384509A (en) * | 2015-11-10 | 2016-03-09 | 无锡市路华肥料科技有限公司 | Fertilizer for preventing brown planthoppers |
| CN106348936A (en) * | 2016-08-23 | 2017-01-25 | 广西易多收生物科技有限公司 | Multifunctional pesticide fertilizer and preparation method thereof |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1249900A (en) * | 1999-10-27 | 2000-04-12 | 林苏勇 | High-efficiency bisultap powder and its preparation |
| CN102775246A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Fipronil-containing pesticide fertilizer composition |
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2012
- 2012-11-29 CN CN201210499743.9A patent/CN102992899B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1249900A (en) * | 1999-10-27 | 2000-04-12 | 林苏勇 | High-efficiency bisultap powder and its preparation |
| CN102775246A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Fipronil-containing pesticide fertilizer composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103772068B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising neires toxin and nicotinic insecticide utilizing sugar refinery, grain distillery's waste |
| CN103833472A (en) * | 2014-03-21 | 2014-06-04 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide fertilizer for increasing yield and killing pests of corn and preparation method thereof |
| CN103833472B (en) * | 2014-03-21 | 2016-01-20 | 润禾泰华生物科技（北京）有限公司 | A kind of corn insecticide liquid medicine is fertile and preparation method thereof |
| CN104987259A (en) * | 2015-07-20 | 2015-10-21 | 南宁汉和生物科技有限公司 | Special fertilizer for banana and preparation method thereof |
| CN105384509A (en) * | 2015-11-10 | 2016-03-09 | 无锡市路华肥料科技有限公司 | Fertilizer for preventing brown planthoppers |
| CN106348936A (en) * | 2016-08-23 | 2017-01-25 | 广西易多收生物科技有限公司 | Multifunctional pesticide fertilizer and preparation method thereof |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
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Effective date of registration: 20191230 Address after: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee after: Guangxi easy harvest Biotechnology Co., Ltd. Address before: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee before: Ye Changdong |